JP2014503024A - 難燃化熱可塑性成形材料 - Google Patents
難燃化熱可塑性成形材料 Download PDFInfo
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- JP2014503024A JP2014503024A JP2013549805A JP2013549805A JP2014503024A JP 2014503024 A JP2014503024 A JP 2014503024A JP 2013549805 A JP2013549805 A JP 2013549805A JP 2013549805 A JP2013549805 A JP 2013549805A JP 2014503024 A JP2014503024 A JP 2014503024A
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- 239000012778 molding material Substances 0.000 title claims abstract description 25
- 238000009757 thermoplastic moulding Methods 0.000 title claims abstract description 18
- 239000003063 flame retardant Substances 0.000 title description 19
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- 125000004122 cyclic group Chemical group 0.000 claims abstract description 17
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- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
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- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
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- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 1
- GUOSQNAUYHMCRU-UHFFFAOYSA-N 11-Aminoundecanoic acid Chemical compound NCCCCCCCCCCC(O)=O GUOSQNAUYHMCRU-UHFFFAOYSA-N 0.000 description 1
- RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-Tetramethylpiperidine Substances CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 description 1
- FTVFPPFZRRKJIH-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidin-4-amine Chemical compound CC1(C)CC(N)CC(C)(C)N1 FTVFPPFZRRKJIH-UHFFFAOYSA-N 0.000 description 1
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- BDBZTOMUANOKRT-UHFFFAOYSA-N 4-[2-(4-aminocyclohexyl)propan-2-yl]cyclohexan-1-amine Chemical compound C1CC(N)CCC1C(C)(C)C1CCC(N)CC1 BDBZTOMUANOKRT-UHFFFAOYSA-N 0.000 description 1
- VWPQCOZMXULHDM-UHFFFAOYSA-N 9-aminononanoic acid Chemical compound NCCCCCCCCC(O)=O VWPQCOZMXULHDM-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/5399—Phosphorus bound to nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen
- C08L23/0869—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen with unsaturated acids, e.g. [meth]acrylic acid; with unsaturated esters, e.g. [meth]acrylic acid esters
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- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP11151495 | 2011-01-20 | ||
| EP11151495.6 | 2011-01-20 | ||
| PCT/EP2012/050780 WO2012098185A1 (de) | 2011-01-20 | 2012-01-19 | Flammgeschützte thermoplastische formmasse |
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| Publication Number | Publication Date |
|---|---|
| JP2014503024A true JP2014503024A (ja) | 2014-02-06 |
| JP2014503024A5 JP2014503024A5 (cg-RX-API-DMAC7.html) | 2015-03-05 |
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| Application Number | Title | Priority Date | Filing Date |
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| JP2013549805A Pending JP2014503024A (ja) | 2011-01-20 | 2012-01-19 | 難燃化熱可塑性成形材料 |
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| Country | Link |
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| EP (1) | EP2665779B1 (cg-RX-API-DMAC7.html) |
| JP (1) | JP2014503024A (cg-RX-API-DMAC7.html) |
| KR (1) | KR101861400B1 (cg-RX-API-DMAC7.html) |
| CN (1) | CN103328572B (cg-RX-API-DMAC7.html) |
| BR (1) | BR112013017734B1 (cg-RX-API-DMAC7.html) |
| MY (1) | MY163267A (cg-RX-API-DMAC7.html) |
| WO (1) | WO2012098185A1 (cg-RX-API-DMAC7.html) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8653168B2 (en) * | 2011-05-10 | 2014-02-18 | Basf Se | Flame-retardant thermoplastic molding composition |
| US8987357B2 (en) | 2011-05-27 | 2015-03-24 | Basf Se | Thermoplastic molding composition |
| KR102275119B1 (ko) * | 2017-05-19 | 2021-07-07 | 코오롱플라스틱 주식회사 | 폴리아미드 수지 조성물 및 이의 성형품 |
| EP3428210A1 (de) | 2017-07-11 | 2019-01-16 | Covestro Deutschland AG | Flammgeschützte pur/pir - hartschaumstoffe |
| CN107674269A (zh) * | 2017-11-06 | 2018-02-09 | 张永宏 | 静电吸附膜生产模具表面材料的制备方法 |
Citations (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6424855A (en) * | 1987-07-04 | 1989-01-26 | Basf Ag | Fire retardant thermoplastic molding material based on reinforced polyamide |
| JPH03197553A (ja) * | 1989-02-18 | 1991-08-28 | Basf Ag | 防炎熱可塑性成形材料 |
| JPH04318064A (ja) * | 1991-01-12 | 1992-11-09 | Basf Ag | 防炎加工した熱可塑性成形材料 |
| JPH06100785A (ja) * | 1992-09-16 | 1994-04-12 | Asahi Chem Ind Co Ltd | 耐ドリップ性難燃耐熱耐衝撃性樹脂組成物 |
| JPH06145504A (ja) * | 1992-02-18 | 1994-05-24 | Rhone Poulenc Chim | ポリアミドを基とする難燃化組成物 |
| JPH06263983A (ja) * | 1993-01-21 | 1994-09-20 | Basf Ag | 防炎性黒色熱可塑性成形材料 |
| US5434209A (en) * | 1991-06-27 | 1995-07-18 | Basf Aktiengesellschaft | Flameproofed thermoplastic polyamide molding materials |
| JPH07310011A (ja) * | 1992-05-22 | 1995-11-28 | Elf Atochem Sa | 難燃性熱可塑性組成物とその製造方法 |
| JPH11323343A (ja) * | 1998-05-13 | 1999-11-26 | Chemiprokasei Kaisha Ltd | ホスファゼン誘導体、その製法、それを含む難燃剤、それを含む有機高分子組成物およびその成形品 |
| JP2002201340A (ja) * | 2001-01-09 | 2002-07-19 | Sumitomo Bakelite Co Ltd | エポキシ樹脂組成物及び半導体装置 |
| JP2006052405A (ja) * | 2004-08-12 | 2006-02-23 | Clariant Gmbh | 耐グロウワイヤー性を有する難燃性ポリマー |
| US20060189747A1 (en) * | 2004-06-08 | 2006-08-24 | Detlev Joachimi | Polyamide molding compositions with improved flowability |
| JP2008163317A (ja) * | 2006-12-04 | 2008-07-17 | Mitsubishi Engineering Plastics Corp | 難燃性ポリアミド樹脂組成物および成形品 |
| WO2009037859A1 (ja) * | 2007-09-21 | 2009-03-26 | Mitsui Chemicals, Inc. | 難燃性ポリアミド組成物 |
| WO2010001972A1 (ja) * | 2008-07-04 | 2010-01-07 | 株式会社高木化学研究所 | 難燃性原着ポリエステル繊維、これを用いた難燃材および難燃性原着ポリエステル繊維の製造方法 |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2071250A (en) | 1931-07-03 | 1937-02-16 | Du Pont | Linear condensation polymers |
| US2071251A (en) | 1931-07-03 | 1937-02-16 | Du Pont | Fiber and method of producing it |
| US2130523A (en) | 1935-01-02 | 1938-09-20 | Du Pont | Linear polyamides and their production |
| US2130948A (en) | 1937-04-09 | 1938-09-20 | Du Pont | Synthetic fiber |
| US2241322A (en) | 1938-09-30 | 1941-05-06 | Du Pont | Process for preparing polyamides from cyclic amides |
| US2312966A (en) | 1940-04-01 | 1943-03-02 | Du Pont | Polymeric material |
| US2512606A (en) | 1945-09-12 | 1950-06-27 | Du Pont | Polyamides and method for obtaining same |
| IL24111A (en) | 1964-08-24 | 1969-02-27 | Du Pont | Linear polyamides |
| NL8001764A (nl) | 1980-03-26 | 1981-10-16 | Stamicarbon | Bereiding van hoogmoleculair polytramethyleenadipamide. |
| NL8001763A (nl) | 1980-03-26 | 1981-10-16 | Stamicarbon | Bereiding van polytetramethyleenadipamide. |
| NL8001762A (nl) | 1980-03-26 | 1981-10-16 | Stamicarbon | Bereiding van voorwerpen op de basis van polyamide. |
| DE4413177A1 (de) | 1994-04-15 | 1995-10-19 | Basf Ag | Inhärent hitzestabilisierte Polyamide |
| DE102004027872A1 (de) * | 2004-06-08 | 2006-01-05 | Lanxess Deutschland Gmbh | Polyamid-Formmassen mit verbesserter Fließfähigkeit |
| KR20080092984A (ko) | 2006-02-07 | 2008-10-16 | 바스프 에스이 | 정전기 방지 폴리우레탄 |
| DE102006045869A1 (de) | 2006-09-28 | 2008-04-03 | Evonik Goldschmidt Gmbh | Antistatika für Beschichtungsstoffe, Druckfarben und Drucklacke |
| US8197715B2 (en) | 2006-12-19 | 2012-06-12 | Base Se | Thermoplastic moulding compositions having improved ductility |
| JP5018460B2 (ja) | 2007-12-26 | 2012-09-05 | 東洋インキＳｃホールディングス株式会社 | カーボンナノチューブ分散体及びそれを用いてなる樹脂組成物ならびに成形体 |
| DE102009000641A1 (de) | 2009-02-05 | 2010-08-12 | Evonik Goldschmidt Gmbh | Verfahren zur Herstellung von antistatisch angerüsteten Kunststeinen für Flächengebilde |
-
2012
- 2012-01-19 WO PCT/EP2012/050780 patent/WO2012098185A1/de not_active Ceased
- 2012-01-19 MY MYPI2013002651A patent/MY163267A/en unknown
- 2012-01-19 KR KR1020137021720A patent/KR101861400B1/ko not_active Expired - Fee Related
- 2012-01-19 EP EP12701706.9A patent/EP2665779B1/de not_active Not-in-force
- 2012-01-19 BR BR112013017734-9A patent/BR112013017734B1/pt not_active IP Right Cessation
- 2012-01-19 JP JP2013549805A patent/JP2014503024A/ja active Pending
- 2012-01-19 CN CN201280005623.7A patent/CN103328572B/zh active Active
Patent Citations (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6424855A (en) * | 1987-07-04 | 1989-01-26 | Basf Ag | Fire retardant thermoplastic molding material based on reinforced polyamide |
| JPH03197553A (ja) * | 1989-02-18 | 1991-08-28 | Basf Ag | 防炎熱可塑性成形材料 |
| JPH04318064A (ja) * | 1991-01-12 | 1992-11-09 | Basf Ag | 防炎加工した熱可塑性成形材料 |
| US5434209A (en) * | 1991-06-27 | 1995-07-18 | Basf Aktiengesellschaft | Flameproofed thermoplastic polyamide molding materials |
| JPH06145504A (ja) * | 1992-02-18 | 1994-05-24 | Rhone Poulenc Chim | ポリアミドを基とする難燃化組成物 |
| US5466741A (en) * | 1992-02-18 | 1995-11-14 | Rhone-Poulenc Chimie | Flame-retardant, noncorrosive polyamide compositions |
| JPH07310011A (ja) * | 1992-05-22 | 1995-11-28 | Elf Atochem Sa | 難燃性熱可塑性組成物とその製造方法 |
| JPH06100785A (ja) * | 1992-09-16 | 1994-04-12 | Asahi Chem Ind Co Ltd | 耐ドリップ性難燃耐熱耐衝撃性樹脂組成物 |
| JPH06263983A (ja) * | 1993-01-21 | 1994-09-20 | Basf Ag | 防炎性黒色熱可塑性成形材料 |
| US5405890A (en) * | 1993-01-21 | 1995-04-11 | Basf Aktiengesellschaft | Flameproofed black polyamide molding materials |
| JPH11323343A (ja) * | 1998-05-13 | 1999-11-26 | Chemiprokasei Kaisha Ltd | ホスファゼン誘導体、その製法、それを含む難燃剤、それを含む有機高分子組成物およびその成形品 |
| JP2002201340A (ja) * | 2001-01-09 | 2002-07-19 | Sumitomo Bakelite Co Ltd | エポキシ樹脂組成物及び半導体装置 |
| US20060189747A1 (en) * | 2004-06-08 | 2006-08-24 | Detlev Joachimi | Polyamide molding compositions with improved flowability |
| JP2008501836A (ja) * | 2004-06-08 | 2008-01-24 | ランクセス・ドイチュランド・ゲーエムベーハー | 改良された流動性を有するポリアミド成形用組成物 |
| JP2006052405A (ja) * | 2004-08-12 | 2006-02-23 | Clariant Gmbh | 耐グロウワイヤー性を有する難燃性ポリマー |
| US20060183835A1 (en) * | 2004-08-12 | 2006-08-17 | Clariant Gmbh | Flame-retardant polymers with glow-wire resistance |
| JP2008163317A (ja) * | 2006-12-04 | 2008-07-17 | Mitsubishi Engineering Plastics Corp | 難燃性ポリアミド樹脂組成物および成形品 |
| US20100069539A1 (en) * | 2006-12-04 | 2010-03-18 | Mitsubishi Engineering-Plastics Corporation | Flame-retardant polyamide resin composition and molded article |
| WO2009037859A1 (ja) * | 2007-09-21 | 2009-03-26 | Mitsui Chemicals, Inc. | 難燃性ポリアミド組成物 |
| WO2010001972A1 (ja) * | 2008-07-04 | 2010-01-07 | 株式会社高木化学研究所 | 難燃性原着ポリエステル繊維、これを用いた難燃材および難燃性原着ポリエステル繊維の製造方法 |
| US20110086225A1 (en) * | 2008-07-04 | 2011-04-14 | Takagi Chemicals, Inc. | Flame-retardant spun-dyed polysete fiber, flame- retardant material comprising the same, and process for producing flame-retardant spun-dyed polyester fiber |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2665779A1 (de) | 2013-11-27 |
| KR20140007846A (ko) | 2014-01-20 |
| CN103328572A (zh) | 2013-09-25 |
| WO2012098185A1 (de) | 2012-07-26 |
| CN103328572B (zh) | 2016-08-10 |
| KR101861400B1 (ko) | 2018-05-28 |
| EP2665779B1 (de) | 2016-08-03 |
| MY163267A (en) | 2017-08-30 |
| BR112013017734A2 (pt) | 2016-10-11 |
| BR112013017734B1 (pt) | 2020-05-26 |
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