JP2014515422A5 - - Google Patents
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- Publication number
- JP2014515422A5 JP2014515422A5 JP2014512955A JP2014512955A JP2014515422A5 JP 2014515422 A5 JP2014515422 A5 JP 2014515422A5 JP 2014512955 A JP2014512955 A JP 2014512955A JP 2014512955 A JP2014512955 A JP 2014512955A JP 2014515422 A5 JP2014515422 A5 JP 2014515422A5
- Authority
- JP
- Japan
- Prior art keywords
- article
- fluoropolymer
- irradiated
- ppm
- fluoride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920002313 fluoropolymer Polymers 0.000 claims description 42
- 239000004811 fluoropolymer Substances 0.000 claims description 42
- 239000000203 mixture Substances 0.000 claims description 27
- 150000003839 salts Chemical class 0.000 claims description 21
- -1 fluoride ions Chemical class 0.000 claims description 17
- 229910052751 metal Inorganic materials 0.000 claims description 17
- 239000002184 metal Substances 0.000 claims description 17
- 230000005855 radiation Effects 0.000 claims description 17
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 15
- 229910044991 metal oxide Inorganic materials 0.000 claims description 15
- 150000004706 metal oxides Chemical class 0.000 claims description 14
- 229920000642 polymer Polymers 0.000 claims description 13
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- 239000011575 calcium Substances 0.000 claims description 10
- 229910052791 calcium Inorganic materials 0.000 claims description 10
- 150000001768 cations Chemical class 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 9
- 239000002033 PVDF binder Substances 0.000 claims description 8
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims description 8
- 239000008227 sterile water for injection Substances 0.000 claims description 6
- 239000011701 zinc Substances 0.000 claims description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 5
- 150000001450 anions Chemical class 0.000 claims description 5
- 239000012530 fluid Substances 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 239000011777 magnesium Substances 0.000 claims description 5
- 229910052749 magnesium Inorganic materials 0.000 claims description 5
- 239000011591 potassium Substances 0.000 claims description 5
- 229910052700 potassium Inorganic materials 0.000 claims description 5
- 239000011734 sodium Substances 0.000 claims description 5
- 229910052708 sodium Inorganic materials 0.000 claims description 5
- 239000000243 solution Substances 0.000 claims description 5
- 229910052725 zinc Inorganic materials 0.000 claims description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 4
- 229910019142 PO4 Inorganic materials 0.000 claims description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims 3
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 claims 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims 3
- 239000010452 phosphate Substances 0.000 claims 3
- 229920001577 copolymer Polymers 0.000 claims 2
- NBMMYUUHZVNLKL-UHFFFAOYSA-N ethene;1,1,2-trifluoroethene Chemical group C=C.FC=C(F)F NBMMYUUHZVNLKL-UHFFFAOYSA-N 0.000 claims 2
- 229920001519 homopolymer Polymers 0.000 claims 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 2
- 230000005865 ionizing radiation Effects 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 claims 1
- 230000001954 sterilising effect Effects 0.000 description 9
- 238000004659 sterilization and disinfection Methods 0.000 description 8
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 7
- 229910052731 fluorine Inorganic materials 0.000 description 3
- 239000011737 fluorine Substances 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 239000012633 leachable Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000011787 zinc oxide Substances 0.000 description 3
- 206010073306 Exposure to radiation Diseases 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000010894 electron beam technology Methods 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 210000002966 serum Anatomy 0.000 description 2
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 238000010504 bond cleavage reaction Methods 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 150000004675 formic acid derivatives Chemical class 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- AVVSGTOJTRSKRL-UHFFFAOYSA-L hydrogen phosphate;lead(2+) Chemical compound [Pb+2].OP([O-])([O-])=O AVVSGTOJTRSKRL-UHFFFAOYSA-L 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 239000011775 sodium fluoride Substances 0.000 description 1
- 235000013024 sodium fluoride Nutrition 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161489826P | 2011-05-25 | 2011-05-25 | |
| US61/489,826 | 2011-05-25 | ||
| PCT/US2012/039050 WO2012162341A1 (en) | 2011-05-25 | 2012-05-23 | Irradiated fluoropolymer articles having low leachable fluoride ions |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2017051717A Division JP6374047B2 (ja) | 2011-05-25 | 2017-03-16 | 浸出可能なフルオリドイオン含量が低い、放射線照射されたフルオロポリマー物品 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2014515422A JP2014515422A (ja) | 2014-06-30 |
| JP2014515422A5 true JP2014515422A5 (enExample) | 2015-07-09 |
Family
ID=47217683
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014512955A Pending JP2014515422A (ja) | 2011-05-25 | 2012-05-23 | 浸出可能なフルオリドイオン含量が低い、放射線照射されたフルオロポリマー物品 |
| JP2017051717A Active JP6374047B2 (ja) | 2011-05-25 | 2017-03-16 | 浸出可能なフルオリドイオン含量が低い、放射線照射されたフルオロポリマー物品 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2017051717A Active JP6374047B2 (ja) | 2011-05-25 | 2017-03-16 | 浸出可能なフルオリドイオン含量が低い、放射線照射されたフルオロポリマー物品 |
Country Status (5)
| Country | Link |
|---|---|
| US (2) | US9120912B2 (enExample) |
| EP (1) | EP2714789B1 (enExample) |
| JP (2) | JP2014515422A (enExample) |
| CN (1) | CN103597021B (enExample) |
| WO (1) | WO2012162341A1 (enExample) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9120912B2 (en) * | 2011-05-25 | 2015-09-01 | Arkema Inc. | Irradiated fluoropolymer articles having low leachable fluoride ions |
| EP3052533B1 (en) | 2013-09-30 | 2019-06-26 | Arkema, Inc. | Heat stabilized polyvinylidene fluoride polymer composition |
| US9982812B2 (en) * | 2014-03-10 | 2018-05-29 | Saint-Gobain Performance Plastics Corporation | Multilayer flexible tube and methods for making same |
| US10295089B2 (en) | 2014-03-10 | 2019-05-21 | Saint-Gobain Performance Plastics Corporation | Multilayer flexible tube and methods for making same |
| US9728298B2 (en) * | 2015-06-26 | 2017-08-08 | Daikin America, Inc. | Radiation crosslinked fluoropolymer compositions containing low level of extractable fluorides |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3962373A (en) * | 1974-10-21 | 1976-06-08 | Allied Chemical Corporation | Compositions of 3,3,3-trifluoro-2-trifluoromethyl propene/vinylidene fluoride copolymer and polytetrafluoroethylene |
| US5516564A (en) | 1993-04-28 | 1996-05-14 | Costar Corporation | Sterile irradiated hydrophobic pipette tip |
| JP3730533B2 (ja) * | 2001-05-02 | 2006-01-05 | 日本原子力研究所 | フッ素樹脂の改質方法 |
| WO2003029306A1 (en) | 2001-09-26 | 2003-04-10 | Nichias Corporation | Moldings of fluororubbers and process for their production |
| JP3927088B2 (ja) * | 2002-07-15 | 2007-06-06 | 旭硝子株式会社 | ふっ素ゴム成形体及びその製造方法 |
| JP2004263038A (ja) | 2003-02-28 | 2004-09-24 | Nichias Corp | フッ素ゴム成形体及びその製造方法 |
| FR2852016B1 (fr) | 2003-03-03 | 2006-07-07 | Atofina | Procede de fabrication de pvdf thermiquement stable |
| FR2852017B1 (fr) | 2003-03-03 | 2005-04-22 | Atofina | Procede de fabrication de pvdf thermiquement stable |
| US7192646B2 (en) | 2003-06-04 | 2007-03-20 | The Goodyear Tire & Rubber Company | Hose construction containing fluoroelastomer composition and fluoroplastic barrier |
| US7241817B2 (en) | 2003-06-06 | 2007-07-10 | Arkema France | Process for grafting a fluoropolymer and multilayer structures comprising this grafted polymer |
| US7642313B2 (en) | 2004-06-25 | 2010-01-05 | Arkema Inc. | Fluoropolymer with inorganic fluoride filler |
| FR2876626B1 (fr) * | 2004-10-19 | 2007-01-05 | Arkema Sa | Utilisation d'un polymere fluore pour proteger la surface d' un materiau inorganique contre la corrosion |
| US20060246008A1 (en) | 2005-04-29 | 2006-11-02 | Jenkins Lauri L | Process for the formulation of therapeutic protein |
| US20060243666A1 (en) | 2005-04-29 | 2006-11-02 | Jenkins Lauri L | Process for the preparation of protein separation solution |
| JP5189728B2 (ja) * | 2005-06-08 | 2013-04-24 | 日本バルカー工業株式会社 | フッ素ゴムシール材 |
| US7514480B2 (en) | 2005-06-21 | 2009-04-07 | Arkema Inc. | Low level radiation treatment for improving polymer properties |
| JP5352238B2 (ja) | 2005-12-29 | 2013-11-27 | アーケマ・インコーポレイテッド | 多層フルオロポリマーフィルム |
| WO2007122599A2 (en) * | 2006-04-21 | 2007-11-01 | Arkema France | Multilayer structure having a grafted polyvinylidene fluoride blend layer |
| US8357739B2 (en) * | 2006-12-11 | 2013-01-22 | Sabic Innovative Plastics Ip B.V. | Low fluoride thermoplastic composition, method of manufacture and product made therefrom |
| US9120912B2 (en) * | 2011-05-25 | 2015-09-01 | Arkema Inc. | Irradiated fluoropolymer articles having low leachable fluoride ions |
-
2012
- 2012-05-23 US US14/118,981 patent/US9120912B2/en active Active
- 2012-05-23 CN CN201280025362.5A patent/CN103597021B/zh not_active Expired - Fee Related
- 2012-05-23 EP EP12789894.8A patent/EP2714789B1/en active Active
- 2012-05-23 JP JP2014512955A patent/JP2014515422A/ja active Pending
- 2012-05-23 WO PCT/US2012/039050 patent/WO2012162341A1/en not_active Ceased
-
2015
- 2015-07-24 US US14/808,220 patent/US9403960B2/en active Active
-
2017
- 2017-03-16 JP JP2017051717A patent/JP6374047B2/ja active Active
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