JP2013513020A - 熱可塑性マトリックス中のｃｎｔ浸出繊維 - Google Patents
熱可塑性マトリックス中のｃｎｔ浸出繊維 Download PDFInfo
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- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/42—Coatings containing inorganic materials
- C03C25/44—Carbon, e.g. graphite
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/10—Reinforcing macromolecular compounds with loose or coherent fibrous material characterised by the additives used in the polymer mixture
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
- C08K3/041—Carbon nanotubes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
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- Carbon And Carbon Compounds (AREA)
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| US26779409P | 2009-12-08 | 2009-12-08 | |
| US61/267,794 | 2009-12-08 | ||
| PCT/US2010/059565 WO2011072071A1 (en) | 2009-12-08 | 2010-12-08 | Cnt-infused fibers in thermoplastic matrices |
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| JP2013513020A true JP2013513020A (ja) | 2013-04-18 |
| JP2013513020A5 JP2013513020A5 (cg-RX-API-DMAC10.html) | 2014-01-23 |
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| JP2012543264A Pending JP2013513020A (ja) | 2009-12-08 | 2010-12-08 | 熱可塑性マトリックス中のｃｎｔ浸出繊維 |
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Cited By (3)
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| JP7382460B1 (ja) | 2022-07-14 | 2023-11-16 | ニッタ株式会社 | 射出成形体及びその製造方法、複合繊維の製造方法、ｃｎｔ付着炭素繊維及びその製造方法、並びに炭素繊維複合材の製造方法 |
| WO2024053535A1 (ja) * | 2022-09-08 | 2024-03-14 | Dic株式会社 | 導電性樹脂組成物、マスターバッチ、成形体及びそれらの製造方法 |
| WO2025109800A1 (ja) * | 2023-11-21 | 2025-05-30 | 住友ゴム工業株式会社 | ラケット用ストリング |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
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| US11058039B2 (en) | 2015-12-29 | 2021-07-06 | 3M Innovative Properties Company | Composites for high frequency electromagnetic interference (EMI) applications |
| KR101777945B1 (ko) * | 2016-02-04 | 2017-09-12 | 고려대학교 산학협력단 | 플라즈마 처리를 통한 표면이 개질된 탄소섬유를 구비한 탄소 섬유 강화 폴리머 복합재 및 그 제조 방법 |
| CN107541038A (zh) * | 2016-06-27 | 2018-01-05 | 汉达精密电子(昆山)有限公司 | 碳纤维阻燃聚碳酸酯复合材料及其产品 |
| CN107641305A (zh) * | 2016-07-21 | 2018-01-30 | 汉达精密电子(昆山)有限公司 | 纳米碳管改性的玻璃纤维聚碳酸酯复合材料及其产品 |
| CN107722586A (zh) * | 2016-08-11 | 2018-02-23 | 汉达精密电子(昆山)有限公司 | 碳纳米管增强聚碳酸酯/碳纤维复合材料及其成型品 |
| DE102017209357A1 (de) * | 2017-06-01 | 2018-12-06 | Albis Plastic Gmbh | Compound |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006082829A1 (ja) * | 2005-02-02 | 2006-08-10 | Otsuka Chemical Co., Ltd. | カーボンナノチューブ担持無機粒子 |
| JP2007502246A (ja) * | 2003-07-28 | 2007-02-08 | ウィリアム・マーシュ・ライス・ユニバーシティ | ポリマー複合物を得るための、有機シランによるカーボンナノチューブのサイドウォール官能化 |
| JP2007523033A (ja) * | 2004-01-30 | 2007-08-16 | サーントル ナシオナル ドゥ ラ ルシェルシェ シャーンティフィク（セーエンヌエールエス） | 支持体に結合させたカーボンナノチューブ及びそれを含む複合体の製造方法 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6863942B2 (en) * | 1998-06-19 | 2005-03-08 | The Research Foundation Of State University Of New York | Free-standing and aligned carbon nanotubes and synthesis thereof |
| CA2450014A1 (en) * | 2001-06-08 | 2002-12-19 | Eikos, Inc. | Nanocomposite dielectrics |
| CN101230145B (zh) * | 2003-02-13 | 2012-05-30 | 斯蒂茨丁荷兰聚合物学会 | 增强聚合物 |
| US20050062024A1 (en) * | 2003-08-06 | 2005-03-24 | Bessette Michael D. | Electrically conductive pressure sensitive adhesives, method of manufacture, and use thereof |
| CN105696138B (zh) * | 2004-11-09 | 2019-02-01 | 得克萨斯大学体系董事会 | 纳米纤维纱线、带和板的制造和应用 |
| US8148276B2 (en) * | 2005-11-28 | 2012-04-03 | University Of Hawaii | Three-dimensionally reinforced multifunctional nanocomposites |
| CN100591613C (zh) * | 2006-08-11 | 2010-02-24 | 清华大学 | 碳纳米管复合材料及其制造方法 |
| US20100080978A1 (en) * | 2006-12-04 | 2010-04-01 | Universite Catholique De Louvain | Polymer composite material structures comprising carbon based conductive loads |
| CN101582302B (zh) * | 2008-05-14 | 2011-12-21 | 清华大学 | 碳纳米管/导电聚合物复合材料 |
| US20100032629A1 (en) * | 2008-08-07 | 2010-02-11 | Benoit Brule | Adhesive composition containing carbon nanotubes and a copolyamide |
| US20110123735A1 (en) * | 2009-11-23 | 2011-05-26 | Applied Nanostructured Solutions, Llc | Cnt-infused fibers in thermoset matrices |
-
2010
- 2010-12-08 KR KR1020127017728A patent/KR20120124404A/ko not_active Withdrawn
- 2010-12-08 US US12/963,589 patent/US20110297892A1/en not_active Abandoned
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- 2010-12-08 EP EP10836652.7A patent/EP2509918A4/en not_active Withdrawn
- 2010-12-08 CA CA2779709A patent/CA2779709A1/en not_active Abandoned
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- 2010-12-08 BR BR112012013904A patent/BR112012013904A2/pt not_active IP Right Cessation
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- 2012-05-07 ZA ZA2012/03339A patent/ZA201203339B/en unknown
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007502246A (ja) * | 2003-07-28 | 2007-02-08 | ウィリアム・マーシュ・ライス・ユニバーシティ | ポリマー複合物を得るための、有機シランによるカーボンナノチューブのサイドウォール官能化 |
| JP2007523033A (ja) * | 2004-01-30 | 2007-08-16 | サーントル ナシオナル ドゥ ラ ルシェルシェ シャーンティフィク（セーエンヌエールエス） | 支持体に結合させたカーボンナノチューブ及びそれを含む複合体の製造方法 |
| WO2006082829A1 (ja) * | 2005-02-02 | 2006-08-10 | Otsuka Chemical Co., Ltd. | カーボンナノチューブ担持無機粒子 |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP7382460B1 (ja) | 2022-07-14 | 2023-11-16 | ニッタ株式会社 | 射出成形体及びその製造方法、複合繊維の製造方法、ｃｎｔ付着炭素繊維及びその製造方法、並びに炭素繊維複合材の製造方法 |
| WO2024014101A1 (ja) * | 2022-07-14 | 2024-01-18 | ニッタ株式会社 | 射出成形体及びその製造方法、複合繊維の製造方法、ｃｎｔ付着炭素繊維及びその製造方法、並びに炭素繊維複合材の製造方法 |
| JP2024011474A (ja) * | 2022-07-14 | 2024-01-25 | ニッタ株式会社 | 射出成形体及びその製造方法、複合繊維の製造方法、ｃｎｔ付着炭素繊維及びその製造方法、並びに炭素繊維複合材の製造方法 |
| WO2024053535A1 (ja) * | 2022-09-08 | 2024-03-14 | Dic株式会社 | 導電性樹脂組成物、マスターバッチ、成形体及びそれらの製造方法 |
| JPWO2024053535A1 (cg-RX-API-DMAC10.html) * | 2022-09-08 | 2024-03-14 | ||
| JP7568165B2 (ja) | 2022-09-08 | 2024-10-16 | Dic株式会社 | 導電性樹脂組成物、マスターバッチ、成形体及びそれらの製造方法 |
| WO2025109800A1 (ja) * | 2023-11-21 | 2025-05-30 | 住友ゴム工業株式会社 | ラケット用ストリング |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20120124404A (ko) | 2012-11-13 |
| AU2010328139A1 (en) | 2012-05-31 |
| AU2010328139B2 (en) | 2014-09-18 |
| ZA201203339B (en) | 2013-01-30 |
| WO2011072071A1 (en) | 2011-06-16 |
| US20110297892A1 (en) | 2011-12-08 |
| EP2509918A1 (en) | 2012-10-17 |
| EP2509918A4 (en) | 2013-09-25 |
| CA2779709A1 (en) | 2011-06-16 |
| CN102648155A (zh) | 2012-08-22 |
| BR112012013904A2 (pt) | 2016-04-26 |
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