JP2017187619A5 - - Google Patents

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JP2017187619A5
JP2017187619A5 JP2016076320A JP2016076320A JP2017187619A5 JP 2017187619 A5 JP2017187619 A5 JP 2017187619A5 JP 2016076320 A JP2016076320 A JP 2016076320A JP 2016076320 A JP2016076320 A JP 2016076320A JP 2017187619 A5 JP2017187619 A5 JP 2017187619A5
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本発明は次の構成からなる。すなわち、
[I] 樹脂Aを主成分とするフィルムであって、紫外線吸収剤、可視光線吸収色素のうち少なくとも1種類以上含有し、波長380〜410nmにおける光線透過率が10%以下、波長440nmにおける光線透過率が80%以上である、光学フィルム。
[II] 樹脂Aを主成分とするフィルムの少なくとも片面に硬化性樹脂Bを主成分とする樹脂B層を積層した積層フィルムであって、少なくとも1層に紫外線吸収剤、可視光線吸収色素のうち少なくとも1種類以上含有し、波長380〜410nmにおける光線透過率が10%以下、波長440nmにおける光線透過率が80%以上である、光学フィルム。
[III] 樹脂Aを主成分とするフィルムに対して樹脂B層と反対面に、硬化性樹脂Bと異なる硬化性樹脂Cを主成分とする樹脂Cを積層してなる、[II]に記載の光学フィルム。
[IV] 前記樹脂Aを主成分とするフィルムに紫外線吸収剤を含み、前記樹脂B層および/または樹脂C層に可視光線吸収色素を含んでなる、[II]または[III]に記載の光学フィルム。
[V] 前記紫外線吸収剤が320〜380nmの波長帯域に極大吸収波長を有する紫外線吸収剤である[I]〜[IV]のいずれかに記載の光学フィルム。
[VI] 前記可視光線吸収色素が390nm〜420nmの波長帯域に極大吸収波長を有する色素である[I]〜[V]のいずれかに記載の光学フィルム。
[VII] 前記樹脂Aが、アクリル、シクロオレフィンコポリマー、トリアセチルセルロース、ポリエステル、ポリカーボネートのいずれかから選択された[I]〜[VI]のいずれかに記載の光学フィルム。
[VIII] 前記可視光線吸収色素の少なくとも1種類が、アントラキノン、アゾメチン、インドール、トリアジン、ナフタルイミド、フタロシアニンのいずれかの骨格を有する、[I]〜[VII]のいずれかに記載の光学フィルム。
[IX] 波長300〜380nmにおける光線透過率の最大値が10%以下である、[I]〜[VIII]のいずれかに記載の光学フィルム。
[X] 前記紫外線吸収剤の少なくとも1種類がトリアジン骨格構造を有する、[I]〜[IX]のいずれかに記載の光学フィルム。
[XI] 85℃250時間促進耐熱試験後のヘイズ値が1.5以下である、[I]〜[X]のいずれかに記載の光学フィルム。
[XII] フィルムの少なくとも片面にプライマー層を設けてなる、[I]〜[XI]のいずれかに記載の光学フィルム。
[XIII] [I]〜[XII]のいずれかに記載の光学フィルムを用いた画像表示装置。
[XIV] [I]〜[XII]のいずれかに記載の光学フィルムを用いた車載用ディスプレイ。
The present invention has the following configuration. That is,
[I] A film containing resin A as a main component, containing at least one or more of an ultraviolet light absorbing agent and a visible light absorbing dye, having a light transmittance of 10% or less at a wavelength of 380 to 410 nm and a light transmission at a wavelength of 440 nm An optical film, the rate of which is 80% or more.
[II] A laminated film in which a resin B layer containing a curable resin B as a main component is laminated on at least one side of a film containing a resin A as a main component, and at least one layer comprises an ultraviolet absorber and a visible light absorbing dye An optical film containing at least one or more types, having a light transmittance of 10% or less at a wavelength of 380 to 410 nm and a light transmittance of 80% or more at a wavelength of 440 nm.
[III] described in [II], in which a resin C containing a curable resin C different from the curable resin B as a main component is laminated on the side opposite to the resin B layer to a film containing the resin A as a main component Optical film.
[IV] The optical according to [II] or [III], wherein the film containing the resin A as a main component contains an ultraviolet light absorber, and the resin B layer and / or the resin C layer contains a visible light absorbing dye. the film.
[V] The optical film according to any one of [I] to [IV], wherein the ultraviolet absorber has a maximum absorption wavelength in a wavelength band of 320 to 380 nm.
[VI] The optical film according to any one of [I] to [V], wherein the visible light absorbing dye is a dye having a maximum absorption wavelength in a wavelength band of 390 nm to 420 nm.
[VII] The optical film according to any one of [I] to [VI], wherein the resin A is selected from any of acrylic, cycloolefin copolymer, triacetyl cellulose, polyester, and polycarbonate.
[VIII] The optical film according to any one of [I] to [VII], wherein at least one of the visible light absorbing dyes has a skeleton of any one of anthraquinone, azomethine, indole, triazine, naphthalimide and phthalocyanine.
[IX] The optical film according to any one of [I] to [VIII], wherein the maximum value of light transmittance at a wavelength of 300 to 380 nm is 10% or less.
[X] The optical film according to any one of [I] to [IX], wherein at least one of the ultraviolet absorbers has a triazine skeleton structure.
[XI] The optical film according to any one of [I] to [X], which has a haze value of 1.5 or less after the 85 ° C. 250 hour accelerated heat resistance test.
[XII] The optical film according to any one of [I] to [XI], wherein a primer layer is provided on at least one side of the film.
[XIII] An image display device using the optical film according to any one of [I] to [XII].
[XIV] An in-vehicle display using the optical film according to any one of [I] to [XII].

本発明の光学フィルムは、波長440nmにおける光線透過率が80%以上であることが必要である。波長440nmにおける光線透過率が80%を下回る場合は、可視光短波長領域の光線がカットされることにより、光学フィルム自体が強く黄色味を呈し、優れた透明性を発現することができない。波長440nmにおける光線透過率は、好ましくは85%以上であり、より好ましくは90%以上である。
本発明で述べるところの光学フィルムとは、フラットパネルディスプレイ用途では、偏光板を構成する偏光子保護フィルムや位相差フィルム、アンチグレアやクリアハードコート有するディスプレイ前面に位置する各種表面処理フィルム、その他輝度向上フィルム、視野角向上フィルム、透明導電性フィルムなどが挙げられる。ディスプレイ用途以外では、光学機器として利用される透明電波遮断フィルム、建築用途であるウンドウフィルム、人工灯などに利用される紫外線遮断フィルム、電子デバイス用途ではフォトリソ材料の工程・離型フィルム、その他食品、医療、インクなどの分野においても、内容物の光劣化抑制などを目的としたフィルム用途が挙げられる。特に、光学フィルムとしては、ディスプレイ用途での利用が主流であり、本発明の光学フィルムは、外光をカットする目的で利用されるディスプレイ部材に好適な特性を有するものであり、アンチグレアフィルムや偏光子保護フィルム、位相差フィルムとして最も好適に利用することが出来る。
The optical film of the present invention is required to have a light transmittance of 80% or more at a wavelength of 440 nm. When the light transmittance at a wavelength of 440 nm is less than 80%, the light film in the visible light short wavelength region is cut, so that the optical film itself has a strong yellowish color and can not exhibit excellent transparency. The light transmittance at a wavelength of 440 nm is preferably 85% or more, more preferably 90% or more.
The optical film described in the present invention means, in flat panel display applications, a polarizer protective film or a retardation film constituting a polarizing plate, various surface treated films located on the front of a display having anti-glare or clear hard coat, and other luminance improvements A film, a viewing angle improvement film, a transparent conductive film etc. are mentioned. Outside display applications, transparent wave blocking film to be utilized as an optical apparatus, window fin dough film, ultraviolet blocking film, step-release film photolithographic materials in electronic device applications to be utilized such as artificial light architectural applications, other Also in the fields of food, medicine, ink, etc., film applications for the purpose of suppressing the light deterioration of contents and the like can be mentioned. In particular, as the optical film, use in display applications is mainstream, and the optical film of the present invention has properties suitable for a display member used for the purpose of cutting external light, and it is an antiglare film or a polarized light It can be most suitably used as a child protective film or a retardation film.

紫外線吸収剤は、一般的に380nm以下の波長領域の紫外線を吸収する能力に特化しており、紫外線領域と可視光領域の境界近傍(380〜400nm付近)や、可視光短波長領域(400nm〜430nm)の光線を吸収する能力は優れていない。そのため、紫外線吸収剤を含有させることのみで、紫外線領域と可視光領域の境界近傍(380〜400nm付近)や可視光短波長領域(400〜430nm)の光線をカットするためには、後述する一部の長波長紫外線吸収を除いて、高濃度に含有させる必要がある。紫外線領域、および、可視光短波長領域(380nm〜430nm)の波長カットを、単独の紫外線吸収剤により達成可能な紫外線吸収剤としては、あくまで一例であるが、市販の紫外線吸収剤としては2−(5−クロロ2H−ベンゾトリアゾール−2−イル)−6−第三ブチル−4−メチルフェノールや、2,4,6−トリス(2−ヒドロキシ−4−ヘキシルオキシ−3−メチルフェニル)−1,3,5−トリアジンの構造で記される化合物などが挙げられる。
Ultraviolet absorbers are generally specialized in the ability to absorb ultraviolet light in the wavelength range of 380 nm or less, and in the vicinity of the boundary between the ultraviolet range and the visible light range (approximately 380 to 400 nm) or in the visible light short wavelength range (400 nm to 400 nm) The ability to absorb light at 430 nm) is not good. Therefore, in order to cut light in the vicinity of the boundary between the ultraviolet light region and the visible light region (approximately 380 to 400 nm) or in the visible light short wavelength region (400 to 430 nm) only by containing the ultraviolet light absorber, It needs to be contained in high concentration except for long wavelength ultraviolet ray absorption of part. The UV absorber capable of achieving wavelength cutting in the ultraviolet region and the visible light short wavelength region (380 nm to 430 nm) with a single ultraviolet absorber is merely an example, but as a commercially available ultraviolet absorber, (5-chloro - 2H-benzotriazol-2-yl) -6-tert-butyl-4-methylphenol, 2,4,6-tris (2-hydroxy-4-hexyloxy-3-methylphenyl)- The compound etc. which are described by the structure of 1, 3, 5- triazine are mentioned.

次に、本発明の光学フィルムの好ましい製造方法を以下に説明する。もちろん本発明は係る例に限定して解釈されるものではない。
熱可塑性樹脂をペレットなどの形態で用意する。ペレットは、必要に応じて、熱風中あるいは真空下で乾燥された後、押出機に供給される。押出機内において、融点以上に加熱溶融された樹脂は、ギポンプ等で樹脂の押出量を均一化され、フィルター等を介して異物や変性した樹脂などが取り除かれる。これらの樹脂はダイにて目的の形状に成形された後、吐出される。そして、ダイから吐出されたシートは、キャスティングドラム等の冷却体上に押し出され、冷却固化され、キャスティングフィルムが得られる。この際、ワイヤー状、テープ状、針状あるいはナイフ状等の電極を用いて、静電気力によりキャスティングドラム等の冷却体に密着させ急冷固化させることが好ましい。また、スリット状、スポット状、面状の装置からエアーを吹き出してキャスティングドラム等の冷却体に密着させ急冷固化させたり、ニップロールにて冷却体に密着させ急冷固化させたりする方法も好ましい。
このようにして得られたキャスティングフィルムは、つづいて長手方向および幅方向に二軸延伸されることが好ましい。延伸は、逐次に二軸延伸しても良いし、同時に二軸延伸してもよい。また、さらに長手方向および/または幅方向に再延伸を行ってもよい。
Next, the preferable manufacturing method of the optical film of this invention is demonstrated below. Of course, the present invention is not construed as being limited to such examples.
The thermoplastic resin is prepared in the form of pellets and the like. The pellets are supplied to an extruder after being dried in hot air or under vacuum if necessary. In the extruder, the resin is heated and melted above the melting point is uniform the extrusion amount of the resin with formic A pump or the like, or a foreign object denatured resin are removed through a filter or the like. These resins are molded into a desired shape by a die and then discharged. Then, the sheet discharged from the die is extruded onto a cooling body such as a casting drum and cooled and solidified to obtain a casting film. Under the present circumstances, it is preferable to closely_contact | adhere to cooling bodies, such as a casting drum etc., by electrostatic force using a wire-like, tape-like, needle-like or knife-like electrode, and to make it harden rapidly. It is also preferable to blow air from a slit-like, spot-like or plane-like device to adhere closely to a cooling body such as a casting drum to cause rapid solidification, or to closely adhere to a cooling body with a nip roll to cause rapid solidification.
It is preferable that the casting film thus obtained is subsequently biaxially stretched in the longitudinal direction and the width direction. The stretching may be sequentially biaxially stretched or may be simultaneously biaxially stretched. In addition, re-stretching may be performed in the longitudinal direction and / or the width direction.

Claims (14)

樹脂Aを主成分とするフィルムであって、紫外線吸収剤、可視光線吸収色素のうち少なくとも1種類以上含有し、波長380〜410nmにおける光線透過率が10%以下、波長440nmにおける光線透過率が80%以上である、光学フィルム。 A film containing resin A as a main component, containing at least one or more of an ultraviolet light absorbing agent and a visible light absorbing dye, and having a light transmittance of 10% or less at a wavelength of 380 to 410 nm and a light transmittance of 80 at a wavelength of 440 nm % Or more, optical film. 樹脂Aを主成分とするフィルムの少なくとも片面に硬化性樹脂Bを主成分とする樹脂B層を積層した積層フィルムであって、少なくとも1層に紫外線吸収剤、可視光線吸収色素のうち少なくとも1種類以上含有し、波長380〜410nmにおける光線透過率が10%以下、波長440nmにおける光線透過率が80%以上である、光学フィルム。 A laminated film in which a resin B layer containing a curable resin B as a main component is laminated on at least one side of a film containing a resin A as a main component, and at least one layer of an ultraviolet light absorber and a visible light absorbing dye in at least one layer. The optical film which contains above, the light transmittance in wavelength 380-410 nm is 10% or less, and the light transmittance in wavelength 440 nm is 80% or more. 樹脂Aを主成分とするフィルムに対して樹脂B層と反対面に、硬化性樹脂Bと異なる硬化性樹脂Cを主成分とする樹脂Cを積層してなる、請求項2に記載の光学フィルム。 3. The optical film according to claim 2, wherein a resin C mainly composed of a curable resin C different from the curable resin B is laminated on a surface opposite to the resin B layer with respect to a film mainly composed of a resin A. . 前記樹脂Aを主成分とするフィルムに紫外線吸収剤を含み、前記樹脂B層および/または樹脂C層に可視光線吸収色素を含んでなる、請求項2または3に記載の光学フィルム。 The optical film according to claim 2, wherein the film containing the resin A as a main component contains an ultraviolet absorber, and the resin B layer and / or the resin C layer contains a visible light absorbing dye. 前記紫外線吸収剤が320〜380nmの波長帯域に極大吸収波長を有する紫外線吸収剤である請求項1〜4のいずれかに記載の光学フィルム。 The optical film according to any one of claims 1 to 4, wherein the ultraviolet absorber has a maximum absorption wavelength in a wavelength range of 320 to 380 nm. 前記可視光線吸収色素が390nm〜420nmの波長帯域に極大吸収波長を有する色素である請求項1〜5のいずれかに記載の光学フィルム。 The optical film according to any one of claims 1 to 5, wherein the visible light absorbing dye is a dye having a maximum absorption wavelength in a wavelength band of 390 nm to 420 nm. 前記樹脂Aが、アクリル、シクロオレフィンコポリマー、トリアセチルセルロース、ポリエステル、ポリカーボネートのいずれかから選択された請求項1〜6のいずれかに記載の光学フィルム。 The optical film according to any one of claims 1 to 6, wherein the resin A is selected from any of acrylic, cycloolefin copolymer, triacetyl cellulose, polyester and polycarbonate. 前記可視光線吸収色素の少なくとも1種類が、アントラキノン、アゾメチン、インドール、トリアジン、ナフタルイミド、フタロシアニンのいずれかの骨格を有する、請求項1〜7のいずれかに記載の光学フィルム。 The optical film according to any one of claims 1 to 7, wherein at least one of the visible light absorbing dyes has a skeleton of any one of anthraquinone, azomethine, indole, triazine, naphthalimide and phthalocyanine. 波長300〜380nmにおける光線透過率の最大値が10%以下である、請求項1〜8のいずれかに記載の光学フィルム。 The optical film according to any one of claims 1 to 8, wherein the maximum value of light transmittance at a wavelength of 300 to 380 nm is 10% or less. 前記紫外線吸収剤の少なくとも1種類がトリアジン骨格構造を有する、請求項1〜9のいずれかに記載の光学フィルム。 The optical film according to any one of claims 1 to 9, wherein at least one of the ultraviolet absorbers has a triazine skeleton structure. 85℃250時間促進耐熱試験のヘイズ値が1.5以下である、請求項1〜10のいずれかに記載の光学フィルム。 The optical film according to any one of claims 1 to 10, wherein the haze value after the 85 ° C 250 hour accelerated heat resistance test is 1.5 or less. フィルムの少なくとも片面にプライマー層を設けてなる、請求項1〜11のいずれかに記載の光学フィルム。 The optical film according to any one of claims 1 to 11, wherein a primer layer is provided on at least one side of the film. 請求項1〜12のいずれかに記載の光学フィルムを用いた画像表示装置。 The image display apparatus using the optical film in any one of Claims 1-12. 請求項1〜12のいずれかに記載の光学フィルムを用いた車載用ディスプレイ。
An on-vehicle display using the optical film according to any one of claims 1 to 12.
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