JP2014027053A5 - - Google Patents

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JP2014027053A5
JP2014027053A5 JP2012164849A JP2012164849A JP2014027053A5 JP 2014027053 A5 JP2014027053 A5 JP 2014027053A5 JP 2012164849 A JP2012164849 A JP 2012164849A JP 2012164849 A JP2012164849 A JP 2012164849A JP 2014027053 A5 JP2014027053 A5 JP 2014027053A5
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liquid crystal
crystal polymer
metal
polymer composite
coupling agent
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JP2012164849A
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JP5869976B2 (en
JP2014027053A (en
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Priority to TW102124351A priority patent/TWI552865B/en
Priority to PCT/JP2013/068891 priority patent/WO2014017300A1/en
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以上の知見を基礎として完成した本発明は一側面において、粗面化処理されていない金属材料に窒素を含む官能基を有するカップリング剤の水溶液を用いた表面処理を行い、この処理面に液晶ポリマーを圧着又は射出成形で接合させる、金属−液晶ポリマー複合体の製造方法である。 The present invention completed on the basis of the above knowledge, in one aspect, performs a surface treatment using an aqueous solution of a coupling agent having a functional group containing nitrogen on a metal material that has not been roughened, and a liquid crystal is applied to the treated surface. This is a method for producing a metal-liquid crystal polymer composite in which a polymer is joined by pressure bonding or injection molding.

本発明に係る金属−液晶ポリマー複合体の製造方法は更に別の一実施形態において、前記カップリング剤の水溶液を用いた表面処理を行った金属材料が、前記金属材料表面のSi、Ti、Alの下方に、Cu、Al、Cr、Ag、Ni、In、Snのいずれか1種以上の金属又はその酸化物の層を有する。 In another embodiment of the method for producing a metal-liquid crystal polymer composite according to the present invention, the metal material subjected to the surface treatment using the aqueous solution of the coupling agent is Si, Ti, Al on the surface of the metal material. The layer of one or more metals of Cu, Al, Cr, Ag, Ni, In, and Sn, or an oxide thereof is provided below.

本発明に係る金属−液晶ポリマー複合体の製造方法は更に別の一実施形態において、前記カップリング剤の水溶液を用いた表面処理を、カップリング剤が均一に溶解した溶液で行う。 In still another embodiment of the method for producing a metal-liquid crystal polymer composite according to the present invention, the surface treatment using the aqueous solution of the coupling agent is performed with a solution in which the coupling agent is uniformly dissolved.

本発明に係る金属−液晶ポリマー複合体の製造方法は更に別の一実施形態において、前記カップリング剤の水溶液を用いた表面処理を、カップリング剤が溶解したpH7〜14の溶液で行う。
In still another embodiment of the method for producing a metal-liquid crystal polymer composite according to the present invention, the surface treatment using the aqueous solution of the coupling agent is performed with a solution having a pH of 7 to 14 in which the coupling agent is dissolved.

Claims (12)

粗面化処理されていない金属材料に窒素を含む官能基を有するカップリング剤の水溶液を用いた表面処理を行い、この処理面に液晶ポリマーを圧着又は射出成形で接合させる、金属−液晶ポリマー複合体の製造方法。 A metal-liquid crystal polymer composite in which a metal material that has not been roughened is subjected to a surface treatment using an aqueous solution of a coupling agent having a functional group containing nitrogen, and a liquid crystal polymer is bonded to the treated surface by pressure bonding or injection molding. Body manufacturing method. 前記カップリング剤の主成分元素がSi、Ti及びAlのいずれかである請求項1に記載の金属−液晶ポリマー複合体の製造方法。   The method for producing a metal-liquid crystal polymer composite according to claim 1, wherein a main component element of the coupling agent is any one of Si, Ti, and Al. 前記窒素を含む官能基がアミノ基、イソシアネート基及びウレイド基のいずれかである請求項1又は2に記載の金属−液晶ポリマー複合体の製造方法。   The method for producing a metal-liquid crystal polymer composite according to claim 1 or 2, wherein the functional group containing nitrogen is any one of an amino group, an isocyanate group, and a ureido group. 前記カップリング剤の水溶液を用いた表面処理を行った金属材料が、前記金属材料表面のSi、Ti、Alの下方に、Cu、Al、Cr、Ag、Ni、In、Snのいずれか1種以上の金属又はその酸化物の層を有する請求項1〜3のいずれかに記載の金属−液晶ポリマー複合体の製造方法。 The metal material subjected to the surface treatment using the aqueous solution of the coupling agent is any one of Cu, Al, Cr, Ag, Ni, In, and Sn below Si, Ti, and Al on the surface of the metal material. The method for producing a metal-liquid crystal polymer composite according to any one of claims 1 to 3, comprising a layer of the above metal or an oxide thereof. 前記カップリング剤の水溶液を用いた表面処理を、カップリング剤が均一に溶解した溶液で行う請求項1〜4のいずれかに記載の金属−液晶ポリマー複合体の製造方法。 The method for producing a metal-liquid crystal polymer composite according to any one of claims 1 to 4, wherein the surface treatment using the aqueous solution of the coupling agent is performed with a solution in which the coupling agent is uniformly dissolved. 前記カップリング剤の水溶液を用いた表面処理を、カップリング剤が溶解したpH7〜14の溶液で行う請求項1〜5のいずれかに記載の金属−液晶ポリマー複合体の製造方法。 The method for producing a metal-liquid crystal polymer composite according to any one of claims 1 to 5, wherein the surface treatment using the aqueous solution of the coupling agent is performed with a solution having a pH of 7 to 14 in which the coupling agent is dissolved. プレス加工または曲げ加工した後に金属材料に前記表面処理を施し、この処理面に液晶ポリマーを圧着又は射出成形で接合させる請求項1〜6のいずれかに記載の金属−液晶ポリマー複合体の製造方法。   The method for producing a metal-liquid crystal polymer composite according to any one of claims 1 to 6, wherein the metal material is subjected to the surface treatment after being pressed or bent, and the liquid crystal polymer is bonded to the treated surface by pressure bonding or injection molding. . 金属材料に前記表面処理を施した後にプレス加工または曲げ加工し、前記表面処理面に液晶ポリマーを圧着又は射出成形で接合させる請求項1〜7のいずれかに記載の金属−液晶ポリマー複合体の製造方法。   The metal-liquid crystal polymer composite according to any one of claims 1 to 7, wherein after the surface treatment is applied to the metal material, press working or bending is performed, and a liquid crystal polymer is bonded to the surface treated surface by pressure bonding or injection molding. Production method. 請求項7又は8に記載の金属−液晶ポリマー複合体の製造方法で得られた金属−液晶ポリマー複合体を備えた電子部品。   The electronic component provided with the metal-liquid crystal polymer composite obtained by the manufacturing method of the metal-liquid crystal polymer composite of Claim 7 or 8. 前記金属材料が白色めっきをしたリードフレームであり、
液晶ポリマーと接合させるための前記金属材料の表面が、前記リードフレームの白色めっき表面に窒素を分子内に有するカップリング剤処理で形成されており、
前記リードフレームをケース電極とし、前記ケース電極上にLEDチップが実装され、前記チップが周辺を前記液晶ポリマーからなるケースボディで覆われ、前記ケースボディ内に蛍光体を含有する封止樹脂が充填されることで構成されたLEDパッケージである請求項9に記載の電子部品。
The metal material is a lead frame plated with white,
The surface of the metal material for bonding with the liquid crystal polymer is formed by a coupling agent treatment having nitrogen in the molecule on the white plating surface of the lead frame,
The lead frame is a case electrode, an LED chip is mounted on the case electrode, the chip is covered with a case body made of the liquid crystal polymer, and the case body is filled with a sealing resin containing a phosphor The electronic component according to claim 9, wherein the electronic component is an LED package configured as described above.
前記金属材料が陰極端子、陽極端子、及び、最表層が金属ペーストで覆われたコンデンサ本体の一部または全部であり、
前記陰極端子、前記陽極端子、及び、前記コンデンサ本体が液晶ポリマーで覆われて構成されたアルミ、タンタル及びニオブのいずれかのコンデンサである請求項9に記載の電子部品。
The metal material is a cathode terminal, an anode terminal, and a part or all of the capacitor body in which the outermost layer is covered with a metal paste,
10. The electronic component according to claim 9, wherein the cathode terminal, the anode terminal, and the capacitor body are any one of an aluminum, tantalum, and niobium capacitor configured by being covered with a liquid crystal polymer.
前記液晶ポリマーは、前記金属材料との熱膨張係数の差が±10ppm/℃である請求項9〜11のいずれかに記載の電子部品。   The electronic component according to claim 9, wherein the liquid crystal polymer has a difference in thermal expansion coefficient of ± 10 ppm / ° C. from the metal material.
JP2012164849A 2012-07-25 2012-07-25 Method for producing metal-liquid crystal polymer composite Active JP5869976B2 (en)

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JP2012164849A JP5869976B2 (en) 2012-07-25 2012-07-25 Method for producing metal-liquid crystal polymer composite
TW102124351A TWI552865B (en) 2012-07-25 2013-07-08 Metal-liquid crystal polymer composite manufacturing method and electronic parts
PCT/JP2013/068891 WO2014017300A1 (en) 2012-07-25 2013-07-10 Method for producing metal-liquid crystal polymer complex and electronic component

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JP2012164849A JP5869976B2 (en) 2012-07-25 2012-07-25 Method for producing metal-liquid crystal polymer composite

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JP2014027053A JP2014027053A (en) 2014-02-06
JP2014027053A5 true JP2014027053A5 (en) 2015-02-19
JP5869976B2 JP5869976B2 (en) 2016-02-24

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WO2016109611A2 (en) 2014-12-30 2016-07-07 Koninklijke Philips N.V. Led package with integrated features for gas or liquid cooling
CN108431298B (en) 2016-01-27 2019-06-21 株式会社新技术研究所 Copper or copper alloy articles and manufacturing method comprising surface modified poly ester system resin
JP6454858B2 (en) * 2016-06-15 2019-01-23 株式会社新技術研究所 Copper alloy article containing polyester resin and method for producing the same
JP6511614B2 (en) 2017-08-02 2019-05-15 株式会社新技術研究所 Composite of metal and resin
CN113193348A (en) * 2021-04-25 2021-07-30 江门市德众泰工程塑胶科技有限公司 Preparation method of antenna containing LCP (liquid Crystal Polymer) base material

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JPH0720635B2 (en) * 1987-04-29 1995-03-08 豊田合成株式会社 Insert reaction injection molding
JP3117699B2 (en) * 1990-07-07 2000-12-18 日本ケミコン株式会社 Exterior method of solid capacitor
JP2001237591A (en) * 2000-02-25 2001-08-31 Sony Corp Electromagnetic wave shield material and manufacturing method thereof
TW200535259A (en) * 2004-02-06 2005-11-01 Furukawa Circuit Foil Treated copper foil and circuit board
JP2006245303A (en) * 2005-03-03 2006-09-14 Nikko Kinzoku Kk Surface treatment method of copper foil
JP2010199166A (en) * 2009-02-24 2010-09-09 Panasonic Corp Lead frame for optical semiconductor apparatus, and method of manufacturing the same
JP2010287588A (en) * 2009-06-09 2010-12-24 Nec Tokin Corp Solid electrolytic capacitor
JP2011088296A (en) * 2009-10-20 2011-05-06 Bridgestone Corp Composite member

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