JP2012524785A - 高効率触媒を用いたアルキレンオキシド簡易製造方法 - Google Patents
高効率触媒を用いたアルキレンオキシド簡易製造方法 Download PDFInfo
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- JP2012524785A JP2012524785A JP2012507296A JP2012507296A JP2012524785A JP 2012524785 A JP2012524785 A JP 2012524785A JP 2012507296 A JP2012507296 A JP 2012507296A JP 2012507296 A JP2012507296 A JP 2012507296A JP 2012524785 A JP2012524785 A JP 2012524785A
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- catalyst
- alkylene oxide
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- 239000003054 catalyst Substances 0.000 title claims abstract description 300
- 125000002947 alkylene group Chemical group 0.000 title claims abstract description 119
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 59
- 238000006243 chemical reaction Methods 0.000 claims abstract description 185
- 238000000034 method Methods 0.000 claims abstract description 89
- 238000005660 chlorination reaction Methods 0.000 claims abstract description 56
- 229910052709 silver Inorganic materials 0.000 claims abstract description 46
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 45
- 239000004332 silver Substances 0.000 claims abstract description 45
- 230000032683 aging Effects 0.000 claims abstract description 44
- 239000007789 gas Substances 0.000 claims description 94
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 80
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 claims description 57
- 229960003750 ethyl chloride Drugs 0.000 claims description 57
- 230000008569 process Effects 0.000 claims description 54
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims description 48
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 45
- 239000005977 Ethylene Substances 0.000 claims description 45
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- 229910052760 oxygen Inorganic materials 0.000 claims description 34
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 31
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- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 claims description 19
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- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
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- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 2
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Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/22—Synthesis of the oxirane ring by oxidation of saturated compounds with air or molecular oxygen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/24—Synthesis of the oxirane ring by splitting off HAL—Y from compounds containing the radical HAL—C—C—OY
- C07D301/26—Y being hydrogen
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Epoxy Compounds (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
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| PCT/US2010/031668 WO2010123842A1 (en) | 2009-04-21 | 2010-04-20 | Simplified method for producing alkylene oxides with a high efficiency catalyst as it ages |
Publications (2)
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| JP2012524785A true JP2012524785A (ja) | 2012-10-18 |
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| SG (1) | SG175770A1 (enExample) |
| TW (1) | TWI508955B (enExample) |
| WO (1) | WO2010123842A1 (enExample) |
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| JP2015208702A (ja) * | 2014-04-24 | 2015-11-24 | 東ソー株式会社 | 触媒性能の経時変化解析方法および触媒性能の経時変化解析装置 |
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| JP5756087B2 (ja) * | 2009-04-21 | 2015-07-29 | ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー | 高効率触媒による特定のアルキレンオキサイド製造パラメーターを達成かつ維持する改良方法 |
| US8742147B2 (en) | 2010-12-08 | 2014-06-03 | Shell Oil Company | Process for improving the selectivity of an EO catalyst |
| EP2649059B1 (en) | 2010-12-10 | 2016-02-24 | Dow Technology Investments LLC | Method of reducing the value of an alkylene oxide production parameter in a process of making an alkylene oxide using a high efficiency catalyst |
| WO2012082389A1 (en) * | 2010-12-15 | 2012-06-21 | Dow Technology Investments Llc | Method of starting-up a process of producing an alkylene oxide using a high-efficiency catalyst |
| EP2714670B2 (en) | 2011-04-29 | 2022-03-02 | Shell Internationale Research Maatschappij B.V. | Process for improving the selectivity of an eo catalyst |
| CN108707125A (zh) * | 2011-10-18 | 2018-10-26 | 哈桑·伊萨·阿拉哈迈迪 | 具有添加缓和剂的环氧化方法 |
| SG11201403042SA (en) * | 2011-12-09 | 2014-10-30 | Dow Technology Investments Llc | Method of maintaining the value of an alkylene oxide production parameter in a process of making an alkylene oxide using a high efficiency catalyst |
| SG11201507353RA (en) * | 2013-03-15 | 2015-10-29 | Dow Technology Investments Llc | Method for the production of ethylene oxide |
| CN105330617B (zh) * | 2014-07-18 | 2018-12-28 | 中国石油化工股份有限公司 | 一种生产环氧乙烷的方法 |
| CA2972690C (en) * | 2014-12-30 | 2023-08-22 | Dow Technology Investments Llc | Process for manufacturing ethylene oxide using scaled selectivity values |
| CN109312215B (zh) | 2016-08-05 | 2021-03-26 | 神岛化学工业株式会社 | 稀土类硫氧化物蓄冷材料 |
| CN111450778B (zh) * | 2019-01-22 | 2023-04-07 | 中国石化工程建设有限公司 | 一种用于制备聚α-烯烃的聚合反应系统和方法 |
| CN111939846B (zh) * | 2019-05-17 | 2023-01-03 | 中国石化工程建设有限公司 | 一种合成聚α-烯烃的装置及方法 |
| US11249446B2 (en) | 2019-10-25 | 2022-02-15 | Dow Global Technologies Llc | Nonlinear model predictive control of a process |
| TW202239752A (zh) | 2020-12-29 | 2022-10-16 | 荷蘭商蜆殼國際研究所 | 用於生產環氧乙烷之製程 |
| WO2022214539A1 (en) | 2021-04-08 | 2022-10-13 | Shell Internationale Research Maatschappij B.V. | Moderator and catalyst performance optimization for epoxidation of ethylene |
| CN118019732A (zh) * | 2021-09-23 | 2024-05-10 | 陶氏环球技术有限责任公司 | 用于降低高选择性环氧乙烷催化剂的老化相关失活的方法 |
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2010
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- 2010-04-20 WO PCT/US2010/031668 patent/WO2010123842A1/en not_active Ceased
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- 2010-04-20 CN CN201080017744.4A patent/CN102414187B/zh active Active
- 2010-04-20 KR KR1020117027498A patent/KR101745737B1/ko not_active Expired - Fee Related
- 2010-04-20 EP EP10718767.6A patent/EP2421840B1/en not_active Revoked
- 2010-04-20 SG SG2011077575A patent/SG175770A1/en unknown
- 2010-04-20 CA CA2758818A patent/CA2758818C/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005516900A (ja) * | 2001-11-20 | 2005-06-09 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | オレフィンのエポキシ化の方法およびシステム |
| JP2005518356A (ja) * | 2001-11-20 | 2005-06-23 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | オレフィンのエポキシ化のプロセスおよびシステム |
| JP2006522138A (ja) * | 2003-04-01 | 2006-09-28 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | オレフィンのエポキシ化方法とその方法において使用される触媒 |
| WO2009035809A1 (en) * | 2007-09-11 | 2009-03-19 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Ethylene oxide production using fixed moderator concentration |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2015208702A (ja) * | 2014-04-24 | 2015-11-24 | 東ソー株式会社 | 触媒性能の経時変化解析方法および触媒性能の経時変化解析装置 |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20120014159A (ko) | 2012-02-16 |
| CA2758818A1 (en) | 2010-10-28 |
| WO2010123842A1 (en) | 2010-10-28 |
| CN102414187A (zh) | 2012-04-11 |
| CA2758818C (en) | 2018-05-29 |
| US8389751B2 (en) | 2013-03-05 |
| TWI508955B (zh) | 2015-11-21 |
| TW201100394A (en) | 2011-01-01 |
| EP2421840B1 (en) | 2015-12-16 |
| US20100267974A1 (en) | 2010-10-21 |
| SG175770A1 (en) | 2011-12-29 |
| KR101745737B1 (ko) | 2017-06-09 |
| CN102414187B (zh) | 2016-06-01 |
| EP2421840A1 (en) | 2012-02-29 |
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