JP2013508274A5 - - Google Patents

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JP2013508274A5
JP2013508274A5 JP2012534224A JP2012534224A JP2013508274A5 JP 2013508274 A5 JP2013508274 A5 JP 2013508274A5 JP 2012534224 A JP2012534224 A JP 2012534224A JP 2012534224 A JP2012534224 A JP 2012534224A JP 2013508274 A5 JP2013508274 A5 JP 2013508274A5
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catalyst
ligand
hydroformylation
reaction
contacting
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JP2012534224A
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JP5823967B2 (ja
JP2013508274A (ja
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Priority claimed from PCT/US2010/051576 external-priority patent/WO2011046781A1/en
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JP2012534224A 2009-10-16 2010-10-06 気相ヒドロホルミル化方法 Active JP5823967B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US25245009P 2009-10-16 2009-10-16
US61/252,450 2009-10-16
PCT/US2010/051576 WO2011046781A1 (en) 2009-10-16 2010-10-06 Gas phase hydroformylation process

Publications (3)

Publication Number Publication Date
JP2013508274A JP2013508274A (ja) 2013-03-07
JP2013508274A5 true JP2013508274A5 (enExample) 2013-11-21
JP5823967B2 JP5823967B2 (ja) 2015-11-25

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JP2012534224A Active JP5823967B2 (ja) 2009-10-16 2010-10-06 気相ヒドロホルミル化方法

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US (1) US8586800B2 (enExample)
EP (1) EP2488539B2 (enExample)
JP (1) JP5823967B2 (enExample)
CN (2) CN102574878A (enExample)
WO (1) WO2011046781A1 (enExample)
ZA (1) ZA201202751B (enExample)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013184350A1 (en) * 2012-06-04 2013-12-12 Dow Technology Investments Llc Hydroformylation process
DE102013201668B4 (de) 2013-02-01 2019-05-16 Evonik Degussa Gmbh Verfahren zur selektiven Ruthenium-katalysierten Hydroaminomethylierung von Olefinen
DE102013217174A1 (de) 2013-08-28 2015-03-05 Evonik Industries Ag Zusammensetzung und deren Verwendung in Verfahren zur Hydroformylierung von ungesättigten Verbindungen
DE102014209533A1 (de) * 2014-05-20 2015-12-17 Evonik Degussa Gmbh Gemische von Monophosphitligand und deren Verwendung zur Katalyse einer Hydroformylierungsreaktion
CN104475161B (zh) * 2014-12-03 2016-09-14 中国石油大学(北京) 铁磁性纳米颗粒固载铑络合物的氢甲酰化催化剂的制法
EP3029045B1 (de) * 2014-12-04 2018-06-13 Evonik Degussa GmbH Bisphosphite die eine 2,3 -Biphenol-Einheit als Zentral-Baustein aufweisen
EP3130399B1 (de) 2015-08-12 2021-07-07 Basf Se Verfahren zur hydroformylierung von olefinen und/oder alkinen in der gasphase mit einem gemisch aus wasserstoff und kohlenmonoxid in gegenwart von heterogenem katalysator
CN110997608B (zh) 2017-08-24 2023-07-25 三菱化学株式会社 二羟基联苯化合物、双亚磷酸酯化合物、催化剂、醛类的制造方法以及醇的制造方法
US10654784B2 (en) * 2018-10-05 2020-05-19 Evonik Operations Gmbh Process for hydroformylating short-chain olefins in the gas phase
EP4074722A1 (de) * 2021-04-16 2022-10-19 Evonik Operations GmbH Diphosphite mit einem offenen, 3-methylierten flügelbaustein
CN113181966B (zh) * 2021-04-25 2022-08-30 中国科学院兰州化学物理研究所 一种用于烯烃氢甲酰化反应的碳负载氮配位钴铁双金属催化剂的制备及应用
ES2987273T3 (es) * 2021-05-18 2024-11-14 Evonik Oxeno Gmbh & Co Kg Procedimiento para la regeneración de un catalizador para la hidroformilación de olefinas en la fase gaseosa
CN118317834A (zh) * 2021-12-16 2024-07-09 陶氏技术投资有限责任公司 化合物、包含此类化合物的过渡金属络合物加氢甲酰化催化剂前体组合物和加氢甲酰化方法
CN118338965A (zh) * 2021-12-16 2024-07-12 陶氏技术投资有限责任公司 包含此类化合物的过渡金属络合物加氢甲酰化催化剂前体组合物和加氢甲酰化方法
CN114931961B (zh) * 2022-06-10 2024-02-27 万华化学集团股份有限公司 一种氢甲酰化催化剂及其应用
CN116019116B (zh) * 2022-12-07 2024-01-12 孟州农达生化制品有限公司 一种农药粉剂及其使用方法
CN117380223B (zh) * 2023-10-12 2025-11-04 北京高新利华科技股份有限公司 铑基催化剂及其制法和应用
WO2025170886A1 (en) * 2024-02-06 2025-08-14 Eastman Chemical Company Purge for a gas-stripping hydroformylation reactor for oxo aldehydes
CN119591482B (zh) * 2024-11-19 2026-01-23 成都欣华源科技有限责任公司 一种高碳烯烃氢甲酰化连续循环工艺及系统

Family Cites Families (56)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3352924A (en) 1963-01-23 1967-11-14 Exxon Research Engineering Co Carbonylation reactions
US3415906A (en) 1964-05-29 1968-12-10 Hooker Chemical Corp Phosphite phospholane and phosphorinane compounds
US3527809A (en) 1967-08-03 1970-09-08 Union Carbide Corp Hydroformylation process
US4487972A (en) 1967-10-02 1984-12-11 Mobil Oil Corporation Production of oxygenated compounds
US3847997A (en) 1969-06-12 1974-11-12 Phillips Petroleum Co Hydroformylation process and catalyst
US4098727A (en) 1970-07-23 1978-07-04 Mobil Oil Corporation Insoluble polymers having functional groups containing chemically bonded Group VIII metal
US4045493A (en) 1975-02-03 1977-08-30 Standard Oil Company (Indiana) Hydroformylation of olefins
US4148830A (en) 1975-03-07 1979-04-10 Union Carbide Corporation Hydroformylation of olefins
US4144191A (en) 1977-06-06 1979-03-13 The Dow Chemical Company Amine-resin supported rhodium-cobalt carbonyl bimetallic clusters as novel hydroformylation catalysts
US4185038A (en) 1978-07-14 1980-01-22 Conoco, Inc. Hydroformylation catalysts containing rhodium (I) or iridium (I) chemically bound directly to inorganic polymers
US4386013A (en) 1981-08-24 1983-05-31 Occidental Research Corporation Hydroformylation process utilizing novel catalyst
US4361711A (en) 1981-12-18 1982-11-30 The Standard Oil Company Alcohols from olefins and synthesis gas
US4504684A (en) 1982-01-06 1985-03-12 The Standard Oil Company Metal coordination polymers as hydroformylation and hydrogenation catalysts
GB8334359D0 (en) 1983-12-23 1984-02-01 Davy Mckee Ltd Process
US4599206A (en) 1984-02-17 1986-07-08 Union Carbide Corporation Transition metal complex catalyzed reactions
US4567302A (en) 1984-07-20 1986-01-28 Angus Chemical Polymeric quaternary ammonium salts possessing antimicrobial activity and methods for preparation and use thereof
US4737588A (en) 1984-12-28 1988-04-12 Union Carbide Corporation Transition metal complex catalyzed reactions
US4668651A (en) 1985-09-05 1987-05-26 Union Carbide Corporation Transition metal complex catalyzed processes
US4885401A (en) 1985-09-05 1989-12-05 Union Carbide Corporation Bis-phosphite compounds
US4748261A (en) 1985-09-05 1988-05-31 Union Carbide Corporation Bis-phosphite compounds
US4774361A (en) 1986-05-20 1988-09-27 Union Carbide Corporation Transition metal complex catalyzed reactions
US4835299A (en) 1987-03-31 1989-05-30 Union Carbide Corporation Process for purifying tertiary organophosphites
US5113022A (en) 1988-08-05 1992-05-12 Union Carbide Chemicals & Plastics Technology Corporation Ionic phosphites used in homogeneous transition metal catalyzed processes
US4861918A (en) * 1988-08-12 1989-08-29 Union Carbide Corporation Reactivation of hydroformylation catalysts
US5277532A (en) 1989-07-31 1994-01-11 Cefin S.P.A. Mechanical acceleration device in can welding machines
KR910006419B1 (ko) 1989-09-25 1991-08-24 한국과학기술원 옥소 반응용 폴리스티렌 담지 로듐 촉매의 제조방법
DE4026406A1 (de) 1990-08-21 1992-02-27 Basf Ag Rhodiumhydroformylierungskatalysatoren mit bis-phosphit-liganden
US5179055A (en) 1990-09-24 1993-01-12 New York University Cationic rhodium bis(dioxaphosphorus heterocycle) complexes and their use in the branched product regioselective hydroformylation of olefins
US5183943A (en) 1991-03-18 1993-02-02 Union Carbide Chemicals & Plastics Technology Corporation Reactivation of hydroformylation catalysts
TW213465B (enExample) 1991-06-11 1993-09-21 Mitsubishi Chemicals Co Ltd
US5409877A (en) 1991-08-22 1995-04-25 Director-General Of Agency Of Industrial Science And Technology Catalyst for producing aldehyde and alcohol from olefin, carbon monoxide and hydrogen
DE4204808A1 (de) 1992-02-18 1993-08-19 Basf Ag Verfahren zur herstellung von (omega)-formylalkancarbonsaeureestern
CN1029774C (zh) * 1992-06-19 1995-09-20 联合碳化化学品及塑料有限公司 铑络合物加氢甲酰化催化剂以及该催化剂的前体组合物
US5312996A (en) 1992-06-29 1994-05-17 Union Carbide Chemicals & Plastics Technology Corporation Hydroformylation process for producing 1,6-hexanedials
US5288918A (en) * 1992-09-29 1994-02-22 Union Carbide Chemicals & Plastics Technology Corporation Hydroformylation process
US5364950A (en) 1992-09-29 1994-11-15 Union Carbide Chimicals & Plastics Technology Corporation Process for stabilizing phosphite ligands in hydroformylation reaction mixtures
US5767321A (en) 1995-12-06 1998-06-16 Union Carbide Chemicals & Plastics Technology Corporation Metal-ligand complex catalyzed processes
US5789625A (en) * 1995-12-06 1998-08-04 Union Carbide Chemicals & Plastics Technology Corporation Metal-ligand complex catalyzed processes
US5741942A (en) 1996-11-26 1998-04-21 Union Carbide Chemicals & Plastics Technology Corporation Metal-ligand complex catalyzed processes
EA001218B1 (ru) * 1995-12-06 2000-12-25 Юнион Карбайд Кемикалз Энд Пластикс Текнолоджи Корпорейшн Способ отделения кислотных соединений фосфора в присутствии металл-органофосфитного комплексного катализатора
US5892119A (en) 1996-11-26 1999-04-06 Union Carbide Chemicals & Plastics Technology Corporation Metal-ligand complex catalyzed processes
US5874640A (en) 1996-11-26 1999-02-23 Union Carbide Chemicals & Plastics Technology Corporation Metal-ligand complex catalyzed processes
US5789333A (en) 1997-03-05 1998-08-04 Iowa State University Research Foundation, Inc. Catalyst system comprising a first catalyst system tethered to a supported catalyst
US6121184A (en) 1997-07-29 2000-09-19 E. I. Du Pont De Nemours And Company Supported bis(phosphorus) ligands
US6229052B1 (en) 1998-05-29 2001-05-08 E. I. Du Pont De Nemours And Company Hydroformylation of olefins using supported bis(phosphorus) ligands
US6090987A (en) 1998-07-06 2000-07-18 Union Carbide Chemicals & Plastics Technology Corporation Metal-ligand complex catalyzed processes
WO2001014060A2 (en) 1999-08-25 2001-03-01 Massachusetts Institute Of Technology Surface-confined catalytic compositions
US6380421B1 (en) 1999-09-20 2002-04-30 E. I. Du Pont De Nemours And Company Multidentate phosphite ligands, catalytic compositions containing such ligands and catalytic processes utilizing such catalytic compositions
US6515161B1 (en) * 1999-09-20 2003-02-04 E. I. Du Pont De Nemours And Company Hydroformylation process utilizing multidentate phosphite ligands
US6420611B1 (en) * 1999-09-20 2002-07-16 E. I. Du Pont De Nemours And Company Composition comprising polymeric phosphite
US6307110B1 (en) 2000-03-15 2001-10-23 Union Carbide Chemicals & Plastics Technology Corporation Separation processes
US6294700B1 (en) 2000-03-15 2001-09-25 Union Carbide Chemicals & Plastics Technology Corporation Separation processes
US6362354B1 (en) 2000-11-17 2002-03-26 E. I. Du Pont De Nemours And Company Phosphonite ligands, catalyst compositions and hydroformylation process utilizing same
US6437192B1 (en) 2000-11-17 2002-08-20 E. I. Du Pont De Nmeours And Company Hydroformylation of conjugated dienes to alkenals using phosphonite ligands
DE10220799A1 (de) * 2002-05-10 2003-12-11 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von C13-Alkoholgemischen
DE10251262A1 (de) * 2002-11-04 2004-05-13 Basf Ag Verfahren zur Herstellung von Aldehyden aus Alkanen

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