JP2017052692A - 非対称耐衝撃性を有する強化ガラス及びガラス積層体 - Google Patents
非対称耐衝撃性を有する強化ガラス及びガラス積層体 Download PDFInfo
- Publication number
- JP2017052692A JP2017052692A JP2016205137A JP2016205137A JP2017052692A JP 2017052692 A JP2017052692 A JP 2017052692A JP 2016205137 A JP2016205137 A JP 2016205137A JP 2016205137 A JP2016205137 A JP 2016205137A JP 2017052692 A JP2017052692 A JP 2017052692A
- Authority
- JP
- Japan
- Prior art keywords
- glass
- impact resistance
- tempered glass
- coating
- asymmetric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011521 glass Substances 0.000 title claims description 76
- 239000006058 strengthened glass Substances 0.000 title abstract 6
- 238000000576 coating method Methods 0.000 claims abstract description 69
- 229910003460 diamond Inorganic materials 0.000 claims abstract description 9
- 239000010432 diamond Substances 0.000 claims abstract description 9
- 238000007373 indentation Methods 0.000 claims abstract description 7
- 230000003287 optical effect Effects 0.000 claims abstract description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract 6
- 239000000377 silicon dioxide Substances 0.000 claims abstract 3
- 239000011248 coating agent Substances 0.000 claims description 58
- 239000005341 toughened glass Substances 0.000 claims description 57
- 238000000034 method Methods 0.000 claims description 15
- 238000005496 tempering Methods 0.000 claims description 10
- 230000007547 defect Effects 0.000 claims description 9
- 229920000642 polymer Polymers 0.000 claims description 8
- 230000032798 delamination Effects 0.000 claims description 5
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- 239000003513 alkali Substances 0.000 claims description 3
- 230000008569 process Effects 0.000 claims description 3
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 2
- 229910001491 alkali aluminosilicate Inorganic materials 0.000 claims description 2
- 239000010410 layer Substances 0.000 description 26
- 238000012360 testing method Methods 0.000 description 19
- 239000000463 material Substances 0.000 description 16
- 239000000523 sample Substances 0.000 description 15
- 239000010408 film Substances 0.000 description 14
- 239000005340 laminated glass Substances 0.000 description 9
- 229910004298 SiO 2 Inorganic materials 0.000 description 8
- 239000011247 coating layer Substances 0.000 description 7
- 238000001723 curing Methods 0.000 description 5
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 5
- 238000005342 ion exchange Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 239000005354 aluminosilicate glass Substances 0.000 description 4
- 238000001704 evaporation Methods 0.000 description 4
- 230000008020 evaporation Effects 0.000 description 4
- 238000007679 ring-on-ring test Methods 0.000 description 4
- 239000010409 thin film Substances 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 238000009501 film coating Methods 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- -1 potassium nitride Chemical class 0.000 description 3
- 238000005546 reactive sputtering Methods 0.000 description 3
- 239000004065 semiconductor Substances 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 230000001133 acceleration Effects 0.000 description 2
- 239000002318 adhesion promoter Substances 0.000 description 2
- 239000006117 anti-reflective coating Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000012459 cleaning agent Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 239000013068 control sample Substances 0.000 description 2
- 230000002596 correlated effect Effects 0.000 description 2
- 239000012634 fragment Substances 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 150000004767 nitrides Chemical class 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 238000001552 radio frequency sputter deposition Methods 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000006121 base glass Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000000572 ellipsometry Methods 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 238000010583 slow cooling Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
- B32B17/10036—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10165—Functional features of the laminated safety glass or glazing
- B32B17/10174—Coatings of a metallic or dielectric material on a constituent layer of glass or polymer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10165—Functional features of the laminated safety glass or glazing
- B32B17/10174—Coatings of a metallic or dielectric material on a constituent layer of glass or polymer
- B32B17/10201—Dielectric coatings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
- B32B17/10761—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing vinyl acetal
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
- C03C17/30—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/3411—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials
- C03C17/3417—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials all coatings being oxide coatings
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C21/00—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface
- C03C21/001—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in liquid phase, e.g. molten salts, solutions
- C03C21/002—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in liquid phase, e.g. molten salts, solutions to perform ion-exchange between alkali ions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/73—Anti-reflective coatings with specific characteristics
- C03C2217/734—Anti-reflective coatings with specific characteristics comprising an alternation of high and low refractive indexes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
- Y10T428/263—Coating layer not in excess of 5 mils thick or equivalent
- Y10T428/264—Up to 3 mils
- Y10T428/265—1 mil or less
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
- Y10T428/266—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension of base or substrate
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31609—Particulate metal or metal compound-containing
- Y10T428/31612—As silicone, silane or siloxane
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31645—Next to addition polymer from unsaturated monomers
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Surface Treatment Of Glass (AREA)
- Laminated Bodies (AREA)
- Joining Of Glass To Other Materials (AREA)
- Re-Forming, After-Treatment, Cutting And Transporting Of Glass Products (AREA)
Abstract
Description
乗客が衝撃を与えた場合にガラスが破損する必要があるため、自動車産業は典型的には、自動車用窓ガラスの破損閾値を設定しており、これは球落下試験等の方法を用いて試験できる。
Claims (5)
- 強化ガラス積層体であって:
第1の表面及び該第1の表面の反対に配置された第2の表面を有する、強化ガラスの少なくとも1つの層;並びに
前記強化ガラスの前記第1の表面に接着された、シリカを含む1つ以上のコーティング;
を備え、
前記1つ以上のコーティングは、前記強化ガラスの少なくとも1つの層に非対称耐衝撃性を付与し、
前記1つ以上のコーティングは、4〜40gの負荷によるバーコビッチダイヤモンド圧子を用いたインデンテーション後に光学顕微鏡で検査した場合に離層を示さない、
強化ガラス積層体。 - 前記強化ガラスは、アルカリアルミノシリケート、アルカリアルミノボロシリケート又はこれらの組合せを含み、
前記非対称耐衝撃性は、前記第1の表面に向かう方向への衝撃に対する耐衝撃性よりも低い、前記第2の表面に向かう方向への衝撃に対する耐衝撃性を含む、請求項1に記載の強化ガラス積層体。 - 前記コーティングは、Al2O3、TiO2、Nb2O5、Ta2O5、ZrO2又はこれらの組合せからなる群から選択される少なくとも1つのさらなる酸化物をさらに含む、請求項1または2に記載の強化ガラス積層体。
- 視認できる欠点が実質的にないガラスを提供し、
前記ガラスを化学的テンパリング、熱的テンパリング、あるいはその両方によって強化し、
シリカを含むコーティングを前記強化したガラスの少なくとも1つの表面に施して、非対称耐衝撃性を有する強化ガラス積層体得る、
各工程を有してなり、
前記コーティングは、4〜40gの負荷によるバーコビッチダイヤモンド圧子を用いたインデンテーション後に光学顕微鏡で検査した場合に離層を示さない、
強化ガラス積層体を製造する方法。 - 視認できる欠点が実質的にないガラスを提供し、
前記ガラスを化学的テンパリング、熱的テンパリング、あるいはその両方によって強化し、
ケイ質ポリマーを含むコーティングを前記強化したガラスの少なくとも1つの表面に施し、
295℃以上の温度で前記コーティングを硬化させて非対称耐衝撃性を有する強化ガラス積層体得る、
強化ガラス積層体を製造する方法。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201161563074P | 2011-11-23 | 2011-11-23 | |
US61/563,074 | 2011-11-23 |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2014543495A Division JP2015507588A (ja) | 2011-11-23 | 2012-11-14 | 非対称耐衝撃性を有する強化ガラス及びガラス積層体 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2017052692A true JP2017052692A (ja) | 2017-03-16 |
JP6425255B2 JP6425255B2 (ja) | 2018-11-21 |
Family
ID=47228085
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2014543495A Pending JP2015507588A (ja) | 2011-11-23 | 2012-11-14 | 非対称耐衝撃性を有する強化ガラス及びガラス積層体 |
JP2016205137A Active JP6425255B2 (ja) | 2011-11-23 | 2016-10-19 | 非対称耐衝撃性を有する強化ガラス及びガラス積層体 |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2014543495A Pending JP2015507588A (ja) | 2011-11-23 | 2012-11-14 | 非対称耐衝撃性を有する強化ガラス及びガラス積層体 |
Country Status (6)
Country | Link |
---|---|
US (1) | US20130127202A1 (ja) |
EP (1) | EP2782753B1 (ja) |
JP (2) | JP2015507588A (ja) |
KR (1) | KR20140096145A (ja) |
CN (1) | CN104220252A (ja) |
WO (1) | WO2013078039A1 (ja) |
Families Citing this family (64)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10035331B2 (en) | 2011-06-24 | 2018-07-31 | Corning Incorporated | Light-weight hybrid glass laminates |
US9616641B2 (en) | 2011-06-24 | 2017-04-11 | Corning Incorporated | Light-weight hybrid glass laminates |
US10596783B2 (en) | 2012-05-31 | 2020-03-24 | Corning Incorporated | Stiff interlayers for laminated glass structures |
CN104703793B (zh) | 2012-06-01 | 2018-09-18 | 康宁股份有限公司 | 用于优化的破碎性能的玻璃层压件构造 |
EP2861542A1 (en) | 2012-06-14 | 2015-04-22 | Corning Incorporated | Process for laminating thin glass laminates |
EP2679551A1 (en) | 2012-06-28 | 2014-01-01 | Corning Incorporated | Process and system for fine tuning precision glass sheet bending |
US9435915B1 (en) * | 2012-09-28 | 2016-09-06 | Rockwell Collins, Inc. | Antiglare treatment for glass |
TWI606986B (zh) * | 2012-10-03 | 2017-12-01 | 康寧公司 | 用於保護玻璃表面的物理氣相沉積層 |
US10487009B2 (en) | 2012-10-12 | 2019-11-26 | Corning Incorporated | Articles having retained strength |
CN105339316B (zh) | 2013-02-25 | 2018-11-09 | 康宁股份有限公司 | 制造薄玻璃块的方法 |
US9221715B2 (en) * | 2013-07-25 | 2015-12-29 | Apple Inc. | Chemical strengthening of anti-reflective coatings (ARC) |
WO2015031151A1 (en) | 2013-08-26 | 2015-03-05 | Corning Incorporated | Method for localized annealing of chemically strengthened glass |
CN109624445A (zh) * | 2013-08-29 | 2019-04-16 | 康宁股份有限公司 | 薄玻璃层压结构 |
JP6530754B2 (ja) | 2013-08-30 | 2019-06-12 | コーニング インコーポレイテッド | 軽量、高剛性ガラスラミネート構造 |
US10160688B2 (en) | 2013-09-13 | 2018-12-25 | Corning Incorporated | Fracture-resistant layered-substrates and articles including the same |
EP3057915B1 (en) | 2013-10-14 | 2022-04-20 | Corning Incorporated | Ion exchange processes and chemically strengthened glass substrates resulting therefrom |
GB2520535A (en) * | 2013-11-25 | 2015-05-27 | Essex Safety Glass Ltd | Laminated glazings |
KR101585720B1 (ko) | 2013-12-20 | 2016-01-14 | 주식회사 포스코 | 유리층이 형성된 금속 봉지재 및 그 제조방법 |
US9321677B2 (en) * | 2014-01-29 | 2016-04-26 | Corning Incorporated | Bendable glass stack assemblies, articles and methods of making the same |
US20150251377A1 (en) * | 2014-03-07 | 2015-09-10 | Corning Incorporated | Glass laminate structures for head-up display system |
US10800143B2 (en) | 2014-03-07 | 2020-10-13 | Corning Incorporated | Glass laminate structures for head-up display system |
US9573833B2 (en) | 2014-03-31 | 2017-02-21 | Corning Incorporated | Method and lift jet floatation system for shaping thin glass |
CN116039378A (zh) | 2014-05-15 | 2023-05-02 | Agc株式会社 | 玻璃物品以及玻璃物品的制造方法 |
DE102014108057A1 (de) * | 2014-06-06 | 2015-12-17 | Schott Ag | Kratzfestes, chemisch vorgespanntes Glassubstrat und dessen Verwendung |
KR102331876B1 (ko) | 2014-07-10 | 2021-11-29 | 코닝 인코포레이티드 | 냉간 성형된 유리 아플리케 |
US11097974B2 (en) | 2014-07-31 | 2021-08-24 | Corning Incorporated | Thermally strengthened consumer electronic glass and related systems and methods |
CN107074616B (zh) | 2014-08-01 | 2020-04-03 | 康宁股份有限公司 | 玻璃成形设备和方法 |
WO2016037083A1 (en) | 2014-09-05 | 2016-03-10 | Corning Incorporated | Glass articles and methods for improving the reliability of glass articles |
CN106795033B (zh) * | 2014-10-07 | 2020-02-07 | 肖特股份有限公司 | 具有提高的强度的玻璃层压材料 |
US10669194B2 (en) | 2014-10-22 | 2020-06-02 | Corning Incorporated | Glass strengthening by ion exchange and lamination |
WO2016069835A2 (en) | 2014-10-29 | 2016-05-06 | Corning Incorporated | Apparatus and method for shaping or forming heated glass sheets |
EP3215469A1 (en) | 2014-11-07 | 2017-09-13 | Corning Incorporated | Induction heating method and apparatus for shaping thin glass |
WO2016085867A1 (en) * | 2014-11-26 | 2016-06-02 | Corning Incorporated | Methods for producing strengthened and durable glass containers |
CN106143069A (zh) * | 2015-04-21 | 2016-11-23 | 乔森 | 超级前挡玻璃 |
WO2016183059A1 (en) | 2015-05-11 | 2016-11-17 | Corning Incorporated | Surface display units with opaque screen |
WO2016196532A1 (en) | 2015-06-02 | 2016-12-08 | Corning Incorporated | Multi-functional material system for surface display unit |
KR20180014753A (ko) | 2015-06-02 | 2018-02-09 | 코닝 인코포레이티드 | 광-반응성 얇은 유리 적층물 |
US10286631B2 (en) | 2015-06-03 | 2019-05-14 | Precision Glass Bending Corporation | Bent, veneer-encapsulated heat-treated safety glass panels and methods of manufacture |
JP6849650B2 (ja) | 2015-07-10 | 2021-03-24 | コーニング インコーポレイテッド | 冷間形成積層体 |
DE102015213075A1 (de) * | 2015-07-13 | 2017-01-19 | Schott Ag | Asymmetrisch aufgebaute, auf beiden Oberflächenseiten chemisch vorgespannte Dünnglasscheibe, Verfahren zu deren Herstellung sowie deren Verwendung |
WO2017011023A1 (en) | 2015-07-15 | 2017-01-19 | Biltmore Technologies, Inc. | Opacity-changing impact resistant laminates |
US10350861B2 (en) | 2015-07-31 | 2019-07-16 | Corning Incorporated | Laminate structures with enhanced damping properties |
WO2017123573A2 (en) | 2016-01-12 | 2017-07-20 | Corning Incorporated | Thin thermally and chemically strengthened glass-based articles |
US11364860B2 (en) * | 2016-03-17 | 2022-06-21 | Agc Glass Europe | Exterior glass trim element for vehicle |
CN105956272B (zh) * | 2016-04-29 | 2019-06-28 | 大连楼兰科技股份有限公司 | 在汽车碰撞中采用efgm模拟风窗玻璃碎裂的方法 |
US11286201B2 (en) | 2017-01-31 | 2022-03-29 | AGC Inc. | Cover glass and glass laminate |
US20200180278A1 (en) * | 2017-04-26 | 2020-06-11 | Corning Incorporated | High heat transfer, strengthened glass laminate and related heating system and method |
CN107473607A (zh) * | 2017-07-28 | 2017-12-15 | 浙江上方电子装备有限公司 | 一种夹胶式电致变色玻璃、制备方法及其应用 |
JP7018767B2 (ja) * | 2017-12-28 | 2022-02-14 | 日本板硝子株式会社 | ウインドシールド |
TWI821234B (zh) | 2018-01-09 | 2023-11-11 | 美商康寧公司 | 具光改變特徵之塗覆製品及用於製造彼等之方法 |
CN108751733B (zh) * | 2018-05-31 | 2020-02-21 | 厦门大学 | 一种二氧化硅溶胶增强的中空安全玻璃及其制备方法 |
WO2019245819A1 (en) * | 2018-06-22 | 2019-12-26 | Corning Incorporated | Glass laminate construction with controlled breakage for pedestrian safety |
CN111204989A (zh) * | 2018-11-22 | 2020-05-29 | 康宁股份有限公司 | 低翘曲的强化制品以及制造其的不对称离子交换方法 |
CN113727954A (zh) | 2019-04-23 | 2021-11-30 | 康宁股份有限公司 | 具有确定的应力分布曲线的玻璃层叠物及其制作方法 |
US12117635B2 (en) * | 2019-04-30 | 2024-10-15 | 3M Innovative Properties Company | Optical stack |
WO2021025981A1 (en) | 2019-08-06 | 2021-02-11 | Corning Incorporated | Glass laminate with buried stress spikes to arrest cracks and methods of making the same |
WO2021030313A1 (en) * | 2019-08-13 | 2021-02-18 | Ringel Reut | Multi-layer metal article and method of making the same |
WO2021090242A1 (en) * | 2019-11-05 | 2021-05-14 | Agp America S.A. | Automotive glazing with anti-fingerprint coating |
US20220009824A1 (en) | 2020-07-09 | 2022-01-13 | Corning Incorporated | Anti-glare substrate for a display article including a textured region with primary surface features and secondary surface features imparting a surface roughness that increases surface scattering |
US20230415457A1 (en) * | 2020-11-25 | 2023-12-28 | Corning Incorporated | Glass laminates containing low expansion glass |
CN113820879A (zh) * | 2020-12-02 | 2021-12-21 | 法国圣戈班玻璃公司 | 用于玻璃的液晶投影层、玻璃、车辆以及制造玻璃的方法 |
CN112592057B (zh) * | 2020-12-14 | 2022-03-18 | 江苏烨明光电有限公司 | 一种高强度防爆led灯玻壳及其制备方法 |
EP4442665A1 (en) * | 2021-11-30 | 2024-10-09 | Industry University Cooperation Foundation of Korea Aerospace University | Glass having visual internal roughness and method for manufacturing same |
KR20240020764A (ko) | 2022-08-08 | 2024-02-16 | 삼성디스플레이 주식회사 | 전자 장치 및 그 전자 장치의 제조 방법 |
Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60125662A (ja) * | 1983-12-13 | 1985-07-04 | 旭硝子株式会社 | 2層安全ガラス板の製法 |
JPH0867965A (ja) * | 1994-08-24 | 1996-03-12 | Glaverbel Sa | 被覆基体及びその形成方法 |
JPH11145495A (ja) * | 1997-11-04 | 1999-05-28 | Asahi Glass Co Ltd | 太陽電池用ガラス基板およびその製造方法 |
JP2001316135A (ja) * | 2000-05-02 | 2001-11-13 | Bridgestone Corp | フィルム強化ガラスの製造方法 |
JP2002277990A (ja) * | 2001-03-22 | 2002-09-25 | Nagase Chemtex Corp | 複写機天版用ガラスおよびその製造方法 |
JP2003137603A (ja) * | 2001-10-25 | 2003-05-14 | Sun Tec Corp Kk | 光触媒層を有する熱強化ガラス成形体及びその製造法 |
JP2008037671A (ja) * | 2006-08-02 | 2008-02-21 | Asahi Glass Co Ltd | 赤外線遮蔽膜付きガラス板 |
JP2009192919A (ja) * | 2008-02-15 | 2009-08-27 | Agc Techno Glass Co Ltd | 光学多層膜付きガラス部材とその製造方法 |
JP2011510904A (ja) * | 2008-02-05 | 2011-04-07 | コーニング インコーポレイテッド | 電子装置のカバープレートとして使用するための耐損傷性ガラス物品 |
JP2013016026A (ja) * | 2011-07-04 | 2013-01-24 | Dainippon Printing Co Ltd | タッチパネル部材、座標検出装置、積層部材および、積層部材の製造方法 |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE650097A (ja) * | 1963-07-08 | 1965-01-04 | ||
US3816222A (en) * | 1967-04-27 | 1974-06-11 | Glaverbel | Method for preparing vitreous body by diffusion of ions through a coating layer |
DE4331263A1 (de) * | 1993-09-15 | 1995-03-16 | Bischoff Glastechnik | Glasscheibe und Verglasungseinheit |
US6231999B1 (en) * | 1996-06-21 | 2001-05-15 | Cardinal Ig Company | Heat temperable transparent coated glass article |
ES2162370T3 (es) * | 1997-06-10 | 2001-12-16 | Nippon Sheet Glass Co Ltd | Vidrio laminado para vehiculos. |
US5928783A (en) * | 1998-03-09 | 1999-07-27 | National Starch And Chemical Investment Holding Corporation | Pressure sensitive adhesive compositions |
EP0945254B1 (en) * | 1998-03-17 | 2004-12-22 | Chi Mei Optoelectronics Corporation | Material comprising an anti-reflective coating on a flexible glass substrate |
WO2000000855A1 (en) * | 1998-06-30 | 2000-01-06 | Kimberly-Clark Worldwide, Inc. | Coating composition for reducing reflection and fogging |
DE19927683C1 (de) * | 1999-06-17 | 2001-01-25 | Sekurit Saint Gobain Deutsch | Sonnen- und Wärmestrahlen reflektierende Verbundglasscheibe |
EP1164112A1 (en) * | 2000-06-16 | 2001-12-19 | Denglas Technologies, LLC | Multilayer antireflection coatings for heat-treatable inorganic substrates and methods for making same |
EP1748035B1 (en) * | 2002-03-01 | 2010-10-20 | Cardinal CG Company | Thin film coating having transparent base layer |
KR100511790B1 (ko) * | 2003-04-10 | 2005-09-02 | 엘지전자 주식회사 | 전면필터 및 그 제조방법 |
EP3521015B1 (en) * | 2003-07-11 | 2023-09-06 | Pilkington Group Limited | Solar control glazing |
US20080014466A1 (en) * | 2006-07-11 | 2008-01-17 | Ronghua Wei | Glass with scratch-resistant coating |
US20080160321A1 (en) * | 2007-01-03 | 2008-07-03 | 3M Innovative Properties Company | Single pane glazing laminates |
JP2008260654A (ja) * | 2007-04-12 | 2008-10-30 | Aomoriken Kogyo Gijutsu Kyoiku Shinkokai | 高い太陽光透過性能を有するガラス |
KR20110050522A (ko) * | 2008-08-21 | 2011-05-13 | 코닝 인코포레이티드 | 전자 장치용 내구성 유리 하우징/인클로저 |
WO2011149694A1 (en) * | 2010-05-26 | 2011-12-01 | Corning Incorporated | Ion-exchanging an ar coated glass and process |
CN109384399A (zh) * | 2011-11-30 | 2019-02-26 | 康宁股份有限公司 | 具有光学涂层和易清洁涂层的玻璃制品的制备方法 |
TWI606986B (zh) * | 2012-10-03 | 2017-12-01 | 康寧公司 | 用於保護玻璃表面的物理氣相沉積層 |
-
2012
- 2012-10-19 US US13/655,968 patent/US20130127202A1/en not_active Abandoned
- 2012-11-14 WO PCT/US2012/064923 patent/WO2013078039A1/en active Application Filing
- 2012-11-14 KR KR1020147017067A patent/KR20140096145A/ko not_active Application Discontinuation
- 2012-11-14 EP EP12791659.1A patent/EP2782753B1/en active Active
- 2012-11-14 CN CN201280057189.7A patent/CN104220252A/zh active Pending
- 2012-11-14 JP JP2014543495A patent/JP2015507588A/ja active Pending
-
2016
- 2016-10-19 JP JP2016205137A patent/JP6425255B2/ja active Active
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60125662A (ja) * | 1983-12-13 | 1985-07-04 | 旭硝子株式会社 | 2層安全ガラス板の製法 |
JPH0867965A (ja) * | 1994-08-24 | 1996-03-12 | Glaverbel Sa | 被覆基体及びその形成方法 |
JPH11145495A (ja) * | 1997-11-04 | 1999-05-28 | Asahi Glass Co Ltd | 太陽電池用ガラス基板およびその製造方法 |
JP2001316135A (ja) * | 2000-05-02 | 2001-11-13 | Bridgestone Corp | フィルム強化ガラスの製造方法 |
JP2002277990A (ja) * | 2001-03-22 | 2002-09-25 | Nagase Chemtex Corp | 複写機天版用ガラスおよびその製造方法 |
JP2003137603A (ja) * | 2001-10-25 | 2003-05-14 | Sun Tec Corp Kk | 光触媒層を有する熱強化ガラス成形体及びその製造法 |
JP2008037671A (ja) * | 2006-08-02 | 2008-02-21 | Asahi Glass Co Ltd | 赤外線遮蔽膜付きガラス板 |
JP2011510904A (ja) * | 2008-02-05 | 2011-04-07 | コーニング インコーポレイテッド | 電子装置のカバープレートとして使用するための耐損傷性ガラス物品 |
JP2009192919A (ja) * | 2008-02-15 | 2009-08-27 | Agc Techno Glass Co Ltd | 光学多層膜付きガラス部材とその製造方法 |
JP2013016026A (ja) * | 2011-07-04 | 2013-01-24 | Dainippon Printing Co Ltd | タッチパネル部材、座標検出装置、積層部材および、積層部材の製造方法 |
Also Published As
Publication number | Publication date |
---|---|
WO2013078039A1 (en) | 2013-05-30 |
KR20140096145A (ko) | 2014-08-04 |
EP2782753A1 (en) | 2014-10-01 |
CN104220252A (zh) | 2014-12-17 |
US20130127202A1 (en) | 2013-05-23 |
EP2782753B1 (en) | 2020-09-09 |
JP2015507588A (ja) | 2015-03-12 |
JP6425255B2 (ja) | 2018-11-21 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6425255B2 (ja) | 非対称耐衝撃性を有する強化ガラス及びガラス積層体 | |
US11919803B2 (en) | Articles with a low-elastic modulus layer and retained strength | |
KR102362297B1 (ko) | 중간 접착력 및 잔류 강도를 갖는 필름을 갖는 유리 제품 | |
CN109562992B (zh) | 罩构件及显示装置 | |
JP2015507588A5 (ja) | ||
JP2016526003A (ja) | 制御された破断強度を有するガラス−被膜積層体 | |
CN110099877B (zh) | 具有裂纹减缓的单和多层膜以保留制品强度和耐划痕性的玻璃基制品 | |
CN111936310A (zh) | 包括光学透明聚合硬涂层的可折叠玻璃制品及其制造方法 | |
CN107848876A (zh) | 具有中等粘附性、保留强度和光学透射率的膜的玻璃制品 | |
CN116063005A (zh) | 用于保持制品强度和耐刮擦性的具有硬膜和裂纹减缓复合结构的基于玻璃的制品 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20170704 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20170928 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20180220 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20180418 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20180919 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20181017 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 6425255 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |