JP2014508220A - 鉄金属含有表面から錆を取り除く方法 - Google Patents
鉄金属含有表面から錆を取り除く方法 Download PDFInfo
- Publication number
- JP2014508220A JP2014508220A JP2013550611A JP2013550611A JP2014508220A JP 2014508220 A JP2014508220 A JP 2014508220A JP 2013550611 A JP2013550611 A JP 2013550611A JP 2013550611 A JP2013550611 A JP 2013550611A JP 2014508220 A JP2014508220 A JP 2014508220A
- Authority
- JP
- Japan
- Prior art keywords
- composition
- acid
- ferrous metal
- containing surface
- synthetic hectorite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
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- 239000002184 metal Substances 0.000 title claims abstract description 31
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- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 title claims abstract description 22
- 239000000203 mixture Substances 0.000 claims abstract description 70
- 238000000034 method Methods 0.000 claims abstract description 60
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000004927 clay Substances 0.000 claims abstract description 17
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- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 30
- 239000002253 acid Substances 0.000 claims description 18
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 16
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 12
- 229910000831 Steel Inorganic materials 0.000 claims description 10
- -1 aliphatic hydroxy acid Chemical class 0.000 claims description 10
- 239000010959 steel Substances 0.000 claims description 10
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 9
- 150000001735 carboxylic acids Chemical class 0.000 claims description 6
- NCNCGGDMXMBVIA-UHFFFAOYSA-L iron(ii) hydroxide Chemical compound [OH-].[OH-].[Fe+2] NCNCGGDMXMBVIA-UHFFFAOYSA-L 0.000 claims description 6
- 229910001209 Low-carbon steel Inorganic materials 0.000 claims description 5
- 235000014413 iron hydroxide Nutrition 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract description 7
- 239000007921 spray Substances 0.000 abstract description 5
- 230000009974 thixotropic effect Effects 0.000 abstract description 5
- 238000000518 rheometry Methods 0.000 abstract description 3
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- 238000003756 stirring Methods 0.000 description 15
- 229940094522 laponite Drugs 0.000 description 10
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- 239000003960 organic solvent Substances 0.000 description 3
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Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/08—Iron or steel
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/08—Iron or steel
- C23G1/088—Iron or steel solutions containing organic acids
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents ; Methods for using cleaning compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/20—Water-insoluble oxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/265—Carboxylic acids or salts thereof
-
- C11D2111/16—
Abstract
Description
本発明は、とりわけ、鉄金属(ferrous metal)含有表面から錆を取り除くための方法に関する。
加工中、または単に大気に曝される際に、金属酸化物層、すなわち錆は、しばしば鉄金属表面の全体または一部分に形成され、それにより、その外見および/またはさらなる使用のための適合性は損なわれる。1つの例は、様々な物品の製造において使用される鋼(例えば、軟鋼)である。従って、金属酸化物層を取り除くことがしばしば望ましい。慣習的に、この除去は、錆びついた金属表面を、強酸(例えば、硝酸、硫酸、塩酸、またはリン酸)で処理することによって達成されている。しかし、これらの高度に酸性で腐食性および苛性の化学物質は、しばしば、環境および安全性の観点から望ましくない。
特定の局面において、本発明は、鉄金属含有表面から錆を取り除くための方法に関する。上記方法は、上記表面を、(a)カルボン酸;(b)合成ヘクトライト粘土;および(c)水を含む組成物と接触させることを含む。本発明はまた、とりわけ、前述の方法によって処理された鉄金属含有表面に関する。
以下の詳細な説明の目的のために、本発明は、それと反対に明確に特定される場合を除いて、様々な代替のバリエーションおよびステップの順序を想定し得ることが理解されるべきである。さらに、任意の操作例中、または別段示される場合以外、例えば、本明細書および特許請求の範囲において使用される成分の量を表す全ての数字は、全ての例において、用語「約」によって修飾されるものとして理解されるべきである。従って、それと反対に示されない限り、以下の、本明細書および添付の特許請求の範囲に明記される数値パラメータは、本発明によって得られるべき所望される特性に依存して変化し得る近似値である。少なくとも、および特許請求の範囲への均等論の適用を制限する試みとしてではなく、各数値パラメータは、多くの報告された有効数字を考慮して、および通常の丸め技術を適用することによって少なくとも解釈されるべきである。
を含む化合物である。
5つの溶液を、表1に列挙される成分および量(グラム)を用いて調製した。3×4インチの露出した冷間圧延鋼パネル(ACT Test Panels LLC 273 Industrial Dr.Hillsdale,MI 49242から入手可能)を市販のアルカリ性クリーナー(PPG Industries,Inc.から市販のCK2010)でクリーニングし、次にそのパネルを塩スプレーチャンバーに4時間置くことによって、錆びついたパネルを調製した。上記パネルを脱イオン水ですすぎ、上記溶液の適用前に周囲条件下で空気乾燥させた。
水平面から約80°の角度で配置された1セットの錆びた鋼パネルの上に、上記溶液の各々の一部分をピペットによって適用した。2時間後、パネルを脱イオン水ですすぎ、取り除かれた錆のおおよその百分率を調査した。結果は、表2にある。
3つの溶液を、表3に列挙される成分および量(グラム)を用いて調製した。各実施例において、撹拌しながら、粘土を水の中へふるい入れた。Laponite RD含有物質は、混合後数分後に粘度の増大を示した。20分以内に、その溶液は、可視可能な粒子なく透明になった。ベントナイト溶液は、水への添加後、粘度において非常にわずかな変化を示し、その物質は、不透明な青緑色のままであった。カオリン物質は、添加後の粘度において全く変化を示さなかった。各粘土が加えられた後、溶液を約20分間撹拌し、クエン酸を加え、得られた混合物を約10分間撹拌した。
表5に列挙される成分および量(グラム)を用いて、同じ理論上の量の塩化物を含む3つの溶液を調製した。それぞれの場合において、製造者の推奨に従って、Laponite RDを水の中に混ぜた。次に、溶液を撹拌しながらクエン酸をゆっくりと加えた。次に、実施例3Aについて、撹拌しながら塩酸を滴下して加えた。次に、実施例3Bについて、撹拌しながら塩化ナトリウムを加えた。次に、実施例3Cについて、撹拌しながら塩化アンモニウムを加えた。
表6に列挙される成分および量(グラム)を用いて、同じ理論上の量のカルボン酸含有化合物を含む3つの溶液を調製した。それぞれの場合において、製造者の推奨に従って、Laponite RDを水の中に混ぜた。次に、溶液を撹拌しながら、酸をゆっくりと加えた。
Claims (20)
- 鉄金属含有表面から錆を取り除くための方法であって、該方法は、該表面を、
(a)カルボン酸;
(b)合成ヘクトライト粘土;および
(c)水
を含む組成物と接触させることを含む、方法。 - 請求項1の方法によって処理された鉄金属含有表面。
- 前記錆は、酸化鉄および/または水酸化鉄を含む、請求項1に記載の方法。
- 前記鉄金属は鋼を含む、請求項1に記載の方法。
- 前記鋼は軟鋼を含む、請求項1に記載の方法。
- 前記カルボン酸は、脂肪族ヒドロキシ酸を含む、請求項1に記載の方法。
- 前記脂肪族ヒドロキシル酸は、クエン酸を含む、請求項6に記載の方法。
- 前記カルボン酸は、前記組成物の総重量に基づいて、該組成物中に少なくとも10重量%の量、および30重量%以下の量で存在する、請求項1に記載の方法。
- 前記合成ヘクトライト粘土は、化学式NaO3(Mg,Li)3Si4O10(F,OH)2を有する、請求項1に記載の方法。
- 前記合成ヘクトライトの平均直径は、1ナノメートル〜30ナノメートルである、請求項1に記載の方法。
- 前記合成ヘクトライト粘土は、前記組成物の総重量に基づいて、該組成物中に少なくとも1重量%の量、および10重量%以下の量で存在する、請求項1に記載の方法。
- 前記組成物は、塩化物イオン源をさらに含む、請求項1に記載の方法。
- 前記組成物は、少なくとも1,000Pa・sの低ずり粘度、および0.50Pa・s以下の高ずり粘度を有する、請求項1に記載の方法。
- 前記組成物は、少なくとも4,000Pa・sの低ずり粘度、および0.01Pa・s以下の高ずり粘度を有する、請求項13に記載の方法。
- 前記組成物は、6.0以下のpHを有する、請求項1に記載の方法。
- 前記接触させることは、前記金属含有表面の上に前記組成物をスプレーすることを含む、請求項1に記載の方法。
- 前記鉄金属含有表面は、実質的に垂直に配向される、請求項17に記載の方法。
- 鉄金属含有表面から錆を取り除くための方法であって、該方法は、前記鉄金属含有表面の少なくとも一部分の上に組成物をスプレーにより適用することを含み、該組成物は、
(a)カルボン酸;
(b)合成ヘクトライト粘土;および
(c)水
を含み、
(i)該鉄金属含有表面は、実質的に垂直に配向され、(ii)該組成物は、少なくとも1,000Pa・sの低ずり粘度、および0.50Pa・s以下の高ずり粘度を有する、
方法。 - 前記組成物は、塩化物イオン源をさらに含む、請求項18に記載の方法。
- 前記カルボン酸は、クエン酸を含む、請求項18に記載の方法。
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US13/011,151 US20120189485A1 (en) | 2011-01-21 | 2011-01-21 | Methods of removing rust from a ferrous metal-containing surface |
US13/011,151 | 2011-01-21 | ||
PCT/US2012/022004 WO2012100146A1 (en) | 2011-01-21 | 2012-01-20 | Methods of removing rust from a ferrous metal-containing surface |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103898529A (zh) * | 2014-04-22 | 2014-07-02 | 东北大学 | 一种除锈方法 |
JP2017193768A (ja) * | 2016-04-22 | 2017-10-26 | ショーボンド建設株式会社 | 鋼材の下地処理方法、および下地処理剤 |
JP7426641B1 (ja) | 2023-09-18 | 2024-02-02 | スズカファイン株式会社 | 既設鋼材の錆の除去方法 |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8852357B2 (en) | 2011-09-30 | 2014-10-07 | Ppg Industries Ohio, Inc | Rheology modified pretreatment compositions and associated methods of use |
CN109628940B (zh) * | 2019-01-21 | 2021-11-12 | 常熟理工学院 | 一种多羟基苯甲酸型水基中性除锈剂 |
KR102166122B1 (ko) | 2020-04-13 | 2020-10-15 | 케이알건설 주식회사 | 강 교량의 녹 또는 페인트 제거방법 |
CN115768923A (zh) * | 2020-06-10 | 2023-03-07 | 凯密特尔有限责任公司 | 无膦酸盐的水性酸浸组合物及其用途 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20020037822A1 (en) * | 2000-07-19 | 2002-03-28 | Foley Peter Robert | Cleaning composition |
US20060079424A1 (en) * | 2004-09-23 | 2006-04-13 | Perry Stephen C | Buffered acid cleaner and method of production |
US20100056415A1 (en) * | 2006-12-05 | 2010-03-04 | Henkel G & Co. KGaA | Compositions for treating hard surfaces |
EP2166075A1 (en) * | 2008-09-23 | 2010-03-24 | The Procter and Gamble Company | Cleaning composition |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE622957A (ja) * | 1961-09-28 | |||
CN1070957A (zh) * | 1992-09-29 | 1993-04-14 | 王光宇 | 安全酸洗液 |
US6514350B1 (en) * | 2000-09-15 | 2003-02-04 | Ashland Inc. | Process for removing rust from metal surfaces |
GB2385597B (en) * | 2002-02-21 | 2004-05-12 | Reckitt Benckiser Inc | Hard surface cleaning compositions |
US20040149311A1 (en) * | 2002-11-15 | 2004-08-05 | The Procter & Gamble Company | Method for cleaning cookware and tableware with film-forming liquid dishwashing compositions, and compositions therefore |
US20060076299A1 (en) * | 2004-10-08 | 2006-04-13 | The Hong Kong University Of Science And Technology | Synthesis of bentonite clay-based iron nanocomposite and its use as a heterogeneous photo fenton catalyst |
CN100532649C (zh) * | 2006-02-27 | 2009-08-26 | 徐州正菱涂装有限公司 | 一种钢铁构件涂装的前处理工艺 |
CN101356260B (zh) * | 2006-07-31 | 2011-05-18 | 雷克特本克斯尔(英国)有限公司 | 改进的硬质表面清洁组合物 |
US20090197792A1 (en) * | 2008-02-05 | 2009-08-06 | Amcol International Corporation | Drip resistant acidic compositions for sprayable and non-sprayable application |
-
2011
- 2011-01-21 US US13/011,151 patent/US20120189485A1/en not_active Abandoned
-
2012
- 2012-01-20 TR TR2018/07940T patent/TR201807940T4/tr unknown
- 2012-01-20 JP JP2013550611A patent/JP5693754B2/ja not_active Expired - Fee Related
- 2012-01-20 CA CA2825284A patent/CA2825284A1/en not_active Abandoned
- 2012-01-20 MX MX2013008465A patent/MX2013008465A/es unknown
- 2012-01-20 BR BR112013018680A patent/BR112013018680A2/pt not_active Application Discontinuation
- 2012-01-20 AU AU2012207164A patent/AU2012207164B2/en not_active Ceased
- 2012-01-20 EP EP12706349.3A patent/EP2665845B1/en not_active Not-in-force
- 2012-01-20 SG SG2013055413A patent/SG192055A1/en unknown
- 2012-01-20 PL PL12706349T patent/PL2665845T3/pl unknown
- 2012-01-20 WO PCT/US2012/022004 patent/WO2012100146A1/en active Application Filing
- 2012-01-20 CN CN201280010699.9A patent/CN103415651B/zh not_active Expired - Fee Related
- 2012-01-20 KR KR1020137021700A patent/KR20130117853A/ko not_active Application Discontinuation
- 2012-01-20 ES ES12706349.3T patent/ES2666452T3/es active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20020037822A1 (en) * | 2000-07-19 | 2002-03-28 | Foley Peter Robert | Cleaning composition |
US20060079424A1 (en) * | 2004-09-23 | 2006-04-13 | Perry Stephen C | Buffered acid cleaner and method of production |
US20100056415A1 (en) * | 2006-12-05 | 2010-03-04 | Henkel G & Co. KGaA | Compositions for treating hard surfaces |
EP2166075A1 (en) * | 2008-09-23 | 2010-03-24 | The Procter and Gamble Company | Cleaning composition |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103898529A (zh) * | 2014-04-22 | 2014-07-02 | 东北大学 | 一种除锈方法 |
CN103898529B (zh) * | 2014-04-22 | 2017-02-15 | 东北大学 | 一种除锈方法 |
JP2017193768A (ja) * | 2016-04-22 | 2017-10-26 | ショーボンド建設株式会社 | 鋼材の下地処理方法、および下地処理剤 |
JP7426641B1 (ja) | 2023-09-18 | 2024-02-02 | スズカファイン株式会社 | 既設鋼材の錆の除去方法 |
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CA2825284A1 (en) | 2012-07-26 |
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ES2666452T3 (es) | 2018-05-04 |
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US20120189485A1 (en) | 2012-07-26 |
MX2013008465A (es) | 2013-12-06 |
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PL2665845T3 (pl) | 2018-08-31 |
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