JP2014512949A - エチレンをエチレンオキシドに酸化するための触媒の製造方法 - Google Patents

エチレンをエチレンオキシドに酸化するための触媒の製造方法 Download PDF

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JP2014512949A
JP2014512949A JP2014504438A JP2014504438A JP2014512949A JP 2014512949 A JP2014512949 A JP 2014512949A JP 2014504438 A JP2014504438 A JP 2014504438A JP 2014504438 A JP2014504438 A JP 2014504438A JP 2014512949 A JP2014512949 A JP 2014512949A
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catalyst
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JP2014512949A5 (enrdf_load_stackoverflow
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ローゼンダール,トビアス
モイレル,トルシュテン
カタリナ ドブネル,コルネリア
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BASF SE
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/30Loose or shaped packing elements, e.g. Raschig rings or Berl saddles, for pouring into the apparatus for mass or heat transfer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66Silver or gold
    • B01J23/68Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/683Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66Silver or gold
    • B01J23/68Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/688Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with manganese, technetium or rhenium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • B01J37/0203Impregnation the impregnation liquid containing organic compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • B01J37/0213Preparation of the impregnating solution
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D301/00Preparation of oxiranes
    • C07D301/02Synthesis of the oxirane ring
    • C07D301/03Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04Alumina
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30Details relating to random packing elements
    • B01J2219/302Basic shape of the elements
    • B01J2219/30223Cylinder
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30Details relating to random packing elements
    • B01J2219/304Composition or microstructure of the elements
    • B01J2219/30416Ceramic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30Details relating to random packing elements
    • B01J2219/304Composition or microstructure of the elements
    • B01J2219/30475Composition or microstructure of the elements comprising catalytically active material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30Details relating to random packing elements
    • B01J2219/31Size details
    • B01J2219/312Sizes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/50Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/55Cylinders or rings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/612Surface area less than 10 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66Pore distribution
    • B01J35/69Pore distribution bimodal
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Epoxy Compounds (AREA)
JP2014504438A 2011-04-14 2012-04-13 エチレンをエチレンオキシドに酸化するための触媒の製造方法 Pending JP2014512949A (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP11162381 2011-04-14
EP11162381.5 2011-04-14
PCT/IB2012/051833 WO2012140613A1 (de) 2011-04-14 2012-04-13 Verfahren zur herstellung eines katalysators zur oxidation von ethen zu ethylenoxid

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JP2014512949A true JP2014512949A (ja) 2014-05-29
JP2014512949A5 JP2014512949A5 (enrdf_load_stackoverflow) 2015-06-11

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EP (1) EP2696969A4 (enrdf_load_stackoverflow)
JP (1) JP2014512949A (enrdf_load_stackoverflow)
CN (1) CN103596677A (enrdf_load_stackoverflow)
WO (1) WO2012140613A1 (enrdf_load_stackoverflow)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015066513A (ja) * 2013-09-30 2015-04-13 株式会社日本触媒 アルキレンオキシド製造用触媒およびアルキレンオキシドの製造方法
JP2016165697A (ja) * 2015-03-10 2016-09-15 三菱化学株式会社 エチレンオキシド製造用触媒及びそれを用いたエチレンオキシドの製造方法
JP2016165696A (ja) * 2015-03-10 2016-09-15 三菱化学株式会社 エチレンオキシド製造用触媒及びそれを用いたエチレンオキシドの製造方法
JP2019524439A (ja) * 2016-08-08 2019-09-05 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se エチレンのエチレンオキシドへの酸化用触媒

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI808125B (zh) * 2018-02-07 2023-07-11 德商巴斯夫歐洲公司 有效地將乙烯氧化轉化為環氧乙烷之催化劑

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002248351A (ja) * 2001-02-27 2002-09-03 Mitsubishi Chemicals Corp レニウム含有触媒を用いるオレフィンオキシドの製造方法
JP2008509807A (ja) * 2004-08-12 2008-04-03 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー 形状化触媒の調製法、その触媒、およびその触媒の使用
JP2010537993A (ja) * 2007-08-27 2010-12-09 エスデー リ−ツェンスフェルヴェールトゥングスゲゼルシャフト エムベーハー ウント コー. カーゲー 酸化オレフィン製造工程

Family Cites Families (4)

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Publication number Priority date Publication date Assignee Title
CN1175932C (zh) * 2002-07-10 2004-11-17 中国石油化工股份有限公司 乙烯环氧化银催化剂的制备方法
US20040224841A1 (en) * 2003-05-07 2004-11-11 Marek Matusz Silver-containing catalysts, the manufacture of such silver-containing catalysts, and the use thereof
CA2524890C (en) * 2003-05-07 2012-09-11 Shell Internationale Research Maatschappij B.V. Silver-containing catalysts, the manufacture of such silver­containing catalysts, and the use thereof
WO2006102189A1 (en) * 2005-03-22 2006-09-28 Shell Internationale Research Maatschappij B.V. A reactor system and process for the manufacture of ethylene oxide

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002248351A (ja) * 2001-02-27 2002-09-03 Mitsubishi Chemicals Corp レニウム含有触媒を用いるオレフィンオキシドの製造方法
JP2008509807A (ja) * 2004-08-12 2008-04-03 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー 形状化触媒の調製法、その触媒、およびその触媒の使用
JP2010537993A (ja) * 2007-08-27 2010-12-09 エスデー リ−ツェンスフェルヴェールトゥングスゲゼルシャフト エムベーハー ウント コー. カーゲー 酸化オレフィン製造工程

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015066513A (ja) * 2013-09-30 2015-04-13 株式会社日本触媒 アルキレンオキシド製造用触媒およびアルキレンオキシドの製造方法
JP2016165697A (ja) * 2015-03-10 2016-09-15 三菱化学株式会社 エチレンオキシド製造用触媒及びそれを用いたエチレンオキシドの製造方法
JP2016165696A (ja) * 2015-03-10 2016-09-15 三菱化学株式会社 エチレンオキシド製造用触媒及びそれを用いたエチレンオキシドの製造方法
JP2019524439A (ja) * 2016-08-08 2019-09-05 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se エチレンのエチレンオキシドへの酸化用触媒
US11400437B2 (en) 2016-08-08 2022-08-02 Basf Se Catalyst for the oxidation of ethylene to ethylene oxide

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WO2012140613A1 (de) 2012-10-18
CN103596677A (zh) 2014-02-19
EP2696969A4 (de) 2014-11-26
EP2696969A1 (de) 2014-02-19

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