JP2016505677A - バイオマス系ポリマーエマルジョンの調製方法 - Google Patents
バイオマス系ポリマーエマルジョンの調製方法 Download PDFInfo
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Abstract
Description
Claims (1)
- バイオマス系ポリマーエマルジョンの調製方法であって、
1) カルダノール系重合性乳化剤を調製する工程と、該工程は、モル質量比に基づいて、1部のカルダノールを1〜3時間真空脱水して無水にし、室温で10〜100部の溶剤aに溶解させた後、0.8〜1.2部のスルホン化剤と0.8〜1.2部の強塩基を加え、得られた混合物を70℃〜150℃で2〜6時間反応させ、混合物を室温に冷却し、塩酸を使用してそのpH値を1〜5に調節し、70〜150℃で1〜3時間反応させ、室温に冷却し、一晩放置し、ろ過し、0℃〜5℃の10〜100部の溶剤aを使用して洗浄して白色固形物を生成し、白色固形物を乾燥させ、10〜100部の無水溶剤bに溶解させてから、0.8〜1.5部の改質剤および0.8〜1.5部のトリエチルアミンを加えて、得られた溶液を0〜5℃で0.5〜24時間反応させて、カルダノール系重合性乳化剤を調製するものであり、
前記強塩基は水酸化カリウムおよび水酸化ナトリウムの少なくともいずれかであり、
前記溶剤aは水、エタノール、メタノール、テトラヒドロフラン、アセトン、ジオキサン、アセトニトリル、ジメチルホルムアミド、ジメチルスルホキシド、またはそれらの混合物であり、
前記溶剤bは無水ジクロロメタン、テトラヒドロフラン、アセトニトリル、またはそれらの混合物であり、
前記改質剤は塩化アクリロイル、塩化メタクリロイル、塩化アリル、またはそれらの混合物であり、
前記スルホン化剤はNa2S2O5であり、
2) ヒマシ油系ポリウレタンプレポリマーを調製する工程と、該工程は、モル質量比に基づき、0〜20℃の1部の乾燥ヒマシ油を供給し、ヒマシ油に質量濃度10〜30%のアセトン溶解無水マレイン酸を液滴状で5〜30分間加え、得られた混合物を25〜50℃に加熱し、0.5〜24時間反応させ、次に、混合物を60〜80℃に継続して加熱し、4〜5時間反応させ、溶剤を30〜40℃の真空下で除去し、混合物を室温に冷却して、赤橙色の無水マレイン酸改質ヒマシ油を生成し、
前記無水マレイン酸改質ヒマシ油を60℃に加熱してから、1.0〜2.5部のイソシアネート、0.1〜1部の触媒、0.1〜1部の鎖延長剤を液滴状で加え、1〜6時間反応させて、粘稠重合性ヒマシ油系ポリウレタンプレポリマーを生成するものであり、
前記イソシアネートは1,6−ヘキサメチレンジイソシアネート、1,6−オクタメチレンジイソシアネートまたはイソホロンジイソシアネートであり、
前記触媒はテトラメチルジアミノブタン、トリエチレンジアミン、ジブチル錫ジラウレート、またはオクタン酸第一錫であり、
前記鎖延長剤はエチレンジアミン、ジエチレントリアミン、ヘキサメチレンジアミン、イソホロンジアミン、p−フェニレンンジアミン、またはそれらの混合物であり、
3) バイオマス系グラフトポリマーエマルジョンを調製する工程とを含み、該工程は、モル質量比に基づいて、工程2で得られた1部のヒマシ油系ポリウレタンプレポリマーと、工程1で得られた0.1〜0.5部のカルダノール系重合性乳化剤と、0.5〜2部のアクリレートモノマーと、5〜50部の水を混合し、得られた溶液を50〜60℃で0.5〜2時間膨潤させ、溶液を70〜90℃に加熱し、溶液に0.001〜0.1部の開始剤を含む水溶液を液滴状で加え、溶液を2〜4時間は反応させて、バイオマス系ポリマーエマルジョンを生成するものであり、
前記アクリレートモノマーはメチルメタクリレートまたはブチルアクリレートであり、
前記開始剤は過硫酸カリウムおよび過硫酸アンモニウムの少なくともいずれかである
方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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CN201210572455.1A CN103044628B (zh) | 2012-12-25 | 2012-12-25 | 一种生物质基聚合物乳液的制备方法 |
CN201210572455.1 | 2012-12-25 | ||
PCT/CN2013/088594 WO2014101640A1 (zh) | 2012-12-25 | 2013-12-05 | 一种生物质基聚合物乳液的制备方法 |
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JP2016505677A true JP2016505677A (ja) | 2016-02-25 |
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KR20150069593A (ko) * | 2013-12-13 | 2015-06-24 | (주)엘지하우시스 | 접착력이 향상된 단열재용 접착제 조성물 |
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CN113583207B (zh) * | 2021-07-01 | 2022-08-26 | 山西省应用化学研究所(有限公司) | 基于蓖麻油的水性聚氨酯乳液及胶粘剂的制备方法 |
CN113582771B (zh) * | 2021-08-24 | 2023-11-10 | 温州医科大学 | 一种基于高分子缓释肥料的制备方法 |
CN113999366A (zh) * | 2021-11-30 | 2022-02-01 | 淄博尚正新材料科技有限公司 | 水性uv固化树脂的制备方法 |
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CN115895379B (zh) * | 2022-11-10 | 2023-08-29 | 浩力森涂料(上海)有限公司 | 耐热碱腐蚀蓖麻油改性乳液及其制备方法 |
CN116854852B (zh) * | 2023-09-05 | 2023-11-10 | 山东天一化学股份有限公司 | 一种改性溴化聚苯乙烯的制备方法及其应用 |
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JP2005239992A (ja) * | 2004-02-25 | 2005-09-08 | Yasuhara Chemical Co Ltd | ポリ乳酸系樹脂組成物 |
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CN1089977A (zh) * | 1993-10-25 | 1994-07-27 | 山西省水利科学研究所 | 蓖麻油钢闸门防腐涂料及其制造方法 |
AU2156700A (en) * | 1998-12-10 | 2000-06-26 | Cardolite Corp. | Cardanol derivative and method of making the cardanol derivative |
DE102004009818A1 (de) * | 2004-02-28 | 2005-09-15 | Bayer Materialscience Ag | Hydrophobe, niedrigviskose Polyole |
CN101434807A (zh) * | 2008-12-26 | 2009-05-20 | 扬州美涂士金陵特种涂料有限公司 | 底面合一的环氧重防腐蚀涂料 |
US20120129963A1 (en) * | 2009-07-08 | 2012-05-24 | Elena Benedetti | Synthesis of novel multifunctional cardanol's derivatives and their use as halogen free polyurethanic foams precursors |
CN101967222B (zh) | 2010-09-19 | 2012-04-25 | 中国林业科学研究院林产化学工业研究所 | 一种环氧化蓖麻油改性的水性聚氨酯的制备方法 |
CN102093534B (zh) | 2010-12-26 | 2012-08-08 | 华南理工大学 | 一种聚氨酯水分散体的制备方法及含有聚氨酯水分散体的水性聚氨酯涂料 |
CN102199255B (zh) * | 2011-04-07 | 2013-01-09 | 合肥工业大学 | 一种热解封型聚氨酯-丙烯酸酯乳液及其制备方法 |
CN102786637A (zh) * | 2011-05-17 | 2012-11-21 | 上海富臣化工有限公司 | 一种复合改性的水性聚氨酯树脂及其制备方法 |
CN103044628B (zh) * | 2012-12-25 | 2014-12-10 | 中盈长江国际新能源投资有限公司 | 一种生物质基聚合物乳液的制备方法 |
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EP2940051A4 (en) | 2016-08-24 |
WO2014101640A1 (zh) | 2014-07-03 |
DK2940051T3 (da) | 2017-11-13 |
AU2013369943B2 (en) | 2016-06-16 |
US9255169B2 (en) | 2016-02-09 |
US20150291720A1 (en) | 2015-10-15 |
RU2602809C1 (ru) | 2016-11-20 |
CN103044628B (zh) | 2014-12-10 |
KR20150095858A (ko) | 2015-08-21 |
CN103044628A (zh) | 2013-04-17 |
AU2013369943A1 (en) | 2015-07-16 |
CA2896318A1 (en) | 2014-07-03 |
KR101719359B1 (ko) | 2017-03-23 |
EP2940051B1 (en) | 2017-09-27 |
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