JP2014515419A - 射出成形品およびその製造方法 - Google Patents
射出成形品およびその製造方法 Download PDFInfo
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- JP2014515419A JP2014515419A JP2014512873A JP2014512873A JP2014515419A JP 2014515419 A JP2014515419 A JP 2014515419A JP 2014512873 A JP2014512873 A JP 2014512873A JP 2014512873 A JP2014512873 A JP 2014512873A JP 2014515419 A JP2014515419 A JP 2014515419A
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- poly
- arylene ether
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- 238000002347 injection Methods 0.000 title claims abstract description 33
- 238000004519 manufacturing process Methods 0.000 title description 3
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- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 112
- 239000000203 mixture Substances 0.000 claims abstract description 90
- 239000003086 colorant Substances 0.000 claims abstract description 45
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- 239000003063 flame retardant Substances 0.000 claims abstract description 10
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 8
- 230000007547 defect Effects 0.000 claims abstract description 7
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- 238000000034 method Methods 0.000 claims description 45
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- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 12
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- 229920001519 homopolymer Polymers 0.000 claims description 11
- 239000000049 pigment Substances 0.000 claims description 11
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 claims description 11
- 229920000638 styrene acrylonitrile Polymers 0.000 claims description 11
- 239000006229 carbon black Substances 0.000 claims description 10
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 9
- 239000005977 Ethylene Substances 0.000 claims description 9
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- 229920002857 polybutadiene Polymers 0.000 claims description 6
- 238000003860 storage Methods 0.000 claims description 4
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- 229920005989 resin Polymers 0.000 description 24
- 239000011347 resin Substances 0.000 description 24
- DDTHMESPCBONDT-UHFFFAOYSA-N 4-(4-oxocyclohexa-2,5-dien-1-ylidene)cyclohexa-2,5-dien-1-one Chemical compound C1=CC(=O)C=CC1=C1C=CC(=O)C=C1 DDTHMESPCBONDT-UHFFFAOYSA-N 0.000 description 17
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 15
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- 125000001183 hydrocarbyl group Chemical group 0.000 description 14
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- NXXYKOUNUYWIHA-UHFFFAOYSA-N 2,6-Dimethylphenol Chemical compound CC1=CC=CC(C)=C1O NXXYKOUNUYWIHA-UHFFFAOYSA-N 0.000 description 10
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- 238000000465 moulding Methods 0.000 description 8
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- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 7
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 7
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- 230000001590 oxidative effect Effects 0.000 description 7
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 7
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 6
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 6
- 229920005996 polystyrene-poly(ethylene-butylene)-polystyrene Polymers 0.000 description 6
- 238000000926 separation method Methods 0.000 description 6
- 239000004408 titanium dioxide Substances 0.000 description 6
- OWICEWMBIBPFAH-UHFFFAOYSA-N (3-diphenoxyphosphoryloxyphenyl) diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=C(OP(=O)(OC=2C=CC=CC=2)OC=2C=CC=CC=2)C=CC=1)(=O)OC1=CC=CC=C1 OWICEWMBIBPFAH-UHFFFAOYSA-N 0.000 description 5
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- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 125000002723 alicyclic group Chemical group 0.000 description 4
- 150000004982 aromatic amines Chemical class 0.000 description 4
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- 238000011067 equilibration Methods 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 235000021317 phosphate Nutrition 0.000 description 4
- 150000003097 polyterpenes Chemical class 0.000 description 4
- 150000003505 terpenes Chemical class 0.000 description 4
- 235000007586 terpenes Nutrition 0.000 description 4
- QDRFIDSUGRGGAY-UHFFFAOYSA-N 4-(3,5-dimethyl-4-oxocyclohexa-2,5-dien-1-ylidene)-2,6-dimethylcyclohexa-2,5-dien-1-one Chemical compound C1=C(C)C(=O)C(C)=CC1=C1C=C(C)C(=O)C(C)=C1 QDRFIDSUGRGGAY-UHFFFAOYSA-N 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 125000004122 cyclic group Chemical group 0.000 description 3
- MIHINWMALJZIBX-UHFFFAOYSA-N cyclohexa-2,4-dien-1-ol Chemical class OC1CC=CC=C1 MIHINWMALJZIBX-UHFFFAOYSA-N 0.000 description 3
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 description 3
- 238000005227 gel permeation chromatography Methods 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
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- 125000005842 heteroatom Chemical group 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000005011 phenolic resin Substances 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 239000012521 purified sample Substances 0.000 description 3
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000004711 α-olefin Substances 0.000 description 3
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 description 2
- IANQTJSKSUMEQM-UHFFFAOYSA-N 1-benzofuran Chemical compound C1=CC=C2OC=CC2=C1 IANQTJSKSUMEQM-UHFFFAOYSA-N 0.000 description 2
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Chemical compound C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 2
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 125000004648 C2-C8 alkenyl group Chemical group 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 241000255777 Lepidoptera Species 0.000 description 2
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- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 2
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- JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 description 2
- 238000005984 hydrogenation reaction Methods 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
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- DMDRBXCDTZRMHZ-UHFFFAOYSA-N 1,4-bis(2,4,6-trimethylanilino)anthracene-9,10-dione Chemical compound CC1=CC(C)=CC(C)=C1NC(C=1C(=O)C2=CC=CC=C2C(=O)C=11)=CC=C1NC1=C(C)C=C(C)C=C1C DMDRBXCDTZRMHZ-UHFFFAOYSA-N 0.000 description 1
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- NQAJBKZEQYYFGK-UHFFFAOYSA-N 2-[[4-[2-(4-cyclohexylphenoxy)ethyl-ethylamino]-2-methylphenyl]methylidene]propanedinitrile Chemical compound C=1C=C(C=C(C#N)C#N)C(C)=CC=1N(CC)CCOC(C=C1)=CC=C1C1CCCCC1 NQAJBKZEQYYFGK-UHFFFAOYSA-N 0.000 description 1
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- MSFGZHUJTJBYFA-UHFFFAOYSA-M sodium dichloroisocyanurate Chemical compound [Na+].ClN1C(=O)[N-]C(=O)N(Cl)C1=O MSFGZHUJTJBYFA-UHFFFAOYSA-M 0.000 description 1
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- LIPMRGQQBZJCTM-UHFFFAOYSA-N tris(2-propan-2-ylphenyl) phosphate Chemical compound CC(C)C1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C(C)C)OC1=CC=CC=C1C(C)C LIPMRGQQBZJCTM-UHFFFAOYSA-N 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
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- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
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- B29K2071/00—Use of polyethers, e.g. PEEK, i.e. polyether-etherketone or PEK, i.e. polyetherketone or derivatives thereof, as moulding material
- B29K2071/12—PPO, i.e. polyphenylene oxide; PPE, i.e. polyphenylene ether
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Abstract
【選択図】図1
Description
グレー色のポリ(アリーレンエーテル)組成物を用いて、大型の、頂部開放の長方形ボックスを射出成形すると、射出成形機のゲートに関連した位置に黒い環が現れた。図1は黒い環が現れたボックス面の図である。この黒い環の発生原因については明らかではなかった。後述の実施例に記載の実験により、成形用組成物中の黒い着色剤の濃度を下げることによって、この黒い環が低減でき得ることがわかった。いかなる特別の機構仮説にも束縛されることなく、本発明者は、バルク組成に対する過剰の黒色顔料ではなく、白色顔料の局部的不足に付随すると考える。射出成形プロセスによって、成形ゲート周囲に個々の着色剤の分離(すなわち、空間的分離)が起こると考える理由がないことを考慮すれば、これは驚くべきことである。
式中、R1は、少なくとも1つが未置換または置換C6−C24アリールであることを条件として、それぞれ独立にC1−C24ヒドロカルビルである。一部の実施形態では、R1はそれぞれ独立に、未置換または置換C6−C24アリールである。一部の実施形態では、該アリールホスファイトは、トリス(2,4−ジ−tert−ブチルフェニル)ホスファイト(CAS登録番号第31570−04−4号)を含む。アリールホスファイトが該ポリ(アリーレンエーテル)組成物中に存在する場合、その量は、ポリ(アリーレンエーテル)組成物の合計質量に対して約0.1〜約1質量%であり、具体的には約0.3〜約0.5質量%である。
実施例1および2、比較実施例1〜8
Claims (14)
- ポリ(アリーレンエーテル)組成物を射出成形して射出成形品を形成するステップを備えた、射出成形品における美的欠陥の低減方法であって、
前記射出成形品の一部は、少なくとも10cmの第1の寸法と、少なくとも10cmの第2の寸法と、1cm以下の第3の寸法と、を有し、
前記ポリ(アリーレンエーテル)組成物は、その合計質量に対して、25℃のクロロホルム中で測定した固有粘度が約0.3〜約0.55dL/gの、約50〜約70質量%のポリ(アリーレンエーテル)と、ポリスチレンとポリブタジエンとを含む、約12〜約30質量%のゴム変性ポリスチレンと、約5〜約25質量%の有機リン酸エステル難燃剤と、合計量が約0.3〜約1質量%の第1の着色剤および第2の着色剤と、を含むことを特徴とする方法。 - 前記第1の着色剤は白色顔料を含み、第2の着色剤は黒色顔料を含むことを特徴とする請求項1に記載の方法。
- 前記第1の着色剤は約0.25〜約1.0質量%の白色顔料を含み、第2の着色剤は約0.04〜約0.1質量%のカーボンブラックを含むことを特徴とする請求項1に記載の方法。
- 前記ポリ(アリーレンエーテル)組成物は、0.2質量%以下のポリ(エチレン酸化物)−ポリ(プロピレン酸化物)ブロックコポリマーを含むことを特徴とする請求項1に記載の方法。
- 前記ポリ(アリーレンエーテル)組成物は、約1〜約5質量%の炭化水素樹脂をさらに含むことを特徴とする請求項1に記載の方法。
- 前記ポリ(アリーレンエーテル)組成物は、約0.025〜約0.4質量%のポリ(スチレン−アクリロニトリル)−カプセル化ポリテトラフルオロエチレンをさらに含むことを特徴とする請求項1に記載の方法。
- 前記ポリ(アリーレンエーテル)組成物は、約0.5〜約4質量%のエチレンホモポリマーをさらに含むことを特徴とする請求項1乃至請求項6のいずれかに記載の方法。
- 前記ポリ(アリーレンエーテル)組成物は、約1〜約4質量%の、アルケニル芳香族化合物と共役ジエンとの水素化ブロックコポリマーをさらに含むことを特徴とする請求項1乃至請求項6のいずれかに記載の方法。
- 前記射出成形は、バレル温度が約270〜約310℃、型温度が約45〜約70℃の射出成形機を使用するステップを備えることを特徴とする請求項1乃至請求項6のいずれかに記載の方法。
- 前記射出成形品は、鉛酸蓄電池用のケースであることを特徴とする請求項1乃至請求項6のいずれかに記載の方法。
- 前記射出成形品表面のCIE1976L*a*b*パラメータは、ASTM D2244−09bに準拠して測定して、L*が約25〜約45であり、a*が−10〜約10であり、b*が−10〜約10であることを特徴とする請求項1乃至請求項6のいずれかに記載の方法。
- 前記第1の着色剤は約0.25〜約1.0質量%の白色顔料を含み、第2の着色剤は約0.04〜約0.1質量%のカーボンブラックを含み;
前記ポリ(アリーレンエーテル)組成物は、0.2質量%以下のポリ(エチレン酸化物)−ポリ(プロピレン酸化物)ブロックコポリマーを含み;
前記ポリ(アリーレンエーテル)組成物はさらに、約1〜約5質量%の炭化水素樹脂と、約0.025〜約0.4質量%のポリ(スチレン−アクリロニトリル)−カプセル化ポリテトラフルオロエチレンと、約0.5〜約4質量%のエチレンホモポリマーと、約1〜約4質量%の、アルケニル芳香族化合物と共役ジエンとの水素化ブロックコポリマーと、を含み;
前記射出成形は、バレル温度が約270〜約310℃、型温度が約45〜約70℃の射出成形機を使用するステップを備え;
前記射出成形品は、鉛酸蓄電池用のケースであることを特徴とする請求項1に記載の方法。 - 請求項1乃至請求項6のいずれかに記載の方法で形成されたことを特徴とする射出成形品。
- 鉛酸蓄電池用のケースであることを特徴とする請求項13に記載の射出成形品。
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WO2024048546A1 (ja) * | 2022-09-01 | 2024-03-07 | グローバルポリアセタール株式会社 | ポリフェニレンエーテル系樹脂組成物および成形品 |
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US8524137B2 (en) | 2013-09-03 |
EP2714802B1 (en) | 2020-04-29 |
EP2714802A4 (en) | 2015-09-09 |
EP2714802A2 (en) | 2014-04-09 |
WO2012162017A3 (en) | 2013-03-21 |
KR101757689B1 (ko) | 2017-07-14 |
CN103562313A (zh) | 2014-02-05 |
KR20140027286A (ko) | 2014-03-06 |
JP5932983B2 (ja) | 2016-06-08 |
WO2012162017A2 (en) | 2012-11-29 |
CN103562313B (zh) | 2016-06-01 |
US20120298548A1 (en) | 2012-11-29 |
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