JP2013030420A - 表面フッ素化ｂ型酸化チタンを含むリチウムイオン電池用負極材料とその製造方法、およびそれを用いたリチウムイオン電池 - Google Patents

表面フッ素化ｂ型酸化チタンを含むリチウムイオン電池用負極材料とその製造方法、およびそれを用いたリチウムイオン電池 Download PDF

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Publication number
JP2013030420A
JP2013030420A JP2011167046A JP2011167046A JP2013030420A JP 2013030420 A JP2013030420 A JP 2013030420A JP 2011167046 A JP2011167046 A JP 2011167046A JP 2011167046 A JP2011167046 A JP 2011167046A JP 2013030420 A JP2013030420 A JP 2013030420A
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JP
Japan
Prior art keywords
titanium oxide
type titanium
lithium ion
fluorine
ion battery
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2011167046A
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English (en)
Japanese (ja)
Other versions
JP2013030420A5 (enExample
Inventor
Minoru Inaba
稔 稲葉
Akimasa Tasaka
明政 田坂
Morihiro Saito
守弘 齋藤
Mikihiro Takagi
幹大 高木
Hitoshi Takebayashi
仁 竹林
Yoshio Hatsushiro
善夫 初代
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toyo Tanso Co Ltd
Doshisha Co Ltd
Original Assignee
Toyo Tanso Co Ltd
Doshisha Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toyo Tanso Co Ltd, Doshisha Co Ltd filed Critical Toyo Tanso Co Ltd
Priority to JP2011167046A priority Critical patent/JP2013030420A/ja
Priority to EP12820524.2A priority patent/EP2738843A4/en
Priority to KR1020147001681A priority patent/KR20140042874A/ko
Priority to PCT/JP2012/068921 priority patent/WO2013018638A1/ja
Priority to US14/235,679 priority patent/US20140170497A1/en
Priority to CN201280037823.0A priority patent/CN103782421A/zh
Priority to TW101127176A priority patent/TW201338252A/zh
Publication of JP2013030420A publication Critical patent/JP2013030420A/ja
Publication of JP2013030420A5 publication Critical patent/JP2013030420A5/ja
Pending legal-status Critical Current

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G23/00—Compounds of titanium
    • C01G23/04—Oxides; Hydroxides
    • C01G23/047—Titanium dioxide
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/50—Solid solutions
    • C01P2002/52—Solid solutions containing elements as dopants
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
    • C01P2002/85—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by XPS, EDX or EDAX data
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/01—Particle morphology depicted by an image
    • C01P2004/03—Particle morphology depicted by an image obtained by SEM
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/021—Physical characteristics, e.g. porosity, surface area
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/027—Negative electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H01M4/1315—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx containing halogen atoms, e.g. LiCoOxFy
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Composite Materials (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
JP2011167046A 2011-07-29 2011-07-29 表面フッ素化ｂ型酸化チタンを含むリチウムイオン電池用負極材料とその製造方法、およびそれを用いたリチウムイオン電池 Pending JP2013030420A (ja)

Priority Applications (7)

Application Number Priority Date Filing Date Title
JP2011167046A JP2013030420A (ja) 2011-07-29 2011-07-29 表面フッ素化ｂ型酸化チタンを含むリチウムイオン電池用負極材料とその製造方法、およびそれを用いたリチウムイオン電池
EP12820524.2A EP2738843A4 (en) 2011-07-29 2012-07-26 NEGATIVE ELECTRODE MATERIAL FOR LITHIUM ION BATTERIES WITH A SURFACE FLUORINATED B-TITANIUM DIOXIDE POWDER, METHOD OF MANUFACTURING THEREOF AND LITHIUM ION BATTERY THEREWITH
KR1020147001681A KR20140042874A (ko) 2011-07-29 2012-07-26 표면 불소화 b형 산화 티타늄 분말을 포함하는 리튬 이온 전지용 부극 재료와 그 제조 방법 및 그것을 사용한 리튬 이온 전지
PCT/JP2012/068921 WO2013018638A1 (ja) 2011-07-29 2012-07-26 表面フッ素化ｂ型酸化チタン粉末を含むリチウムイオン電池用負極材料とその製造方法、およびそれを用いたリチウムイオン電池
US14/235,679 US20140170497A1 (en) 2011-07-29 2012-07-26 Negative electrode material for lithium ion batteries containing surface-fluorinated b-type titanium oxide powder, method for producing same, and lithium ion battery using same
CN201280037823.0A CN103782421A (zh) 2011-07-29 2012-07-26 含表面氟化b型氧化钛粉末的锂离子电池用负极材料及其制造方法、和使用其的锂离子电池
TW101127176A TW201338252A (zh) 2011-07-29 2012-07-27 含有表面氟化ｂ型氧化鈦粉末之鋰離子電池用負極材料與其製造方法、及使用其之鋰離子電池

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2011167046A JP2013030420A (ja) 2011-07-29 2011-07-29 表面フッ素化ｂ型酸化チタンを含むリチウムイオン電池用負極材料とその製造方法、およびそれを用いたリチウムイオン電池

Publications (2)

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JP2013030420A true JP2013030420A (ja) 2013-02-07
JP2013030420A5 JP2013030420A5 (enExample) 2014-09-04

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JP2011167046A Pending JP2013030420A (ja) 2011-07-29 2011-07-29 表面フッ素化ｂ型酸化チタンを含むリチウムイオン電池用負極材料とその製造方法、およびそれを用いたリチウムイオン電池

Country Status (7)

Country Link
US (1) US20140170497A1 (enExample)
EP (1) EP2738843A4 (enExample)
JP (1) JP2013030420A (enExample)
KR (1) KR20140042874A (enExample)
CN (1) CN103782421A (enExample)
TW (1) TW201338252A (enExample)
WO (1) WO2013018638A1 (enExample)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013069429A (ja) * 2011-09-20 2013-04-18 Toshiba Corp 非水電解質電池及び電池パック
JP2014063702A (ja) * 2012-09-24 2014-04-10 Kaneka Corp 負極活物質の製造方法及び非水電解質二次電池

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6692810B2 (ja) * 2014-11-20 2020-05-13 ハイドロ−ケベック カチオン空孔によるナノメータアナターゼ格子、その生成方法、およびその使用
CN109904439B (zh) * 2017-12-11 2022-02-22 中信国安盟固利动力科技有限公司 一种新型钛基材料的低温制备方法
EP3954673A1 (en) * 2020-08-14 2022-02-16 Paul Scherrer Institut A method for preparing surface fluorinated battery materials
SE546073C2 (en) * 2020-08-14 2024-05-07 Tiotech As An electrode material and a battery comprising titanium dioxide bronze
CN112563499B (zh) * 2020-12-03 2022-04-15 南通百川新材料有限公司 一种锂离子电池TiO2负极的改性方法
IT202100000704A1 (it) * 2021-01-15 2022-07-15 Milano Politecnico Fluorurazione superficiale con fluoro elementare di litio metallico usato come anodo in batterie a litio metallico
CN114759172A (zh) * 2021-05-07 2022-07-15 广州倬粤电能科技有限公司 一种用于锌基电池的石墨烯/氧化锌负极材料的制备方法

Citations (3)

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Publication number Priority date Publication date Assignee Title
JP2005302601A (ja) * 2004-04-14 2005-10-27 Matsushita Electric Ind Co Ltd 電池用負極活物質、その製造方法および非水電解質二次電池
WO2010110035A1 (ja) * 2009-03-25 2010-09-30 株式会社 東芝 非水電解質電池用負極活物質、その製造方法、非水電解質電池及び電池パック
JP2012033355A (ja) * 2010-07-29 2012-02-16 Toshiba Corp 電池用活物質、非水電解質電池、電池パック、及び自動車

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Publication number Priority date Publication date Assignee Title
JP2010123401A (ja) * 2008-11-19 2010-06-03 Mitsubishi Chemicals Corp 非水電解質二次電池用電極材、非水電解質二次電池用電極及びそれを用いた非水電解質二次電池
WO2010137154A1 (ja) * 2009-05-28 2010-12-02 株式会社 東芝 電池用活物質、非水電解質電池および電池パック
CN101630735A (zh) * 2009-06-09 2010-01-20 北京交通大学 锂离子电池负极材料尖晶石型钛酸锂Li4Ti5O12的改性方法

Patent Citations (3)

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Publication number Priority date Publication date Assignee Title
JP2005302601A (ja) * 2004-04-14 2005-10-27 Matsushita Electric Ind Co Ltd 電池用負極活物質、その製造方法および非水電解質二次電池
WO2010110035A1 (ja) * 2009-03-25 2010-09-30 株式会社 東芝 非水電解質電池用負極活物質、その製造方法、非水電解質電池及び電池パック
JP2012033355A (ja) * 2010-07-29 2012-02-16 Toshiba Corp 電池用活物質、非水電解質電池、電池パック、及び自動車

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013069429A (ja) * 2011-09-20 2013-04-18 Toshiba Corp 非水電解質電池及び電池パック
JP2014063702A (ja) * 2012-09-24 2014-04-10 Kaneka Corp 負極活物質の製造方法及び非水電解質二次電池

Also Published As

Publication number Publication date
EP2738843A1 (en) 2014-06-04
WO2013018638A1 (ja) 2013-02-07
CN103782421A (zh) 2014-05-07
EP2738843A4 (en) 2015-04-29
US20140170497A1 (en) 2014-06-19
KR20140042874A (ko) 2014-04-07
TW201338252A (zh) 2013-09-16

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