JP2013236987A5 - - Google Patents
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- Publication number
- JP2013236987A5 JP2013236987A5 JP2012109948A JP2012109948A JP2013236987A5 JP 2013236987 A5 JP2013236987 A5 JP 2013236987A5 JP 2012109948 A JP2012109948 A JP 2012109948A JP 2012109948 A JP2012109948 A JP 2012109948A JP 2013236987 A5 JP2013236987 A5 JP 2013236987A5
- Authority
- JP
- Japan
- Prior art keywords
- absorption
- amine
- amino
- solution
- tower
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000010521 absorption reaction Methods 0.000 claims description 90
- 150000001412 amines Chemical class 0.000 claims description 52
- 239000007788 liquid Substances 0.000 claims description 49
- 239000007789 gas Substances 0.000 claims description 46
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 39
- 230000008929 regeneration Effects 0.000 claims description 39
- 238000011069 regeneration method Methods 0.000 claims description 39
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 claims description 30
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims description 30
- 230000002745 absorbent Effects 0.000 claims description 24
- 239000002250 absorbent Substances 0.000 claims description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 21
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 claims description 20
- 150000003141 primary amines Chemical class 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 18
- 229920000768 polyamine Polymers 0.000 claims description 18
- 239000002131 composite material Substances 0.000 claims description 14
- KVKFRMCSXWQSNT-UHFFFAOYSA-N n,n'-dimethylethane-1,2-diamine Chemical compound CNCCNC KVKFRMCSXWQSNT-UHFFFAOYSA-N 0.000 claims description 10
- PVOAHINGSUIXLS-UHFFFAOYSA-N 1-Methylpiperazine Chemical compound CN1CCNCC1 PVOAHINGSUIXLS-UHFFFAOYSA-N 0.000 claims description 9
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 claims description 8
- JCBPETKZIGVZRE-UHFFFAOYSA-N 2-aminobutan-1-ol Chemical compound CCC(N)CO JCBPETKZIGVZRE-UHFFFAOYSA-N 0.000 claims description 8
- BKMMTJMQCTUHRP-UHFFFAOYSA-N 2-aminopropan-1-ol Chemical group CC(N)CO BKMMTJMQCTUHRP-UHFFFAOYSA-N 0.000 claims description 8
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 8
- GGHDAUPFEBTORZ-UHFFFAOYSA-N propane-1,1-diamine Chemical compound CCC(N)N GGHDAUPFEBTORZ-UHFFFAOYSA-N 0.000 claims description 8
- 125000004122 cyclic group Chemical group 0.000 claims description 7
- 150000002430 hydrocarbons Chemical group 0.000 claims description 6
- CYXGZZFAAUDHQL-UHFFFAOYSA-N 1-n,1-n'-dimethylpropane-1,1-diamine Chemical compound CCC(NC)NC CYXGZZFAAUDHQL-UHFFFAOYSA-N 0.000 claims description 5
- NSMWYRLQHIXVAP-UHFFFAOYSA-N 2,5-dimethylpiperazine Chemical compound CC1CNC(C)CN1 NSMWYRLQHIXVAP-UHFFFAOYSA-N 0.000 claims description 5
- JOMNTHCQHJPVAZ-UHFFFAOYSA-N 2-methylpiperazine Chemical compound CC1CNCCN1 JOMNTHCQHJPVAZ-UHFFFAOYSA-N 0.000 claims description 5
- CJKRXEBLWJVYJD-UHFFFAOYSA-N N,N'-diethylethylenediamine Chemical compound CCNCCNCC CJKRXEBLWJVYJD-UHFFFAOYSA-N 0.000 claims description 5
- IMUDHTPIFIBORV-UHFFFAOYSA-N aminoethylpiperazine Chemical compound NCCN1CCNCC1 IMUDHTPIFIBORV-UHFFFAOYSA-N 0.000 claims description 5
- WFCSWCVEJLETKA-UHFFFAOYSA-N 2-piperazin-1-ylethanol Chemical compound OCCN1CCNCC1 WFCSWCVEJLETKA-UHFFFAOYSA-N 0.000 claims description 3
- 239000004215 Carbon black (E152) Substances 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 125000000524 functional group Chemical group 0.000 claims description 3
- 229930195733 hydrocarbon Natural products 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- NWYYWIJOWOLJNR-UHFFFAOYSA-N 2-Amino-3-methyl-1-butanol Chemical compound CC(C)C(N)CO NWYYWIJOWOLJNR-UHFFFAOYSA-N 0.000 claims description 2
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 claims 3
- 229920006395 saturated elastomer Polymers 0.000 description 23
- 238000011084 recovery Methods 0.000 description 16
- 238000006243 chemical reaction Methods 0.000 description 15
- 238000002485 combustion reaction Methods 0.000 description 9
- 238000010586 diagram Methods 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- YVLHRYOHNHUVOA-UHFFFAOYSA-N 2,2-dimethylpropane-1,1-diamine Chemical compound CC(C)(C)C(N)N YVLHRYOHNHUVOA-UHFFFAOYSA-N 0.000 description 5
- 238000001816 cooling Methods 0.000 description 4
- KODLUXHSIZOKTG-UHFFFAOYSA-N 1-aminobutan-2-ol Chemical compound CCC(O)CN KODLUXHSIZOKTG-UHFFFAOYSA-N 0.000 description 3
- YLZOPXRUQYQQID-UHFFFAOYSA-N 3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)-1-[4-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]piperazin-1-yl]propan-1-one Chemical compound N1N=NC=2CN(CCC=21)CCC(=O)N1CCN(CC1)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F YLZOPXRUQYQQID-UHFFFAOYSA-N 0.000 description 3
- 239000006096 absorbing agent Substances 0.000 description 3
- 239000012752 auxiliary agent Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 150000002169 ethanolamines Chemical class 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- 239000000498 cooling water Substances 0.000 description 2
- 239000003546 flue gas Substances 0.000 description 2
- 239000002803 fossil fuel Substances 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 230000001172 regenerating effect Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000010792 warming Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- GOJUJUVQIVIZAV-UHFFFAOYSA-N 2-amino-4,6-dichloropyrimidine-5-carbaldehyde Chemical group NC1=NC(Cl)=C(C=O)C(Cl)=N1 GOJUJUVQIVIZAV-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2012109948A JP5986796B2 (ja) | 2012-05-11 | 2012-05-11 | 複合アミン吸収液、ｃｏ２又はｈ２ｓ又はその双方の除去装置及び方法 |
| EP13788078.7A EP2848298B1 (en) | 2012-05-11 | 2013-04-25 | Composite amine absorbing solution and method for removing co2, h2s, or both |
| CA2872593A CA2872593C (en) | 2012-05-11 | 2013-04-25 | Complex amine absorbent, and device and method for removing one or both of co2 and h2s |
| AU2013258901A AU2013258901B2 (en) | 2012-05-11 | 2013-04-25 | Composite amine absorbing solution, and device and method for removing CO2, H2S, or both |
| US14/399,107 US10137407B2 (en) | 2012-05-11 | 2013-04-25 | Complex amine absorbent, and device and method for removing one or both of CO2 and H2S |
| PCT/JP2013/062259 WO2013168588A1 (ja) | 2012-05-11 | 2013-04-25 | 複合アミン吸収液、ｃｏ2又はｈ2ｓ又はその双方の除去装置及び方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2012109948A JP5986796B2 (ja) | 2012-05-11 | 2012-05-11 | 複合アミン吸収液、ｃｏ２又はｈ２ｓ又はその双方の除去装置及び方法 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2013236987A JP2013236987A (ja) | 2013-11-28 |
| JP2013236987A5 true JP2013236987A5 (enrdf_load_stackoverflow) | 2014-11-06 |
| JP5986796B2 JP5986796B2 (ja) | 2016-09-06 |
Family
ID=49550634
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012109948A Active JP5986796B2 (ja) | 2012-05-11 | 2012-05-11 | 複合アミン吸収液、ｃｏ２又はｈ２ｓ又はその双方の除去装置及び方法 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US10137407B2 (enrdf_load_stackoverflow) |
| EP (1) | EP2848298B1 (enrdf_load_stackoverflow) |
| JP (1) | JP5986796B2 (enrdf_load_stackoverflow) |
| AU (1) | AU2013258901B2 (enrdf_load_stackoverflow) |
| CA (1) | CA2872593C (enrdf_load_stackoverflow) |
| WO (1) | WO2013168588A1 (enrdf_load_stackoverflow) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6841676B2 (ja) | 2017-01-31 | 2021-03-10 | 三菱重工エンジニアリング株式会社 | 複合アミン吸収液、ｃｏ２又はｈ２ｓ又はその双方の除去装置及び方法 |
| GB201813839D0 (en) * | 2018-06-26 | 2018-10-10 | Carbon Clean Solutions Ltd | System and process of capturing carbon dioxide from flue gases |
| CN113457382A (zh) * | 2021-07-22 | 2021-10-01 | 浙江天地环保科技股份有限公司 | 一种低粘度的co2捕集混合吸收剂配方 |
| EP4395917A4 (en) | 2021-08-31 | 2025-10-15 | Univ Yale | CARBON SEQUESTRATION SYSTEMS AND METHODS USING ENHANCED WEATHERING |
Family Cites Families (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU506199B2 (en) * | 1975-06-26 | 1979-12-20 | Exxon Research And Engineering Company | Absorbtion of co2 from gaseous feeds |
| DE2551717C3 (de) * | 1975-11-18 | 1980-11-13 | Basf Ag, 6700 Ludwigshafen | und ggf. COS aus Gasen |
| CA1091429A (en) * | 1977-01-06 | 1980-12-16 | Guido Sartori | Process for removing carbon dioxide containing acidic gases from gaseous mixtures |
| US4100257A (en) * | 1977-02-14 | 1978-07-11 | Exxon Research & Engineering Co. | Process and amine-solvent absorbent for removing acidic gases from gaseous mixtures |
| US4100099A (en) * | 1977-03-28 | 1978-07-11 | The Dow Chemical Company | Quaternary salt-polyamine inhibitor for sour gas conditioning solutions |
| JPH0644972B2 (ja) * | 1988-03-11 | 1994-06-15 | ユニオン・カーバイド・コーポレーション | エチレンアミン促進剤を含有する第三級アルカノールアミン吸収剤及びその使用法 |
| JPH04349921A (ja) * | 1991-05-27 | 1992-12-04 | Mitsubishi Heavy Ind Ltd | 排煙脱炭吸収剤 |
| JP2809368B2 (ja) * | 1993-04-05 | 1998-10-08 | 関西電力株式会社 | 燃焼排ガス中の二酸化炭素の回収方法 |
| JPH06343858A (ja) * | 1993-06-08 | 1994-12-20 | Mitsubishi Heavy Ind Ltd | 二酸化炭素吸収剤 |
| JPH0751537A (ja) | 1993-06-30 | 1995-02-28 | Mitsubishi Heavy Ind Ltd | Ｃｏ２ 含有ガス中のｃｏ２ を除去する方法 |
| DE19828977A1 (de) * | 1998-06-29 | 1999-12-30 | Basf Ag | Verfahren zur Entfernung saurer Gasbestandteile aus Gasen |
| US6165433A (en) * | 1999-06-10 | 2000-12-26 | Praxair Technology, Inc. | Carbon dioxide recovery with composite amine blends |
| JP4690659B2 (ja) | 2004-03-15 | 2011-06-01 | 三菱重工業株式会社 | Ｃｏ２回収装置 |
| US7368476B2 (en) * | 2004-04-07 | 2008-05-06 | Pharmacyclics, Inc. | Hydroxamates as therapeutic agents |
| DE112007000375B4 (de) * | 2006-02-14 | 2021-01-07 | Basf Se | Verfahren zum Entfernen saurer Gase und Verfahren zur Umrüstung von Anlagen zur Entfernung saurer Gase |
| EP1998870B2 (de) * | 2006-03-16 | 2015-09-02 | Basf Se | Verfahren zum inkontaktbringen zweier phasen, deren kontakt von wärmeentwicklung begleitet ist |
| JP5230080B2 (ja) | 2006-06-06 | 2013-07-10 | 三菱重工業株式会社 | 吸収液、ｃｏ２の除去装置及び方法 |
| JP2008013400A (ja) | 2006-07-05 | 2008-01-24 | Research Institute Of Innovative Technology For The Earth | 排ガス中の二酸化炭素を吸収及び脱離して回収する方法 |
| US7901488B2 (en) * | 2006-10-04 | 2011-03-08 | Board Of Regents, The University Of Texas System | Regeneration of an aqueous solution from an acid gas absorption process by matrix stripping |
| JP5215595B2 (ja) * | 2007-06-18 | 2013-06-19 | 三菱重工業株式会社 | 吸収液、吸収液を用いたｃｏ２又はｈ２ｓ除去装置及び方法 |
| CA2726922C (en) * | 2008-06-23 | 2018-01-02 | Basf Se | Absorption medium and method for removing acid gases from a gas stream |
| KR101035148B1 (ko) * | 2008-10-28 | 2011-05-17 | 한국전력공사 | 산성가스 분리용 흡수제 |
| EP2435540B1 (en) * | 2009-05-26 | 2018-04-04 | Basf Se | Process for recovery of carbon dioxide from a fluid stream, in particular from syngas |
| DE102010004073A1 (de) * | 2010-01-05 | 2011-07-07 | Uhde GmbH, 44141 | CO2-Entfernung aus Gasen mit niedrigen CO2-Partialdrücken mittels 1,2 Diaminopropan |
| WO2011121635A1 (ja) * | 2010-03-29 | 2011-10-06 | 株式会社 東芝 | 酸性ガス吸収剤、酸性ガス除去装置および酸性ガス除去方法 |
| US9266102B2 (en) * | 2013-03-29 | 2016-02-23 | The University Of Kentucky Research Foundation | Catalysts and methods of increasing mass transfer rate of acid gas scrubbing solvents |
-
2012
- 2012-05-11 JP JP2012109948A patent/JP5986796B2/ja active Active
-
2013
- 2013-04-25 US US14/399,107 patent/US10137407B2/en active Active
- 2013-04-25 CA CA2872593A patent/CA2872593C/en active Active
- 2013-04-25 EP EP13788078.7A patent/EP2848298B1/en active Active
- 2013-04-25 WO PCT/JP2013/062259 patent/WO2013168588A1/ja active Application Filing
- 2013-04-25 AU AU2013258901A patent/AU2013258901B2/en active Active
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