JP2013533349A5 - - Google Patents
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- Publication number
- JP2013533349A5 JP2013533349A5 JP2013517592A JP2013517592A JP2013533349A5 JP 2013533349 A5 JP2013533349 A5 JP 2013533349A5 JP 2013517592 A JP2013517592 A JP 2013517592A JP 2013517592 A JP2013517592 A JP 2013517592A JP 2013533349 A5 JP2013533349 A5 JP 2013533349A5
- Authority
- JP
- Japan
- Prior art keywords
- group
- optionally substituted
- metal complex
- hydrocarbyl
- microns
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 238000000034 method Methods 0.000 description 14
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 8
- 125000001183 hydrocarbyl group Chemical group 0.000 description 6
- 239000003446 ligand Substances 0.000 description 6
- 150000004696 coordination complex Chemical class 0.000 description 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-M phenolate Chemical compound [O-]C1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-M 0.000 description 4
- 229940031826 phenolate Drugs 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 125000004429 atom Chemical group 0.000 description 3
- 125000005842 heteroatom Chemical group 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 229910052726 zirconium Inorganic materials 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- 239000004705 High-molecular-weight polyethylene Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- ARYGEYDQRDUPAI-UHFFFAOYSA-N CC(CC(C)Oc(cccc1)c1-c1cc(C)cc(-[n]2c(cccc3)c3c3c2cccc3)c1O)Oc1ccccc1-c(cc(C)cc1-[n]2c3ccccc3c3c2cccc3)c1O Chemical compound CC(CC(C)Oc(cccc1)c1-c1cc(C)cc(-[n]2c(cccc3)c3c3c2cccc3)c1O)Oc1ccccc1-c(cc(C)cc1-[n]2c3ccccc3c3c2cccc3)c1O ARYGEYDQRDUPAI-UHFFFAOYSA-N 0.000 description 1
- LIAIAZLOXRVXTI-UHFFFAOYSA-N CC(COc1ccccc1-c(cc(C(C)(C)C)cc1C2=C(C=CC=C3C4(C)C)C3=CC3=CC=CCC23)c1O)COc1ccccc1-c1cc4cc(-c2c(cccc3)c3cc3c2cccc3)c1O Chemical compound CC(COc1ccccc1-c(cc(C(C)(C)C)cc1C2=C(C=CC=C3C4(C)C)C3=CC3=CC=CCC23)c1O)COc1ccccc1-c1cc4cc(-c2c(cccc3)c3cc3c2cccc3)c1O LIAIAZLOXRVXTI-UHFFFAOYSA-N 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000004414 alkyl thio group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000005110 aryl thio group Chemical group 0.000 description 1
- 125000004104 aryloxy group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 125000000707 boryl group Chemical group B* 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- 150000002363 hafnium compounds Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 125000001072 heteroaryl group Chemical group 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052809 inorganic oxide Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 125000002950 monocyclic group Chemical group 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- -1 phosphino, amino Chemical group 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000003107 substituted aryl group Chemical group 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US36170310P | 2010-07-06 | 2010-07-06 | |
| US61/361,703 | 2010-07-06 | ||
| PCT/IB2011/002283 WO2012004680A2 (en) | 2010-07-06 | 2011-07-01 | Process for producing high molecular weight polyethylene |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2013533349A JP2013533349A (ja) | 2013-08-22 |
| JP2013533349A5 true JP2013533349A5 (https=) | 2014-10-16 |
| JP5916724B2 JP5916724B2 (ja) | 2016-05-11 |
Family
ID=44906238
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013517592A Expired - Fee Related JP5916724B2 (ja) | 2010-07-06 | 2011-07-01 | 高分子量ポリエチレンの製造方法 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US9212234B2 (https=) |
| EP (1) | EP2591020B1 (https=) |
| JP (1) | JP5916724B2 (https=) |
| KR (1) | KR20130124171A (https=) |
| CN (1) | CN102958959B (https=) |
| BR (1) | BR112012032539A2 (https=) |
| WO (1) | WO2012004680A2 (https=) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8722819B2 (en) | 2010-07-06 | 2014-05-13 | Ticona Gmbh | Process for producing high molecular weight polyethylene |
| BR112012032615A2 (pt) | 2010-07-06 | 2017-06-20 | Ticona Gmbh | "fibras e membranas de polietileno de alto peso molecular,sua produção e uso" |
| CN102958959B (zh) | 2010-07-06 | 2015-11-25 | 提克纳有限公司 | 产生高分子量聚乙烯的方法 |
| JP2013529719A (ja) | 2010-07-06 | 2013-07-22 | ティコナ ゲゼルシャフト ミット ベシュレンクテル ハフツング | 高分子量ポリエチレンの製造方法 |
| CN104105720A (zh) * | 2011-12-19 | 2014-10-15 | 提克纳有限公司 | 制备高分子量聚乙烯的方法 |
| EP2880097B1 (en) | 2012-08-03 | 2023-10-18 | ExxonMobil Chemical Patents Inc. | Process to prepare a vinyl terminated polyethylene with long chain branching |
| WO2014022013A1 (en) | 2012-08-03 | 2014-02-06 | Exxonmobil Chemical Patents Inc. | Polyalphaolefins prepared using modified salan catalyst compounds |
| US9382349B2 (en) | 2012-08-03 | 2016-07-05 | Exxonmobil Chemical Patents Inc. | Polyalphaolefins prepared using modified Salan catalyst compounds |
| CN104364321A (zh) * | 2012-08-03 | 2015-02-18 | 埃克森美孚化学专利公司 | 含Salan 配体的卤化催化剂 |
| US8957172B2 (en) | 2012-08-03 | 2015-02-17 | Exxonmobil Chemical Patents Inc. | Nonsymmetric catalysts comprising salan ligands |
| WO2014022008A1 (en) * | 2012-08-03 | 2014-02-06 | Exxonmobil Chemical Patents Inc. | Catalysts comprising salan ligands |
| CN104428324B (zh) | 2012-11-02 | 2018-08-17 | 埃克森美孚化学专利公司 | 负载型Salan催化剂 |
| CN105121558B (zh) | 2013-03-13 | 2017-09-26 | 埃克森美孚化学专利公司 | 二苯基胺salan催化剂 |
| US9200099B2 (en) | 2013-06-20 | 2015-12-01 | Exxonmobil Chemical Patents Inc. | Salenol catalyst |
| WO2014204681A1 (en) | 2013-06-20 | 2014-12-24 | Exxonmobil Chemical Patents Inc. | Long-bridged salen catalyst |
| CN105392776B (zh) | 2013-06-20 | 2019-02-12 | 埃克森美孚化学专利公司 | 硫代-Salalen催化剂 |
| US8962779B2 (en) | 2013-07-16 | 2015-02-24 | Dow Global Technologies Llc | Method of forming polyaryl polymers |
| US9410016B2 (en) | 2013-07-16 | 2016-08-09 | Dow Global Technologies Llc | Aromatic polyacetals and articles comprising them |
| US8933239B1 (en) | 2013-07-16 | 2015-01-13 | Dow Global Technologies Llc | Bis(aryl)acetal compounds |
| US9063420B2 (en) | 2013-07-16 | 2015-06-23 | Rohm And Haas Electronic Materials Llc | Photoresist composition, coated substrate, and method of forming electronic device |
| US9290589B2 (en) | 2013-12-13 | 2016-03-22 | Exxonmobil Chemical Patents Inc. | Cyclopentadienyl-substituted salan catalysts |
| CN106132924B (zh) | 2014-03-31 | 2019-03-19 | 埃克森美孚化学专利公司 | 亚苯基桥连的salalen催化剂 |
| ES2949011T3 (es) * | 2014-06-30 | 2023-09-25 | Dow Global Technologies Llc | Sistemas de catalizador para la polimerización de olefinas |
| EP3161021B1 (en) * | 2014-06-30 | 2019-11-20 | Dow Global Technologies LLC | Process for olefin polymerization |
| ES2769005T3 (es) * | 2014-07-24 | 2020-06-24 | Dow Global Technologies Llc | Catalizadores de bis-bifenilfenoxi para la polimerización de polímeros basados en etileno de bajo peso molecular |
| US12428504B2 (en) * | 2019-11-04 | 2025-09-30 | Dow Global Technologies Llc | Biphenylphenol polymerization catalysts |
| CN116724062A (zh) * | 2021-02-15 | 2023-09-08 | 陶氏环球技术有限责任公司 | 联苯酚聚合催化剂 |
Family Cites Families (60)
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| JPH062776B2 (ja) | 1984-12-21 | 1994-01-12 | 日本石油株式会社 | 超高分子量ポリエチレンの製造方法 |
| EP0205960B1 (en) | 1985-06-17 | 1990-10-24 | AlliedSignal Inc. | Very low creep, ultra high moduls, low shrink, high tenacity polyolefin fiber having good strength retention at high temperatures and method to produce such fiber |
| JPH0692509B2 (ja) | 1985-12-17 | 1994-11-16 | 日本石油株式会社 | 高強度・高弾性率繊維又はフイルム製造用ポリエチレン溶液の製造法 |
| IL85097A (en) | 1987-01-30 | 1992-02-16 | Exxon Chemical Patents Inc | Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes |
| US5384299A (en) | 1987-01-30 | 1995-01-24 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
| US5153157A (en) | 1987-01-30 | 1992-10-06 | Exxon Chemical Patents Inc. | Catalyst system of enhanced productivity |
| DE3833445A1 (de) | 1988-10-01 | 1990-04-05 | Basf Ag | Vermeidung von farbigen verunreinigungen bei der herstellung von ultrahochmolekularen ethylenpolymerisaten mittels eines titan enthaltenden katalysatorsystems |
| AU6158390A (en) | 1989-08-03 | 1991-03-11 | Exxon Chemical Patents Inc. | Very high molecular weight polyethylene |
| US5064802A (en) | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
| DE69224287T2 (de) | 1992-01-06 | 1998-08-27 | The Dow Chemical Co., Midland, Mich. | Katalysatorzusammensetzung |
| EP0641362B1 (en) | 1992-04-20 | 1998-11-11 | Exxon Chemical Patents Inc. | Ethylene/branched olefin copolymers |
| DE59304393D1 (de) | 1992-06-24 | 1996-12-12 | Hoechst Ag | Verfahren zur Herstellung eines Katalysatorsystems für die Polymerisation und Copolymerisation von Ethylen zu ultrahochmolekularen Ethylpolymeren |
| EP0622379B1 (de) | 1993-04-29 | 1998-07-08 | Ticona GmbH | Verfahren zur Herstellung eines Katalysatorsystems für die Polymerisation und Copolymerisation von Ethylen zu ultrahochmolekularen Ethylenhomo- und copolymeren |
| IT1271406B (it) | 1993-09-13 | 1997-05-28 | Spherilene Srl | Procedimento per la preparazione di polimeri dell'etilene e prodotti ottenuti |
| ES2150529T3 (es) | 1994-04-07 | 2000-12-01 | Bp Chem Int Ltd | Procedimiento de polimerizacion. |
| US5527929A (en) | 1994-08-02 | 1996-06-18 | The Dow Chemical Company | Zwitterionic biscyclopentadienyl complexes |
| JP3355572B2 (ja) | 1994-08-23 | 2002-12-09 | 新日本石油株式会社 | オレフィン類重合触媒およびそれを用いたポリオレフィンの製造方法 |
| FI101716B1 (fi) | 1995-09-19 | 1998-08-14 | Valtion Teknillinen | Sopeutettu UHMWPE-PA-seos |
| US6486089B1 (en) | 1995-11-09 | 2002-11-26 | Exxonmobil Oil Corporation | Bimetallic catalyst for ethylene polymerization reactions with uniform component distribution |
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| US6051525A (en) | 1997-07-14 | 2000-04-18 | Mobil Corporation | Catalyst for the manufacture of polyethylene with a broad or bimodal molecular weight distribution |
| JP2001512127A (ja) | 1997-08-01 | 2001-08-21 | ザ ダウ ケミカル カンパニー | 触媒活性剤 |
| ATE243700T1 (de) | 1998-02-20 | 2003-07-15 | Dow Global Technologies Inc | Expandierte anionen enthaltende katalysatoraktivatoren |
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| US6211311B1 (en) | 1999-05-25 | 2001-04-03 | Equistar Chemicals, L.P. | Supported olefin polymerization catalysts |
| US6265504B1 (en) | 1999-09-22 | 2001-07-24 | Equistar Chemicals, Lp | Preparation of ultra-high-molecular-weight polyethylene |
| KR100998236B1 (ko) | 2000-01-26 | 2010-12-06 | 미쓰이 가가쿠 가부시키가이샤 | 올레핀 중합체 및 그의 제조 방법 |
| KR100351386B1 (ko) | 2000-04-24 | 2002-09-05 | 삼성종합화학주식회사 | 초고분자량 폴리에틸렌 제조용 촉매 및 이를 이용한초고분자량 폴리에틸렌 제조방법 |
| US6503439B1 (en) | 2000-06-15 | 2003-01-07 | Albert H. Burstein | Process for forming shaped articles of ultra high molecular weight polyethylene suitable for use as a prosthetic device or a component thereof |
| DE10122111B4 (de) | 2001-05-08 | 2007-03-01 | Ticona Gmbh | Verfahren zur Herstellung von Olefinpolymeren, sowie ausgewählte Katalysatoren |
| US7091292B2 (en) | 2002-04-24 | 2006-08-15 | Symyx Technologies, Inc. | Bridged bi-aromatic catalysts, complexes, and methods of using the same |
| US6897276B2 (en) * | 2002-04-24 | 2005-05-24 | Symyx Technologies, Inc. | Bridged bi-aromatic ligands, catalysts, processes for polymerizing and polymers therefrom |
| US7060848B2 (en) * | 2002-04-24 | 2006-06-13 | Symyx Technologies, Inc. | Bridged bi-aromatic catalysts, complexes, and methods of using the same |
| US20040110853A1 (en) * | 2002-08-20 | 2004-06-10 | Wang Louis Chun | Process for preparing molded porous articles and the porous articles prepared therefrom |
| WO2005003184A1 (en) | 2003-06-11 | 2005-01-13 | Exxonmobil Chemical Patents Inc. | Polymerization processes using antistatic agents |
| US6767975B1 (en) | 2003-07-14 | 2004-07-27 | Equistar Chemicals, Lp | Olefin polymerization with pyridine moiety-containing singe-site catalysts |
| EP1722154A2 (en) | 2004-03-05 | 2006-11-15 | Salvador Plaxats Oller | Plug valve for liquefied gas containers |
| CA2562090C (en) | 2004-04-29 | 2014-12-02 | Symyx Technologies, Inc. | Bridged bi-aromatic catalysts, complexes, and methods of using the same |
| BRPI0511840B1 (pt) | 2004-06-07 | 2016-04-19 | Ticona Llc | pó de moldagem, processo para formação de um artigo poroso e artigo poroso |
| WO2006020624A1 (en) | 2004-08-09 | 2006-02-23 | Dow Global Technologies Inc. | Supported bis(hydroxyarylaryloxy) catalysts for manufacture of polymers |
| US20060281879A1 (en) * | 2005-06-13 | 2006-12-14 | Univation Technologies, Llc | Catalyst compositions comprising small silica support materials and methods of use in polymerization reactions |
| DE102005052654A1 (de) * | 2005-11-04 | 2007-05-16 | Ticona Gmbh | Verfahren zur Herstellung von ultrahochmolekularen Polymeren unter Verwendung von speziellen verbrückten Metallocen-Katalysatoren |
| US7598329B2 (en) | 2005-11-04 | 2009-10-06 | Ticona Gmbh | Process for manufacturing ultra high molecular weight polymers using novel bridged metallocene catalysts |
| BRPI0705994A2 (pt) | 2007-10-19 | 2009-10-06 | Braskem Sa | processo de preparação de suporte catalìtico e catalisadores bimetálicos suportados para a produção de homopolìmeros e copolìmeros de etileno com alfa-olefinas de alto e ultra alto peso molecular e com ampla distribuição de peso molecular em processos em lama, massa e fase gás e os produtos assim obtidos |
| BRPI0703586B1 (pt) | 2007-10-19 | 2018-02-06 | Braskem S.A | Catalisador metaloceno suportado, e, copolímeros de etileno com alfa-olefinas de alto e ultra alto peso molecular |
| US8835577B2 (en) | 2007-11-15 | 2014-09-16 | Univation Technologies, Llc | Catalyst systems having a tailored hydrogen response |
| US20090163679A1 (en) | 2007-12-19 | 2009-06-25 | Braskem S.A. | Suspension polymerization process for manufacturing ultra high molecular weight polyethylene, a multimodal ultra high molecular weight polyethylene homopolymeric or copolymeric composition, a ultra high molecular weight polyethylene, and their uses |
| CN101654492B (zh) | 2008-08-21 | 2012-06-20 | 中国石化扬子石油化工有限公司 | 超高分子量聚乙烯、其制备方法及其应用 |
| EP2491060B1 (en) * | 2008-12-31 | 2015-04-08 | Symyx Solutions, Inc. | Method for producing very-high or ultra-high molecular weight polyethylene |
| KR20130059355A (ko) | 2010-05-03 | 2013-06-05 | 티코나 엘엘씨 | 폴리에틸렌 분말 및 그로부터 제조된 다공성 제품 |
| JP2013529719A (ja) | 2010-07-06 | 2013-07-22 | ティコナ ゲゼルシャフト ミット ベシュレンクテル ハフツング | 高分子量ポリエチレンの製造方法 |
| KR20130089165A (ko) | 2010-07-06 | 2013-08-09 | 티코나 게엠베하 | 초고분자량 폴리에틸렌, 및 이의 제조 방법 및 용도 |
| BR112012032615A2 (pt) | 2010-07-06 | 2017-06-20 | Ticona Gmbh | "fibras e membranas de polietileno de alto peso molecular,sua produção e uso" |
| US8722819B2 (en) | 2010-07-06 | 2014-05-13 | Ticona Gmbh | Process for producing high molecular weight polyethylene |
| CN102958958A (zh) | 2010-07-06 | 2013-03-06 | 提克纳有限公司 | 产生高分子量聚乙烯的方法 |
| CN102958959B (zh) | 2010-07-06 | 2015-11-25 | 提克纳有限公司 | 产生高分子量聚乙烯的方法 |
| WO2012004681A2 (en) | 2010-07-06 | 2012-01-12 | Ticona Gmbh | Shaped high molecular weight polyethylene articles, their production and use |
-
2011
- 2011-07-01 CN CN201180031659.8A patent/CN102958959B/zh not_active Expired - Fee Related
- 2011-07-01 KR KR1020127033704A patent/KR20130124171A/ko not_active Withdrawn
- 2011-07-01 WO PCT/IB2011/002283 patent/WO2012004680A2/en not_active Ceased
- 2011-07-01 JP JP2013517592A patent/JP5916724B2/ja not_active Expired - Fee Related
- 2011-07-01 EP EP11778675.6A patent/EP2591020B1/en not_active Not-in-force
- 2011-07-01 BR BR112012032539A patent/BR112012032539A2/pt not_active IP Right Cessation
- 2011-07-01 US US13/700,879 patent/US9212234B2/en not_active Expired - Fee Related
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