JP2012528910A5 - - Google Patents
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- Publication number
- JP2012528910A5 JP2012528910A5 JP2012513593A JP2012513593A JP2012528910A5 JP 2012528910 A5 JP2012528910 A5 JP 2012528910A5 JP 2012513593 A JP2012513593 A JP 2012513593A JP 2012513593 A JP2012513593 A JP 2012513593A JP 2012528910 A5 JP2012528910 A5 JP 2012528910A5
- Authority
- JP
- Japan
- Prior art keywords
- mass
- polymerization
- solution
- butyl acrylate
- prepolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 16
- MOYAFQVGZZPNRA-UHFFFAOYSA-N Terpinolene Chemical compound CC(C)=C1CCC(C)=CC1 MOYAFQVGZZPNRA-UHFFFAOYSA-N 0.000 claims description 12
- 238000006116 polymerization reaction Methods 0.000 claims description 11
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 9
- 239000000178 monomer Substances 0.000 claims description 9
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 8
- 238000007720 emulsion polymerization reaction Methods 0.000 claims description 6
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 238000010528 free radical solution polymerization reaction Methods 0.000 claims description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
- DPBJAVGHACCNRL-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate Chemical compound CN(C)CCOC(=O)C=C DPBJAVGHACCNRL-UHFFFAOYSA-N 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- JNDVNJWCRZQGFQ-UHFFFAOYSA-N 2-methyl-N,N-bis(methylamino)hex-2-enamide Chemical compound CCCC=C(C)C(=O)N(NC)NC JNDVNJWCRZQGFQ-UHFFFAOYSA-N 0.000 claims description 3
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 claims description 2
- 125000002091 cationic group Chemical group 0.000 claims 12
- 239000004815 dispersion polymer Substances 0.000 claims 7
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims 6
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims 6
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims 4
- 125000003277 amino group Chemical group 0.000 claims 4
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims 4
- 239000003505 polymerization initiator Substances 0.000 claims 4
- 125000001453 quaternary ammonium group Chemical group 0.000 claims 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical class CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims 3
- 239000007864 aqueous solution Substances 0.000 claims 3
- 239000006185 dispersion Substances 0.000 claims 3
- 239000000243 solution Substances 0.000 claims 3
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims 2
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 claims 2
- 235000011054 acetic acid Nutrition 0.000 claims 2
- 239000002253 acid Substances 0.000 claims 2
- 235000019253 formic acid Nutrition 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 claims 2
- 230000000379 polymerizing effect Effects 0.000 claims 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims 2
- 235000019260 propionic acid Nutrition 0.000 claims 2
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 claims 2
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims 2
- 239000002904 solvent Substances 0.000 claims 2
- 150000003440 styrenes Chemical class 0.000 claims 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims 2
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 239000002270 dispersing agent Substances 0.000 claims 1
- 239000000839 emulsion Substances 0.000 claims 1
- 239000003607 modifier Substances 0.000 claims 1
- 239000000123 paper Substances 0.000 claims 1
- 229920000642 polymer Polymers 0.000 claims 1
- 238000004513 sizing Methods 0.000 claims 1
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 8
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 6
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 6
- 229960005070 ascorbic acid Drugs 0.000 description 4
- 235000010323 ascorbic acid Nutrition 0.000 description 4
- 239000011668 ascorbic acid Substances 0.000 description 4
- 239000008367 deionised water Substances 0.000 description 4
- 229910021641 deionized water Inorganic materials 0.000 description 4
- 239000011541 reaction mixture Substances 0.000 description 4
- 229960000583 acetic acid Drugs 0.000 description 2
- 239000002518 antifoaming agent Substances 0.000 description 2
- 238000009529 body temperature measurement Methods 0.000 description 2
- WQAQPCDUOCURKW-UHFFFAOYSA-N butanethiol Chemical compound CCCCS WQAQPCDUOCURKW-UHFFFAOYSA-N 0.000 description 2
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethanethiol Chemical compound CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 description 2
- 239000012362 glacial acetic acid Substances 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 2
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 239000002861 polymer material Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 235000007586 terpenes Nutrition 0.000 description 2
- BWSZXUOMATYHHI-UHFFFAOYSA-N tert-butyl octaneperoxoate Chemical compound CCCCCCCC(=O)OOC(C)(C)C BWSZXUOMATYHHI-UHFFFAOYSA-N 0.000 description 2
- HJUGFYREWKUQJT-UHFFFAOYSA-N tetrabromomethane Chemical compound BrC(Br)(Br)Br HJUGFYREWKUQJT-UHFFFAOYSA-N 0.000 description 2
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 description 2
- YAJYJWXEWKRTPO-UHFFFAOYSA-N 2,3,3,4,4,5-hexamethylhexane-2-thiol Chemical compound CC(C)C(C)(C)C(C)(C)C(C)(C)S YAJYJWXEWKRTPO-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 1
- -1 monocyclic terpenes Chemical class 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- WMXCDAVJEZZYLT-UHFFFAOYSA-N tert-butylthiol Chemical compound CC(C)(C)S WMXCDAVJEZZYLT-UHFFFAOYSA-N 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP09161929.6 | 2009-06-04 | ||
| EP09161929 | 2009-06-04 | ||
| PCT/EP2010/057615 WO2010139683A1 (de) | 2009-06-04 | 2010-06-01 | Feinteilige, kationische, wässrige polymerdispersionen, verfahren zu ihrer herstellung und ihre verwendung |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2012528910A JP2012528910A (ja) | 2012-11-15 |
| JP2012528910A5 true JP2012528910A5 (https=) | 2014-02-06 |
Family
ID=42557255
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012513593A Ceased JP2012528910A (ja) | 2009-06-04 | 2010-06-01 | 微細なカチオン性水性ポリマー分散液、その製造法及びその使用 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US8901227B2 (https=) |
| EP (1) | EP2438097B1 (https=) |
| JP (1) | JP2012528910A (https=) |
| CN (1) | CN102459369A (https=) |
| BR (1) | BRPI1011137A2 (https=) |
| ES (1) | ES2405607T3 (https=) |
| WO (1) | WO2010139683A1 (https=) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR112013012463B1 (pt) | 2010-11-25 | 2020-04-22 | Basf Se | dispersão polimérica aquosa finamente dividida, catiônica ou anfótera, processos de preparar uma dispersão polimérica aquosa finamente dividida, catiônica ou anfótera e de fabricar um coloide protetivo catiônico ou anfótero, coloide protetivo catiônico ou anfótero, e, uso das dispersões poliméricas aquosas, catiônicas ou anfóteras, finamente divididas |
| KR101970857B1 (ko) * | 2012-03-29 | 2019-04-19 | 데이진 가부시키가이샤 | 섬유용 방염 가공제 |
| CN103788296B (zh) * | 2013-12-06 | 2016-04-27 | 江苏苏博特新材料股份有限公司 | 一种阳离子聚丙烯酰胺共聚物耐高温水包水分散液及其低粘度制备方法 |
| US20170369604A1 (en) * | 2014-12-19 | 2017-12-28 | Basf Se | Finely divided, cationic, aqueous polymer dispersions, method for the production thereof, and the use thereof |
| ES2840649T3 (es) | 2015-12-01 | 2021-07-07 | Solenis Technologies Cayman Lp | Dispersiones poliméricas acuosas catiónicas finamente divididas, método para la producción de las mismas, y el uso de las mismas |
| FI127745B (en) * | 2015-12-31 | 2019-01-31 | Kemira Oyj | Cationic surfactant |
| EP3478734B1 (en) | 2016-06-30 | 2021-03-31 | Solenis Technologies Cayman, L.P. | Finely divided, cationic, aqueous polymer dispersions, method for the production thereof, and use thereof |
| RS67579B1 (sr) | 2017-03-30 | 2026-01-30 | Kemira Oyj | Kompozicija za površinsko keljenje, postupak proizvodnje i upotreba iste |
| FR3100249B1 (fr) * | 2019-08-28 | 2021-10-29 | Arkema France | Procédé de traitement de dispersions polymères basé sur l’utilisation de peroxydes organiques spécifiques |
| EP4085080A1 (en) * | 2019-12-30 | 2022-11-09 | Kemira OYJ | Polymer dispersion, its use and process for its preparation |
| EP4289873A1 (en) * | 2022-06-10 | 2023-12-13 | Solenis Technologies Cayman, L.P. | High molecular weight polymeric dispersions manufactured under controlled adiabatic conditions |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2452585B2 (de) | 1974-11-06 | 1981-07-30 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung scherstabiler wäßriger Copolymerisat-Dispersionen |
| DE2454397C2 (de) | 1974-11-16 | 1983-01-27 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung scherstabiler kationischer wäßriger Copolymerisat- Dispersionen |
| DE3039976A1 (de) | 1980-10-23 | 1982-06-03 | Basf Ag, 6700 Ludwigshafen | Feinteilige, stickstoffhaltige monomere einpolymerisiert enthaltende polymerdispersion |
| DE3103917A1 (de) | 1981-02-05 | 1982-08-19 | Bayer Ag, 5090 Leverkusen | Kationisches leimungsmittel fuer papier und verfahren zu seiner herstellung |
| DE3401573A1 (de) | 1984-01-18 | 1985-07-25 | Bayer Ag, 5090 Leverkusen | Kationisches leimungsmittel fuer papier und verfahren zu seiner herstellung |
| US6011103A (en) * | 1996-02-23 | 2000-01-04 | Arakawa Kagaku Kogyo Kabushiki Kaisha | Aqueous dispersion of cationic fine grain gel and process for preparing the same |
| MY118538A (en) * | 1997-01-20 | 2004-12-31 | Ciba Spec Chem Water Treat Ltd | Polymeric compositions and their production and uses |
| JP4645927B2 (ja) * | 2000-03-15 | 2011-03-09 | 星光Ｐｍｃ株式会社 | カチオン性エマルション型表面サイズ剤 |
| EP1180527B1 (de) | 2000-08-16 | 2005-04-06 | Bayer Chemicals AG | Kationische Polymerdispersionen zur Papierleimung |
| DE102004027735A1 (de) * | 2004-06-07 | 2005-12-22 | Basf Ag | Feinteilige, amphotere, wässrige Polymerdispersionen, Verfahren zu ihrer Herstellung und ihre Verwendung |
| DE102005023799A1 (de) * | 2005-05-19 | 2006-11-23 | Basf Ag | Wässrige Dispersionen von wasserlöslichen und/oder in Wasser quellbaren anionischen Polymerisaten, Verfahren zu ihrer Herstellung und ihre Verwendung |
| US20100022701A1 (en) | 2006-12-14 | 2010-01-28 | Basf Se | Finely divided, cationic polymer dispersions |
-
2010
- 2010-06-01 ES ES10724434T patent/ES2405607T3/es active Active
- 2010-06-01 US US13/376,078 patent/US8901227B2/en not_active Expired - Fee Related
- 2010-06-01 BR BRPI1011137A patent/BRPI1011137A2/pt not_active IP Right Cessation
- 2010-06-01 JP JP2012513593A patent/JP2012528910A/ja not_active Ceased
- 2010-06-01 CN CN201080024668XA patent/CN102459369A/zh active Pending
- 2010-06-01 EP EP10724434A patent/EP2438097B1/de active Active
- 2010-06-01 WO PCT/EP2010/057615 patent/WO2010139683A1/de not_active Ceased
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