JP2013508274A5 - - Google Patents
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- JP2013508274A5 JP2013508274A5 JP2012534224A JP2012534224A JP2013508274A5 JP 2013508274 A5 JP2013508274 A5 JP 2013508274A5 JP 2012534224 A JP2012534224 A JP 2012534224A JP 2012534224 A JP2012534224 A JP 2012534224A JP 2013508274 A5 JP2013508274 A5 JP 2013508274A5
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- ligand
- hydroformylation
- reaction
- contacting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000003054 catalyst Substances 0.000 claims 12
- 239000003446 ligand Substances 0.000 claims 11
- 238000000034 method Methods 0.000 claims 10
- 238000007037 hydroformylation reaction Methods 0.000 claims 9
- 238000006243 chemical reaction Methods 0.000 claims 8
- 229910052751 metal Inorganic materials 0.000 claims 6
- 239000002184 metal Substances 0.000 claims 6
- 230000003197 catalytic effect Effects 0.000 claims 5
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 claims 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 5
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims 4
- 239000000872 buffer Substances 0.000 claims 4
- 229910002091 carbon monoxide Inorganic materials 0.000 claims 4
- 229910052739 hydrogen Inorganic materials 0.000 claims 4
- 239000001257 hydrogen Substances 0.000 claims 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 3
- 125000004432 carbon atom Chemical group C* 0.000 claims 3
- 150000001336 alkenes Chemical class 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 claims 2
- 238000010574 gas phase reaction Methods 0.000 claims 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 2
- 150000008301 phosphite esters Chemical class 0.000 claims 2
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 239000007853 buffer solution Substances 0.000 claims 1
- 238000010924 continuous production Methods 0.000 claims 1
- 230000000694 effects Effects 0.000 claims 1
- 239000012530 fluid Substances 0.000 claims 1
- 239000007789 gas Substances 0.000 claims 1
- 229930195733 hydrocarbon Natural products 0.000 claims 1
- 150000002431 hydrogen Chemical class 0.000 claims 1
- 230000000977 initiatory effect Effects 0.000 claims 1
- 239000006193 liquid solution Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000000376 reactant Substances 0.000 claims 1
- 239000012495 reaction gas Substances 0.000 claims 1
- 229910052703 rhodium Inorganic materials 0.000 claims 1
- 239000010948 rhodium Substances 0.000 claims 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US25245009P | 2009-10-16 | 2009-10-16 | |
| US61/252,450 | 2009-10-16 | ||
| PCT/US2010/051576 WO2011046781A1 (en) | 2009-10-16 | 2010-10-06 | Gas phase hydroformylation process |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2013508274A JP2013508274A (ja) | 2013-03-07 |
| JP2013508274A5 true JP2013508274A5 (enExample) | 2013-11-21 |
| JP5823967B2 JP5823967B2 (ja) | 2015-11-25 |
Family
ID=43568184
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012534224A Active JP5823967B2 (ja) | 2009-10-16 | 2010-10-06 | 気相ヒドロホルミル化方法 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US8586800B2 (enExample) |
| EP (1) | EP2488539B2 (enExample) |
| JP (1) | JP5823967B2 (enExample) |
| CN (2) | CN102574878A (enExample) |
| WO (1) | WO2011046781A1 (enExample) |
| ZA (1) | ZA201202751B (enExample) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2872823A1 (en) * | 2012-06-04 | 2013-12-12 | Dow Technology Investments Llc | Hydroformylation process |
| DE102013201668B4 (de) | 2013-02-01 | 2019-05-16 | Evonik Degussa Gmbh | Verfahren zur selektiven Ruthenium-katalysierten Hydroaminomethylierung von Olefinen |
| DE102013217174A1 (de) * | 2013-08-28 | 2015-03-05 | Evonik Industries Ag | Zusammensetzung und deren Verwendung in Verfahren zur Hydroformylierung von ungesättigten Verbindungen |
| DE102014209533A1 (de) * | 2014-05-20 | 2015-12-17 | Evonik Degussa Gmbh | Gemische von Monophosphitligand und deren Verwendung zur Katalyse einer Hydroformylierungsreaktion |
| CN104475161B (zh) * | 2014-12-03 | 2016-09-14 | 中国石油大学(北京) | 铁磁性纳米颗粒固载铑络合物的氢甲酰化催化剂的制法 |
| EP3029045B1 (de) * | 2014-12-04 | 2018-06-13 | Evonik Degussa GmbH | Bisphosphite die eine 2,3 -Biphenol-Einheit als Zentral-Baustein aufweisen |
| EP3130399B1 (de) | 2015-08-12 | 2021-07-07 | Basf Se | Verfahren zur hydroformylierung von olefinen und/oder alkinen in der gasphase mit einem gemisch aus wasserstoff und kohlenmonoxid in gegenwart von heterogenem katalysator |
| JP7180603B2 (ja) | 2017-08-24 | 2022-11-30 | 三菱ケミカル株式会社 | ジヒドロキシビフェニル化合物、ビスホスファイト化合物、触媒、アルデヒド類の製造方法及びアルコールの製造方法 |
| US10654784B2 (en) * | 2018-10-05 | 2020-05-19 | Evonik Operations Gmbh | Process for hydroformylating short-chain olefins in the gas phase |
| EP4074722A1 (de) * | 2021-04-16 | 2022-10-19 | Evonik Operations GmbH | Diphosphite mit einem offenen, 3-methylierten flügelbaustein |
| CN113181966B (zh) * | 2021-04-25 | 2022-08-30 | 中国科学院兰州化学物理研究所 | 一种用于烯烃氢甲酰化反应的碳负载氮配位钴铁双金属催化剂的制备及应用 |
| EP4091712B1 (de) * | 2021-05-18 | 2024-05-15 | Evonik Oxeno GmbH & Co. KG | Verfahren zur regenerierung eines katalysators für die hydroformylierung von olefinen in der gasphase |
| CN118338965A (zh) * | 2021-12-16 | 2024-07-12 | 陶氏技术投资有限责任公司 | 包含此类化合物的过渡金属络合物加氢甲酰化催化剂前体组合物和加氢甲酰化方法 |
| EP4448170B1 (en) * | 2021-12-16 | 2025-08-20 | Dow Technology Investments LLC | Compounds, transition metal complex hydroformylation catalyst precuror compositions comprising such compounds, and hydroformylation processes |
| CN114931961B (zh) * | 2022-06-10 | 2024-02-27 | 万华化学集团股份有限公司 | 一种氢甲酰化催化剂及其应用 |
| CN116019116B (zh) * | 2022-12-07 | 2024-01-12 | 孟州农达生化制品有限公司 | 一种农药粉剂及其使用方法 |
| CN117380223B (zh) * | 2023-10-12 | 2025-11-04 | 北京高新利华科技股份有限公司 | 铑基催化剂及其制法和应用 |
| WO2025170886A1 (en) * | 2024-02-06 | 2025-08-14 | Eastman Chemical Company | Purge for a gas-stripping hydroformylation reactor for oxo aldehydes |
| CN119591482A (zh) * | 2024-11-19 | 2025-03-11 | 成都欣华源科技有限责任公司 | 一种高碳烯烃氢甲酰化连续循环工艺及系统 |
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| US5277532A (en) | 1989-07-31 | 1994-01-11 | Cefin S.P.A. | Mechanical acceleration device in can welding machines |
| KR910006419B1 (ko) | 1989-09-25 | 1991-08-24 | 한국과학기술원 | 옥소 반응용 폴리스티렌 담지 로듐 촉매의 제조방법 |
| DE4026406A1 (de) | 1990-08-21 | 1992-02-27 | Basf Ag | Rhodiumhydroformylierungskatalysatoren mit bis-phosphit-liganden |
| US5179055A (en) | 1990-09-24 | 1993-01-12 | New York University | Cationic rhodium bis(dioxaphosphorus heterocycle) complexes and their use in the branched product regioselective hydroformylation of olefins |
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| DE4204808A1 (de) | 1992-02-18 | 1993-08-19 | Basf Ag | Verfahren zur herstellung von (omega)-formylalkancarbonsaeureestern |
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| US6362354B1 (en) | 2000-11-17 | 2002-03-26 | E. I. Du Pont De Nemours And Company | Phosphonite ligands, catalyst compositions and hydroformylation process utilizing same |
| US6437192B1 (en) | 2000-11-17 | 2002-08-20 | E. I. Du Pont De Nmeours And Company | Hydroformylation of conjugated dienes to alkenals using phosphonite ligands |
| DE10220799A1 (de) * | 2002-05-10 | 2003-12-11 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von C13-Alkoholgemischen |
| DE10251262A1 (de) * | 2002-11-04 | 2004-05-13 | Basf Ag | Verfahren zur Herstellung von Aldehyden aus Alkanen |
-
2010
- 2010-10-06 CN CN2010800468045A patent/CN102574878A/zh active Pending
- 2010-10-06 US US13/499,317 patent/US8586800B2/en not_active Expired - Fee Related
- 2010-10-06 JP JP2012534224A patent/JP5823967B2/ja active Active
- 2010-10-06 EP EP10765548.2A patent/EP2488539B2/en active Active
- 2010-10-06 WO PCT/US2010/051576 patent/WO2011046781A1/en not_active Ceased
- 2010-10-06 CN CN201710599890.6A patent/CN107266298A/zh active Pending
-
2012
- 2012-04-16 ZA ZA2012/02751A patent/ZA201202751B/en unknown
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