JP2013513718A - 硫化水素を除去する改良法 - Google Patents
硫化水素を除去する改良法 Download PDFInfo
- Publication number
- JP2013513718A JP2013513718A JP2012544667A JP2012544667A JP2013513718A JP 2013513718 A JP2013513718 A JP 2013513718A JP 2012544667 A JP2012544667 A JP 2012544667A JP 2012544667 A JP2012544667 A JP 2012544667A JP 2013513718 A JP2013513718 A JP 2013513718A
- Authority
- JP
- Japan
- Prior art keywords
- zinc
- octoate
- molar ratio
- octanoic acid
- fluid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 18
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 title description 13
- 229910000037 hydrogen sulfide Inorganic materials 0.000 title description 13
- 239000011701 zinc Substances 0.000 claims abstract description 28
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 27
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 27
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 claims abstract description 22
- CHJMFFKHPHCQIJ-UHFFFAOYSA-L zinc;octanoate Chemical compound [Zn+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O CHJMFFKHPHCQIJ-UHFFFAOYSA-L 0.000 claims abstract description 22
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000010426 asphalt Substances 0.000 claims abstract description 11
- 150000003568 thioethers Chemical class 0.000 claims abstract description 7
- 239000003921 oil Substances 0.000 claims abstract description 5
- 239000003208 petroleum Substances 0.000 claims abstract description 5
- 239000010779 crude oil Substances 0.000 claims abstract description 3
- 239000002002 slurry Substances 0.000 claims abstract description 3
- 239000012530 fluid Substances 0.000 claims description 10
- 229910052751 metal Inorganic materials 0.000 claims description 10
- 239000002184 metal Substances 0.000 claims description 10
- 239000007788 liquid Substances 0.000 claims description 3
- 150000001735 carboxylic acids Chemical class 0.000 abstract description 7
- 239000000203 mixture Substances 0.000 abstract description 4
- 238000009472 formulation Methods 0.000 abstract 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 7
- 150000007942 carboxylates Chemical class 0.000 description 5
- 125000005474 octanoate group Chemical group 0.000 description 5
- 239000002253 acid Substances 0.000 description 2
- 239000003849 aromatic solvent Substances 0.000 description 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 125000004430 oxygen atom Chemical group O* 0.000 description 2
- 238000000197 pyrolysis Methods 0.000 description 2
- 239000002516 radical scavenger Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000005292 vacuum distillation Methods 0.000 description 2
- OBETXYAYXDNJHR-SSDOTTSWSA-M (2r)-2-ethylhexanoate Chemical compound CCCC[C@@H](CC)C([O-])=O OBETXYAYXDNJHR-SSDOTTSWSA-M 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000001875 compounds Chemical group 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000011346 highly viscous material Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052976 metal sulfide Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- -1 oxo zinc carboxylate Chemical class 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000012925 reference material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G17/00—Refining of hydrocarbon oils in the absence of hydrogen, with acids, acid-forming compounds or acid-containing liquids, e.g. acid sludge
- C10G17/09—Refining of hydrocarbon oils in the absence of hydrogen, with acids, acid-forming compounds or acid-containing liquids, e.g. acid sludge with acid salts
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10C—WORKING-UP PITCH, ASPHALT, BITUMEN, TAR; PYROLIGNEOUS ACID
- C10C3/00—Working-up pitch, asphalt, bitumen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
- C10G29/06—Metal salts, or metal salts deposited on a carrier
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1033—Oil well production fluids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/201—Impurities
- C10G2300/207—Acid gases, e.g. H2S, COS, SO2, HCN
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Water Supply & Treatment (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Materials Engineering (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
Description
なし。
非適用。
μ−Zn4O−μ−(O2C8H15)6
Claims (12)
- 石油ストリームから硫化物類を除去する方法であって、有機液に有効量の亜鉛オクトエートを添加する工程を含み、オクタン酸と錯形成する亜鉛のモル比は1:2ではない、方法。
- 前記亜鉛オクトエートは、オキソ亜鉛オクトエートである、請求項1記載の方法。
- 前記亜鉛オクトエートは、四核オキソ亜鉛オクトエートである、請求項1記載の方法。
- 亜鉛対オクタン酸のモル比は、1:2を超える、請求項1記載の方法。
- 前記亜鉛オクトエートは、流体中に添加され、前記流体の粘度は、1:2モル比の亜鉛対オクタン酸を有する同様の流体の粘度よりも小さい、請求項1記載の方法。
- 前記石油ストリームは、アスファルト、原油、油スラリ、およびそれらの任意の組み合わせからなるリストより選択されるものである、請求項1記載の方法。
- 前記亜鉛対オクタン酸のモル比は、2.1:3である、請求項1記載の方法。
- 前記亜鉛対オクタン酸のモル比は、1.97:3である、請求項1記載の方法。
- 前記亜鉛対オクタン酸のモル比は、2.1:3から1.97:3である、請求項1記載の方法。
- 前記有機液に添加される亜鉛オクトエートの用量は、1から2000ppmである、請求項1記載の方法。
- 前記添加された亜鉛オクトエートは、硫化物類の少なくとも50%を減少させる、請求項1記載の方法。
- 前記亜鉛オクトエートは、低粘度流体中に添加され、亜鉛金属量は、前記流体の5重量%から20重量%の間である、請求項1記載の方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/638,365 | 2009-12-15 | ||
US12/638,365 US8246813B2 (en) | 2009-12-15 | 2009-12-15 | Method of removing hydrogen sulfide |
PCT/US2010/060000 WO2011081860A2 (en) | 2009-12-15 | 2010-12-13 | Improved method of removing hydrogen sulphide |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2013513718A true JP2013513718A (ja) | 2013-04-22 |
JP5722339B2 JP5722339B2 (ja) | 2015-05-20 |
Family
ID=44141735
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2012544667A Active JP5722339B2 (ja) | 2009-12-15 | 2010-12-13 | 硫化水素を除去する改良法 |
Country Status (14)
Country | Link |
---|---|
US (1) | US8246813B2 (ja) |
EP (1) | EP2513258B1 (ja) |
JP (1) | JP5722339B2 (ja) |
KR (1) | KR20120123315A (ja) |
CN (1) | CN102656255B (ja) |
AR (1) | AR079454A1 (ja) |
BR (1) | BR112012014431B1 (ja) |
CA (2) | CA3062357C (ja) |
ES (1) | ES2566931T3 (ja) |
HU (1) | HUE028899T2 (ja) |
MX (1) | MX2012006914A (ja) |
RU (1) | RU2554872C2 (ja) |
SG (1) | SG181732A1 (ja) |
WO (1) | WO2011081860A2 (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2018097108A1 (ja) | 2016-11-22 | 2018-05-31 | 株式会社クラレ | 含硫黄化合物除去用の組成物 |
JP2018528063A (ja) * | 2015-07-03 | 2018-09-27 | ドルフ ケタール ケミカルズ (インディア)プライヴェート リミテッド | 硫化水素捕捉添加剤組成物及びそれを含む媒体。 |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9278307B2 (en) * | 2012-05-29 | 2016-03-08 | Baker Hughes Incorporated | Synergistic H2 S scavengers |
US9587181B2 (en) * | 2013-01-10 | 2017-03-07 | Baker Hughes Incorporated | Synergistic H2S scavenger combination of transition metal salts with water-soluble aldehydes and aldehyde precursors |
US9719027B2 (en) * | 2013-02-19 | 2017-08-01 | Baker Hughes Incorporated | Low viscosity metal-based hydrogen sulfide scavengers |
US10577542B2 (en) | 2013-02-19 | 2020-03-03 | Baker Hughes, A Ge Company, Llc | Low viscosity metal-based hydrogen sulfide scavengers |
EP2792732B1 (en) * | 2013-04-15 | 2016-11-02 | Baker Hughes Incorporated | Metal carboxylate salts as h2s scavengers in mixed production or dry gas systems |
US9480946B2 (en) | 2013-04-15 | 2016-11-01 | Baker Hughes Incorporated | Metal carboxylate salts as H2S scavengers in mixed production or dry gas or wet gas systems |
US9353026B2 (en) | 2013-07-19 | 2016-05-31 | Baker Hughes Incorporated | Oil soluble hydrogen sulfide scavenger |
US9783458B2 (en) * | 2014-01-31 | 2017-10-10 | Innophos, Inc. | Hydrogen sulfide scavenger |
US9988580B2 (en) | 2014-04-18 | 2018-06-05 | Amperage Energy Inc. | System and method for removing hydrogen sulfide from oilfield effluents |
PL3400260T3 (pl) * | 2016-01-08 | 2021-12-06 | Innophos, Inc. | Kompozycje pochłaniacza dla gatunków siarki |
US10093868B1 (en) | 2017-11-15 | 2018-10-09 | Baker Hughes, A Ge Company, Llc | Ionic liquid-based hydrogen sulfide and mercaptan scavengers |
US11981817B2 (en) | 2019-02-28 | 2024-05-14 | Ecolab Usa Inc. | Hydrogen sulfide scavengers for asphalt |
US11247167B2 (en) | 2020-02-11 | 2022-02-15 | Foremark Performance Chemicals | Scavenging system including at least one mixed acetal compound to remove hydrogen sulfide and/or mercaptans from a fluid stream |
BR112022020835A2 (pt) | 2020-04-22 | 2022-12-27 | Totalenergies Onetech | Composição e método para sequestrarem sulfeto de hidrogênio e mercaptanos em correntes de hidrocarboneto, uso do aditivo e corrente de hidrocarbonetos |
CA3204264A1 (en) | 2021-01-13 | 2022-07-21 | Daniel Robert DREYER | Hydrogen sulfide scavengers |
CN113372894A (zh) * | 2021-06-11 | 2021-09-10 | 四川正蓉上之登科技有限公司 | 一种高效快速可溶性除硫缓蚀剂及其制备方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63113096A (ja) * | 1986-08-11 | 1988-05-18 | エア・プロダクツ・アンド・ケミカルズ・インコ−ポレイテツド | 二金属触媒を用いる重質油の接触的ハイドロコンバ−ジヨン |
US5000835A (en) * | 1989-10-02 | 1991-03-19 | Exxon Chemical Patents, Inc. | Method of reducing H2 S in asphalt |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US500835A (en) * | 1893-07-04 | James aitchison and thomas bradley | ||
US2282703A (en) * | 1936-10-28 | 1942-05-12 | Standard Oil Co | Asphalt preparation |
US3674450A (en) * | 1971-04-23 | 1972-07-04 | Cities Service Oil Co | Antistatic additive for hydrocarbon fuels |
SU692988A1 (ru) * | 1977-08-08 | 1979-10-25 | Всесоюзный Научно-Исследовательский Институт По Сбору,Подготовке И Транспорту Нефти И Нефтепродуктов | Реагент дл предотвращени образовани сероводорода в заводн емом нефт ном пласте |
GB2137633B (en) | 1983-03-31 | 1986-10-29 | Exxon Research Engineering Co | Decreasing h2s emission in bitumen/sulphur mixtures |
US6599472B1 (en) * | 2000-11-03 | 2003-07-29 | Surface Chemists Of Florida Inc. | Oil soluble scavengers for sulfides and mercaptans |
US20050145137A1 (en) * | 2003-12-31 | 2005-07-07 | Buras Paul J. | Process for preparing bitumen compositions with reduced hydrogen sulfide emission |
US8034231B2 (en) * | 2008-02-20 | 2011-10-11 | Baker Hughes Incorporated | Method for reducing hydrogen sulfide evolution from asphalt |
-
2009
- 2009-12-15 US US12/638,365 patent/US8246813B2/en active Active
-
2010
- 2010-12-13 EP EP10841490.5A patent/EP2513258B1/en active Active
- 2010-12-13 CA CA3062357A patent/CA3062357C/en active Active
- 2010-12-13 CN CN201080056853.7A patent/CN102656255B/zh active Active
- 2010-12-13 SG SG2012044228A patent/SG181732A1/en unknown
- 2010-12-13 ES ES10841490.5T patent/ES2566931T3/es active Active
- 2010-12-13 MX MX2012006914A patent/MX2012006914A/es active IP Right Grant
- 2010-12-13 WO PCT/US2010/060000 patent/WO2011081860A2/en active Application Filing
- 2010-12-13 JP JP2012544667A patent/JP5722339B2/ja active Active
- 2010-12-13 BR BR112012014431-6A patent/BR112012014431B1/pt active IP Right Grant
- 2010-12-13 CA CA2784112A patent/CA2784112C/en active Active
- 2010-12-13 KR KR1020127018070A patent/KR20120123315A/ko active IP Right Grant
- 2010-12-13 RU RU2012124527/04A patent/RU2554872C2/ru not_active Application Discontinuation
- 2010-12-13 HU HUE10841490A patent/HUE028899T2/en unknown
- 2010-12-14 AR ARP100104620A patent/AR079454A1/es active IP Right Grant
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63113096A (ja) * | 1986-08-11 | 1988-05-18 | エア・プロダクツ・アンド・ケミカルズ・インコ−ポレイテツド | 二金属触媒を用いる重質油の接触的ハイドロコンバ−ジヨン |
US5000835A (en) * | 1989-10-02 | 1991-03-19 | Exxon Chemical Patents, Inc. | Method of reducing H2 S in asphalt |
EP0421683B1 (en) * | 1989-10-02 | 1997-05-21 | Exxon Chemical Patents Inc. | Method of reducing H2S in asphalt |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2018528063A (ja) * | 2015-07-03 | 2018-09-27 | ドルフ ケタール ケミカルズ (インディア)プライヴェート リミテッド | 硫化水素捕捉添加剤組成物及びそれを含む媒体。 |
WO2018097108A1 (ja) | 2016-11-22 | 2018-05-31 | 株式会社クラレ | 含硫黄化合物除去用の組成物 |
US11434433B2 (en) | 2016-11-22 | 2022-09-06 | Kuraray Co., Ltd. | Composition for removal of sulfur-containing compound |
Also Published As
Publication number | Publication date |
---|---|
SG181732A1 (en) | 2012-07-30 |
EP2513258A4 (en) | 2013-11-13 |
EP2513258A2 (en) | 2012-10-24 |
BR112012014431B1 (pt) | 2018-12-26 |
CN102656255A (zh) | 2012-09-05 |
JP5722339B2 (ja) | 2015-05-20 |
US20110139686A1 (en) | 2011-06-16 |
EP2513258B1 (en) | 2016-03-23 |
RU2012124527A (ru) | 2014-01-27 |
CN102656255B (zh) | 2015-06-03 |
MX2012006914A (es) | 2012-07-17 |
ES2566931T3 (es) | 2016-04-18 |
AR079454A1 (es) | 2012-01-25 |
US8246813B2 (en) | 2012-08-21 |
HUE028899T2 (en) | 2017-02-28 |
CA3062357A1 (en) | 2011-07-07 |
BR112012014431A2 (pt) | 2017-04-04 |
CA2784112A1 (en) | 2011-07-07 |
CA3062357C (en) | 2021-12-07 |
RU2554872C2 (ru) | 2015-06-27 |
KR20120123315A (ko) | 2012-11-08 |
CA2784112C (en) | 2020-03-10 |
WO2011081860A3 (en) | 2011-10-27 |
WO2011081860A2 (en) | 2011-07-07 |
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