JP5823967B2 - 気相ヒドロホルミル化方法 - Google Patents

気相ヒドロホルミル化方法 Download PDF

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JP5823967B2
JP5823967B2 JP2012534224A JP2012534224A JP5823967B2 JP 5823967 B2 JP5823967 B2 JP 5823967B2 JP 2012534224 A JP2012534224 A JP 2012534224A JP 2012534224 A JP2012534224 A JP 2012534224A JP 5823967 B2 JP5823967 B2 JP 5823967B2
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catalyst
ligand
hydroformylation
reaction
radicals
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JP2013508274A5 (enExample
JP2013508274A (ja
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ダブリュ．ウェグマン リチャード
ダブリュ．ウェグマン リチャード
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ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー
ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B41/00—Formation or introduction of functional groups containing oxygen
    • C07B41/06—Formation or introduction of functional groups containing oxygen of carbonyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/06—Phosphorus compounds without P—C bonds
    • C07F9/08—Esters of oxyacids of phosphorus
    • C07F9/141—Esters of phosphorous acids
    • C07F9/145—Esters of phosphorous acids with hydroxyaryl compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/6574—Esters of oxyacids of phosphorus
    • C07F9/65746—Esters of oxyacids of phosphorus the molecule containing more than one cyclic phosphorus atom

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Molecular Biology (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
JP2012534224A 2009-10-16 2010-10-06 気相ヒドロホルミル化方法 Expired - Fee Related JP5823967B2 (ja)

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US25245009P 2009-10-16 2009-10-16
US61/252,450 2009-10-16
PCT/US2010/051576 WO2011046781A1 (en) 2009-10-16 2010-10-06 Gas phase hydroformylation process

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JP2013508274A JP2013508274A (ja) 2013-03-07
JP2013508274A5 JP2013508274A5 (enExample) 2013-11-21
JP5823967B2 true JP5823967B2 (ja) 2015-11-25

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JP2012534224A Expired - Fee Related JP5823967B2 (ja) 2009-10-16 2010-10-06 気相ヒドロホルミル化方法

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US (1) US8586800B2 (enExample)
EP (1) EP2488539B2 (enExample)
JP (1) JP5823967B2 (enExample)
CN (2) CN102574878A (enExample)
WO (1) WO2011046781A1 (enExample)
ZA (1) ZA201202751B (enExample)

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CN104379258B (zh) * 2012-06-04 2017-05-03 陶氏技术投资有限责任公司 加氢甲酰化方法
DE102013201668B4 (de) 2013-02-01 2019-05-16 Evonik Degussa Gmbh Verfahren zur selektiven Ruthenium-katalysierten Hydroaminomethylierung von Olefinen
DE102013217174A1 (de) * 2013-08-28 2015-03-05 Evonik Industries Ag Zusammensetzung und deren Verwendung in Verfahren zur Hydroformylierung von ungesättigten Verbindungen
DE102014209533A1 (de) * 2014-05-20 2015-12-17 Evonik Degussa Gmbh Gemische von Monophosphitligand und deren Verwendung zur Katalyse einer Hydroformylierungsreaktion
CN104475161B (zh) * 2014-12-03 2016-09-14 中国石油大学(北京) 铁磁性纳米颗粒固载铑络合物的氢甲酰化催化剂的制法
EP3029045B1 (de) * 2014-12-04 2018-06-13 Evonik Degussa GmbH Bisphosphite die eine 2,3 -Biphenol-Einheit als Zentral-Baustein aufweisen
EP3130399B1 (de) 2015-08-12 2021-07-07 Basf Se Verfahren zur hydroformylierung von olefinen und/oder alkinen in der gasphase mit einem gemisch aus wasserstoff und kohlenmonoxid in gegenwart von heterogenem katalysator
JP7180603B2 (ja) 2017-08-24 2022-11-30 三菱ケミカル株式会社 ジヒドロキシビフェニル化合物、ビスホスファイト化合物、触媒、アルデヒド類の製造方法及びアルコールの製造方法
US10654784B2 (en) * 2018-10-05 2020-05-19 Evonik Operations Gmbh Process for hydroformylating short-chain olefins in the gas phase
EP4074722A1 (de) * 2021-04-16 2022-10-19 Evonik Operations GmbH Diphosphite mit einem offenen, 3-methylierten flügelbaustein
CN113181966B (zh) * 2021-04-25 2022-08-30 中国科学院兰州化学物理研究所 一种用于烯烃氢甲酰化反应的碳负载氮配位钴铁双金属催化剂的制备及应用
EP4091712B1 (de) * 2021-05-18 2024-05-15 Evonik Oxeno GmbH & Co. KG Verfahren zur regenerierung eines katalysators für die hydroformylierung von olefinen in der gasphase
US20250128245A1 (en) * 2021-12-16 2025-04-24 Dow Technology Investments Llc Compounds, transition metal complex hydroformylation catalyst precuror compositions comprising such compounds, and hydroformylation processes
CN118338965A (zh) * 2021-12-16 2024-07-12 陶氏技术投资有限责任公司 包含此类化合物的过渡金属络合物加氢甲酰化催化剂前体组合物和加氢甲酰化方法
CN114931961B (zh) * 2022-06-10 2024-02-27 万华化学集团股份有限公司 一种氢甲酰化催化剂及其应用
CN116019116B (zh) * 2022-12-07 2024-01-12 孟州农达生化制品有限公司 一种农药粉剂及其使用方法
CN117380223B (zh) * 2023-10-12 2025-11-04 北京高新利华科技股份有限公司 铑基催化剂及其制法和应用
WO2025170886A1 (en) * 2024-02-06 2025-08-14 Eastman Chemical Company Purge for a gas-stripping hydroformylation reactor for oxo aldehydes
CN119591482B (zh) * 2024-11-19 2026-01-23 成都欣华源科技有限责任公司 一种高碳烯烃氢甲酰化连续循环工艺及系统

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Also Published As

Publication number Publication date
WO2011046781A1 (en) 2011-04-21
EP2488539B1 (en) 2016-01-06
US20120190894A1 (en) 2012-07-26
US8586800B2 (en) 2013-11-19
JP2013508274A (ja) 2013-03-07
EP2488539A1 (en) 2012-08-22
EP2488539B2 (en) 2023-12-20
CN102574878A (zh) 2012-07-11
ZA201202751B (en) 2013-06-26
CN107266298A (zh) 2017-10-20

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