JP2016515044A5 - - Google Patents
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- Publication number
- JP2016515044A5 JP2016515044A5 JP2015561708A JP2015561708A JP2016515044A5 JP 2016515044 A5 JP2016515044 A5 JP 2016515044A5 JP 2015561708 A JP2015561708 A JP 2015561708A JP 2015561708 A JP2015561708 A JP 2015561708A JP 2016515044 A5 JP2016515044 A5 JP 2016515044A5
- Authority
- JP
- Japan
- Prior art keywords
- mercury
- ferrous sulfide
- industrial
- scrubber
- suspension
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims 27
- 229910052753 mercury Inorganic materials 0.000 claims 26
- 239000007789 gas Substances 0.000 claims 21
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 claims 16
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims 12
- 238000000034 method Methods 0.000 claims 12
- 239000000725 suspension Substances 0.000 claims 10
- 239000007788 liquid Substances 0.000 claims 7
- 239000003153 chemical reaction reagent Substances 0.000 claims 6
- 239000011541 reaction mixture Substances 0.000 claims 6
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims 4
- 239000003546 flue gas Substances 0.000 claims 4
- 239000000203 mixture Substances 0.000 claims 4
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims 3
- 229910001680 bayerite Inorganic materials 0.000 claims 3
- 229910001679 gibbsite Inorganic materials 0.000 claims 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 3
- 239000000243 solution Substances 0.000 claims 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims 2
- 238000006477 desulfuration reaction Methods 0.000 claims 2
- 230000023556 desulfurization Effects 0.000 claims 2
- 229910000474 mercury oxide Inorganic materials 0.000 claims 2
- UKWHYYKOEPRTIC-UHFFFAOYSA-N mercury(ii) oxide Chemical compound [Hg]=O UKWHYYKOEPRTIC-UHFFFAOYSA-N 0.000 claims 2
- 230000003647 oxidation Effects 0.000 claims 2
- 238000007254 oxidation reaction Methods 0.000 claims 2
- 239000011780 sodium chloride Substances 0.000 claims 2
- HYHCSLBZRBJJCH-UHFFFAOYSA-M sodium hydrosulfide Chemical compound [Na+].[SH-] HYHCSLBZRBJJCH-UHFFFAOYSA-M 0.000 claims 2
- 238000001179 sorption measurement Methods 0.000 claims 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims 1
- 239000003929 acidic solution Substances 0.000 claims 1
- 230000002378 acidificating effect Effects 0.000 claims 1
- 239000003513 alkali Substances 0.000 claims 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- 239000007900 aqueous suspension Substances 0.000 claims 1
- 239000003518 caustics Substances 0.000 claims 1
- 239000003245 coal Substances 0.000 claims 1
- 238000000151 deposition Methods 0.000 claims 1
- 239000012530 fluid Substances 0.000 claims 1
- 239000000446 fuel Substances 0.000 claims 1
- 150000002500 ions Chemical class 0.000 claims 1
- 229910052742 iron Inorganic materials 0.000 claims 1
- -1 iron ion Chemical class 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- 239000007921 spray Substances 0.000 claims 1
- QXKXDIKCIPXUPL-UHFFFAOYSA-N sulfanylidenemercury Chemical compound [Hg]=S QXKXDIKCIPXUPL-UHFFFAOYSA-N 0.000 claims 1
- 238000005406 washing Methods 0.000 claims 1
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201361773927P | 2013-03-07 | 2013-03-07 | |
| US61/773,927 | 2013-03-07 | ||
| US14/193,973 US9034285B1 (en) | 2014-02-28 | 2014-02-28 | Use of ferrous sulfide suspension for the removal of mercury from flue gases |
| US14/193,973 | 2014-02-28 | ||
| PCT/US2014/021714 WO2014138572A1 (en) | 2013-03-07 | 2014-03-07 | Use of ferrous sulfide suspension for the removal of mercury from flue gases |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2016515044A JP2016515044A (ja) | 2016-05-26 |
| JP2016515044A5 true JP2016515044A5 (https=) | 2017-03-30 |
| JP6486840B2 JP6486840B2 (ja) | 2019-03-20 |
Family
ID=51491996
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015561708A Active JP6486840B2 (ja) | 2013-03-07 | 2014-03-07 | 煙道ガスからの水銀の除去のための、硫化第一鉄懸濁液の使用 |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JP6486840B2 (https=) |
| KR (1) | KR102164080B1 (https=) |
| CN (1) | CN105188888B (https=) |
| CA (1) | CA2904381C (https=) |
| DE (1) | DE112014001129B4 (https=) |
| GB (1) | GB2526239B (https=) |
| WO (1) | WO2014138572A1 (https=) |
| ZA (1) | ZA201507347B (https=) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI640355B (zh) * | 2015-09-01 | 2018-11-11 | 雷多斯集團有限責任公司 | 硫化亞鐵於自氣體移除硒之用途 |
| CN109012091B (zh) * | 2018-07-31 | 2021-05-04 | 中南大学 | 一种协同脱除烟气中Hg0和废液中Hg2+的方法 |
| CN110075695A (zh) * | 2019-05-30 | 2019-08-02 | 江苏新聚环保科技有限公司 | 废气处理装置 |
| CN116642845B (zh) * | 2023-04-21 | 2024-05-07 | 苏州科技大学 | 一种用于检测环境水中痕量Hg2+的比色纳米传感器 |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62140629A (ja) * | 1985-12-12 | 1987-06-24 | Mitsubishi Heavy Ind Ltd | 燃焼排ガス中の水銀を除去する方法 |
| US4726939A (en) * | 1985-12-23 | 1988-02-23 | Touro Freddie J | Process for the removal of mercury from precious metal-cyanide liquors |
| US4915818A (en) * | 1988-02-25 | 1990-04-10 | Mobil Oil Corporation | Use of dilute aqueous solutions of alkali polysulfides to remove trace amounts of mercury from liquid hydrocarbons |
| DE68902710T2 (de) * | 1988-07-25 | 1993-03-18 | Jgc Corp | Verfahren zum entfernen von quecksilber aus einem fluessigen kohlenwasserstoff. |
| US4962276A (en) * | 1989-01-17 | 1990-10-09 | Mobil Oil Corporation | Process for removing mercury from water or hydrocarbon condensate |
| JPH10216476A (ja) * | 1997-01-31 | 1998-08-18 | Kawasaki Heavy Ind Ltd | 排ガス処理方法及び装置 |
| US6503470B1 (en) | 1999-03-31 | 2003-01-07 | The Babcock & Wilcox Company | Use of sulfide-containing liquors for removing mercury from flue gases |
| US6855859B2 (en) | 1999-03-31 | 2005-02-15 | The Babcock & Wilcox Company | Method for controlling elemental mercury emissions |
| US6284199B1 (en) * | 1999-03-31 | 2001-09-04 | Mcdermott Technology, Inc. | Apparatus for control of mercury |
| US7037474B2 (en) | 1999-03-31 | 2006-05-02 | The Babcock & Wilcox Company | Use of sulfide-containing liquors for removing mercury from flue gases |
| NL1017206C2 (nl) | 2001-01-26 | 2002-07-29 | Cdem Holland Bv | Werkwijze voor het verwijderen van kwik uit een gasstroom. |
| US7288499B1 (en) | 2001-04-30 | 2007-10-30 | Ada Technologies, Inc | Regenerable high capacity sorbent for removal of mercury from flue gas |
| US6719828B1 (en) | 2001-04-30 | 2004-04-13 | John S. Lovell | High capacity regenerable sorbent for removal of mercury from flue gas |
| JP2006160542A (ja) * | 2004-12-03 | 2006-06-22 | Tosoh Corp | 硫化鉄粒子含有溶液、その製造方法、及びそれを用いた重金属処理剤並びに重金属の処理方法 |
| US7790830B2 (en) | 2005-09-30 | 2010-09-07 | Wootech, Ltd. | Swellable sol-gels, methods of making, and use thereof |
| US7704920B2 (en) | 2005-11-30 | 2010-04-27 | Basf Catalysts Llc | Pollutant emission control sorbents and methods of manufacture |
| US7575629B2 (en) | 2005-11-30 | 2009-08-18 | Basf Catalysts Llc | Pollutant emission control sorbents and methods of manufacture |
| US8217131B2 (en) | 2006-10-02 | 2012-07-10 | Abs Materials, Inc. | Method for extracting a metal particulate from an aqueous solution using a sol-gel derived sorbent |
| WO2009114795A2 (en) | 2008-03-14 | 2009-09-17 | Medical Care Corporation | Non-natural pattern identification for cognitive assessment |
| US8197687B2 (en) | 2008-08-19 | 2012-06-12 | Perry Equipment Corporation | Contaminant adsorbent fluted filter element |
| JP5239718B2 (ja) * | 2008-10-07 | 2013-07-17 | 学校法人早稲田大学 | 重金属類を含有する排水の水処理方法 |
| US8088283B2 (en) | 2009-05-29 | 2012-01-03 | Battelle Memorial Institute | Continuous batch reactor, system, and process for treatment of metal-contaminated fluids |
| JP5554162B2 (ja) * | 2010-06-30 | 2014-07-23 | 三菱重工業株式会社 | 排ガス中の水銀処理システム |
| US20120135214A1 (en) | 2010-11-30 | 2012-05-31 | Steven Bruce Dawes | Sorbent For Removal Of A Contaminant From A Fluid |
| WO2013052876A1 (en) | 2011-10-07 | 2013-04-11 | Nalco Company | Gas stream treatment process |
-
2014
- 2014-03-07 GB GB1517093.9A patent/GB2526239B/en not_active Expired - Fee Related
- 2014-03-07 CA CA2904381A patent/CA2904381C/en active Active
- 2014-03-07 JP JP2015561708A patent/JP6486840B2/ja active Active
- 2014-03-07 KR KR1020157026587A patent/KR102164080B1/ko active Active
- 2014-03-07 DE DE112014001129.0T patent/DE112014001129B4/de active Active
- 2014-03-07 CN CN201480026020.4A patent/CN105188888B/zh active Active
- 2014-03-07 WO PCT/US2014/021714 patent/WO2014138572A1/en not_active Ceased
-
2015
- 2015-10-05 ZA ZA2015/07347A patent/ZA201507347B/en unknown
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