JP2017508037A5 - - Google Patents
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- Publication number
- JP2017508037A5 JP2017508037A5 JP2016549574A JP2016549574A JP2017508037A5 JP 2017508037 A5 JP2017508037 A5 JP 2017508037A5 JP 2016549574 A JP2016549574 A JP 2016549574A JP 2016549574 A JP2016549574 A JP 2016549574A JP 2017508037 A5 JP2017508037 A5 JP 2017508037A5
- Authority
- JP
- Japan
- Prior art keywords
- article
- resin layer
- binder resin
- microspheres
- amount
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920000642 polymer Polymers 0.000 claims 4
- 239000011230 binding agent Substances 0.000 claims 3
- 239000004005 microsphere Substances 0.000 claims 3
- 229920002635 polyurethane Polymers 0.000 claims 3
- 239000004814 polyurethane Substances 0.000 claims 3
- 239000011347 resin Substances 0.000 claims 3
- 229920005989 resin Polymers 0.000 claims 3
- 125000001931 aliphatic group Chemical group 0.000 claims 2
- 125000003545 alkoxy group Chemical group 0.000 claims 2
- 239000011521 glass Substances 0.000 claims 2
- 229920005862 polyol Polymers 0.000 claims 2
- 150000003077 polyols Chemical class 0.000 claims 2
- 239000000919 ceramic Substances 0.000 claims 1
- 239000003431 cross linking reagent Substances 0.000 claims 1
- 239000002241 glass-ceramic Substances 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
Claims (5)
- 物品であって、
(a)複数のソフトセグメントと複数のハードセグメントとを含む脂肪族ポリウレタンポリマーを含むバインダー樹脂層であって、前記ソフトセグメントがポリ(アルコキシ)ポリオールを含み、前記ポリ(アルコキシ)ポリオールが架橋剤を本質的に含まない、バインダー樹脂層と、
(b)前記バインダー樹脂層の第1の主表面に部分的に包埋されかつこれと接着された複数の微小球と、を含み、
前記脂肪族ポリウレタンポリマーの前記セグメント及び部分の特定の化学的同一性及び相対量が、10℃以下のガラス転移温度を前記物品に付与し、かつ25℃〜175℃で15MPa未満変化する貯蔵弾性率を前記物品に付与するのに十分である、物品。 - 前記ポリウレタンポリマーの重量に対して、前記ハードセグメントの量が15〜85重量パーセントであり、前記ソフトセグメントの量が15〜85重量パーセントであり、前記ハードセグメント及び前記ソフトセグメントの総量が少なくとも80重量パーセントである、請求項1に記載の物品。
- 前記貯蔵弾性率の変化が、25℃〜175℃で7MPa未満である、請求項1又は2に記載の物品。
- 前記複数の微小球が、ガラス、ポリマー、ガラスセラミックス、セラミックス、金属、及びこれらの組み合わせのうちの少なくとも1つから選択される、請求項1〜3のいずれか一項に記載の物品。
- 前記物品の前記表面の少なくとも約60%が前記複数の微小球で覆われている、請求項1〜4のいずれか一項に記載の物品。
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201461939534P | 2014-02-13 | 2014-02-13 | |
US61/939,534 | 2014-02-13 | ||
US201461973357P | 2014-04-01 | 2014-04-01 | |
US61/973,357 | 2014-04-01 | ||
PCT/US2015/015828 WO2015123526A1 (en) | 2014-02-13 | 2015-02-13 | Flexible microsphere articles having high temperature stability |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2017508037A JP2017508037A (ja) | 2017-03-23 |
JP2017508037A5 true JP2017508037A5 (ja) | 2018-03-22 |
JP6513096B2 JP6513096B2 (ja) | 2019-05-15 |
Family
ID=52630489
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2016549574A Active JP6513096B2 (ja) | 2014-02-13 | 2015-02-13 | 高温安定性を有する可撓性微小球物品 |
Country Status (6)
Country | Link |
---|---|
US (1) | US10239277B2 (ja) |
EP (1) | EP3105047B1 (ja) |
JP (1) | JP6513096B2 (ja) |
KR (1) | KR20160123330A (ja) |
CN (1) | CN105980143B (ja) |
WO (1) | WO2015123526A1 (ja) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2016130172A1 (en) | 2015-02-13 | 2016-08-18 | 3M Innovative Properties Company | Flexible microsphere articles having high temperature stability |
JP6681212B2 (ja) * | 2015-11-30 | 2020-04-15 | 株式会社潤工社 | ポリウレタンチューブ |
US10414186B2 (en) | 2015-12-18 | 2019-09-17 | 3M Innovative Properties Company | Process for depositing dry powder particles onto a substrate and attaching the particles to the substrate |
US10773275B2 (en) | 2015-12-18 | 2020-09-15 | 3M Innovative Properties Company | Process for depositing dry powder particles onto a substrate and adhesively bonding the particles to the substrate |
CN109311265A (zh) | 2016-03-30 | 2019-02-05 | 3M创新有限公司 | 以随机分布的微球的预定图案为特征的制品及其制备方法 |
EP3497490A1 (en) * | 2016-08-12 | 2019-06-19 | 3M Innovative Properties Company | Truncated beadfilm constructions and methods of making the same |
EP3515703A1 (en) * | 2016-09-21 | 2019-07-31 | 3M Innovative Properties Company | Protective display film with glass |
US11555113B2 (en) | 2019-09-10 | 2023-01-17 | Ticona Llc | Liquid crystalline polymer composition |
CN116829631A (zh) * | 2020-12-21 | 2023-09-29 | 斯瓦蒙卢森堡公司 | 热塑性聚合物结构及其制备方法 |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
UST987003I4 (en) | 1978-07-31 | 1979-10-02 | Minnesota Mining And Manufacturing Company | Retroluminometer |
JP2546853B2 (ja) | 1987-09-03 | 1996-10-23 | オーツタイヤ株式会社 | 装飾性ビーズコートシートおよびその製造方法 |
ITMI913213A1 (it) * | 1991-11-29 | 1993-05-30 | Minnesota Mining & Mfg | Nastro altamente conformabile per segnaletica stradale sottoposta ad intense condizioni di traffico |
CA2147711C (en) * | 1994-05-20 | 2005-08-16 | James H. C. Harper | Retroreflective article with non-continuous top coat |
EP0853707A1 (en) * | 1995-10-05 | 1998-07-22 | Minnesota Mining And Manufacturing Company | Flexible raised pavement marker, mounting device and method |
US5620775A (en) | 1995-11-03 | 1997-04-15 | Minnesota Mining And Manufacturing Company | Low refractive index glass microsphere coated article having a smooth surface and a method for preparing same |
KR19990071467A (ko) * | 1995-11-22 | 1999-09-27 | 스프레이그 로버트 월터 | 폴리우레탄 상부 코팅이 스크린 인쇄된 내구성이 있는 도로표지용 테이프 |
US5882771A (en) * | 1996-04-10 | 1999-03-16 | Minnesota Mining And Manufacturing Company | Conformable embossable retroreflective sheeting |
US5976669A (en) | 1996-12-20 | 1999-11-02 | 3M Innovative Properties Company | Retroreflective article having launderably durable bead-bond |
US6156436A (en) | 1997-04-04 | 2000-12-05 | 3M Innovative Properties Company | Use of a crystalline bead bond layer in a retroreflective article |
US5959775A (en) * | 1997-12-23 | 1999-09-28 | 3M Innovative Properties Company | Urethane/acrylate bead bond for retroreflective articles |
JP2001172497A (ja) * | 1999-12-17 | 2001-06-26 | Takeda Badische Urethane Kogyo Kk | 熱可塑性エラストマー |
WO2007105897A1 (en) * | 2006-03-14 | 2007-09-20 | Lg Chem, Ltd. | Reflective sheet for printing |
US20080139722A1 (en) | 2006-12-08 | 2008-06-12 | 3M Innovative Properties Company | Vibration damping polymer composites |
US20090246439A1 (en) * | 2008-03-31 | 2009-10-01 | 3M Innovative Properties Company | Decorative sheet |
US8420217B2 (en) | 2008-07-25 | 2013-04-16 | 3M Innovative Properties Company | Elastic bonding films |
GB2499683B (en) * | 2012-04-27 | 2014-03-12 | Balmoral Comtec Ltd | Macrospheres |
KR102132308B1 (ko) | 2012-10-04 | 2020-07-09 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 열성형성 미소구체 물품 |
WO2014210249A1 (en) | 2013-06-26 | 2014-12-31 | 3M Innovative Properties Company | Stain resistant microsphere articles |
JP5686867B2 (ja) * | 2013-08-03 | 2015-03-18 | 三菱樹脂株式会社 | 積層ポリエステルフィルム |
-
2015
- 2015-02-13 CN CN201580008180.0A patent/CN105980143B/zh active Active
- 2015-02-13 KR KR1020167024723A patent/KR20160123330A/ko not_active Application Discontinuation
- 2015-02-13 WO PCT/US2015/015828 patent/WO2015123526A1/en active Application Filing
- 2015-02-13 US US15/117,494 patent/US10239277B2/en active Active
- 2015-02-13 JP JP2016549574A patent/JP6513096B2/ja active Active
- 2015-02-13 EP EP15708634.9A patent/EP3105047B1/en active Active
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