JP2013508486A5 - - Google Patents
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- JP2013508486A5 JP2013508486A5 JP2012534608A JP2012534608A JP2013508486A5 JP 2013508486 A5 JP2013508486 A5 JP 2013508486A5 JP 2012534608 A JP2012534608 A JP 2012534608A JP 2012534608 A JP2012534608 A JP 2012534608A JP 2013508486 A5 JP2013508486 A5 JP 2013508486A5
- Authority
- JP
- Japan
- Prior art keywords
- curable composition
- alkyl group
- group
- composition according
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
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- 229920005989 resin Polymers 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 3
- 238000001721 transfer moulding Methods 0.000 claims description 3
- CMLFRMDBDNHMRA-UHFFFAOYSA-N 2h-1,2-benzoxazine Chemical group C1=CC=C2C=CNOC2=C1 CMLFRMDBDNHMRA-UHFFFAOYSA-N 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims 10
- 238000000034 method Methods 0.000 claims 6
- -1 benzoxazine compound Chemical class 0.000 claims 5
- 229920006395 saturated elastomer Polymers 0.000 claims 4
- 125000003710 aryl alkyl group Chemical group 0.000 claims 3
- 125000003118 aryl group Chemical group 0.000 claims 3
- 125000002619 bicyclic group Chemical group 0.000 claims 3
- 239000007795 chemical reaction product Substances 0.000 claims 3
- 125000002950 monocyclic group Chemical group 0.000 claims 3
- 150000003459 sulfonic acid esters Chemical class 0.000 claims 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 2
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 claims 2
- 150000001412 amines Chemical class 0.000 claims 2
- 239000000835 fiber Substances 0.000 claims 2
- 125000001188 haloalkyl group Chemical group 0.000 claims 2
- 229910052736 halogen Inorganic materials 0.000 claims 2
- 150000002367 halogens Chemical class 0.000 claims 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 2
- 125000004043 oxo group Chemical group O=* 0.000 claims 2
- 125000001424 substituent group Chemical group 0.000 claims 2
- 125000004172 4-methoxyphenyl group Chemical group [H]C1=C([H])C(OC([H])([H])[H])=C([H])C([H])=C1* 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 230000004913 activation Effects 0.000 claims 1
- 239000000654 additive Substances 0.000 claims 1
- 230000000996 additive effect Effects 0.000 claims 1
- 125000003342 alkenyl group Chemical group 0.000 claims 1
- 125000000304 alkynyl group Chemical group 0.000 claims 1
- 239000003054 catalyst Substances 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 125000000753 cycloalkyl group Chemical group 0.000 claims 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims 1
- 239000003822 epoxy resin Substances 0.000 claims 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- 238000001802 infusion Methods 0.000 claims 1
- 125000000040 m-tolyl group Chemical group [H]C1=C([H])C(*)=C([H])C(=C1[H])C([H])([H])[H] 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- ZHCAAFJSYLFLPX-UHFFFAOYSA-N nitrocyclohexatriene Chemical group [O-][N+](=O)C1=CC=C=C[CH]1 ZHCAAFJSYLFLPX-UHFFFAOYSA-N 0.000 claims 1
- 125000003261 o-tolyl group Chemical group [H]C1=C([H])C(*)=C(C([H])=C1[H])C([H])([H])[H] 0.000 claims 1
- 125000001037 p-tolyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])[H] 0.000 claims 1
- RUVINXPYWBROJD-UHFFFAOYSA-N para-methoxyphenyl Natural products COC1=CC=C(C=CC)C=C1 RUVINXPYWBROJD-UHFFFAOYSA-N 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 229920000647 polyepoxide Polymers 0.000 claims 1
- 125000002130 sulfonic acid ester group Chemical group 0.000 claims 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims 1
- 239000003377 acid catalyst Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- VRZVPALEJCLXPR-UHFFFAOYSA-N ethyl 4-methylbenzenesulfonate Chemical compound CCOS(=O)(=O)C1=CC=C(C)C=C1 VRZVPALEJCLXPR-UHFFFAOYSA-N 0.000 description 2
- VUQUOGPMUUJORT-UHFFFAOYSA-N methyl 4-methylbenzenesulfonate Chemical compound COS(=O)(=O)C1=CC=C(C)C=C1 VUQUOGPMUUJORT-UHFFFAOYSA-N 0.000 description 2
- 238000000465 moulding Methods 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N p-toluenesulfonic acid Substances CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP09173729.6 | 2009-10-22 | ||
| EP09173729 | 2009-10-22 | ||
| PCT/EP2010/064541 WO2011047939A1 (en) | 2009-10-22 | 2010-09-30 | Curable composition comprising a benzoxazine compound and a sulfonic acid ester having a cyclic structure as a heat-activatable catalyst |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2013508486A JP2013508486A (ja) | 2013-03-07 |
| JP2013508486A5 true JP2013508486A5 (https=) | 2013-11-14 |
Family
ID=41718465
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012534608A Ceased JP2013508486A (ja) | 2009-10-22 | 2010-09-30 | ベンゾオキサジン化合物および熱活性化触媒としての環状構造を有するスルホン酸エステルを含有する硬化性組成物 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US8748563B2 (https=) |
| JP (1) | JP2013508486A (https=) |
| KR (1) | KR20120099020A (https=) |
| CN (1) | CN102575062B (https=) |
| WO (1) | WO2011047939A1 (https=) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2834308B1 (en) * | 2012-06-27 | 2018-04-18 | Toray Industries, Inc. | Benzoxazine resin composition, prepreg, and fiber-reinforced composite material |
| DE102012215510A1 (de) | 2012-08-31 | 2014-05-28 | Henkel Ag & Co. Kgaa | Flammgeschützte Benzoxazin-haltige Zusammensetzung |
| US9416302B2 (en) * | 2012-09-28 | 2016-08-16 | 3M Innovative Properties Company | Polybenzoxazine composition |
| KR20160003641A (ko) * | 2013-04-30 | 2016-01-11 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 폴리(벤족사진)의 제조 방법 |
| EP3058013B1 (en) | 2013-10-16 | 2018-01-31 | 3M Innovative Properties Company | Benzoxazine polymerization |
| JP6291221B2 (ja) * | 2013-11-19 | 2018-03-14 | Ｊｘｔｇエネルギー株式会社 | プリプレグ、繊維強化複合材料及び粒子含有樹脂組成物 |
| EP3455287A4 (en) | 2016-05-10 | 2020-02-26 | Huntsman Advanced Materials Americas LLC | BENZOTHIAZOLES AS LATENT CATALYSTS FOR BENZOXAZINE RESINS |
| DE102017212772B3 (de) * | 2017-07-25 | 2018-01-25 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Halogenfreie Sulfonsäureester und/oder Sulfinsäureester als Flammschutzmittel in Kunststoffen, diese enthaltende Kunststoffzusammensetzungen und deren Verwendung |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5763358A (en) * | 1980-10-02 | 1982-04-16 | Sumitomo Chem Co Ltd | Resin composition |
| DE3433851C2 (de) | 1984-09-14 | 1987-01-08 | Gurit-Essex Ag, Freienbach | Chemisch härtbare Harze aus 1-Oxa-3-aza-tetralin-Gruppen enthaltenden Verbindungen und cycloaliphatischen Epoxid-harzen, Verfahren zu deren Herstellung sowie Verwendung solcher Harze |
| DE58909626D1 (de) | 1988-07-18 | 1996-04-25 | Gurit Essex Ag | Zu schwerentflammbaren und hochtemperaturbeständigen Kunststoffen härtbare Harze und Verfahren zu deren Herstellung |
| US5443911A (en) | 1990-05-21 | 1995-08-22 | Gurit-Essex Ag | Curable resins comprising halogenated epoxy resins and 1-oxa-3-aza tetraline compounds, method for preparing and use of resins |
| JPH04108861A (ja) * | 1990-08-28 | 1992-04-09 | Nippon Oil & Fats Co Ltd | 熱硬化性組成物 |
| EP0493310A1 (de) | 1990-12-21 | 1992-07-01 | Gurit-Essex AG | Zu schwerentflammbaren Kunststoffen härtbare Harzmischungen und deren Verwendung |
| US5543516A (en) | 1994-05-18 | 1996-08-06 | Edison Polymer Innovation Corporation | Process for preparation of benzoxazine compounds in solventless systems |
| US6225440B1 (en) | 1998-06-26 | 2001-05-01 | Edison Polymer Innovation Corporation | Cationic ring-opening polymerization of benzoxazines |
| JP3926045B2 (ja) | 1998-09-17 | 2007-06-06 | 住友ベークライト株式会社 | 熱硬化性樹脂組成物 |
| JP2000178332A (ja) | 1998-12-18 | 2000-06-27 | Shikoku Chem Corp | 熱硬化性樹脂組成物 |
| JP4726172B2 (ja) | 2001-09-14 | 2011-07-20 | 四国化成工業株式会社 | 熱硬化性樹脂組成物 |
| JP2006152172A (ja) * | 2004-11-30 | 2006-06-15 | Sumitomo Bakelite Co Ltd | 潜在性触媒および熱硬化性樹脂組成物 |
| JP2007070550A (ja) * | 2005-09-08 | 2007-03-22 | Sumitomo Bakelite Co Ltd | 熱硬化性樹脂組成物、熱硬化性樹脂成形材料及びその硬化物 |
| JP5151095B2 (ja) | 2006-08-31 | 2013-02-27 | 東レ株式会社 | プリプレグおよび繊維強化複合材料 |
| CN101516961B (zh) * | 2006-09-21 | 2012-09-05 | 汉高两合股份公司 | 催化低温聚合 |
| JP5409373B2 (ja) * | 2006-11-13 | 2014-02-05 | ヘンケル コーポレイション | コア−シェルゴムを有するベンゾキサジン組成物 |
| KR20100087281A (ko) * | 2007-10-02 | 2010-08-04 | 킹인더스트리즈,인코포레이티드 | 잠복산 촉매로서의 술폰산염 에스테르류 |
| JP2009173764A (ja) * | 2008-01-24 | 2009-08-06 | Toray Ind Inc | プリプレグおよび炭素繊維強化複合材料 |
-
2010
- 2010-09-30 CN CN201080047416.9A patent/CN102575062B/zh not_active Expired - Fee Related
- 2010-09-30 JP JP2012534608A patent/JP2013508486A/ja not_active Ceased
- 2010-09-30 KR KR20127010304A patent/KR20120099020A/ko not_active Withdrawn
- 2010-09-30 WO PCT/EP2010/064541 patent/WO2011047939A1/en not_active Ceased
-
2012
- 2012-04-23 US US13/453,451 patent/US8748563B2/en not_active Expired - Fee Related
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