JP2017508037A5 - - Google Patents

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Publication number
JP2017508037A5
JP2017508037A5 JP2016549574A JP2016549574A JP2017508037A5 JP 2017508037 A5 JP2017508037 A5 JP 2017508037A5 JP 2016549574 A JP2016549574 A JP 2016549574A JP 2016549574 A JP2016549574 A JP 2016549574A JP 2017508037 A5 JP2017508037 A5 JP 2017508037A5
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JP
Japan
Prior art keywords
article
resin layer
binder resin
microspheres
amount
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JP2016549574A
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English (en)
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JP6513096B2 (ja
JP2017508037A (ja
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Priority claimed from PCT/US2015/015828 external-priority patent/WO2015123526A1/en
Publication of JP2017508037A publication Critical patent/JP2017508037A/ja
Publication of JP2017508037A5 publication Critical patent/JP2017508037A5/ja
Application granted granted Critical
Publication of JP6513096B2 publication Critical patent/JP6513096B2/ja
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Claims (5)

  1. 物品であって、
    (a)複数のソフトセグメントと複数のハードセグメントとを含む脂肪族ポリウレタンポリマーを含むバインダー樹脂層であって、前記ソフトセグメントがポリ(アルコキシ)ポリオールを含み、前記ポリ(アルコキシ)ポリオールが架橋剤を本質的に含まない、バインダー樹脂層と、
    (b)前記バインダー樹脂層の第1の主表面に部分的に包埋されかつこれと接着された複数の微小球と、を含み、
    前記脂肪族ポリウレタンポリマーの前記セグメント及び部分の特定の化学的同一性及び相対量が、10℃以下のガラス転移温度を前記物品に付与し、かつ25℃〜175℃で15MPa未満変化する貯蔵弾性率を前記物品に付与するのに十分である、物品。
  2. 前記ポリウレタンポリマーの重量に対して、前記ハードセグメントの量が15〜85重量パーセントであり、前記ソフトセグメントの量が15〜85重量パーセントであり、前記ハードセグメント及び前記ソフトセグメントの総量が少なくとも80重量パーセントである、請求項1に記載の物品。
  3. 前記貯蔵弾性率の変化が、25℃〜175℃で7MPa未満である、請求項1又は2に記載の物品。
  4. 前記複数の微小球が、ガラス、ポリマー、ガラスセラミックス、セラミックス、金属、及びこれらの組み合わせのうちの少なくとも1つから選択される、請求項1〜のいずれか一項に記載の物品。
  5. 前記物品の前記表面の少なくとも約60%が前記複数の微小球で覆われている、請求項1〜のいずれか一項に記載の物品。
JP2016549574A 2014-02-13 2015-02-13 高温安定性を有する可撓性微小球物品 Active JP6513096B2 (ja)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201461939534P 2014-02-13 2014-02-13
US61/939,534 2014-02-13
US201461973357P 2014-04-01 2014-04-01
US61/973,357 2014-04-01
PCT/US2015/015828 WO2015123526A1 (en) 2014-02-13 2015-02-13 Flexible microsphere articles having high temperature stability

Publications (3)

Publication Number Publication Date
JP2017508037A JP2017508037A (ja) 2017-03-23
JP2017508037A5 true JP2017508037A5 (ja) 2018-03-22
JP6513096B2 JP6513096B2 (ja) 2019-05-15

Family

ID=52630489

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2016549574A Active JP6513096B2 (ja) 2014-02-13 2015-02-13 高温安定性を有する可撓性微小球物品

Country Status (6)

Country Link
US (1) US10239277B2 (ja)
EP (1) EP3105047B1 (ja)
JP (1) JP6513096B2 (ja)
KR (1) KR20160123330A (ja)
CN (1) CN105980143B (ja)
WO (1) WO2015123526A1 (ja)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016130172A1 (en) 2015-02-13 2016-08-18 3M Innovative Properties Company Flexible microsphere articles having high temperature stability
JP6681212B2 (ja) * 2015-11-30 2020-04-15 株式会社潤工社 ポリウレタンチューブ
US10414186B2 (en) 2015-12-18 2019-09-17 3M Innovative Properties Company Process for depositing dry powder particles onto a substrate and attaching the particles to the substrate
US10773275B2 (en) 2015-12-18 2020-09-15 3M Innovative Properties Company Process for depositing dry powder particles onto a substrate and adhesively bonding the particles to the substrate
CN109311265A (zh) 2016-03-30 2019-02-05 3M创新有限公司 以随机分布的微球的预定图案为特征的制品及其制备方法
EP3497490A1 (en) * 2016-08-12 2019-06-19 3M Innovative Properties Company Truncated beadfilm constructions and methods of making the same
EP3515703A1 (en) * 2016-09-21 2019-07-31 3M Innovative Properties Company Protective display film with glass
US11555113B2 (en) 2019-09-10 2023-01-17 Ticona Llc Liquid crystalline polymer composition
CN116829631A (zh) * 2020-12-21 2023-09-29 斯瓦蒙卢森堡公司 热塑性聚合物结构及其制备方法

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UST987003I4 (en) 1978-07-31 1979-10-02 Minnesota Mining And Manufacturing Company Retroluminometer
JP2546853B2 (ja) 1987-09-03 1996-10-23 オーツタイヤ株式会社 装飾性ビーズコートシートおよびその製造方法
ITMI913213A1 (it) * 1991-11-29 1993-05-30 Minnesota Mining & Mfg Nastro altamente conformabile per segnaletica stradale sottoposta ad intense condizioni di traffico
CA2147711C (en) * 1994-05-20 2005-08-16 James H. C. Harper Retroreflective article with non-continuous top coat
EP0853707A1 (en) * 1995-10-05 1998-07-22 Minnesota Mining And Manufacturing Company Flexible raised pavement marker, mounting device and method
US5620775A (en) 1995-11-03 1997-04-15 Minnesota Mining And Manufacturing Company Low refractive index glass microsphere coated article having a smooth surface and a method for preparing same
KR19990071467A (ko) * 1995-11-22 1999-09-27 스프레이그 로버트 월터 폴리우레탄 상부 코팅이 스크린 인쇄된 내구성이 있는 도로표지용 테이프
US5882771A (en) * 1996-04-10 1999-03-16 Minnesota Mining And Manufacturing Company Conformable embossable retroreflective sheeting
US5976669A (en) 1996-12-20 1999-11-02 3M Innovative Properties Company Retroreflective article having launderably durable bead-bond
US6156436A (en) 1997-04-04 2000-12-05 3M Innovative Properties Company Use of a crystalline bead bond layer in a retroreflective article
US5959775A (en) * 1997-12-23 1999-09-28 3M Innovative Properties Company Urethane/acrylate bead bond for retroreflective articles
JP2001172497A (ja) * 1999-12-17 2001-06-26 Takeda Badische Urethane Kogyo Kk 熱可塑性エラストマー
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US20090246439A1 (en) * 2008-03-31 2009-10-01 3M Innovative Properties Company Decorative sheet
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GB2499683B (en) * 2012-04-27 2014-03-12 Balmoral Comtec Ltd Macrospheres
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