JP2014069566A - 熱転写箔およびそれを用いた加飾成形体 - Google Patents
熱転写箔およびそれを用いた加飾成形体 Download PDFInfo
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- JP2014069566A JP2014069566A JP2012220343A JP2012220343A JP2014069566A JP 2014069566 A JP2014069566 A JP 2014069566A JP 2012220343 A JP2012220343 A JP 2012220343A JP 2012220343 A JP2012220343 A JP 2012220343A JP 2014069566 A JP2014069566 A JP 2014069566A
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- layer
- thermal transfer
- transfer foil
- resin
- epoxy resin
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Abstract
【解決手段】基材20と、該基材10の一方の面上に、離型層30と、ハードコート層40と、アンカーコート層50と、受容層60と、装飾層70と、接着層80とをこの順に有してなる、熱転写箔10であって、該接着層80が、エポキシ系樹脂と、硬化剤と、硬化触媒と、を少なくとも含んでなる熱転写箔10。前記熱転写箔10によって加飾された加飾層を有してなる加飾成形体。
【選択図】図1
Description
基材と、前記基材の一方の面上に、離型層と、ハードコート層と、アンカーコート層と、受容層と、装飾層と、接着層とをこの順に有してなる、熱転写箔であって、
前記接着層が、エポキシ系樹脂と、硬化剤と、硬化触媒と、を少なくとも含んでなることを特徴とする、熱転写箔が提供される。
上記した熱転写箔によって加飾された加飾層を有してなる加飾成形体が提供される。
上記した熱転写箔を被転写体である金属表面上に転写して加飾する工程を含んでなる、加飾成形体の製造方法が提供される。
本発明による熱転写箔は、基材と、該基材の一方の面上に、少なくとも、離型層と、ハードコート層と、アンカーコート層と、受容層と、装飾層と、接着層とをこの順に有してなるものである。また、基材の他方の面上に、帯電防止層をさらに有してもよい。本発明の一態様によれば、帯電防止層/基材/離型層/ハードコート層/アンカーコート層/受容層/装飾層/接着層の順序で形成されてなる層構成を有する熱転写箔が提供される。本発明による熱転写箔は、被転写体としてアルミ、マグネシウム、およびチタン等の金属表面への加飾に好適に使用することができる。
本発明において、インクリボンは、の受容層上に、熱転写プリンターを用いて装飾層を形成するためのものである。熱転写箔の製造に用いるインクリボンは、基材シートと、該基材シートの一方の面に、少なくとも、剥離層と、インク層とをこの順に有し、インク層上に、接着層および帯電防止層をこの順にさらに有してもよい。また、基材シートの他方の面に耐熱滑性層をさらに有するものがよい。好ましい態様によれば、耐熱滑性層/基材シート/剥離層/インク層/接着層/帯電防止層の順序で形成されてなる層構成を有するインクリボンを用いるのがよい。また、他の態様によれば、インクリボンには、インク層と、金、銀、銅、亜鉛、および黄銅等の金属を蒸着により設けた金属蒸着層とを連続した1枚の基材シート上に面順次に設けてもよい。
本発明による加飾成形体の製造方法は、上記の熱転写箔を被転写体である金属表面上に転写して加飾する工程を含んでなるものでもよい。このような製造工程により加飾成形体を製造することで、金属表面にグラデーション等の複雑な意匠を表現することができる。
<接着層用組成物の調製>
下記の表1に示す組成に従って、エポキシ系樹脂に硬化剤、硬化促進剤、紫外線吸収剤、および光安定剤を添加して攪拌機により混合した後、混合物にアクリル系樹脂を添加して混合することにより、接着層用組成物を調製した。なお、下記の表1中、
JER828、JER1001およびJER1009は、三菱化学社製のビスフェノールA型エポキシ樹脂を、
M22Nは、アルケマ社製の極性基が導入された変性メチルメタクリレート−ブチルアクリレート−メチルメタクリレートの2元共重合体を、
QX40は、三菱化学社製のチオール系硬化剤を、
MT−PE−1は、昭和電工社製のチオール系硬化剤を、
DICY7は、三菱化学社製のジシアンジアミトを、
アミキュアMY−Hは、味の素ファインテクノ社製のアミンアダクトを、
UCAT−3513Nは、サンアプロ社製の脂肪族ジメチルウレアを、
チヌビン400、479、477は、BASF社製の紫外線吸収剤を、
チンビン123は、BASF社製のラジカル捕集剤(光安定剤)を、
ホスタビン3058は、クラリアント社製のラジカル捕集剤(光安定剤)を、
KBM−403は、信越シリコーン社製のシランカップリング剤を、それぞれ表す。
基材フィルム(「F99(品番)」,厚さ:50μm,東レ株式会社製)上に、メラミン樹脂系離型剤(メラミン樹脂の固形分比0.5%の酸触媒(パラトルエンスルホン酸)を添加)を塗工量2g/m2でグラビア印刷し、150℃のオーブン内で60秒間加熱処理して離型層を形成した上に、グラビアリバースコート法によって、下記組成のハードコート層用インキを塗工量12g/m2で塗工して、ハードコート層を形成した。そして、該ハードコート層に水銀燈から紫外線を照射して、未反応のアクリレート(アクリロイル)基が残る程度に架橋硬化させた。
<離型層用インキの組成>
・メラミン樹脂系離型主剤(大日精化(株)製、商品名:EX−114Dメジウム):
100質量部
・硬化剤(大日精化(株)製、商品名:PTC NO.7硬化剤): 10質量部
<ハードコート層用インキの組成>
・紫外線硬化樹脂(成分:ウレタンアクリレート系プレポリマー、 大日精化(株)製、商品名:セイカビーム EXF−HT−S) 60質量部
・反応性無機粒子(反応性コロイダルシリカ粒子、平均粒子径d50:44nm、日産化学工業(株)製、商品名:MIBK−SD−L) 40質量部
・多官能イソシアネート系硬化剤(成分:ヘキサンメチレンジイソシアネート、大日精化(株)製、商品名:PTC−RC3 硬化剤): 10質量部
<アンカーコート層用インキの組成>
・アクリルポリオール系樹脂(大日精化(株)製、商品名:TM−VMAC):
60質量部
・多官能イソシアネート系硬化剤(成分:ヘキサンメチレンジイソシアネート、大日精化(株)製、商品名:PTC−RC3 硬化剤): 25質量部
・塩化ビニル酢酸ビニル共重合体(DNPファインケミカル(株)製、商品名:SAニス) 15質量部
<受容層用インキの組成>
・アクリルポリオール系樹脂(大日精化(株)製、商品名:TM−VMAC):
80質量部
・塩化ビニル酢酸ビニル共重合体(DNPファインケミカル(株)製、商品名:SAニス) 20質量部
熱転写箔の初期粘着性を評価するため、以下のようにして試験サンプルを作製した。
上記した熱転写箔の作製工程において、装飾層上に接着層形成用組成物をコーティングする代わりに、PETフィルム(E−5100、東洋紡社製)のコロナ処理面にコーティングした以外は、上記した熱転写箔と同様にして試験片を作製した。得られた試験片を、23℃、50%RHの環境下に24時間静置した後、25mm×250mmに裁断し、その接着層部分に、表面を洗浄したアルミ板(6061)を載置し、その上から、手動式圧着装置(JIS0237)を用いて、圧着速度約5mm/秒で1往復させて、熱転写箔とアルミ板とを貼り合わせて試験サンプルを得た。
得られた試験サンプルについて、下記のサイクルで、UV照射合計時間が1500時間となるような加速劣化試験を行った。なお、照射条件として、365nmの紫外線を60mW/cm2で照射した。
(1)UV照射:20時間(63℃、50%RH)
(2)シャワー:30秒
(3)結露:4時間(63℃、98RH%)
初期粘着性の評価に使用した試験サンプルと同様のものを、23℃、50%RHの環境下に1月間静置した後、接着層表面のタックの有無を調べた。タックの有無は、上記した初期粘着性の評価と同様にして行い、試験サンプル作製後の初期粘着力に対して、50%以上の初期粘着性を有しているものをタック有り(○)とした。評価結果は、下記の表2に示される通りであった。
成型後の表面を目視にて観察し、印刷の抜けなど不良部がないか確認した。不良部なしを○、不良部ありを×とした。
表1に示す組成に従って、実施例1と同様にして接着層用樹脂組成物の調製を行い、実施例1と同様にして、実施例2〜19の熱転写箔を作製した。また、装飾層および接着層を設けなかった以外は実施例1と同様にして、比較例1の熱転写箔を作製した。続いて、実施例2〜19および比較例1について、実施例1と同様に、初期粘着性、耐候性、保存安定性、および外観の各評価を行った。評価結果は、下記の表2に示される通りであった。
20 基材
30 離型層
40 ハードコート層
50 アンカーコート層
60 受容層
70 装飾層
80 接着層
90 帯電防止層
110 転写層
120 剥離シート
210 インクリボン
220 基材シート
230 剥離層
240 インク層
250 接着層
260 帯電防止層
270 耐熱滑性層
300 加飾成形体
310 被転写体(金属板)
Claims (20)
- 基材と、前記基材の一方の面上に、離型層と、ハードコート層と、アンカーコート層と、受容層と、装飾層と、接着層とをこの順に有してなる、熱転写箔であって、
前記接着層が、エポキシ系樹脂と、硬化剤と、硬化触媒と、を少なくとも含んでなることを特徴とする、熱転写箔。 - 前記硬化剤がチオール系化合物からなり、前記硬化触媒が脂肪族系ジメチルウレアからなる、請求項1に記載の熱転写箔。
- 前記エポキシ系樹脂がビスフェノール型エポキシ樹脂である、請求項1または2に記載の熱転写箔。
- 前記ビスフェノール型エポキシ樹脂が、常温で液状のビスフェノール型エポキシ樹脂およびガラス転移温度が50〜170℃の範囲にある常温で固体のビスフェノール型エポキシ樹脂の2種のビスフェノール型エポキシ樹脂からなる、請求項3に記載の熱転写箔。
- 前記常温で液状のビスフェノール型エポキシ樹脂と、前記常温で固体のビスフェノール型エポキシ樹脂とが、0:64.3〜14.8:44.5の割合で含まれている、請求項4に記載の熱転写箔。
- 前記硬化剤が、前記エポキシ系樹脂に対して0.59〜1.08phr含まれる、請求項1〜5のいずれか一項に記載の熱転写箔。
- 前記硬化触媒が、前記エポキシ系樹脂の合計質量に対して0.1〜3.0%含まれる、請求項1〜6のいずれか一項に記載の熱転写箔。
- 前記接着層が、アクリル系樹脂をさらに含んでなる、請求項1〜6のいずれか一項に記載の熱転写箔。
- 前記アクリル系樹脂が、メチルメタクリレート系共重合体を含んでなる、請求項8に記載の熱転写箔。
- 前記ハードコート層が、電離放射線硬化性樹脂を含んでなる、請求項1〜9のいずれか一項に記載の熱転写箔。
- 前記ハードコート層が、電離放射線硬化性官能基としてビニル基、(メタ)アクリロイル基、アリル基、およびエポキシ基から選ばれる少なくとも1種を有するポリマーと、無機粒子の表面に反応性官能基を有する反応性無機粒子および/または反応性異形無機粒子と、多官能イソシアネートとを含むインキ組成物から形成される、請求項10に記載の熱転写箔。
- 前記アンカーコート層が、アクリルポリオールと多官能イソシアネートが反応してなる樹脂を含んでなる、請求項1〜11のいずれか一項に記載の熱転写箔。
- 前記アンカーコート層が、50〜80質量%のアクリルポリオールと10〜30質量%の多官能イソシアネートが反応してなる樹脂と、0質量%超過30質量%以下の熱可塑性樹脂とを含んでなる、請求項12に記載の熱転写箔。
- 前記受容層が、熱可塑性樹脂を含んでなる、請求項1〜13のいずれか一項に記載の熱転写箔。
- 前記受容層が、アクリルポリオールをさらに含んでなる、請求項14に記載の熱転写箔。
- 前記装飾層が、インク層を有するインクリボンを用いた熱転写プリンターによって、前記インク層が転写して形成されたものである、請求項1〜15のいずれか一項に記載の熱転写箔。
- 前記基材の他方の面上に、帯電防止層をさらに有してなる、請求項1〜16のいずれか一項に記載の熱転写箔。
- 金属表面の加飾に用いられる、請求項1〜17のいずれか一項に記載の熱転写箔。
- 請求項1〜17のいずれか一項に記載の熱転写箔によって加飾された加飾層を有してなる、加飾成形体。
- 請求項1〜17のいずれか一項に記載の熱転写箔を被転写体である金属表面上に転写して加飾する工程を含んでなる、加飾成形体の製造方法。
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