JP2014503356A5 - - Google Patents
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- Publication number
- JP2014503356A5 JP2014503356A5 JP2013549616A JP2013549616A JP2014503356A5 JP 2014503356 A5 JP2014503356 A5 JP 2014503356A5 JP 2013549616 A JP2013549616 A JP 2013549616A JP 2013549616 A JP2013549616 A JP 2013549616A JP 2014503356 A5 JP2014503356 A5 JP 2014503356A5
- Authority
- JP
- Japan
- Prior art keywords
- substituted
- heteroatom
- aryl
- hydrocarbyl
- ligand
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 125000005842 heteroatom Chemical group 0.000 claims 31
- 150000001875 compounds Chemical class 0.000 claims 26
- 239000003446 ligand Substances 0.000 claims 23
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 20
- 125000003118 aryl group Chemical group 0.000 claims 14
- 125000000129 anionic group Chemical group 0.000 claims 13
- 125000000743 hydrocarbylene group Chemical group 0.000 claims 12
- 238000000034 method Methods 0.000 claims 12
- 229910052739 hydrogen Inorganic materials 0.000 claims 10
- 239000001257 hydrogen Substances 0.000 claims 10
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 9
- 125000000217 alkyl group Chemical group 0.000 claims 8
- 239000003054 catalyst Substances 0.000 claims 8
- 238000005865 alkene metathesis reaction Methods 0.000 claims 7
- 125000000753 cycloalkyl group Chemical group 0.000 claims 6
- -1 heteroalkenyl Chemical group 0.000 claims 6
- 230000007935 neutral effect Effects 0.000 claims 6
- 125000003107 substituted aryl group Chemical group 0.000 claims 6
- 229910052717 sulfur Inorganic materials 0.000 claims 6
- 229910002651 NO3 Inorganic materials 0.000 claims 5
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims 5
- 239000013522 chelant Substances 0.000 claims 5
- 229910052760 oxygen Inorganic materials 0.000 claims 5
- 229910052698 phosphorus Inorganic materials 0.000 claims 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 4
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 claims 4
- 125000003545 alkoxy group Chemical group 0.000 claims 4
- 125000002947 alkylene group Chemical group 0.000 claims 4
- 125000004104 aryloxy group Chemical group 0.000 claims 4
- 125000004429 atom Chemical group 0.000 claims 4
- 125000004122 cyclic group Chemical group 0.000 claims 4
- 125000002993 cycloalkylene group Chemical group 0.000 claims 4
- 125000000524 functional group Chemical group 0.000 claims 4
- 229910052723 transition metal Inorganic materials 0.000 claims 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 3
- 229910019142 PO4 Inorganic materials 0.000 claims 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims 3
- 150000001408 amides Chemical class 0.000 claims 3
- 150000001450 anions Chemical class 0.000 claims 3
- 150000007942 carboxylates Chemical class 0.000 claims 3
- 229910052736 halogen Inorganic materials 0.000 claims 3
- 150000002367 halogens Chemical class 0.000 claims 3
- 229910052757 nitrogen Inorganic materials 0.000 claims 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 3
- 239000010452 phosphate Substances 0.000 claims 3
- 229910052709 silver Inorganic materials 0.000 claims 3
- 239000004332 silver Substances 0.000 claims 3
- 229910052708 sodium Inorganic materials 0.000 claims 3
- 239000011734 sodium Substances 0.000 claims 3
- 150000003624 transition metals Chemical class 0.000 claims 3
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical group [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 2
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 claims 2
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 claims 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 2
- 125000005073 adamantyl group Chemical group C12(CC3CC(CC(C1)C3)C2)* 0.000 claims 2
- 150000001299 aldehydes Chemical class 0.000 claims 2
- 125000003342 alkenyl group Chemical group 0.000 claims 2
- 125000004453 alkoxycarbonyl group Chemical group 0.000 claims 2
- 125000004644 alkyl sulfinyl group Chemical group 0.000 claims 2
- 125000004414 alkyl thio group Chemical group 0.000 claims 2
- 150000001412 amines Chemical class 0.000 claims 2
- 229910052788 barium Inorganic materials 0.000 claims 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims 2
- 229910052792 caesium Inorganic materials 0.000 claims 2
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims 2
- 229910052791 calcium Inorganic materials 0.000 claims 2
- 239000011575 calcium Substances 0.000 claims 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- BWOVZCWSJFYBRM-UHFFFAOYSA-N carbononitridic isocyanate Chemical compound O=C=NC#N BWOVZCWSJFYBRM-UHFFFAOYSA-N 0.000 claims 2
- ULDHMXUKGWMISQ-UHFFFAOYSA-N carvone Chemical compound CC(=C)C1CC=C(C)C(=O)C1 ULDHMXUKGWMISQ-UHFFFAOYSA-N 0.000 claims 2
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims 2
- 150000002148 esters Chemical class 0.000 claims 2
- 150000004820 halides Chemical class 0.000 claims 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 2
- 150000002466 imines Chemical class 0.000 claims 2
- 229910052742 iron Inorganic materials 0.000 claims 2
- 150000002576 ketones Chemical class 0.000 claims 2
- 229910052744 lithium Inorganic materials 0.000 claims 2
- 229910052749 magnesium Inorganic materials 0.000 claims 2
- 239000011777 magnesium Substances 0.000 claims 2
- HZVOZRGWRWCICA-UHFFFAOYSA-N methanediyl Chemical compound [CH2] HZVOZRGWRWCICA-UHFFFAOYSA-N 0.000 claims 2
- 229910000073 phosphorus hydride Inorganic materials 0.000 claims 2
- 229910052700 potassium Inorganic materials 0.000 claims 2
- 239000011591 potassium Substances 0.000 claims 2
- 229910052701 rubidium Inorganic materials 0.000 claims 2
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 claims 2
- 229910000077 silane Inorganic materials 0.000 claims 2
- 229910052712 strontium Inorganic materials 0.000 claims 2
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims 2
- 125000005346 substituted cycloalkyl group Chemical group 0.000 claims 2
- 125000005717 substituted cycloalkylene group Chemical group 0.000 claims 2
- 229910052716 thallium Inorganic materials 0.000 claims 2
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 claims 2
- 229910052725 zinc Inorganic materials 0.000 claims 2
- 239000011701 zinc Substances 0.000 claims 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 1
- 239000005973 Carvone Substances 0.000 claims 1
- 238000010499 C–H functionalization reaction Methods 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 125000002252 acyl group Chemical group 0.000 claims 1
- 125000004423 acyloxy group Chemical group 0.000 claims 1
- 125000003302 alkenyloxy group Chemical group 0.000 claims 1
- 125000003282 alkyl amino group Chemical group 0.000 claims 1
- 125000005599 alkyl carboxylate group Chemical group 0.000 claims 1
- 125000004390 alkyl sulfonyl group Chemical group 0.000 claims 1
- 125000000304 alkynyl group Chemical group 0.000 claims 1
- 125000004397 aminosulfonyl group Chemical group NS(=O)(=O)* 0.000 claims 1
- 125000005161 aryl oxy carbonyl group Chemical group 0.000 claims 1
- 125000005163 aryl sulfanyl group Chemical group 0.000 claims 1
- 125000005135 aryl sulfinyl group Chemical group 0.000 claims 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims 1
- 150000001735 carboxylic acids Chemical class 0.000 claims 1
- 150000001768 cations Chemical class 0.000 claims 1
- 238000004132 cross linking Methods 0.000 claims 1
- 125000001316 cycloalkyl alkyl group Chemical group 0.000 claims 1
- 125000004472 dialkylaminosulfonyl group Chemical group 0.000 claims 1
- 125000004404 heteroalkyl group Chemical group 0.000 claims 1
- 125000001072 heteroaryl group Chemical group 0.000 claims 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 claims 1
- 150000002825 nitriles Chemical class 0.000 claims 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims 1
- 229910052762 osmium Inorganic materials 0.000 claims 1
- 125000005010 perfluoroalkyl group Chemical group 0.000 claims 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-M phenolate Chemical compound [O-]C1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-M 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 229910052707 ruthenium Inorganic materials 0.000 claims 1
- 125000001424 substituent group Chemical group 0.000 claims 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims 1
- 150000003462 sulfoxides Chemical class 0.000 claims 1
- 239000011593 sulfur Substances 0.000 claims 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims 1
- 125000004385 trihaloalkyl group Chemical group 0.000 claims 1
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 claims 1
Applications Claiming Priority (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161432849P | 2011-01-14 | 2011-01-14 | |
| US61/432,849 | 2011-01-14 | ||
| US201161433949P | 2011-01-18 | 2011-01-18 | |
| US61/433,949 | 2011-01-18 | ||
| US201161515262P | 2011-08-04 | 2011-08-04 | |
| US61/515,262 | 2011-08-04 | ||
| PCT/US2012/021609 WO2012097379A2 (en) | 2011-01-14 | 2012-01-17 | Z-selective olefin metathesis catalysts and their synthetic procedure |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2014503356A JP2014503356A (ja) | 2014-02-13 |
| JP2014503356A5 true JP2014503356A5 (enExample) | 2015-02-26 |
| JP5893646B2 JP5893646B2 (ja) | 2016-03-23 |
Family
ID=46507707
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013549616A Expired - Fee Related JP5893646B2 (ja) | 2011-01-14 | 2012-01-17 | Ｚ選択的オレフィンメタセシス触媒及びその合成手順 |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US9597674B2 (enExample) |
| EP (1) | EP2663398B1 (enExample) |
| JP (1) | JP5893646B2 (enExample) |
| KR (1) | KR101835170B1 (enExample) |
| CN (1) | CN103402628B (enExample) |
| AU (1) | AU2012206966B2 (enExample) |
| BR (1) | BR112013017938B1 (enExample) |
| CA (1) | CA2824518C (enExample) |
| IL (1) | IL227432A (enExample) |
| PL (1) | PL2663398T3 (enExample) |
| SG (1) | SG191980A1 (enExample) |
| WO (1) | WO2012097379A2 (enExample) |
| ZA (2) | ZA201305726B (enExample) |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2013134192A1 (en) | 2012-03-05 | 2013-09-12 | California Institute Of Technology | Syntheses of z-olefin-containing lepidopteran insect pheromones |
| EP2867243B1 (en) | 2012-06-29 | 2016-04-13 | Apeiron Synthesis S.A. | Metal complexes, their application and methods of carrying out of metathesis reaction |
| WO2014022482A1 (en) | 2012-08-01 | 2014-02-06 | California Institute Of Technology | Solvent-free enyne metathesis polymerization |
| US9234985B2 (en) | 2012-08-01 | 2016-01-12 | California Institute Of Technology | Birefringent polymer brush structures formed by surface initiated ring-opening metathesis polymerization |
| WO2014093687A1 (en) * | 2012-12-12 | 2014-06-19 | California Institute Of Technology | Z-selective metathesis catalysts |
| ES2699416T3 (es) * | 2013-04-09 | 2019-02-11 | Materia Inc | Preparación de tensioactivos mediante metátesis cruzada |
| US9758445B2 (en) | 2013-04-09 | 2017-09-12 | Materia, Inc. | Preparation of surfactants via cross-metathesis |
| US9663440B2 (en) | 2013-04-09 | 2017-05-30 | Materia, Inc. | Cross metathesis of poly-branched poly-olefins |
| WO2014186631A1 (en) * | 2013-05-15 | 2014-11-20 | California Institute Of Technology | Highly z-selective and enantioselective ring opening/cross metathesis |
| US9938253B2 (en) | 2013-06-12 | 2018-04-10 | Trustees Of Boston College | Catalysts for efficient Z-selective metathesis |
| WO2016014954A1 (en) * | 2014-07-25 | 2016-01-28 | California Institute Of Technology | Tandem z-selective metathesis / dihydroxylation |
| CA2999864A1 (en) * | 2015-09-24 | 2017-03-30 | Materia, Inc. | Metal carbene olefin metathesis catalysts |
| CA3006976A1 (en) | 2015-12-10 | 2017-06-15 | California Institute Of Technology | Olefin metathesis catalysts |
| CN114106057B (zh) * | 2016-10-19 | 2023-06-23 | 优美科股份公司及两合公司 | Ru亚烷基络合物的合成与表征 |
| US10320390B1 (en) | 2016-11-17 | 2019-06-11 | X Development Llc | Field programmable gate array including coupled lookup tables |
| EP3630741A1 (en) | 2017-05-30 | 2020-04-08 | Verbio Vereinigte Bioenergie AG | Methods of making olefinic e- and z-isomers |
| RU2020133186A (ru) * | 2018-03-09 | 2022-04-12 | Ппг Индастриз Огайо, Инк. | Составы для координирования с металлом, композиции, содержащие такие составы, и способы катализирования реакций |
| WO2019222244A1 (en) * | 2018-05-15 | 2019-11-21 | California Institute Of Technology | Total synthesis of prostaglandin j natural products by stereoretentive metathesis |
| US11939410B2 (en) * | 2018-06-29 | 2024-03-26 | Apeiron Synthesis S.A. | Organoruthenium complexes as precatalysts for olefin metathesis |
| WO2021011221A1 (en) * | 2019-07-17 | 2021-01-21 | California Institute Of Technology | New syntheses of z-selective olefin metathesis catalysts |
| MX2022008954A (es) * | 2020-03-05 | 2022-08-15 | Firmenich & Cie | Proceso para preparar un compuesto intermediario perfumante. |
| CN115298191A (zh) * | 2020-03-13 | 2022-11-04 | 伊利诺伊大学评议会 | 催化氢化硅烷化的方法 |
| CN114478166B (zh) * | 2020-10-26 | 2024-09-27 | 中国石油天然气股份有限公司 | 一种制备端烯烃的方法 |
| CN118056617B (zh) * | 2022-11-15 | 2026-06-23 | 中国石油天然气股份有限公司 | 一种用于1-己烯自歧化的负载型催化剂及其制备方法 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5312940A (en) | 1992-04-03 | 1994-05-17 | California Institute Of Technology | Ruthenium and osmium metal carbene complexes for olefin metathesis polymerization |
| US6284852B1 (en) * | 1997-10-30 | 2001-09-04 | California Institute Of Technology | Acid activation of ruthenium metathesis catalysts and living ROMP metathesis polymerization in water |
| WO2002014376A2 (en) | 2000-08-10 | 2002-02-21 | Trustees Of Boston College | Recyclable metathesis catalysts |
| EP1455937B1 (en) | 2001-11-15 | 2018-04-11 | Materia, Inc. | Chelating carbene ligand precursors and their use in the synthesis of metathesis catalysts |
| CN1659172B (zh) * | 2002-04-05 | 2012-08-01 | 加州理工学院 | 直接被吸电子基团取代的烯烃使用过渡金属卡宾催化剂的交叉-易位 |
| JP5081620B2 (ja) * | 2004-06-09 | 2012-11-28 | ユーティーアイ リミテッド パートナーシップ | オレフィン複分解反応の触媒としてのカチオン性置換基を含む遷移金属カルベン錯体 |
| FR2878246B1 (fr) | 2004-11-23 | 2007-03-30 | Inst Francais Du Petrole | Procede de co-production d'olefines et d'esters par ethenolyse de corps gras insatures dans des liquides ioniques non-aqueux |
| JP5406525B2 (ja) * | 2005-07-04 | 2014-02-05 | ツァナン・サイテック・カンパニー・リミテッド | ルテニウム錯体配位子、ルテニウム錯体、固定化ルテニウム錯体触媒及びその調製方法と用途 |
| US8877936B2 (en) * | 2008-04-09 | 2014-11-04 | California Institute Of Technology | Ruthenium olefin metathesis catalysts bearing N-heterocyclic carbene ligands with substituted backbone |
| EP2255877B1 (en) | 2009-05-07 | 2014-09-24 | Umicore AG & Co. KG | Method for preparation of ruthenium-based metathesis catalysts with chelating alkylidene ligands |
-
2012
- 2012-01-17 KR KR1020137021063A patent/KR101835170B1/ko not_active Expired - Fee Related
- 2012-01-17 AU AU2012206966A patent/AU2012206966B2/en not_active Ceased
- 2012-01-17 SG SG2013054085A patent/SG191980A1/en unknown
- 2012-01-17 EP EP12734668.2A patent/EP2663398B1/en active Active
- 2012-01-17 CA CA2824518A patent/CA2824518C/en not_active Expired - Fee Related
- 2012-01-17 US US13/978,940 patent/US9597674B2/en active Active
- 2012-01-17 CN CN201280010878.2A patent/CN103402628B/zh active Active
- 2012-01-17 PL PL12734668T patent/PL2663398T3/pl unknown
- 2012-01-17 JP JP2013549616A patent/JP5893646B2/ja not_active Expired - Fee Related
- 2012-01-17 BR BR112013017938-4A patent/BR112013017938B1/pt active IP Right Grant
- 2012-01-17 WO PCT/US2012/021609 patent/WO2012097379A2/en not_active Ceased
-
2013
- 2013-07-11 IL IL227432A patent/IL227432A/en active IP Right Grant
- 2013-07-29 ZA ZA2013/05726A patent/ZA201305726B/en unknown
-
2014
- 2014-11-04 ZA ZA2014/08071A patent/ZA201408071B/en unknown
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