JP2014523480A5 - - Google Patents
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- Publication number
- JP2014523480A5 JP2014523480A5 JP2014514512A JP2014514512A JP2014523480A5 JP 2014523480 A5 JP2014523480 A5 JP 2014523480A5 JP 2014514512 A JP2014514512 A JP 2014514512A JP 2014514512 A JP2014514512 A JP 2014514512A JP 2014523480 A5 JP2014523480 A5 JP 2014523480A5
- Authority
- JP
- Japan
- Prior art keywords
- nickel
- particle form
- ligand
- crystallites
- nickel particle
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 22
- 229910052759 nickel Inorganic materials 0.000 claims 11
- 239000002245 particle Substances 0.000 claims 7
- 239000003446 ligand Substances 0.000 claims 5
- 230000027455 binding Effects 0.000 claims 4
- 125000004429 atoms Chemical group 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 238000005755 formation reaction Methods 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- UVKXJAUUKPDDNW-UHFFFAOYSA-N pent-3-enenitrile Chemical compound CC=CCC#N UVKXJAUUKPDDNW-UHFFFAOYSA-N 0.000 claims 1
- OAICVXFJPJFONN-UHFFFAOYSA-N phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 1
- 229910052698 phosphorus Inorganic materials 0.000 claims 1
- 239000011574 phosphorus Substances 0.000 claims 1
Claims (3)
- ニッケル粒子形態が少なくとも１ｍ2／ｇｍのＢＥＴ比表面積を有し、ニッケル結晶子の少なくとも１０％が２０ｎｍ未満であるサイズ（Ｃ１０）を有し、ニッケル結晶子が１００ｎｍ以下の平均結晶子径を有し、ニッケル結晶子径分布範囲が１．０より大きい、ニッケル結晶子を含むニッケル粒子形態。
- ４〜５重量％のニッケル粒子形態を５．２５重量％の配位子（Ｖ）及び６３００ｐｐｍのＺｎＣｌ2を含む３−ペンテンニトリルと混合する場合、配位子（Ｖ）とニッケル粒子形態のニッケル原子との間の錯体形成の平衡に２時間以内に到達し、配位子（Ｖ）が以下の式を有する、
- １つ又は複数の二座リン含有配位子及び請求項１に記載のニッケル粒子形態を含む有機溶液を混合するステップを含む、触媒活性を有するゼロ価ニッケル−配位子錯体を調製する方法。
Applications Claiming Priority (11)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161495784P | 2011-06-10 | 2011-06-10 | |
| US61/495,784 | 2011-06-10 | ||
| US201161496142P | 2011-06-13 | 2011-06-13 | |
| US61/496,142 | 2011-06-13 | ||
| US201161503917P | 2011-07-01 | 2011-07-01 | |
| US61/503,917 | 2011-07-01 | ||
| US201161507159P | 2011-07-13 | 2011-07-13 | |
| US61/507,159 | 2011-07-13 | ||
| US201161552473P | 2011-10-28 | 2011-10-28 | |
| US61/552,473 | 2011-10-28 | ||
| PCT/US2012/040466 WO2012170297A2 (en) | 2011-06-10 | 2012-06-01 | Nickel form for preparation of catalytic nickel-ligand complexes |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2014523480A JP2014523480A (ja) | 2014-09-11 |
| JP2014523480A5 true JP2014523480A5 (ja) | 2015-07-09 |
| JP6054957B2 JP6054957B2 (ja) | 2016-12-27 |
Family
ID=46321464
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014514512A Active JP6054957B2 (ja) | 2011-06-10 | 2012-06-01 | ニッケル結晶子を含む粒子状ニッケル |
| JP2014514513A Ceased JP2014522408A (ja) | 2011-06-10 | 2012-06-01 | 金属−配位子触媒形成の改善 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014514513A Ceased JP2014522408A (ja) | 2011-06-10 | 2012-06-01 | 金属−配位子触媒形成の改善 |
Country Status (7)
| Country | Link |
|---|---|
| US (3) | US9981257B2 (ja) |
| EP (2) | EP2718015A2 (ja) |
| JP (2) | JP6054957B2 (ja) |
| KR (2) | KR20140036307A (ja) |
| CN (4) | CN107020150B (ja) |
| HK (1) | HK1198960A1 (ja) |
| WO (2) | WO2012170300A2 (ja) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2512673B1 (en) | 2009-12-18 | 2016-09-28 | Invista Technologies S.à.r.l. | Nickel metal compositions and nickel complexes derived from basic nickel carbonates |
| US8937198B2 (en) | 2010-07-07 | 2015-01-20 | Invista North America S.A.R.L. | Process for making nitriles |
| CN103080120B (zh) | 2010-09-07 | 2016-06-01 | 因温斯特技术公司 | 制备镍磷配体配合物 |
| KR20140036307A (ko) * | 2011-06-10 | 2014-03-25 | 인비스타 테크놀러지스 에스.에이.알.엘. | 니켈 금속-리간드 촉매 형성에서의 향상 |
| WO2012170537A2 (en) * | 2011-06-10 | 2012-12-13 | Invista Technologies S.A.R.L. | Calcination and reduction process including a fluidizing bed reactor |
| KR20150045410A (ko) * | 2012-06-01 | 2015-04-28 | 인비스타 테크놀러지스 에스.에이 알.엘. | 안정화된 히드로시안화 리간드 조성물 |
| CN107073586B (zh) * | 2014-07-02 | 2020-06-16 | 英威达纺织（英国）有限公司 | 镍金属粒子制造 |
| US10143999B2 (en) | 2014-11-20 | 2018-12-04 | Invista North America S.A R.L. | Nickel having high ligand-complexation activity and methods for making the same |
| US10307825B2 (en) * | 2015-01-30 | 2019-06-04 | Sumitomo Electric Industries, Ltd. | Metal powder, ink, sintered body, substrate for printed circuit board, and method for manufacturing metal powder |
| CN106693897B (zh) * | 2015-11-12 | 2020-03-10 | 中国科学院大连化学物理研究所 | 一种用于气体分离的多孔甲酸镍晶粒的合成方法 |
| US11406966B2 (en) | 2016-04-22 | 2022-08-09 | Inv Nylon Chemicals Americas, Llc | Heterogeneous catalyst process and nickel catalyst |
| CN108212162B (zh) * | 2016-12-22 | 2021-03-16 | 成功大学 | 纳米镍触媒及碳氧化物的氢化方法 |
| CN109225195B (zh) * | 2018-10-15 | 2021-09-28 | 吉林大学 | 纳米过渡金属硼化物催化剂及其在电催化水裂解制氢方面的应用 |
| CN110803723A (zh) * | 2019-12-03 | 2020-02-18 | 兰州理工大学 | 一种高纯二硫化镍纳米球的固相合成方法 |
| CN112756002B (zh) * | 2020-12-21 | 2022-01-25 | 四川大学 | 一种元素掺杂的过渡金属硫化物超薄片及其制备和应用 |
| CN113372239A (zh) * | 2021-07-21 | 2021-09-10 | 青岛普泰克化工有限公司 | 1,3-丁二烯与氰化氢反应制取c5单烯腈的方法 |
| US20230061536A1 (en) * | 2021-08-30 | 2023-03-02 | Surface Technology, Inc | Plating bath solutions |
| CN114433864B (zh) * | 2022-01-17 | 2024-06-18 | 淮安中顺环保科技有限公司 | 一种纳米镍粉的制备方法 |
| WO2023228075A1 (en) | 2022-05-23 | 2023-11-30 | Inv Nylon Chemicals Americas, Llc | Multidentate phosphite ligands, catalytic compositions containing such ligands, and catalytic processes utilizing such catalytic compositions |
| WO2023228077A1 (en) | 2022-05-23 | 2023-11-30 | Inv Nylon Chemicals Americas, Llc | Multidentate phosphite ligands, catalytic compositions containing such ligands, and catalytic processes utilizing such catalytic compositions |
| WO2024028716A1 (en) | 2022-08-02 | 2024-02-08 | Inv Nylon Chemicals Americas, Llc | Processes for producing nitriles and phosphorus-containing catalysts for use in such processes |
| WO2024028719A2 (en) | 2022-08-02 | 2024-02-08 | Inv Nylon Chemicals Americas, Llc | Bidentate phosphite ligands, catalytic compositions containing such ligands, and catalytic processes utilizing such catalytic compositions |
| WO2024028715A1 (en) | 2022-08-02 | 2024-02-08 | Inv Nylon Chemicals Americas, Llc | Processes for producing nitriles and phosphorus-containing catalysts for use in such processes |
| WO2024028717A1 (en) | 2022-08-02 | 2024-02-08 | Inv Nylon Chemicals Americas, Llc | Arsenic-containing ligands, catalytic compositions containing such ligands, and catalytic processes utilizing such catalytic compositions |
| WO2024028720A1 (en) | 2022-08-02 | 2024-02-08 | Inv Nylon Chemicals Americas, Llc | Bidentate phosphite ligands, catalytic compositions containing such ligands, and catalytic processes utilizing such catalytic compositions |
| WO2024028722A1 (en) | 2022-08-02 | 2024-02-08 | Inv Nylon Chemicals Americas, Llc | Bidentate phosphite ligands, catalytic compositions containing such ligands, and catalytic processes utilizing such catalytic compositions |
| WO2024028718A1 (en) | 2022-08-02 | 2024-02-08 | Inv Nylon Chemicals Americas, Llc | Bidfntate phosphite ligands. catalytic compositions containing such ligands. and catalytic processes utilizing such catalytic compositions |
Family Cites Families (67)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US496217A (en) | 1893-04-25 | Gaston boulet | ||
| GB191214607A (en) | 1912-06-22 | 1913-03-27 | Ernest Eugene Naef | Manufacture of Cyanogen Compounds from Calcium-cyanamide. |
| FR517898A (fr) | 1916-11-10 | 1921-05-14 | Hermann Berger | Perfectionnements apportés à la préparation des catalyseurs à base de nickel, tels, notamment, que ceux devant etre utilisés pour la transformation des acides gras non saturés et de leurs glycérides en composés saturés correspondants |
| GB255884A (en) | 1925-07-22 | 1927-04-28 | Ig Farbenindustrie Ag | Manufacture of nickel catalyst |
| NL79307C (ja) | 1951-06-14 | |||
| US3156580A (en) | 1960-01-29 | 1964-11-10 | Bell Aerospace Corp | Method of surface finishing metal surfaces with epoxy and acrylic resins |
| US3496215A (en) | 1965-11-23 | 1970-02-17 | Du Pont | Hydrocyanation of olefins using selected nickel phosphite catalysts |
| US3496217A (en) | 1967-05-23 | 1970-02-17 | Du Pont | Hydrocyanation of olefins |
| CA879003A (en) * | 1969-03-28 | 1971-08-24 | The International Nickel Company Of Canada | Separation of nickel from cobalt |
| US3655723A (en) | 1969-10-31 | 1972-04-11 | Du Pont | Hydrocyanation of olefins |
| US3631191A (en) | 1970-04-08 | 1971-12-28 | Du Pont | Synthesis of zero valent nickel-tetrakis triaryl phosphite complexes |
| US3766237A (en) | 1972-01-25 | 1973-10-16 | Du Pont | Hydrocyanation of olefins |
| CA970168A (en) | 1972-10-20 | 1975-07-01 | Vladimir N. Mackiw | Production of nickel powder from impure nickel compounds |
| US3847959A (en) * | 1972-10-25 | 1974-11-12 | Du Pont | Process of preparing a zerovalent nickel complex with organic phosphorus compounds |
| US3846461A (en) | 1972-10-25 | 1974-11-05 | Du Pont | Process of preparing a zerovalent nickel complex with organic phosphorus compounds |
| CA988306A (en) | 1973-04-09 | 1976-05-04 | International Nickel Company Of Canada | Reduction of nickel oxide |
| US3903120A (en) * | 1973-06-19 | 1975-09-02 | Du Pont | Preparation of zerovalent nickel complexes from elemental nickel |
| CA1038169A (en) * | 1975-06-25 | 1978-09-12 | Inco Limited | Carbonylation process |
| US4118342A (en) | 1977-06-21 | 1978-10-03 | Labofina S. A. | Process for producing catalysts |
| US4416825A (en) | 1982-02-23 | 1983-11-22 | E. I. Du Pont De Nemours & Co. | Preparation of zerovalent nickel complexes |
| NL191511C (nl) | 1983-01-20 | 1995-08-21 | Unilever Nv | Werkwijze voor de bereiding van een nikkel-bevattende katalysator. |
| US4946068A (en) | 1985-09-30 | 1990-08-07 | Amoco Corporation | Fresh catalyst container |
| US4749801A (en) | 1986-06-04 | 1988-06-07 | E. I. Du Pont De Nemours And Company | [Hexakis(pentenenitrilo)nickel II]bis-[μ-(cyano) bis(triphenylborane) (I)], its method of preparation and its use |
| BR9408151A (pt) | 1993-11-23 | 1997-08-05 | Du Pont | Processos de hidrocianação de precursor de catalisador |
| DE9405113U1 (de) | 1994-03-25 | 1994-05-26 | Mauser Werke Gmbh | Kunststoff-Behälter |
| ATE196745T1 (de) * | 1994-04-14 | 2000-10-15 | Du Pont | Nickel und phosphinebidentat enthaltende katalysatorzusammen- setzungen zur hydrocyanierung von monoolefinen |
| US5512696A (en) | 1995-07-21 | 1996-04-30 | E. I. Du Pont De Nemours And Company | Hydrocyanation process and multidentate phosphite and nickel catalyst composition therefor |
| FR2739378B1 (fr) * | 1995-09-29 | 1997-10-31 | Rhone Poulenc Fibres | Procede d'hydrocyanation de composes organiques a insaturation ethylenique |
| US5981722A (en) | 1995-11-20 | 1999-11-09 | Board Of Regents For The University Of Oklahoma | Trypsin inhibitors with insecticidal properties obtained from PENTACLETHRA MACROLOBA |
| US5787353A (en) * | 1996-03-26 | 1998-07-28 | Southeastern Technologies, Inc. | Process for the in situ recovery of chemical values from UF 6 gaseous diffusion process equipment |
| MY124170A (en) * | 1997-07-29 | 2006-06-30 | Invista Tech Sarl | Hydrocyanation processes and multidentate phosphite ligand and nickel catalyst compositions therefor |
| US6031120A (en) | 1997-07-29 | 2000-02-29 | E. I. Du Pont De Nemours And Company | Selective synthesis of organodiphosphite compounds |
| US7097890B1 (en) | 1998-07-31 | 2006-08-29 | Chevron Phillips Chemical Co. Lp | Polymer with pendent cyclic olefinic functions for oxygen scavenging packaging |
| EP0985448A1 (en) * | 1998-08-28 | 2000-03-15 | Engelhard Corporation | Nickel catalyst |
| US6048996A (en) * | 1999-08-26 | 2000-04-11 | E. I. Du Pont De Nemours And Company | Insoluble promoters for nickel-catalyzed hydrocyanation of monoolefins |
| EP1151814A4 (en) | 1999-11-12 | 2006-11-02 | Mitsui Mining & Smelting Co | NICKEL POWDER AND CONDUCTIVE PASTE |
| JP2001335326A (ja) | 2000-05-24 | 2001-12-04 | Sumitomo Metal Mining Co Ltd | 塩基性炭酸ニッケルの製造方法 |
| DE10136488A1 (de) | 2001-07-27 | 2003-02-06 | Basf Ag | Ni(O) enthaltendes Katalysatorsystem |
| US6893996B2 (en) * | 2001-11-26 | 2005-05-17 | Invista North America S.A.R.L. | Process for the preparation of a nickel/phosphorous ligand catalyst for olefin hydrocyanation |
| US6660876B2 (en) * | 2001-11-26 | 2003-12-09 | E. I. Du Pont De Nemours And Company | Phosphorus-containing compositions and their use in hydrocyanation, isomerization and hydroformylation reactions |
| TW593251B (en) | 2001-11-26 | 2004-06-21 | Du Pont | Process for preparing 3,3',5,5',6,6'-hexaalkyl-2,2'-biphenols, 3,3',4,4',5,5'-hexaalkyl-2,2'-biphenols and 3,3',4,4',5,5',6,6'-octaalkyl-2,2'-biphenols |
| EP1344770A1 (en) * | 2002-03-12 | 2003-09-17 | E.I. du Pont de Nemours and Company | Process for the hydrocyanation of butadiene |
| FR2842197A1 (fr) | 2002-07-15 | 2004-01-16 | Rhodia Polyamide Intermediates | Procede de fabrication de composes nitriles a partir de composes a insaturation ethylenique |
| US20040106815A1 (en) | 2002-12-02 | 2004-06-03 | Ritter Joachim C. | Selective synthesis of organophosphites |
| US6906218B2 (en) | 2002-12-18 | 2005-06-14 | Invista North America S.A.R.L. | Cyclohexane derivatives and methods for their preparation |
| FR2849027B1 (fr) | 2002-12-23 | 2005-01-21 | Rhodia Polyamide Intermediates | Procede de synthese de composes comprenant des fonctions nitriles a partir de composes a insaturations ethyleniques |
| US6897329B2 (en) * | 2003-01-14 | 2005-05-24 | Invista North America S.A.R.L. | Process for the preparation of nickel/phosphorous ligand catalyst for olefin hydrocyanation |
| FR2850966B1 (fr) * | 2003-02-10 | 2005-03-18 | Rhodia Polyamide Intermediates | Procede de fabrication de composes dinitriles |
| DE102004004682A1 (de) | 2004-01-29 | 2005-08-18 | Basf Ag | Verfahren zur Herstellung von Adipodinitril durch Hydrocyanierung von 1,3-Butadien |
| JP4490201B2 (ja) * | 2004-08-04 | 2010-06-23 | Ｄｏｗａホールディングス株式会社 | 凹凸表面をもつ微細な合金粒子粉末およびその製造法 |
| US7223714B2 (en) | 2004-11-04 | 2007-05-29 | Exxonmobil Chemical Patents Inc. | Method of transferring catalyst in a reaction system |
| US20060107792A1 (en) | 2004-11-19 | 2006-05-25 | Michael Collins | Method for producing fine, low bulk density, metallic nickel powder |
| SE529202C2 (sv) * | 2005-05-17 | 2007-05-29 | Sandvik Intellectual Property | Sätt att tillverka en agglomererad pulverblandning av en slurry och agglomererat pulver |
| US7854973B2 (en) | 2005-08-09 | 2010-12-21 | Sonoco Development, Inc. | Container and method for making container for oxygen-sensitive products |
| KR20080104315A (ko) | 2006-03-17 | 2008-12-02 | 인비스타 테크놀러지스 에스.에이.알.엘 | 염기성 첨가제를 사용한 처리에 의한 트리오르가노포스파이트의 정제 방법 |
| US7544851B2 (en) * | 2006-04-25 | 2009-06-09 | Exxonmobil Chemical Patents Inc. | Method of synthesizing aluminophosphate and silicoaluminophosphate molecular sieves |
| US7659422B2 (en) | 2006-07-14 | 2010-02-09 | Invista North America S.A.R.L. | Hydrocyanation process with reduced yield losses |
| MX2009005173A (es) * | 2006-11-17 | 2009-05-25 | Dow Global Technologies Inc | Proceso de hidroxidacion usando un catalizador peprarado a partir de un complejo de grupo oro. |
| JP5123755B2 (ja) * | 2008-06-25 | 2013-01-23 | 三井金属鉱業株式会社 | 高結晶性金属又は金属酸化物粒子の製造方法。 |
| GB2465467B (en) * | 2008-11-24 | 2013-03-06 | Smith International | A cutting element having an ultra hard material cutting layer and a method of manufacturing a cutting element having an ultra hard material cutting layer |
| CN101478044B (zh) | 2009-01-07 | 2012-05-30 | 厦门钨业股份有限公司 | 锂离子二次电池多元复合正极材料及其制备方法 |
| CN101733106B (zh) | 2009-12-16 | 2012-08-29 | 南京大学 | 一种担载型镍催化剂的制法 |
| EP2512673B1 (en) | 2009-12-18 | 2016-09-28 | Invista Technologies S.à.r.l. | Nickel metal compositions and nickel complexes derived from basic nickel carbonates |
| WO2011094411A1 (en) | 2010-01-28 | 2011-08-04 | Packgen | Collapsible drum with reinforced ends |
| CN103080120B (zh) | 2010-09-07 | 2016-06-01 | 因温斯特技术公司 | 制备镍磷配体配合物 |
| KR20140036307A (ko) * | 2011-06-10 | 2014-03-25 | 인비스타 테크놀러지스 에스.에이.알.엘. | 니켈 금속-리간드 촉매 형성에서의 향상 |
| WO2012170537A2 (en) | 2011-06-10 | 2012-12-13 | Invista Technologies S.A.R.L. | Calcination and reduction process including a fluidizing bed reactor |
-
2012
- 2012-06-01 KR KR1020147000651A patent/KR20140036307A/ko not_active Application Discontinuation
- 2012-06-01 CN CN201710015373.XA patent/CN107020150B/zh active Active
- 2012-06-01 KR KR1020147000605A patent/KR101878017B1/ko active IP Right Grant
- 2012-06-01 WO PCT/US2012/040497 patent/WO2012170300A2/en active Application Filing
- 2012-06-01 CN CN201280039036.XA patent/CN103889576B/zh active Active
- 2012-06-01 WO PCT/US2012/040466 patent/WO2012170297A2/en active Application Filing
- 2012-06-01 JP JP2014514512A patent/JP6054957B2/ja active Active
- 2012-06-01 CN CN201280039000.1A patent/CN103732323B/zh active Active
- 2012-06-01 EP EP12728885.0A patent/EP2718015A2/en active Pending
- 2012-06-01 JP JP2014514513A patent/JP2014522408A/ja not_active Ceased
- 2012-06-01 CN CN201510516300.XA patent/CN105148999B/zh active Active
- 2012-06-01 EP EP12728884.3A patent/EP2718014A2/en active Pending
- 2012-06-06 US US13/490,207 patent/US9981257B2/en active Active
- 2012-06-06 US US13/490,177 patent/US9050591B2/en active Active
-
2014
- 2014-12-17 HK HK14112675.1A patent/HK1198960A1/xx unknown
-
2015
- 2015-03-26 US US14/669,121 patent/US9687836B2/en active Active
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