JP2015533844A5 - - Google Patents
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- Publication number
- JP2015533844A5 JP2015533844A5 JP2015538408A JP2015538408A JP2015533844A5 JP 2015533844 A5 JP2015533844 A5 JP 2015533844A5 JP 2015538408 A JP2015538408 A JP 2015538408A JP 2015538408 A JP2015538408 A JP 2015538408A JP 2015533844 A5 JP2015533844 A5 JP 2015533844A5
- Authority
- JP
- Japan
- Prior art keywords
- alkyl
- unsubstituted
- alkoxy
- formula
- salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- -1 cyano, methyl Chemical group 0.000 claims description 105
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 89
- 229910052736 halogen Inorganic materials 0.000 claims description 79
- 150000002367 halogens Chemical class 0.000 claims description 79
- 125000001424 substituent group Chemical group 0.000 claims description 67
- 229910052739 hydrogen Inorganic materials 0.000 claims description 56
- 125000006552 (C3-C8) cycloalkyl group Chemical group 0.000 claims description 43
- 239000001257 hydrogen Substances 0.000 claims description 37
- 150000001875 compounds Chemical class 0.000 claims description 31
- 150000002431 hydrogen Chemical class 0.000 claims description 30
- 150000003839 salts Chemical class 0.000 claims description 26
- 241000607479 Yersinia pestis Species 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 15
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 claims description 11
- 125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 claims description 11
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 claims description 11
- 125000004076 pyridyl group Chemical group 0.000 claims description 11
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 7
- 239000002689 soil Substances 0.000 claims description 6
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 5
- 229920002554 vinyl polymer Polymers 0.000 claims description 5
- 230000009545 invasion Effects 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- 239000000575 pesticide Substances 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 238000009395 breeding Methods 0.000 claims description 2
- 230000001488 breeding effect Effects 0.000 claims description 2
- 125000004216 fluoromethyl group Chemical group [H]C([H])(F)* 0.000 claims description 2
- 235000013305 food Nutrition 0.000 claims description 2
- 125000002962 imidazol-1-yl group Chemical group [*]N1C([H])=NC([H])=C1[H] 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- 125000004353 pyrazol-1-yl group Chemical group [H]C1=NN(*)C([H])=C1[H] 0.000 claims description 2
- 241001124076 Aphididae Species 0.000 claims 4
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims 4
- 241000952611 Aphis craccivora Species 0.000 claims 3
- 241001302798 Bemisia argentifolii Species 0.000 claims 3
- 241000233855 Orchidaceae Species 0.000 claims 3
- 241001414989 Thysanoptera Species 0.000 claims 3
- 241000256118 Aedes aegypti Species 0.000 claims 2
- 241000239290 Araneae Species 0.000 claims 2
- 241000256593 Brachycaudus schwartzi Species 0.000 claims 2
- 229920000742 Cotton Polymers 0.000 claims 2
- 241000254171 Curculionidae Species 0.000 claims 2
- 241000196324 Embryophyta Species 0.000 claims 2
- 241001556089 Nilaparvata lugens Species 0.000 claims 2
- 240000006677 Vicia faba Species 0.000 claims 2
- 235000010749 Vicia faba Nutrition 0.000 claims 2
- 235000002098 Vicia faba var. major Nutrition 0.000 claims 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims 2
- 241000894007 species Species 0.000 claims 2
- 241000254175 Anthonomus grandis Species 0.000 claims 1
- 241000255579 Ceratitis capitata Species 0.000 claims 1
- 241001414720 Cicadellidae Species 0.000 claims 1
- 241000254173 Coleoptera Species 0.000 claims 1
- 241000578422 Graphosoma lineatum Species 0.000 claims 1
- 241000256244 Heliothis virescens Species 0.000 claims 1
- 241001477931 Mythimna unipuncta Species 0.000 claims 1
- 241000721621 Myzus persicae Species 0.000 claims 1
- 244000061176 Nicotiana tabacum Species 0.000 claims 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 claims 1
- 241000238633 Odonata Species 0.000 claims 1
- 241000237509 Patinopecten sp. Species 0.000 claims 1
- 241000320508 Pentatomidae Species 0.000 claims 1
- 241000255588 Tephritidae Species 0.000 claims 1
- 241001454295 Tetranychidae Species 0.000 claims 1
- 235000019504 cigarettes Nutrition 0.000 claims 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- 125000002816 methylsulfanyl group Chemical group [H]C([H])([H])S[*] 0.000 claims 1
- 235000020637 scallop Nutrition 0.000 claims 1
- 125000004205 trifluoroethyl group Chemical group [H]C([H])(*)C(F)(F)F 0.000 claims 1
- 125000000882 C2-C6 alkenyl group Chemical group 0.000 description 71
- 125000003601 C2-C6 alkynyl group Chemical group 0.000 description 71
- 125000004432 carbon atom Chemical group C* 0.000 description 55
- 229910052799 carbon Inorganic materials 0.000 description 51
- 125000006700 (C1-C6) alkylthio group Chemical group 0.000 description 42
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 36
- 125000004737 (C1-C6) haloalkoxy group Chemical group 0.000 description 34
- 125000004093 cyano group Chemical group *C#N 0.000 description 34
- 125000005842 heteroatom Chemical group 0.000 description 34
- 125000004739 (C1-C6) alkylsulfonyl group Chemical group 0.000 description 29
- 229910052760 oxygen Inorganic materials 0.000 description 29
- 125000004738 (C1-C6) alkyl sulfinyl group Chemical group 0.000 description 28
- 229910052717 sulfur Inorganic materials 0.000 description 27
- 125000006771 (C1-C6) haloalkylthio group Chemical group 0.000 description 24
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 22
- 125000003545 alkoxy group Chemical group 0.000 description 20
- 125000001931 aliphatic group Chemical group 0.000 description 18
- 229920006395 saturated elastomer Polymers 0.000 description 18
- 125000001981 tert-butyldimethylsilyl group Chemical group [H]C([H])([H])[Si]([H])(C([H])([H])[H])[*]C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 18
- 125000002723 alicyclic group Chemical group 0.000 description 17
- 125000005913 (C3-C6) cycloalkyl group Chemical group 0.000 description 16
- 229910052757 nitrogen Inorganic materials 0.000 description 16
- 125000006615 aromatic heterocyclic group Chemical group 0.000 description 15
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 15
- GVNVAWHJIKLAGL-UHFFFAOYSA-N 2-(cyclohexen-1-yl)cyclohexan-1-one Chemical compound O=C1CCCCC1C1=CCCCC1 GVNVAWHJIKLAGL-UHFFFAOYSA-N 0.000 description 14
- 101150065749 Churc1 gene Proteins 0.000 description 14
- 102100038239 Protein Churchill Human genes 0.000 description 14
- KWEDUNSJJZVRKR-UHFFFAOYSA-N carbononitridic azide Chemical compound [N-]=[N+]=NC#N KWEDUNSJJZVRKR-UHFFFAOYSA-N 0.000 description 13
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 13
- 125000000171 (C1-C6) haloalkyl group Chemical group 0.000 description 12
- 125000002947 alkylene group Chemical group 0.000 description 12
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 12
- 125000000623 heterocyclic group Chemical group 0.000 description 12
- 125000001624 naphthyl group Chemical group 0.000 description 12
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 12
- 125000006643 (C2-C6) haloalkenyl group Chemical group 0.000 description 10
- 241001465754 Metazoa Species 0.000 description 10
- SNOOUWRIMMFWNE-UHFFFAOYSA-M sodium;6-[(3,4,5-trimethoxybenzoyl)amino]hexanoate Chemical compound [Na+].COC1=CC(C(=O)NCCCCCC([O-])=O)=CC(OC)=C1OC SNOOUWRIMMFWNE-UHFFFAOYSA-M 0.000 description 10
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 description 8
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 8
- 125000004433 nitrogen atom Chemical group N* 0.000 description 8
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 6
- 125000000392 cycloalkenyl group Chemical group 0.000 description 5
- 244000045947 parasite Species 0.000 description 5
- 125000003320 C2-C6 alkenyloxy group Chemical group 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
- 125000004429 atom Chemical group 0.000 description 4
- 125000002837 carbocyclic group Chemical group 0.000 description 4
- 125000005708 carbonyloxy group Chemical group [*:2]OC([*:1])=O 0.000 description 4
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 4
- 125000004970 halomethyl group Chemical group 0.000 description 4
- 125000003253 isopropoxy group Chemical group [H]C([H])([H])C([H])(O*)C([H])([H])[H] 0.000 description 4
- 241000238631 Hexapoda Species 0.000 description 3
- 206010061217 Infestation Diseases 0.000 description 3
- 208000015181 infectious disease Diseases 0.000 description 3
- 125000004765 (C1-C4) haloalkyl group Chemical group 0.000 description 2
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- 125000000753 cycloalkyl group Chemical group 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 125000000232 haloalkynyl group Chemical group 0.000 description 2
- 125000005347 halocycloalkyl group Chemical group 0.000 description 2
- 125000001475 halogen functional group Chemical group 0.000 description 2
- 125000002883 imidazolyl group Chemical group 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 125000003226 pyrazolyl group Chemical group 0.000 description 2
- 125000000168 pyrrolyl group Chemical group 0.000 description 2
- 125000001425 triazolyl group Chemical group 0.000 description 2
- 125000003626 1,2,4-triazol-1-yl group Chemical group [*]N1N=C([H])N=C1[H] 0.000 description 1
- 125000001462 1-pyrrolyl group Chemical group [*]N1C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 125000004206 2,2,2-trifluoroethyl group Chemical group [H]C([H])(*)C(F)(F)F 0.000 description 1
- 125000004105 2-pyridyl group Chemical group N1=C([*])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 125000003349 3-pyridyl group Chemical group N1=C([H])C([*])=C([H])C([H])=C1[H] 0.000 description 1
- 125000000339 4-pyridyl group Chemical group N1=C([H])C([H])=C([*])C([H])=C1[H] 0.000 description 1
- HCOGMSOTWRWESC-UHFFFAOYSA-N COC(c1cc(C(Cc(cccc2)c2I)(C#N)C#N)ccc1)=O Chemical compound COC(c1cc(C(Cc(cccc2)c2I)(C#N)C#N)ccc1)=O HCOGMSOTWRWESC-UHFFFAOYSA-N 0.000 description 1
- QRMCDFQKFFQJRS-UHFFFAOYSA-N COC(c1cccc(C(Cc2ccccc2Br)(C#N)C#N)c1)=O Chemical compound COC(c1cccc(C(Cc2ccccc2Br)(C#N)C#N)c1)=O QRMCDFQKFFQJRS-UHFFFAOYSA-N 0.000 description 1
- YDKWAKLLZCTVNI-UHFFFAOYSA-N COc1ccc(CC(c(cc2)ccc2OC)(C#N)C#N)cc1 Chemical compound COc1ccc(CC(c(cc2)ccc2OC)(C#N)C#N)cc1 YDKWAKLLZCTVNI-UHFFFAOYSA-N 0.000 description 1
- YBCXUXJHQVFHLA-UHFFFAOYSA-N N#CC(Cc(cc1)ccc1Cl)(c(cccc1)c1Cl)C#N Chemical compound N#CC(Cc(cc1)ccc1Cl)(c(cccc1)c1Cl)C#N YBCXUXJHQVFHLA-UHFFFAOYSA-N 0.000 description 1
- RBADEYJCAIEUBP-UHFFFAOYSA-N N#CC(Cc1ccccc1)(c1ccccc1)C#N Chemical compound N#CC(Cc1ccccc1)(c1ccccc1)C#N RBADEYJCAIEUBP-UHFFFAOYSA-N 0.000 description 1
- 230000035784 germination Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 230000000590 parasiticidal effect Effects 0.000 description 1
- 125000004213 tert-butoxy group Chemical group [H]C([H])([H])C(O*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261717722P | 2012-10-24 | 2012-10-24 | |
| US61/717,722 | 2012-10-24 | ||
| PCT/EP2013/072051 WO2014064093A1 (en) | 2012-10-24 | 2013-10-22 | Malononitrile compounds for controlling animal pests |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2018094913A Division JP2018158923A (ja) | 2012-10-24 | 2018-05-16 | 動物有害生物を防除するためのマロノニトリル化合物 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2015533844A JP2015533844A (ja) | 2015-11-26 |
| JP2015533844A5 true JP2015533844A5 (enExample) | 2019-09-12 |
| JP6647865B2 JP6647865B2 (ja) | 2020-02-14 |
Family
ID=49448171
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015538408A Expired - Fee Related JP6647865B2 (ja) | 2012-10-24 | 2013-10-22 | 動物有害生物を防除するためのマロノニトリル化合物 |
| JP2018094913A Pending JP2018158923A (ja) | 2012-10-24 | 2018-05-16 | 動物有害生物を防除するためのマロノニトリル化合物 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2018094913A Pending JP2018158923A (ja) | 2012-10-24 | 2018-05-16 | 動物有害生物を防除するためのマロノニトリル化合物 |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US10292388B2 (enExample) |
| EP (1) | EP2911509B1 (enExample) |
| JP (2) | JP6647865B2 (enExample) |
| CN (1) | CN104869826B (enExample) |
| AR (1) | AR094723A1 (enExample) |
| AU (1) | AU2013336754B2 (enExample) |
| BR (1) | BR112015009174A8 (enExample) |
| CA (1) | CA2888390C (enExample) |
| ES (1) | ES2644339T3 (enExample) |
| MX (1) | MX366818B (enExample) |
| NZ (1) | NZ707308A (enExample) |
| WO (1) | WO2014064093A1 (enExample) |
| ZA (1) | ZA201503573B (enExample) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015158605A1 (en) * | 2014-04-16 | 2015-10-22 | Basf Se | Hetaryl substituted malononitrile compounds |
| ES2765405T3 (es) | 2014-04-17 | 2020-06-09 | Boehringer Ingelheim Animal Health Usa Inc | Utilización de compuestos de malononitrilo para proteger animales de parásitos |
| CN109096146B (zh) * | 2018-09-03 | 2020-11-10 | 杭州中美华东制药有限公司 | 阿那曲唑关键中间体的合成方法 |
| US12108762B2 (en) * | 2020-09-08 | 2024-10-08 | Santanu Maitra | Methods of controlling crop pests using aromatic amide insect repellents, methods of making aromatic amide insect repellents, and novel aromatic amide insect repellents |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE335994C (de) * | 1916-06-28 | 1921-04-22 | Chem Fab Von Heyden Aktien Ges | Verfahren zur Herstellung von Hydantoinen |
| US3558671A (en) | 1967-08-30 | 1971-01-26 | Du Pont | Fluoro- and cyano-substituted 7,7,8,8-tetracyanoquinodimethans and intermediates thereto |
| GB9002830D0 (en) * | 1990-02-08 | 1990-04-04 | Secr Defence | L.c.cyanoalkenes & alkenes |
| JPH1029966A (ja) | 1996-07-17 | 1998-02-03 | Mitsubishi Chem Corp | マロノニトリル誘導体およびこれを有効成分とする除草剤 |
| JP2002533318A (ja) * | 1998-12-22 | 2002-10-08 | ニューロサーチ、アクティーゼルスカブ | イオンチャネル調節剤 |
| JP2003026510A (ja) * | 2001-05-09 | 2003-01-29 | Sumitomo Chem Co Ltd | マロノニトリル化合物およびその有害生物防除用途 |
| JP4513284B2 (ja) * | 2002-07-17 | 2010-07-28 | 住友化学株式会社 | マロノニトリル化合物及びその用途 |
| DE60309874T2 (de) * | 2002-07-17 | 2007-03-15 | Sumitomo Chemical Co., Ltd. | Malonsäuerenitril-verbindungen und ihre verwendung als pestizide |
| JP2009503017A (ja) * | 2005-08-01 | 2009-01-29 | ビーエーエスエフ ソシエタス・ヨーロピア | 害虫を駆除するためのジシアノアルカン酸アミド類 |
| US20090136551A1 (en) * | 2005-08-05 | 2009-05-28 | Basf Aktiengesellschaft | Substituted Dicyanoalkanes For Combating Animal Pests |
| CN101384170B (zh) * | 2005-12-22 | 2012-07-18 | 巴斯夫欧洲公司 | 丙二腈化合物 |
| WO2007147888A1 (en) * | 2006-06-22 | 2007-12-27 | Basf Se | Malononitrile compounds |
-
2013
- 2013-10-22 ES ES13779855.9T patent/ES2644339T3/es active Active
- 2013-10-22 AU AU2013336754A patent/AU2013336754B2/en not_active Ceased
- 2013-10-22 US US14/438,002 patent/US10292388B2/en not_active Expired - Fee Related
- 2013-10-22 CN CN201380067880.8A patent/CN104869826B/zh not_active Expired - Fee Related
- 2013-10-22 JP JP2015538408A patent/JP6647865B2/ja not_active Expired - Fee Related
- 2013-10-22 BR BR112015009174A patent/BR112015009174A8/pt active Search and Examination
- 2013-10-22 MX MX2015005314A patent/MX366818B/es active IP Right Grant
- 2013-10-22 CA CA2888390A patent/CA2888390C/en not_active Expired - Fee Related
- 2013-10-22 NZ NZ707308A patent/NZ707308A/en not_active IP Right Cessation
- 2013-10-22 EP EP13779855.9A patent/EP2911509B1/en not_active Not-in-force
- 2013-10-22 WO PCT/EP2013/072051 patent/WO2014064093A1/en not_active Ceased
- 2013-10-24 AR ARP130103877A patent/AR094723A1/es unknown
-
2015
- 2015-05-21 ZA ZA2015/03573A patent/ZA201503573B/en unknown
-
2018
- 2018-05-16 JP JP2018094913A patent/JP2018158923A/ja active Pending
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