ZA201408071B - Z-selective olefin metathesis catalysts and their synthetic procedure - Google Patents
Z-selective olefin metathesis catalysts and their synthetic procedureInfo
- Publication number
- ZA201408071B ZA201408071B ZA2014/08071A ZA201408071A ZA201408071B ZA 201408071 B ZA201408071 B ZA 201408071B ZA 2014/08071 A ZA2014/08071 A ZA 2014/08071A ZA 201408071 A ZA201408071 A ZA 201408071A ZA 201408071 B ZA201408071 B ZA 201408071B
- Authority
- ZA
- South Africa
- Prior art keywords
- synthetic procedure
- olefin metathesis
- metathesis catalysts
- selective olefin
- selective
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2265—Carbenes or carbynes, i.e.(image)
- B01J31/2269—Heterocyclic carbenes
- B01J31/2273—Heterocyclic carbenes with only nitrogen as heteroatomic ring members, e.g. 1,3-diarylimidazoline-2-ylidenes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2265—Carbenes or carbynes, i.e.(image)
- B01J31/2278—Complexes comprising two carbene ligands differing from each other, e.g. Grubbs second generation catalysts
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
- C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
- C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
- C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
- C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
- C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
- C07F15/0046—Ruthenium compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
- B01J2231/54—Metathesis reactions, e.g. olefin metathesis
- B01J2231/543—Metathesis reactions, e.g. olefin metathesis alkene metathesis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0261—Complexes comprising ligands with non-tetrahedral chirality
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/821—Ruthenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
- B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- C07C2531/22—Organic complexes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161432849P | 2011-01-14 | 2011-01-14 | |
| US201161433949P | 2011-01-18 | 2011-01-18 | |
| US201161515262P | 2011-08-04 | 2011-08-04 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA201408071B true ZA201408071B (en) | 2019-06-26 |
Family
ID=46507707
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA2013/05726A ZA201305726B (en) | 2011-01-14 | 2013-07-29 | Z-selective olefin metathesis catalysts and their synthetic procedure |
| ZA2014/08071A ZA201408071B (en) | 2011-01-14 | 2014-11-04 | Z-selective olefin metathesis catalysts and their synthetic procedure |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA2013/05726A ZA201305726B (en) | 2011-01-14 | 2013-07-29 | Z-selective olefin metathesis catalysts and their synthetic procedure |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US9597674B2 (en) |
| EP (1) | EP2663398B1 (en) |
| JP (1) | JP5893646B2 (en) |
| KR (1) | KR101835170B1 (en) |
| CN (1) | CN103402628B (en) |
| AU (1) | AU2012206966B2 (en) |
| BR (1) | BR112013017938B1 (en) |
| CA (1) | CA2824518C (en) |
| IL (1) | IL227432A (en) |
| PL (1) | PL2663398T3 (en) |
| SG (1) | SG191980A1 (en) |
| WO (1) | WO2012097379A2 (en) |
| ZA (2) | ZA201305726B (en) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2838359A4 (en) | 2012-03-05 | 2015-12-09 | California Inst Of Techn | Syntheses of z-olefin-containing lepidopteran insect pheromones |
| WO2014001109A1 (en) | 2012-06-29 | 2014-01-03 | Apeiron Synthesis S.A. | Metal complexes, their application and methods of carrying out of metathesis reaction |
| US9234985B2 (en) | 2012-08-01 | 2016-01-12 | California Institute Of Technology | Birefringent polymer brush structures formed by surface initiated ring-opening metathesis polymerization |
| WO2014022482A1 (en) | 2012-08-01 | 2014-02-06 | California Institute Of Technology | Solvent-free enyne metathesis polymerization |
| WO2014093687A1 (en) | 2012-12-12 | 2014-06-19 | California Institute Of Technology | Z-selective metathesis catalysts |
| US9663459B2 (en) | 2013-04-09 | 2017-05-30 | Materia, Inc. | Preparation of surfactants via cross-metathesis |
| US9663440B2 (en) | 2013-04-09 | 2017-05-30 | Materia, Inc. | Cross metathesis of poly-branched poly-olefins |
| US9758445B2 (en) | 2013-04-09 | 2017-09-12 | Materia, Inc. | Preparation of surfactants via cross-metathesis |
| US20160101414A1 (en) * | 2013-05-15 | 2016-04-14 | California Institute Of Technology | Highly z-selective and enantioselective ring opening/cross metathesis catalyzed by a resolved stereogenic-at-ru complex |
| PL3008078T3 (en) | 2013-06-12 | 2019-06-28 | Trustees Of Boston College | Catalysts for efficient z-selective metathesis |
| WO2016014954A1 (en) * | 2014-07-25 | 2016-01-28 | California Institute Of Technology | Tandem z-selective metathesis / dihydroxylation |
| WO2017053690A1 (en) * | 2015-09-24 | 2017-03-30 | Materia, Inc. | Metal carbene olefin metathesis catalysts |
| WO2017100585A1 (en) | 2015-12-10 | 2017-06-15 | Materia, Inc. | Olefin metathesis catalysts |
| CN114106057B (en) * | 2016-10-19 | 2023-06-23 | 优美科股份公司及两合公司 | Synthesis and characterization of Ru alkylene complexes |
| US10320390B1 (en) | 2016-11-17 | 2019-06-11 | X Development Llc | Field programmable gate array including coupled lookup tables |
| US11420926B2 (en) | 2017-05-30 | 2022-08-23 | Verbio Vereinigte Bioenergie Ag | Methods of making olefinic E- and Z-isomers |
| MX2020009367A (en) * | 2018-03-09 | 2021-01-15 | Ppg Ind Ohio Inc | Compounds for coordinating with a metal, compositions containing such compounds, and methods of catalyzing reactions. |
| JP7368381B2 (en) * | 2018-05-15 | 2023-10-24 | カリフォルニア・インスティテュート・オブ・テクノロジー | Total synthesis of prostaglandin J natural products by steric preservation metathesis |
| US11939410B2 (en) * | 2018-06-29 | 2024-03-26 | Apeiron Synthesis S.A. | Organoruthenium complexes as precatalysts for olefin metathesis |
| EP3999230A1 (en) * | 2019-07-17 | 2022-05-25 | California Institute of Technology | New syntheses of z-selective olefin metathesis catalysts |
| CN114478166A (en) * | 2020-10-26 | 2022-05-13 | 中国石油天然气股份有限公司 | Method for preparing terminal olefin |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5312940A (en) | 1992-04-03 | 1994-05-17 | California Institute Of Technology | Ruthenium and osmium metal carbene complexes for olefin metathesis polymerization |
| US6284852B1 (en) * | 1997-10-30 | 2001-09-04 | California Institute Of Technology | Acid activation of ruthenium metathesis catalysts and living ROMP metathesis polymerization in water |
| AU2001284773B2 (en) | 2000-08-10 | 2004-08-05 | Trustees Of Boston College | Recyclable metathesis catalysts |
| US6620955B1 (en) | 2001-11-15 | 2003-09-16 | Richard L. Pederson | Chelating carbene ligand precursors and their use in the synthesis of metathesis catalysts |
| AU2003221674A1 (en) * | 2002-04-05 | 2003-10-27 | California Institute Of Technology | Cross-metathesis of olefins directly substituted with an electron-withdrawing group using transition metal carbene catalysts |
| ZA200700170B (en) * | 2004-06-09 | 2008-05-28 | Uti Limited Partnership | Transition metal carbene complexes containing a cationi substituent as catalysts of olefin metathesis reactions |
| FR2878246B1 (en) | 2004-11-23 | 2007-03-30 | Inst Francais Du Petrole | PROCESS FOR CO-PRODUCTION OF OLEFINS AND ESTERS BY ETHENOLYSIS OF UNSATURATED FATTY BODIES IN NON-AQUEOUS IONIC LIQUIDS |
| EP2886549A1 (en) * | 2005-07-04 | 2015-06-24 | Zannan Scitech Co., Ltd. | Ruthenium complex ligand, ruthenium complex and the use of the complex as a catalyst in olefin metathesis reactions |
| US8877936B2 (en) * | 2008-04-09 | 2014-11-04 | California Institute Of Technology | Ruthenium olefin metathesis catalysts bearing N-heterocyclic carbene ligands with substituted backbone |
| EP2255877B1 (en) * | 2009-05-07 | 2014-09-24 | Umicore AG & Co. KG | Method for preparation of ruthenium-based metathesis catalysts with chelating alkylidene ligands |
-
2012
- 2012-01-17 PL PL12734668T patent/PL2663398T3/en unknown
- 2012-01-17 KR KR1020137021063A patent/KR101835170B1/en active IP Right Grant
- 2012-01-17 JP JP2013549616A patent/JP5893646B2/en active Active
- 2012-01-17 CN CN201280010878.2A patent/CN103402628B/en active Active
- 2012-01-17 AU AU2012206966A patent/AU2012206966B2/en not_active Ceased
- 2012-01-17 US US13/978,940 patent/US9597674B2/en active Active
- 2012-01-17 BR BR112013017938-4A patent/BR112013017938B1/en active IP Right Grant
- 2012-01-17 WO PCT/US2012/021609 patent/WO2012097379A2/en active Application Filing
- 2012-01-17 EP EP12734668.2A patent/EP2663398B1/en active Active
- 2012-01-17 SG SG2013054085A patent/SG191980A1/en unknown
- 2012-01-17 CA CA2824518A patent/CA2824518C/en not_active Expired - Fee Related
-
2013
- 2013-07-11 IL IL227432A patent/IL227432A/en active IP Right Grant
- 2013-07-29 ZA ZA2013/05726A patent/ZA201305726B/en unknown
-
2014
- 2014-11-04 ZA ZA2014/08071A patent/ZA201408071B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| IL227432A0 (en) | 2013-09-30 |
| CA2824518C (en) | 2019-03-26 |
| SG191980A1 (en) | 2013-08-30 |
| WO2012097379A3 (en) | 2012-10-11 |
| BR112013017938A2 (en) | 2018-11-27 |
| IL227432A (en) | 2017-12-31 |
| CN103402628A (en) | 2013-11-20 |
| JP2014503356A (en) | 2014-02-13 |
| AU2012206966B2 (en) | 2016-11-17 |
| CA2824518A1 (en) | 2012-07-19 |
| WO2012097379A2 (en) | 2012-07-19 |
| CN103402628B (en) | 2015-12-23 |
| KR101835170B1 (en) | 2018-03-06 |
| US20140106960A1 (en) | 2014-04-17 |
| EP2663398A2 (en) | 2013-11-20 |
| BR112013017938B1 (en) | 2019-10-15 |
| EP2663398B1 (en) | 2018-07-18 |
| US9597674B2 (en) | 2017-03-21 |
| ZA201305726B (en) | 2018-12-19 |
| JP5893646B2 (en) | 2016-03-23 |
| EP2663398A4 (en) | 2014-07-23 |
| PL2663398T3 (en) | 2019-01-31 |
| KR20140021995A (en) | 2014-02-21 |
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