JP2012253004A5 - - Google Patents
Download PDFInfo
- Publication number
- JP2012253004A5 JP2012253004A5 JP2011263721A JP2011263721A JP2012253004A5 JP 2012253004 A5 JP2012253004 A5 JP 2012253004A5 JP 2011263721 A JP2011263721 A JP 2011263721A JP 2011263721 A JP2011263721 A JP 2011263721A JP 2012253004 A5 JP2012253004 A5 JP 2012253004A5
- Authority
- JP
- Japan
- Prior art keywords
- film
- metal oxide
- oxide semiconductor
- porous
- dye
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004065 semiconductor Substances 0.000 claims description 28
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 22
- 239000002105 nanoparticle Substances 0.000 claims description 19
- 239000000758 substrate Substances 0.000 claims description 17
- 229910044991 metal oxide Inorganic materials 0.000 claims description 16
- 150000004706 metal oxides Chemical class 0.000 claims description 16
- 239000010419 fine particle Substances 0.000 claims description 12
- 238000006243 chemical reaction Methods 0.000 claims description 11
- 239000002245 particle Substances 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 7
- 239000004408 titanium dioxide Substances 0.000 claims description 7
- 239000013078 crystal Substances 0.000 claims description 3
- 239000011164 primary particle Substances 0.000 claims description 3
- 230000002378 acidificating effect Effects 0.000 claims description 2
- 239000007864 aqueous solution Substances 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 230000001235 sensitizing effect Effects 0.000 claims description 2
- 239000006185 dispersion Substances 0.000 description 17
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 15
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 12
- 239000002904 solvent Substances 0.000 description 12
- 239000003792 electrolyte Substances 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 238000009835 boiling Methods 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 230000008018 melting Effects 0.000 description 5
- 238000002844 melting Methods 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 239000008151 electrolyte solution Substances 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 230000004888 barrier function Effects 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000002923 metal particle Substances 0.000 description 3
- 229910000510 noble metal Inorganic materials 0.000 description 3
- 239000005022 packaging material Substances 0.000 description 3
- 230000035699 permeability Effects 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- -1 titanium alkoxide Chemical class 0.000 description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 3
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 2
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 2
- 229920002799 BoPET Polymers 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 229920001940 conductive polymer Polymers 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000002985 plastic film Substances 0.000 description 2
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- JBOIAZWJIACNJF-UHFFFAOYSA-N 1h-imidazole;hydroiodide Chemical compound [I-].[NH2+]1C=CN=C1 JBOIAZWJIACNJF-UHFFFAOYSA-N 0.000 description 1
- VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- 229940093475 2-ethoxyethanol Drugs 0.000 description 1
- YSHMQTRICHYLGF-UHFFFAOYSA-N 4-tert-butylpyridine Chemical compound CC(C)(C)C1=CC=NC=C1 YSHMQTRICHYLGF-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- RAXXELZNTBOGNW-UHFFFAOYSA-O Imidazolium Chemical compound C1=C[NH+]=CN1 RAXXELZNTBOGNW-UHFFFAOYSA-O 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001356 alkyl thiols Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 239000012777 electrically insulating material Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000009661 fatigue test Methods 0.000 description 1
- YAGKRVSRTSUGEY-UHFFFAOYSA-N ferricyanide Chemical compound [Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] YAGKRVSRTSUGEY-UHFFFAOYSA-N 0.000 description 1
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- UETZVSHORCDDTH-UHFFFAOYSA-N iron(2+);hexacyanide Chemical compound [Fe+2].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] UETZVSHORCDDTH-UHFFFAOYSA-N 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910001509 metal bromide Inorganic materials 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 229910001511 metal iodide Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-O pyridinium Chemical compound C1=CC=[NH+]C=C1 JUJWROOIHBZHMG-UHFFFAOYSA-O 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- HYHCSLBZRBJJCH-UHFFFAOYSA-N sodium polysulfide Chemical compound [Na+].S HYHCSLBZRBJJCH-UHFFFAOYSA-N 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 125000005207 tetraalkylammonium group Chemical group 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011263721A JP5358790B2 (ja) | 2011-05-11 | 2011-12-01 | 色素増感型光電変換素子用光電極及びその製造方法 |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011106357 | 2011-05-11 | ||
| JP2011106357 | 2011-05-11 | ||
| JP2011263721A JP5358790B2 (ja) | 2011-05-11 | 2011-12-01 | 色素増感型光電変換素子用光電極及びその製造方法 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2012253004A JP2012253004A (ja) | 2012-12-20 |
| JP2012253004A5 true JP2012253004A5 (enExample) | 2013-06-27 |
| JP5358790B2 JP5358790B2 (ja) | 2013-12-04 |
Family
ID=47525616
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011263721A Expired - Fee Related JP5358790B2 (ja) | 2011-05-11 | 2011-12-01 | 色素増感型光電変換素子用光電極及びその製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP5358790B2 (enExample) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2015128105A (ja) | 2013-12-27 | 2015-07-09 | ソニー株式会社 | 半導体ナノ粒子分散体、光電変換素子および撮像装置 |
| JP6344759B2 (ja) * | 2014-04-01 | 2018-06-20 | 学校法人東京理科大学 | 酸化物ナノ粒子含有ペースト、色素増感太陽電池用光電極、および色素増感太陽電池 |
| KR101543530B1 (ko) | 2014-04-30 | 2015-08-12 | 상명대학교 천안산학협력단 | 염료감응 태양전지용 전해질 조성물 |
| KR101519786B1 (ko) * | 2014-04-30 | 2015-05-12 | 상명대학교 천안산학협력단 | 상온 인쇄형 고분자 겔 전해질 조성물 및 이를 이용한 염료감응 태양전지 |
| JP6753310B2 (ja) | 2014-07-08 | 2020-09-09 | 日本ゼオン株式会社 | 粘性分散液およびその製造方法、並びに、多孔質半導体電極基板および色素増感型太陽電池 |
| US20220084757A1 (en) * | 2019-01-31 | 2022-03-17 | Zeon Corporation | Titanium dioxide paste, porous semiconductor electrode substrate, photoelectrode, and dye-sensitized solar cell |
| CN112520819B (zh) * | 2020-12-02 | 2023-08-22 | 西安建筑科技大学 | 一种铋系三维微球异质结光电极及其制备和应用 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002008740A (ja) * | 2000-06-22 | 2002-01-11 | Yamaha Corp | 色素増感型光電池およびその製造方法 |
| JP4291542B2 (ja) * | 2002-03-29 | 2009-07-08 | Ｔｄｋ株式会社 | 光電変換用酸化物半導体電極および色素増感型太陽電池 |
| JP4562467B2 (ja) * | 2004-09-10 | 2010-10-13 | ペクセル・テクノロジーズ株式会社 | 半導体ナノ粒子を含む粘性分散液 |
| JP4801899B2 (ja) * | 2004-12-10 | 2011-10-26 | 学校法人桐蔭学園 | 塗膜形成用組成物、それを用いて得られる電極及び光電変換素子 |
| US20090114277A1 (en) * | 2006-03-02 | 2009-05-07 | Hironori Arakawa | Production Process of Photoelectrode for Dye-Sensitized Solar Cell, Photoelectrode for Dye-Sensitized Solar Cell and Dye-Sensitized Solar Cell. |
| CN102084535B (zh) * | 2008-05-02 | 2014-07-02 | 佩塞尔科技株式会社 | 色素敏化型光电转换元件 |
| JP5630745B2 (ja) * | 2010-01-07 | 2014-11-26 | 日新製鋼株式会社 | 色素増感型太陽電池用光電極の製造方法 |
-
2011
- 2011-12-01 JP JP2011263721A patent/JP5358790B2/ja not_active Expired - Fee Related
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Sun et al. | High efficiency dye-sensitized solar cells based on a bi-layered photoanode made of TiO2 nanocrystallites and microspheres with high thermal stability | |
| JP2012253004A5 (enExample) | ||
| Seidalilir et al. | High-performance and stable gel-state dye-sensitized solar cells using anodic TiO2 nanotube arrays and polymer-based gel electrolytes | |
| JP5075913B2 (ja) | 電解質組成物およびこれを用いた光電変換素子 | |
| Tan et al. | Preparation of nanocrystalline TiO2 thin film at low temperature and its application in dye-sensitized solar cell | |
| Ke et al. | Photoanodes consisting of mesoporous anatase TiO2 beads with various sizes for high-efficiency flexible dye-sensitized solar cells | |
| Syrrokostas et al. | Effects of paste storage on the properties of nanostructured thin films for the development of dye-sensitized solar cells | |
| US9299504B2 (en) | Preparation method of low temperature sintering active electrode paste for dye sensitized solar cell | |
| JP5358790B2 (ja) | 色素増感型光電変換素子用光電極及びその製造方法 | |
| Vaghasiya et al. | Hybrid AgNP–TiO2 thin film based photoanode for dye sensitized solar cell | |
| Gnanasekar et al. | V2O5 Nanosheets as an Efficient, Low‐cost Pt‐free Alternate Counter Electrode for Dye‐Sensitized Solar Cells | |
| EP3168193B1 (en) | Viscous dispersion liquid and method for producing same and porous semiconductor electrode substrate | |
| JP4801899B2 (ja) | 塗膜形成用組成物、それを用いて得られる電極及び光電変換素子 | |
| JP4562467B2 (ja) | 半導体ナノ粒子を含む粘性分散液 | |
| Kiran et al. | Preparation and thickness optimization of TiO2/Nb2O5 photoanode for dye sensitized solar cells | |
| JP2006073488A (ja) | 色素増感太陽電池及びその製造方法 | |
| Chen et al. | Electron transport dynamics in TiO2 films deposited on Ti foils for back-illuminated dye-sensitized solar cells | |
| Jon et al. | TCO-free dye solar cells based on Ti back contact electrode by facile printing method | |
| Giannouli et al. | Effects of using multi‐component electrolytes on the stability and properties of solar cells sensitized with simple organic dyes | |
| Shin et al. | Observation of positive effects of freestanding scattering film in dye-sensitized solar cells | |
| Fu et al. | Facile fabrication of highly porous photoanode at low temperature for all-plastic dye-sensitized solar cells with quasi-solid state electrolyte | |
| JP5713853B2 (ja) | 電解液及び光電変換素子 | |
| Gao et al. | Submicrometer@ nano bimodal TiO2 particles as easily sintered, crack-free, and current-contributed scattering layers for dye-sensitized solar cells | |
| KR101042949B1 (ko) | 금속 산화물층의 염료 코팅 방법, 이를 이용한 염료 감응 태양 전지 및 그 제조 방법 | |
| EP1654746A1 (en) | Photoelectrochemical solar cell made from nanocomposite organic-inorganic materials |