JP2012140572A - Tableware detergent composition for hand washing - Google Patents
Tableware detergent composition for hand washing Download PDFInfo
- Publication number
- JP2012140572A JP2012140572A JP2011001264A JP2011001264A JP2012140572A JP 2012140572 A JP2012140572 A JP 2012140572A JP 2011001264 A JP2011001264 A JP 2011001264A JP 2011001264 A JP2011001264 A JP 2011001264A JP 2012140572 A JP2012140572 A JP 2012140572A
- Authority
- JP
- Japan
- Prior art keywords
- group
- carbon atoms
- component
- washing
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000005406 washing Methods 0.000 title claims abstract description 85
- 239000000203 mixture Substances 0.000 title claims abstract description 79
- 239000003599 detergent Substances 0.000 title abstract description 16
- 150000003839 salts Chemical class 0.000 claims abstract description 23
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 17
- 239000000194 fatty acid Substances 0.000 claims abstract description 17
- 229930195729 fatty acid Natural products 0.000 claims abstract description 17
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 14
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 7
- 150000004985 diamines Chemical class 0.000 claims abstract description 7
- 125000001183 hydrocarbyl group Chemical group 0.000 claims abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 68
- -1 propyleneoxy group Chemical group 0.000 claims description 43
- 238000004851 dishwashing Methods 0.000 claims description 40
- 125000000217 alkyl group Chemical group 0.000 claims description 35
- 150000001875 compounds Chemical class 0.000 claims description 30
- 239000004094 surface-active agent Substances 0.000 claims description 24
- 239000003795 chemical substances by application Substances 0.000 claims description 14
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 claims description 10
- 150000001767 cationic compounds Chemical class 0.000 claims description 6
- 150000002892 organic cations Chemical class 0.000 claims description 6
- 125000000542 sulfonic acid group Chemical group 0.000 claims description 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 5
- QLBRROYTTDFLDX-UHFFFAOYSA-N [3-(aminomethyl)cyclohexyl]methanamine Chemical compound NCC1CCCC(CN)C1 QLBRROYTTDFLDX-UHFFFAOYSA-N 0.000 claims description 4
- 125000003277 amino group Chemical group 0.000 claims description 4
- 125000004103 aminoalkyl group Chemical group 0.000 claims description 4
- 125000004122 cyclic group Chemical group 0.000 claims description 3
- YZCKVEUIGOORGS-OUBTZVSYSA-N Deuterium Chemical compound [2H] YZCKVEUIGOORGS-OUBTZVSYSA-N 0.000 claims description 2
- RTWNYYOXLSILQN-UHFFFAOYSA-N methanediamine Chemical compound NCN RTWNYYOXLSILQN-UHFFFAOYSA-N 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 29
- 230000005587 bubbling Effects 0.000 abstract description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate group Chemical group S(=O)(=O)([O-])[O-] QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract description 2
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 abstract 1
- 239000006260 foam Substances 0.000 description 73
- 235000002639 sodium chloride Nutrition 0.000 description 28
- 238000005187 foaming Methods 0.000 description 27
- 230000008034 disappearance Effects 0.000 description 25
- 230000002688 persistence Effects 0.000 description 18
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 15
- 230000000694 effects Effects 0.000 description 13
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 11
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 10
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 9
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 8
- 230000008033 biological extinction Effects 0.000 description 8
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 8
- 150000002148 esters Chemical class 0.000 description 8
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 8
- 239000008233 hard water Substances 0.000 description 7
- 230000001965 increasing effect Effects 0.000 description 7
- PSBDWGZCVUAZQS-UHFFFAOYSA-N (dimethylsulfonio)acetate Chemical compound C[S+](C)CC([O-])=O PSBDWGZCVUAZQS-UHFFFAOYSA-N 0.000 description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 6
- 238000004140 cleaning Methods 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 229940117986 sulfobetaine Drugs 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 159000000003 magnesium salts Chemical class 0.000 description 5
- 159000000000 sodium salts Chemical class 0.000 description 5
- 238000003860 storage Methods 0.000 description 5
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 4
- 239000005639 Lauric acid Substances 0.000 description 4
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 4
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 4
- 125000002947 alkylene group Chemical group 0.000 description 4
- 230000002708 enhancing effect Effects 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 150000002484 inorganic compounds Chemical class 0.000 description 4
- 229910010272 inorganic material Inorganic materials 0.000 description 4
- 229910001629 magnesium chloride Inorganic materials 0.000 description 4
- 229910001425 magnesium ion Inorganic materials 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 229910001414 potassium ion Inorganic materials 0.000 description 4
- 159000000001 potassium salts Chemical class 0.000 description 4
- 239000008237 rinsing water Substances 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 229910001415 sodium ion Inorganic materials 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 235000019482 Palm oil Nutrition 0.000 description 3
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 description 3
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 3
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 239000003240 coconut oil Substances 0.000 description 3
- 235000019864 coconut oil Nutrition 0.000 description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical class OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 230000001804 emulsifying effect Effects 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 3
- 239000000347 magnesium hydroxide Substances 0.000 description 3
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- 150000007524 organic acids Chemical class 0.000 description 3
- 239000002540 palm oil Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 3
- 229920005573 silicon-containing polymer Polymers 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- FVAUCKIRQBBSSJ-UHFFFAOYSA-M sodium iodide Chemical compound [Na+].[I-] FVAUCKIRQBBSSJ-UHFFFAOYSA-M 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 3
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 2
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 235000021314 Palmitic acid Nutrition 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- 235000019484 Rapeseed oil Nutrition 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 125000002252 acyl group Chemical group 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 235000015278 beef Nutrition 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 150000002169 ethanolamines Chemical class 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000001879 gelation Methods 0.000 description 2
- 150000002430 hydrocarbons Chemical group 0.000 description 2
- 238000007037 hydroformylation reaction Methods 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 239000003752 hydrotrope Substances 0.000 description 2
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 229910001411 inorganic cation Inorganic materials 0.000 description 2
- 229910003002 lithium salt Inorganic materials 0.000 description 2
- 159000000002 lithium salts Chemical class 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 2
- 235000019341 magnesium sulphate Nutrition 0.000 description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 description 2
- 238000010979 pH adjustment Methods 0.000 description 2
- 239000003346 palm kernel oil Substances 0.000 description 2
- 235000019865 palm kernel oil Nutrition 0.000 description 2
- SECPZKHBENQXJG-FPLPWBNLSA-N palmitoleic acid Chemical compound CCCCCC\C=C/CCCCCCCC(O)=O SECPZKHBENQXJG-FPLPWBNLSA-N 0.000 description 2
- 229920001515 polyalkylene glycol Polymers 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 description 2
- 239000003760 tallow Substances 0.000 description 2
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- JIRHAGAOHOYLNO-UHFFFAOYSA-N (3-cyclopentyloxy-4-methoxyphenyl)methanol Chemical compound COC1=CC=C(CO)C=C1OC1CCCC1 JIRHAGAOHOYLNO-UHFFFAOYSA-N 0.000 description 1
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 description 1
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 description 1
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 description 1
- JOLQKTGDSGKSKJ-UHFFFAOYSA-N 1-ethoxypropan-2-ol Chemical compound CCOCC(C)O JOLQKTGDSGKSKJ-UHFFFAOYSA-N 0.000 description 1
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 1
- YDFDTKKXMZRNHR-UHFFFAOYSA-N 1-n,3-n-dimethylcyclohexane-1,3-diamine Chemical compound CNC1CCCC(NC)C1 YDFDTKKXMZRNHR-UHFFFAOYSA-N 0.000 description 1
- IBLKWZIFZMJLFL-UHFFFAOYSA-N 1-phenoxypropan-2-ol Chemical compound CC(O)COC1=CC=CC=C1 IBLKWZIFZMJLFL-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- LBLYYCQCTBFVLH-UHFFFAOYSA-N 2-Methylbenzenesulfonic acid Chemical compound CC1=CC=CC=C1S(O)(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-N 0.000 description 1
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- BODRLKRKPXBDBN-UHFFFAOYSA-N 3,5,5-Trimethyl-1-hexanol Chemical compound OCCC(C)CC(C)(C)C BODRLKRKPXBDBN-UHFFFAOYSA-N 0.000 description 1
- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 description 1
- MFKRHJVUCZRDTF-UHFFFAOYSA-N 3-methoxy-3-methylbutan-1-ol Chemical compound COC(C)(C)CCO MFKRHJVUCZRDTF-UHFFFAOYSA-N 0.000 description 1
- XPFCZYUVICHKDS-UHFFFAOYSA-N 3-methylbutane-1,3-diol Chemical compound CC(C)(O)CCO XPFCZYUVICHKDS-UHFFFAOYSA-N 0.000 description 1
- CVLHGLWXLDOELD-UHFFFAOYSA-N 4-(Propan-2-yl)benzenesulfonic acid Chemical compound CC(C)C1=CC=C(S(O)(=O)=O)C=C1 CVLHGLWXLDOELD-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- 235000021360 Myristic acid Nutrition 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 235000021319 Palmitoleic acid Nutrition 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003377 acid catalyst Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000007259 addition reaction Methods 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000005233 alkylalcohol group Chemical group 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 1
- 235000020661 alpha-linolenic acid Nutrition 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 235000011126 aluminium potassium sulphate Nutrition 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-O bis(2-hydroxyethyl)azanium Chemical compound OCC[NH2+]CCO ZBCBWPMODOFKDW-UHFFFAOYSA-O 0.000 description 1
- 201000004050 brachyolmia-amelogenesis imperfecta syndrome Diseases 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 125000001589 carboacyl group Chemical group 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- XTHPWXDJESJLNJ-UHFFFAOYSA-N chlorosulfonic acid Substances OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 description 1
- SECPZKHBENQXJG-UHFFFAOYSA-N cis-palmitoleic acid Natural products CCCCCCC=CCCCCCCCC(O)=O SECPZKHBENQXJG-UHFFFAOYSA-N 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- HABLENUWIZGESP-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O.CCCCCCCCCC(O)=O HABLENUWIZGESP-UHFFFAOYSA-N 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 238000005227 gel permeation chromatography Methods 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229960004488 linolenic acid Drugs 0.000 description 1
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000000693 micelle Substances 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 125000001419 myristoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 229960002446 octanoic acid Drugs 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 229960002969 oleic acid Drugs 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- 229940106026 phenoxyisopropanol Drugs 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229940050271 potassium alum Drugs 0.000 description 1
- GRLPQNLYRHEGIJ-UHFFFAOYSA-J potassium aluminium sulfate Chemical compound [Al+3].[K+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRLPQNLYRHEGIJ-UHFFFAOYSA-J 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 235000007715 potassium iodide Nutrition 0.000 description 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
- 229910052939 potassium sulfate Inorganic materials 0.000 description 1
- 235000011151 potassium sulphates Nutrition 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 235000009518 sodium iodide Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- UELAIMNOXLAYRW-UHFFFAOYSA-M sodium;1,4-dicyclohexyloxy-1,4-dioxobutane-2-sulfonate Chemical compound [Na+].C1CCCCC1OC(=O)C(S(=O)(=O)[O-])CC(=O)OC1CCCCC1 UELAIMNOXLAYRW-UHFFFAOYSA-M 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000001180 sulfating effect Effects 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- HIFJUMGIHIZEPX-UHFFFAOYSA-N sulfuric acid;sulfur trioxide Chemical compound O=S(=O)=O.OS(O)(=O)=O HIFJUMGIHIZEPX-UHFFFAOYSA-N 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-O triethanolammonium Chemical compound OCC[NH+](CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-O 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
Description
本発明は、手洗い用食器洗浄剤組成物に関する。 The present invention relates to a dishwashing composition for hand washing.
手洗い用食器洗浄剤には、洗浄時に豊かな泡立ちと洗浄時の泡の持続性が求められる。この起泡性／泡持続性は洗浄性及び洗浄持続性と相関がある非常に重要な物性であり、これまで起泡性／泡持続性に優れる洗浄剤の開発が主に行われてきた。一方、近年の水資源への意識の高まりとともに、食器及び／又は洗浄器具から泡を取り除くのに必要な濯ぎ用水を減らすことが望まれている。 A dishwashing agent for hand washing is required to have abundant foaming at the time of washing and the persistence of the foam at the time of washing. This foamability / foam persistence is a very important physical property that correlates with detergency and washing persistence, and until now, the development of a detergent having excellent foamability / foam persistence has been mainly performed. On the other hand, with increasing awareness of water resources in recent years, it is desirable to reduce the amount of rinsing water required to remove foam from dishes and / or cleaning utensils.
特許文献１には、シリコーンポリマー及び脂肪酸を起泡抑制剤として含有する手動食器洗浄組成物が開示されている。 Patent Document 1 discloses a manual dishwashing composition containing a silicone polymer and a fatty acid as a foam inhibitor.
また、特許文献２には、シリコーンポリマーを起泡抑制剤として含有し、シリコーンポリマーを組成物中で安定な分散状態を維持するための添加剤として特定の短鎖モノアルキルアミンを含有する食器洗浄剤組成物が開示されている。 Further, Patent Document 2 discloses a dishwashing containing a silicone polymer as a foam inhibitor and a specific short chain monoalkylamine as an additive for maintaining the silicone polymer in a stable dispersion state in the composition. An agent composition is disclosed.
また、特許文献３には、低分子量有機ジアミン化合物を含有し、Ｍｇ／Ｃａを排除した食器用洗浄剤組成物が開示されている。 Patent Document 3 discloses a dishwashing detergent composition containing a low molecular weight organic diamine compound and excluding Mg / Ca.
しかしながら、特許文献１、２に開示された組成物は濯ぎ時のみならず、洗浄時における泡立ちが抑制され、洗浄時の泡立ち及び泡持続性に問題がある。特許文献３では、組成物の濯ぎ性については何ら記載がない。 However, the compositions disclosed in Patent Documents 1 and 2 have problems with foaming and persistence during washing because foaming is suppressed not only during rinsing but also during washing. In patent document 3, there is no description about the rinse property of a composition.
従って本発明の課題は、洗浄時には豊かな泡立ちと泡持続性を示すが、すすぎ時には瞬時に泡が消え、少量の水ですすぎが完了する手洗い用食器洗浄剤を提供することにある。 Accordingly, an object of the present invention is to provide a dishwashing detergent for hand washing that exhibits abundant foaming and foam persistence during washing, but the foam disappears instantaneously during rinsing and is rinsed with a small amount of water.
本発明は、（ａ）炭素数５〜２２の炭化水素基と、硫酸エステル基又はスルホン酸基とを有する陰イオン界面活性剤〔以下、（ａ）成分という〕１〜５０質量％、（ｂ）炭素数８〜２２の脂肪酸又はその塩〔以下、（ｂ）成分という〕、及び（ｃ）炭素数３〜１２の有機ジアミン〔以下、（ｃ）成分という〕を含有し、（ｂ）／（ｃ）の質量比が０．１〜８である手洗い用食器洗浄剤組成物に関する。 The present invention relates to (a) an anionic surfactant having a hydrocarbon group having 5 to 22 carbon atoms and a sulfate ester group or a sulfonic acid group (hereinafter referred to as component (a)) 1 to 50% by mass, (b ) A fatty acid having 8 to 22 carbon atoms or a salt thereof (hereinafter referred to as component (b)), and (c) an organic diamine having 3 to 12 carbon atoms (hereinafter referred to as component (c)), (b) / It is related with the dishwashing agent composition for hand-washing whose mass ratio of (c) is 0.1-8.
本発明によれば、洗浄時には豊かな泡立ちと洗浄時の泡の持続性を示すが、すすぎ時には瞬時に泡が消え、少量の水ですすぎが完了する手洗い用食器洗浄剤が提供される。 According to the present invention, there is provided a dishwashing agent for hand-washing that exhibits abundant foaming at the time of washing and the persistence of the foam at the time of washing, but the foam disappears instantly at the time of rinsing and the rinsing is completed with a small amount of water.
＜（ａ）成分＞
本発明の（ａ）成分は、炭素数５〜２２の炭化水素基と、硫酸エステル基又はスルホン酸基を有する陰イオン界面活性剤である。硫酸エステル基又はスルホン酸基は塩であってもよい。従って、（ａ）成分は、硫酸エステル基若しくは硫酸エステル基塩又はスルホン酸基若しくはスルホン酸基塩を有することができる。このような陰イオン界面活性剤は非常に起泡性に優れることが知られており、より具体的には、炭素数８〜２２、更に炭素数８〜１８、好ましくは炭素数１０〜１６のアルキル基を有するアルキル硫酸エステル塩、炭素数８〜２２、更に炭素数８〜１８、好ましくは炭素数１０〜１６のアルキル基を有しアルキレン基の炭素数が２及び／又は３であるポリオキシアルキレン基の平均付加モル数が０．１〜６であるポリオキシアルキレン基を有するポリオキシアルキレンアルキルエーテル硫酸エステル塩、炭素数８〜２２、更に炭素数８〜１６のアルキル基を有するアルキルベンゼンスルホン酸塩、炭素数８〜２２、更に炭素数８〜１６のアルカンスルホン酸塩、スルホコハク酸ジアルキル（アルキル基の炭素数はそれぞれ５〜１８）エステル又はその塩、スルホコハク酸モノアルキル（炭素数は５〜１８）エステル又はその塩から選ばれる陰イオン界面活性剤が好適である。塩としてはナトリウム塩、カリウム塩、リチウム塩、マグネシウム塩、アンモニウム塩から選ばれる無機塩、モノエタノールアミン塩、ジエタノールアミン塩、トリエタノールアミン塩から選ばれる有機アミン塩が好適である。
<(A) component>
The component (a) of the present invention is an anionic surfactant having a hydrocarbon group having 5 to 22 carbon atoms and a sulfate ester group or a sulfonic acid group. The sulfate ester group or sulfonic acid group may be a salt. Accordingly, the component (a) can have a sulfate ester group or a sulfate ester group salt, a sulfonic acid group or a sulfonic acid group salt. Such anionic surfactants are known to be very excellent in foaming properties, and more specifically, have 8 to 22 carbon atoms, more preferably 8 to 18 carbon atoms, preferably 10 to 16 carbon atoms. Alkyl sulfate ester salt having an alkyl group, polyoxygen having an alkyl group having 8 to 22 carbon atoms, more preferably 8 to 18 carbon atoms, preferably 10 to 16 carbon atoms, and an alkylene group having 2 and / or 3 carbon atoms Polyoxyalkylene alkyl ether sulfate ester salt having a polyoxyalkylene group having an average addition mole number of alkylene groups of 0.1 to 6, alkylbenzene sulfonic acid having an alkyl group of 8 to 22 carbon atoms and further 8 to 16 carbon atoms Salt, alkanesulfonate having 8 to 22 carbon atoms, and further having 8 to 16 carbon atoms, dialkyl sulfosuccinate (the alkyl group has 5 to 18 carbon atoms, respectively) ester The salts, sulfosuccinic acid monoalkyl (carbon number 5 to 18) anionic surfactant selected from an ester or a salt thereof are preferred. As the salt, an inorganic salt selected from sodium salts, potassium salts, lithium salts, magnesium salts, and ammonium salts, and organic amine salts selected from monoethanolamine salts, diethanolamine salts, and triethanolamine salts are preferable.
（ａ）成分としては、下記一般式（ａ１）の化合物〔以下、（ａ１）成分という〕が洗浄時の起泡性や泡持続性及びすすぎ時の泡消え性の点から好適である。
Ｒ1a−Ｏ−〔（ＰＯ）m／（ＥＯ）n〕−ＳＯ3Ｍ （ａ１）
〔式中、Ｒ1aは、炭素数８〜１８のアルキル基であり、ＰＯとＥＯはそれぞれプロピレンオキシ基とエチレンオキシ基であり、ｍ、ｎはＰＯ又はＥＯの付加モル数を示し、それぞれ０〜１．５となる数である。Ｍは無機又は有機の陽イオンである。ＰＯとＥＯの付加順序は問わない。また、“／”は、ＰＯとＥＯの付加形態がブロックでもランダムでもよいことを意味する。〕
As the component (a), a compound represented by the following general formula (a1) [hereinafter referred to as the component (a1)] is preferable from the viewpoints of foamability at the time of washing, foam persistence, and foam disappearance at the time of rinsing.
R 1a -O - [(PO) m / (EO) n ] -SO 3 M (a1)
[Wherein, R 1a is an alkyl group having 8 to 18 carbon atoms, PO and EO are a propyleneoxy group and an ethyleneoxy group, respectively, m and n represent the added mole number of PO or EO, It is a number which becomes -1.5. M is an inorganic or organic cation. The order of addition of PO and EO does not matter. “/” Means that the addition form of PO and EO may be block or random. ]
ｍは、洗浄時の起泡性、すすぎ時の泡消え性、及び洗浄性能の観点から、０．１〜１．５が好ましく、より好ましくは０．２〜１、更に好ましくは０．４〜０．８の数である。０．１以上で洗浄時の良好な起泡性が得られ、１．５以下で良好な洗浄力とすすぎ時の良好な泡消え性が得られる。また、ｎは洗浄時の起泡性、すすぎ時の泡消え性、及び洗浄性能の観点から、０〜１．５の数が好ましく、より好ましくは０〜１、更に好ましくは０〜０．１の数であり、特に好ましくは０である。 m is preferably from 0.1 to 1.5, more preferably from 0.2 to 1, and still more preferably from 0.4 to 1.5, from the viewpoints of foamability at the time of washing, foam disappearance at the time of rinsing, and washing performance. It is a number of 0.8. When it is 0.1 or more, good foaming property at the time of washing is obtained, and when it is 1.5 or less, good detergency and good foam disappearance property at the time of rinsing are obtained. Further, n is preferably a number of 0 to 1.5, more preferably 0 to 1, and still more preferably 0 to 0.1, from the viewpoints of foamability at the time of washing, foam disappearance at the time of rinsing, and washing performance. And particularly preferably 0.
一般式（ａ１）において、ｍ＋ｎが０である場合、一般式（ａ１）の化合物は洗浄時の起泡性、すすぎ時の泡消え性の観点から、分岐率〔一般式（ａ１）の化合物の総モル数に対して分岐鎖アルキル基を有する化合物の総モル数の割合〕が好ましくは５〜１００モル％、より好ましくは１５〜１００モル％、特に好ましくは２０〜１００モル％の化合物が好適である。 In the general formula (a1), when m + n is 0, the compound of the general formula (a1) has a branching ratio [of the compound of the general formula (a1) from the viewpoint of foaming properties during washing and foam disappearance during rinsing. The ratio of the total number of moles of the compound having a branched alkyl group to the total number of moles] is preferably 5 to 100 mol%, more preferably 15 to 100 mol%, and particularly preferably 20 to 100 mol%. It is.
一般式（ａ１）中のＭはナトリウムイオン、カリウムイオン、リチウムイオン、マグネシウムイオン、アンモニウムイオンから選ばれる無機陽イオン、モノエタノールアンモニウムイオン、ジエタノールアンモニウムイオン、トリエタノールアンモニウムイオンの酸塩から選ばれる有機陽イオンであるが、好ましくはナトリウムイオン、カリウムイオン、マグネシウムイオン、アンモニウムイオンである。 M in the general formula (a1) is an organic cation selected from an inorganic cation selected from sodium ion, potassium ion, lithium ion, magnesium ion, and ammonium ion, monoethanolammonium ion, diethanolammonium ion, and triethanolammonium ion. The cation is preferably sodium ion, potassium ion, magnesium ion or ammonium ion.
一般式（ａ１）の化合物の調製方法としては、特に限定されるものではないが、例えばＲ1a−ＯＨで示される脂肪アルコールに目的に応じてエチレンオキシド及び／又はプロピレンオキシドを所定量付加させた後、三酸化硫黄（液体又は気体）、三酸化硫黄含有ガス、発煙硫酸、クロルスルホン酸から選ばれる硫酸化剤で硫酸エステル化し、所定のアルカリ剤で中和して製造される。エチレンオキシド及び／又はプロピレンオキシドの付加反応は触媒が必要でありＮａＯＨ、ＫＯＨなどの水酸化アルカリを用いることができる。また、特開平８−３２３２００号公報に記載の酸化マグネシウムを主成分とする触媒を用いることができ、前者は付加モル数分布が比較的広いポリオキシエチレンアルキルエーテルを得ることができ、後者は比較的狭い付加モル数分布を有する化合物を得ることができる。また、特開平１０−１５８３８４号公報に開示されているようにアルカリ触媒と金属酸化物触媒を併用することにより付加モル数分布を制御することも可能である。 The method for preparing the compound of the general formula (a1) is not particularly limited. For example, after adding a predetermined amount of ethylene oxide and / or propylene oxide to the fatty alcohol represented by R 1a —OH depending on the purpose. It is produced by sulfate formation with a sulfating agent selected from sulfur trioxide (liquid or gas), sulfur trioxide-containing gas, fuming sulfuric acid and chlorosulfonic acid, and neutralization with a predetermined alkali agent. The addition reaction of ethylene oxide and / or propylene oxide requires a catalyst, and an alkali hydroxide such as NaOH or KOH can be used. Moreover, the catalyst which has a magnesium oxide as a main component as described in Unexamined-Japanese-Patent No. 8-323200 can be used, The former can obtain polyoxyethylene alkyl ether with comparatively wide addition mole number distribution, The latter is comparison. A compound having a narrow addition mole number distribution can be obtained. Further, as disclosed in JP-A-10-158384, it is also possible to control the added mole number distribution by using an alkali catalyst and a metal oxide catalyst in combination.
一般式（ａ１）においてｍ＋ｎが０の場合に好適であるＲ1aが分岐構造を有するアルキル基を含む化合物を得る場合には、原料であるＲ1a−ＯＨで示されるアルコールとして、炭素数８〜１４の１−アルケンをヒドロホルミル化して得られたアルコール（ＯＨ基に対してβ位にメチル基が分岐したアルキル基が１５〜７０モル％含まれる）、炭素数４〜８のアルデヒドを縮合させた後、還元して得られるゲルベ型アルコール（ＯＨ基に対してβ位に炭素数３〜６のアルキル基が分岐した構造のものが１００モル％含まれる）、イソブテンの２量体をヒドロホルミル化して得られる３，５，５−トリメチルヘキサノール、イソブテンの３量体をヒドロホルミル化して得られる多分岐トリデカノール（分岐率は１００モル％である）、石油、石炭を原料とした合成アルコール（分岐率は約２０〜１００モル％）を挙げることができる。 In the case of obtaining a compound in which R 1a, which is suitable when m + n is 0 in the general formula (a1), contains an alkyl group having a branched structure, the alcohol represented by R 1a —OH as a raw material has 8 to 8 carbon atoms. 14 alcohols obtained by hydroformylation of 1-alkene (contains 15 to 70 mol% of an alkyl group having a methyl group branched at the β-position with respect to the OH group) and an aldehyde having 4 to 8 carbon atoms were condensed. Subsequently, a gel-form alcohol obtained by reduction (containing 100 mol% of a structure in which an alkyl group having 3 to 6 carbon atoms is branched at the β-position relative to the OH group) and a dimer of isobutene are hydroformylated. Multi-branched tridecanol obtained by hydroformylation of the trimer of 3,5,5-trimethylhexanol and isobutene obtained (branching rate is 100 mol%), petroleum, coal Raw materials and synthetic alcohols (branched rate of about 20 to 100 mole%) may be mentioned.
本発明では、（ａ１）成分としてすすぎ時の良好な泡消え性の観点から、一般式（ａ１）で表される化合物であって、ｎが０であり、ｍが０．２〜１、更に０．４〜０．８の数である化合物が最も好ましい。 In the present invention, from the viewpoint of good foam extinction at the time of rinsing as the component (a1), the compound is represented by the general formula (a1), n is 0, m is 0.2 to 1, and Most preferred are compounds having a number between 0.4 and 0.8.
本発明では（ａ）成分として、スルホコハク酸モノアルキル（アルキル基の炭素数は５〜１８）エステル又はその塩及びスルホコハク酸ジアルキル（アルキル基の炭素数はそれぞれ５〜１８）エステル又はその塩から選ばれるスルホコハク酸エステル型界面活性剤〔以下、（ａ２）成分という〕を含有することが、すすぎ時の泡消え性の観点から好ましい。また、すすぎ時の泡消え性及び洗浄時の起泡性の観点から、（ａ）成分が（ａ１）成分及び（ａ２）成分であること、すなわち（ａ）成分として（ａ１）成分と（ａ２）成分の両方を含有することが好ましい。 In the present invention, the component (a) is selected from sulfosuccinic acid monoalkyl (alkyl group having 5 to 18 carbon atoms) ester or salt thereof and sulfosuccinic acid dialkyl (alkyl group having 5 to 18 carbon atoms, respectively) ester or salt thereof. It is preferable to contain a sulfosuccinic acid ester type surfactant [hereinafter referred to as component (a2)] from the viewpoint of foam disappearance at the time of rinsing. Further, from the viewpoint of foam extinction at the time of rinsing and foaming at the time of washing, the component (a) is the component (a1) and the component (a2), that is, the component (a1) and the component (a2) as the component (a) ) It is preferable to contain both components.
本発明の（ａ２）成分は、具体的には下記一般式（ａ２）の化合物が好適である。 Specifically, the component (a2) of the present invention is preferably a compound of the following general formula (a2).
〔式中、Ｒ2a、Ｒ3aは、それぞれ、炭素数５〜１８、好ましくは６〜１５、より好ましくは７〜１３のアルキル基又は水素原子であり、Ｒ2a、Ｒ3aの少なくとも一方は炭素数５〜１８のアルキル基である。Ａ1、Ａ2はそれぞれ独立に炭素数２〜４、好ましくは２〜３のアルキレン基、ｘ、ｙは平均付加モル数であり０〜６である。Ｍは無機又は有機の陽イオンである。〕 [Wherein, R 2a and R 3a are each an alkyl group or a hydrogen atom having 5 to 18, preferably 6 to 15 and more preferably 7 to 13 carbon atoms, and at least one of R 2a and R 3a is carbon. It is an alkyl group of formula 5-18. A 1 and A 2 are each independently an alkylene group having 2 to 4 carbon atoms, preferably 2 to 3 carbon atoms, and x and y are average added moles and are 0 to 6. M is an inorganic or organic cation. ]
（ａ２）成分が、スルホコハク酸ジアルキルエステル又はその塩である場合、一般式（ａ２）中のＲ2a、Ｒ3aは、同一あるいは異なっていても良く、洗浄時の起泡性及びすすぎ時の泡消え性の観点から炭素数５〜１８、好ましくは５〜１４、より好ましくは５〜１２のアルキル基である。５以上の炭素数で良好なすすぎ時の泡消え性が得られ、１８以下の炭素数で良好な洗浄時の起泡性が得られる。また、（ａ２）成分が、スルホコハク酸モノアルキルエステル又はその塩である場合、一般式（ａ２）中のＲ2a、Ｒ3aの一方は洗浄時の起泡性及びすすぎ時の泡消え性の観点から炭素数５〜１８、好ましくは５〜１４、より好ましくは５〜１２のアルキル基であり、他方は水素原子である。Ｒ2a、Ｒ3aは洗浄時の起泡性及びすすぎ時の泡消え性の観点から、それぞれ、炭素数５〜１８、好ましくは５〜１４、より好ましくは５〜１２のアルキル基であること、すなわち、（ａ２）成分が、スルホコハク酸ジアルキルエステル又はその塩であることが好ましい。Ａ1、Ａ2は洗浄時の起泡性及びすすぎ時の泡消え性の観点からそれぞれ独立に炭素数２〜４、好ましくは２〜３のアルキレン基である。ｘ、ｙは平均付加モル数であり、洗浄時の起泡性及びすすぎ時の泡消え性の観点から、それぞれ０〜６であり、好ましくは０〜２であり、更に好ましくは０〜１であり、特に好ましくは０である。 When the component (a2) is a sulfosuccinic acid dialkyl ester or a salt thereof, R 2a and R 3a in the general formula (a2) may be the same or different, and the foaming property during washing and the foaming during rinsing From the viewpoint of disappearance, it is an alkyl group having 5 to 18, preferably 5 to 14, more preferably 5 to 12 carbon atoms. When the number of carbons is 5 or more, good foam disappearance at rinsing is obtained, and when the number of carbons is 18 or less, good foaming at washing is obtained. In addition, when the component (a2) is a sulfosuccinic acid monoalkyl ester or a salt thereof, one of R 2a and R 3a in the general formula (a2) is a viewpoint of foamability during washing and foam disappearance during rinsing. To an alkyl group having 5 to 18 carbon atoms, preferably 5 to 14 carbon atoms, more preferably 5 to 12 carbon atoms, and the other is a hydrogen atom. R 2a and R 3a are each an alkyl group having 5 to 18 carbon atoms, preferably 5 to 14 carbon atoms, more preferably 5 to 12 carbon atoms, from the viewpoints of foamability during washing and foam extinction during rinsing. That is, the component (a2) is preferably a sulfosuccinic acid dialkyl ester or a salt thereof. A 1 and A 2 are each independently an alkylene group having 2 to 4 carbon atoms, preferably 2 to 3 carbon atoms, from the viewpoints of foamability at the time of washing and foam disappearance at the time of rinsing. x and y are the average number of moles added, and are each 0 to 6, preferably 0 to 2, more preferably 0 to 1, from the viewpoints of foamability during washing and foam extinction during rinsing. Yes, particularly preferably 0.
一般式（ａ２）中、Ｒ2a、Ｒ3aは、それぞれ、具体的にはヘキシル基、オクチル基、ノニル基、デシル基、ドデシル基、トリデシル基、２−エチルヘキシル基、ｎ−オクチル基、ｓｅｃ−オクチル基、イソペンチル基、イソノニル基、イソデシル基、シクロヘキシル基であり、特にｎ−オクチル基、ｓｅｃ−オクチル基、デシル基、イソデシル基、及び２−エチルヘキシル基から選ばれる基であることが好適である。Ｍとしては、水素イオン、ナトリウムイオン、カリウムイオン、マグネシウムイオン、アンモニウムイオンから選ばれる無機陽イオン、モノエタノールアンモニウムイオン、ジエタノールアンモニウムイオン、トリエタノールアンモニウムイオンから選ばれる有機陽イオンが挙げられるが、好ましくはナトリウムイオン、カリウムイオン、マグネシウムイオン、及びアンモニウムイオンから選ばれる陽イオンである。 In the general formula (a2), R 2a and R 3a are specifically hexyl, octyl, nonyl, decyl, dodecyl, tridecyl, 2-ethylhexyl, n-octyl, sec- An octyl group, an isopentyl group, an isononyl group, an isodecyl group, and a cyclohexyl group, and particularly preferably a group selected from an n-octyl group, a sec-octyl group, a decyl group, an isodecyl group, and a 2-ethylhexyl group. . Examples of M include inorganic cations selected from hydrogen ions, sodium ions, potassium ions, magnesium ions, and ammonium ions, and organic cations selected from monoethanolammonium ions, diethanolammonium ions, and triethanolammonium ions. Is a cation selected from sodium ion, potassium ion, magnesium ion, and ammonium ion.
（ａ２）成分が、スルホコハク酸ジアルキルエステル又はその塩である場合、Ｒ2a、Ｒ3aが同一の化合物の調製方法としては、特に限定されるものではないが、例えば米国特許明細書第２，０２８，０９１号公報に記載の方法を参考して製造することができ、また、Ｒ2a、Ｒ3aが異なる非対称の化合物は、例えば特開昭５８−２４５５５号公報を参考して製造することができる。市販の化合物を用いる場合には、花王（株）製ペレックスＯＴ−Ｐ（Ｒ2a、Ｒ3aが共に２−エチルヘキシル基である化合物）、同ペレックスＴＲ（Ｒ2a、Ｒ3aが共にトリデシル基である化合物）、ＢＡＳＦ社製ＬｕｅｎｓｉｔＡ−ＢＯ（Ｒ2a、Ｒ3aが共に２−エチルヘキシル基である化合物）、三井サイテック株式会社から入手可能であったエアロゾルＡＹ−１００（Ｒ2a、Ｒ3aが共にアミル基である化合物）、同エアロゾルＡ−１９６（Ｒ2a、Ｒ3aが共にシクロヘキシル基である化合物）などを用いることができる。 When the component (a2) is a sulfosuccinic acid dialkyl ester or a salt thereof, a method for preparing a compound in which R 2a and R 3a are the same is not particularly limited. For example, US Pat. No. 2,028 , 091 and an asymmetric compound in which R 2a and R 3a are different can be produced by referring to, for example, JP-A-58-24555. . When a commercially available compound is used, PALEX OT-P (a compound in which R 2a and R 3a are both 2-ethylhexyl groups) manufactured by Kao Corporation, and PELEX TR (both R 2a and R 3a are tridecyl groups) Compound), Lusit A-BO (compound in which R 2a and R 3a are both 2-ethylhexyl groups) manufactured by BASF, and aerosol AY-100 (R 2a and R 3a are both amyl groups) available from Mitsui Cytec Co., Ltd. And the same aerosol A-196 (a compound in which R 2a and R 3a are both cyclohexyl groups).
＜（ｂ）成分＞
本発明の（ｂ）成分は、炭素数８〜２２の脂肪酸又はその塩であり、具体的にはカプリル酸、カプリン酸（デカン酸）、ラウリン酸、ミリスチン酸、パルミチン酸、パルミトレイン酸、ステアリン酸、オレイン酸、リノール酸、リノレイン酸、ベヘン酸などの単独アルキル組成の脂肪酸、椰子油組成、パーム油組成、パーム核油組成、菜種油組成、牛脂組成脂肪酸などの混合脂肪酸、及びこれらを水素で硬化した脂肪酸、乃至はこれらの塩を挙げることができる。脂肪酸の塩としては、ナトリウム塩、カリウム塩、リチウム塩、マグネシウム塩、アンモニウム塩から選ばれる無機塩、モノエタノールアミン塩、ジエタノールアミン塩、トリエタノールアミン塩などの有機アミン塩であるが、長期保管による臭いの劣化や着色の観点から好ましくはナトリウム塩、カリウム塩、マグネシウム塩、より好ましくはナトリウム塩、カリウム塩等のアルカリ金属塩が挙げられる。
<(B) component>
The component (b) of the present invention is a fatty acid having 8 to 22 carbon atoms or a salt thereof. Specifically, caprylic acid, capric acid (decanoic acid), lauric acid, myristic acid, palmitic acid, palmitoleic acid, stearic acid Fatty acids with a single alkyl composition such as oleic acid, linoleic acid, linolenic acid, and behenic acid, coconut oil composition, palm oil composition, palm kernel oil composition, rapeseed oil composition, mixed fatty acids such as beef tallow fatty acid, and these hardened with hydrogen Fatty acids or salts thereof. Fatty acid salts include inorganic salts selected from sodium salts, potassium salts, lithium salts, magnesium salts, ammonium salts, organic amine salts such as monoethanolamine salts, diethanolamine salts, and triethanolamine salts. From the viewpoint of odor deterioration and coloring, sodium salts, potassium salts and magnesium salts are preferable, and alkali metal salts such as sodium salts and potassium salts are more preferable.
（ｂ）成分としては、洗浄時の起泡力、すすぎ時の泡消え性の観点から、好ましくは炭素数８〜１８の脂肪酸又はその塩であり、より好ましくはラウリン酸、ミリスチン酸、パルミチン酸、椰子油組成、パーム油組成、パーム核油組成、菜種油組成、牛脂組成脂肪酸などの混合脂肪酸、又はこれらの塩であり、より更に好ましくはラウリン酸、ミリスチン酸、椰子組成、パーム油組成、パーム核油組成の混合脂肪酸、又はこれらの塩であり、最も好ましくは椰子油組成の混合脂肪酸又はその塩である。 The component (b) is preferably a fatty acid having 8 to 18 carbon atoms or a salt thereof, more preferably lauric acid, myristic acid, palmitic acid, from the viewpoint of foaming power at the time of washing and foam disappearance at the time of rinsing. , Coconut oil composition, palm oil composition, palm kernel oil composition, rapeseed oil composition, beef tallow composition, mixed fatty acids such as fatty acids, or salts thereof, more preferably lauric acid, myristic acid, coconut composition, palm oil composition, palm It is a mixed fatty acid having a core oil composition or a salt thereof, and most preferably a mixed fatty acid having a coconut oil composition or a salt thereof.
＜（ｃ）成分＞
本発明の（ｃ）成分は洗浄時の起泡性や泡持続性及びすすぎ時の泡消え性の点から炭素数３〜１２の有機ジアミンであるが、炭素数３〜１２のアルキレンスペーサーを有する一級ジアミンが好ましく、当該アルキレンスペーサーに環式構造を含むことがより好ましく、当該環式構造が六員環構造であることが更に好ましく、下記式（ｃ１）で表されるジアミンがより更に好ましい。具体的には１，３−ビス（メチルアミノ）シクロヘキサンとイソホロンジアミンを挙げることができ、その中でも、１，３−ビス（アミノメチル）シクロヘキサンが特に好ましい。
<(C) component>
The component (c) of the present invention is an organic diamine having 3 to 12 carbon atoms from the viewpoint of foaming property and foam persistence at the time of washing and foam disappearance at the time of rinsing, but has an alkylene spacer having 3 to 12 carbon atoms. Primary diamines are preferred, the alkylene spacers preferably contain a cyclic structure, the cyclic structure is more preferably a six-membered ring structure, and a diamine represented by the following formula (c1) is still more preferred. Specific examples include 1,3-bis (methylamino) cyclohexane and isophoronediamine. Among them, 1,3-bis (aminomethyl) cyclohexane is particularly preferable.
〔式中、Ｒ1c〜Ｒ12cはそれぞれ、炭素数１〜３のアルキル基、炭素数１〜３のアミノアルキル基、アミノ基又は水素原子であり、かつ、Ｒ1c〜Ｒ12cの中の２つがアミノ基及び炭素数１〜３のアミノアルキル基から選ばれる基である。前記炭素数１〜３のアルキル基は好ましくはメチル基である。〕 [Wherein, R 1c to R 12c are each an alkyl group having 1 to 3 carbon atoms, an aminoalkyl group having 1 to 3 carbon atoms, an amino group, or a hydrogen atom, and 2 in R 1c to R 12c One is a group selected from an amino group and an aminoalkyl group having 1 to 3 carbon atoms. The alkyl group having 1 to 3 carbon atoms is preferably a methyl group. ]
＜手洗い用食器洗浄剤組成物＞
本発明の手洗い用食器洗浄剤組成物は、起泡性／泡持続性を有する（ａ）成分と、消泡効果を有する（ｂ）成分及び（ｃ）成分とを特定条件で併用することにより、比較的洗浄剤の濃度が高い洗浄水においては非常に高い起泡性と泡持続性を示すが、洗浄終了後にすすぎ水の添加により洗浄液中の界面活性剤濃度が低下すると、瞬時に泡が消え、少量の水ですすぎを完了させることができる。この理由は必ずしも定かではないが、水道水中のカルシウムと希釈によりミセルから放出された（ｂ）成分が水難溶性の塩を形成することと、（ｃ）成分が泡に何らかの作用をして泡が消えやすくなっているものと考えられる。（ｂ）成分である脂肪酸又はその塩は消泡剤として公知であり、（ｃ）成分は増泡剤として公知であるが、これを用いた本発明の洗浄剤組成物により、両者の効果が相殺されず、逆に洗浄時には豊かな泡立ちが得られ、一方ですすぎ時には速やかに消泡する効果が得られることは意外な効果である。
<Dishwashing composition for hand washing>
The dishwashing detergent composition for hand-washing of this invention uses (a) component which has foamability / foam persistence, (b) component which has a defoaming effect, and (c) component by using together on specific conditions. In washing water with a relatively high concentration of detergent, very high foaming properties and foam persistence are exhibited, but if the surfactant concentration in the washing solution is lowered by the addition of rinsing water after washing is completed, bubbles are instantly formed. It disappears and can be rinsed with a small amount of water. The reason for this is not necessarily clear, but the component (b) released from the micelles by dilution with calcium in tap water forms a poorly water-soluble salt, and the component (c) has some effect on the bubbles and bubbles are generated. It seems that it is easy to disappear. The fatty acid or salt thereof as the component (b) is known as an antifoaming agent, and the component (c) is known as a foam increasing agent, but the effects of both are achieved by the detergent composition of the present invention using this. It is an unexpected effect that a rich bubbling can be obtained at the time of washing, and on the other hand, an effect of quickly defoaming can be obtained when it is rinsed.
本発明の手洗い用食器洗浄剤組成物は、洗浄時の起泡力、すすぎ時の泡消え性及び経済性の観点から、（ａ）成分を１〜５０質量％、好ましくは１０〜４０質量％、より好ましくは１５〜３０質量％含有する。また、（ｂ）成分を好ましくは１〜１０質量％、より好ましくは２〜５質量％含有する。なお、本発明において質量％や質量比等を求めるための（ｂ）成分の量は、酸型化合物としての量である。また、（ｃ）成分を好ましくは０．１〜２０質量％、より好ましくは０．５〜１０質量％、更に好ましくは１〜６質量％含有する。 The dishwashing composition for hand washing of the present invention has a component (a) of 1 to 50% by mass, preferably 10 to 40% by mass, from the viewpoint of foaming power at the time of washing, foam disappearance at the time of rinsing, and economy. More preferably, it contains 15-30 mass%. Moreover, (b) component becomes like this. Preferably it is 1-10 mass%, More preferably, 2-5 mass% is contained. In addition, the quantity of (b) component for calculating | requiring mass%, mass ratio, etc. in this invention is the quantity as an acid type compound. Moreover, (c) component becomes like this. Preferably it is 0.1-20 mass%, More preferably, it is 0.5-10 mass%, More preferably, 1-6 mass% is contained.
また、本発明の手洗い用食器洗浄剤組成物では、（ｂ）成分／（ｃ）成分の質量比は０．１〜８であり、好ましくは２〜７、より好ましくは４〜６である。すすぎ時の泡消え性の観点から（ｂ）成分／（ｃ）成分の質量比は０．１以上であり、洗浄時の起泡力及び配合安定性の観点から１０以下である。 Moreover, in the dishwashing agent composition for hand-washing of this invention, the mass ratio of (b) component / (c) component is 0.1-8, Preferably it is 2-7, More preferably, it is 4-6. From the viewpoint of foam extinction at the time of rinsing, the mass ratio of the component (b) / (c) is 0.1 or more, and is 10 or less from the viewpoint of foaming power at the time of washing and blending stability.
また、本発明の手洗い用食器洗浄剤組成物では、泡消え性の観点から、（ｂ）成分／（ａ）成分の質量比は０．００１０〜１．０が好ましく、より好ましくは０．０１０〜０．５０、更に好ましくは０．０５０〜０．１０である。 In the dishwashing composition for hand washing of the present invention, the mass ratio of the component (b) / the component (a) is preferably 0.0010 to 1.0, more preferably 0.010, from the viewpoint of foam disappearance. It is -0.50, More preferably, it is 0.050-0.10.
また、本発明の手洗い用食器洗浄剤組成物では、洗浄時の起泡力及びすすぎ時の泡消え性の観点から、（ａ）成分／〔（ｂ）成分＋（ｃ）成分〕の質量比が、好ましくは１〜１５、より好ましくは１．５〜１４、更に好ましくは２〜１２である。 Further, in the dishwashing composition for hand washing of the present invention, the mass ratio of (a) component / [(b) component + (c) component] from the viewpoint of foaming power at the time of washing and foam disappearance at the time of rinsing. However, Preferably it is 1-15, More preferably, it is 1.5-14, More preferably, it is 2-12.
本発明の手洗い用食器洗浄剤組成物では、洗浄時の起泡性や泡持続性及びすすぎ時の泡消え性の観点から、（ａ）成分として（ａ１）成分を、（ａ）成分中、５〜９５質量％、更に２０〜７０質量％、より更に５５〜６５質量％含有することが好ましい。 In the dishwashing detergent composition for hand washing of the present invention, from the viewpoint of foaming property and foam persistence at the time of washing and foam disappearance at the time of rinsing, (a1) component as component (a), It is preferable to contain 5 to 95 mass%, further 20 to 70 mass%, and further 55 to 65 mass%.
また、本発明の手洗い用食器洗浄剤組成物では、起泡力及び泡消え性の観点から、（ｂ）成分／（ａ１）成分の質量比は、好ましくは０．００１〜２、より好ましくは０．０１〜１、更に好ましくは０．０２〜０．５、より更に好ましくは０．０５〜０．２である。 In the dishwashing detergent composition for hand washing of the present invention, the mass ratio of the component (b) / (a1) component is preferably 0.001 to 2, more preferably from the viewpoint of foaming power and foam extinction properties. It is 0.01 to 1, more preferably 0.02 to 0.5, and still more preferably 0.05 to 0.2.
また、本発明の手洗い用食器洗浄剤組成物では、泡消えに優れた組成物を得る観点から、（ａ）成分として（ａ２）成分を、（ａ）成分中、５〜９５質量％、更に３０〜８０質量％、より更に３５〜４５質量％含有することが好ましい。 Moreover, in the dishwashing agent composition for hand-washing of this invention, from the viewpoint of obtaining the composition excellent in foam disappearance, (a) component is (a2) component as (a) component in 5-95 mass%, Furthermore, It is preferable to contain 30-80 mass%, and still more 35-45 mass%.
また、（ａ）成分として（ａ１）成分と（ａ２）成分とを含有する場合、洗浄時の起泡性や泡持続性及びすすぎ時の泡消え性の観点から、（ａ１）／（ａ２）の質量比は、０．１〜１０、更に０．２〜３、より更に０．３〜２が好ましい。 In addition, when the component (a1) and the component (a2) are contained as the component (a), from the viewpoints of foaming property and foam sustainability during washing and foam disappearance during rinsing, (a1) / (a2) The mass ratio is preferably 0.1 to 10, more preferably 0.2 to 3, and still more preferably 0.3 to 2.
また、本発明の手洗い用食器洗浄剤組成物では、起泡力及び泡消え性の観点から、（ｂ）成分／（ａ２）成分の質量比は、好ましくは０．００１〜１１、より好ましくは０．０１〜５、更に好ましくは０．０５〜１、より更に好ましくは０．１〜０．３である。 Moreover, in the dishwashing composition for hand-washing of this invention, from the viewpoint of foaming power and foam extinction, the mass ratio of component (b) / component (a2) is preferably 0.001 to 11, more preferably. 0.01 to 5, more preferably 0.05 to 1, and still more preferably 0.1 to 0.3.
本発明においては洗浄時及びすすぎ時の泡の挙動が非常に重要である。手洗い用食器洗浄剤組成物においては、洗浄時の起泡性／泡持続性を考慮して増泡効果のある界面活性剤を併用することが行われているが、本発明においてはそのような増泡効果のある、（ａ）成分、（ｂ）成分以外の界面活性剤は、すすぎ時の泡消え性に影響を及ぼさない範囲で使用できる。 In the present invention, the behavior of bubbles during washing and rinsing is very important. In the dishwashing detergent composition for hand washing, a surfactant having a foam increasing effect is used in combination in consideration of the foamability / foam persistence at the time of washing. Surfactants other than the component (a) and the component (b), which have a foam increasing effect, can be used within a range that does not affect the foam disappearance during rinsing.
本発明では組成物中の全界面活性剤の含有量に対する（ａ）成分、（ｂ）成分、及び（ｃ）成分の合計質量が６０〜１００質量％、更に８０〜１００質量％、より更に９０〜１００質量％であることが洗浄時の起泡力、すすぎ時の泡消え性及び経済性の観点から好ましい。ここで、全界面活性剤の含有量は、（ａ）成分、（ｂ）成分、並びに、（ａ）成分及び（ｂ）成分以外の界面活性剤の総含有量であり、（ａ）成分及び（ｂ）成分以外の界面活性剤としては、（ｄ）アルキルグリセリルエーテル型界面活性剤〔以下、（ｄ）成分という〕、並びに、（ｅ）（ｅ１）両性界面活性剤、（ｅ２）アルカノールアミド型界面活性剤及び（ｅ３）アミンオキシド型界面活性剤から選ばれる界面活性剤〔以下、（ｅ）成分という〕等が挙げられる。 In the present invention, the total mass of the component (a), the component (b), and the component (c) with respect to the total surfactant content in the composition is 60 to 100% by mass, more preferably 80 to 100% by mass, and still more 90%. From the viewpoints of foaming power at the time of washing, foam disappearance at the time of rinsing, and economical efficiency, it is preferably ˜100 mass%. Here, the content of the total surfactant is the total content of the surfactants other than the component (a), the component (b), and the components (a) and (b). Surfactants other than the component (b) include (d) alkyl glyceryl ether surfactants (hereinafter referred to as component (d)), (e) (e1) amphoteric surfactants, (e2) alkanolamides Type surfactants and surfactants selected from (e3) amine oxide type surfactants (hereinafter referred to as component (e)).
本発明の手洗い用食器洗浄剤組成物は、すすぎ時には瞬時にぬるつきがなくなり、少量の水ですすぎを完了できるという観点から、（ｄ）成分として、アルキル基の炭素数が６〜１８のアルキルグリセリルエーテルを含有することが好ましい。具体的には下記一般式（ｄ１）の化合物が好適である。
Ｒ1d−Ｏ−（Ｇｌｙ）r−Ｈ （ｄ１）
〔式中、Ｒ1dは炭素数６〜１８のアルキル基を示し、Ｇｌｙはグリセリンから２つの水素原子を除いた残基を示し、ｒは平均付加モル数であり、１〜４の数を示す。〕
The dishwashing composition for hand-washing of the present invention is instantly free of moisture when rinsed, and is capable of completing rinsing with a small amount of water. As the component (d), an alkyl group having 6 to 18 carbon atoms is used. It is preferable to contain glyceryl ether. Specifically, the compound of the following general formula (d1) is suitable.
R 1d —O— (Gly) r —H (d1)
[Wherein R 1d represents an alkyl group having 6 to 18 carbon atoms, Gly represents a residue obtained by removing two hydrogen atoms from glycerin, r represents an average number of added moles, and represents a number of 1 to 4. . ]
一般式（ｄ１）において、Ｒ1dは炭素数６〜１８、好ましくは７〜１２、より好ましくは８〜１０のアルキル基である。本発明ではすすぎ時のぬるつき低減の観点から、分岐構造を有する化合物が好適であり、Ｒ1dは分岐構造を有するアルキル基が好ましく、具体例として、２−エチルヘキシル基、ｓｅｃ−オクチル基、イソノニル基及びイソデシル基から選ばれる基がより好ましく、２−エチルヘキシル基又はイソデシル基が更に好ましく、２−エチルヘキシル基が特に好ましい。一般式（ｄ１）において、ｒは１〜３が好ましく、１〜２がより好ましく、ｒ＝１の化合物が最も好ましい。特に好ましい化合物は、Ｒ1dが２−エチルヘキシル基で、かつ、ｒ＝１の化合物である。 In the general formula (d1), R 1d is an alkyl group having 6 to 18 carbon atoms, preferably 7 to 12 carbon atoms, more preferably 8 to 10 carbon atoms. In the present invention, a compound having a branched structure is preferable from the viewpoint of reducing the dullness at the time of rinsing, and R 1d is preferably an alkyl group having a branched structure. Specific examples include 2-ethylhexyl group, sec-octyl group, isononyl. A group selected from a group and an isodecyl group is more preferable, a 2-ethylhexyl group or an isodecyl group is still more preferable, and a 2-ethylhexyl group is particularly preferable. In the general formula (d1), r is preferably 1 to 3, more preferably 1 to 2, and most preferably a compound of r = 1. Particularly preferred compounds are those in which R 1d is a 2-ethylhexyl group and r = 1.
Ｇｌｙで示される構造はグリセリンの１位と３位のヒドロキシ基が結合している−ＣＨ2ＣＨ（ＯＨ）ＣＨ2−で示される構造か、又はグリセリンの１位と２位のヒドロキシ基が結合している−ＣＨ（ＣＨ2ＯＨ）ＣＨ2−で示される構造であり、触媒や反応条件によって異なる。 The structure represented by Gly is the structure represented by —CH 2 CH (OH) CH 2 — in which the 1-position and 3-position hydroxy groups of glycerol are bonded, or the 1-position and 2-position hydroxy groups of glycerol are bonded. The structure is represented by —CH (CH 2 OH) CH 2 —, which varies depending on the catalyst and reaction conditions.
一般式（ｄ１）の化合物を得るには、例えば炭素数６〜１０のアルコールとしてＲ1d−ＯＨで示されるアルキルアルコールを用い、エピハロヒドリンやグリシドールなどのエポキシ化合物とを、ＢＦ3などの酸触媒、あるいはアルミニウム触媒を用いて反応させて製造する方法を用いることができる。 In order to obtain the compound of the general formula (d1), for example, an alkyl alcohol represented by R 1d —OH is used as an alcohol having 6 to 10 carbon atoms, and an epoxy compound such as epihalohydrin or glycidol is reacted with an acid catalyst such as BF 3 , Or the method of manufacturing by making it react using an aluminum catalyst can be used.
（ｄ）成分の含有量は洗浄性能の観点から、組成物中、好ましくは０．５〜２０質量％、より好ましくは１〜１５質量％、２〜１０質量％が更に好ましい。 The content of the component (d) is preferably 0.5 to 20% by mass, more preferably 1 to 15% by mass and 2 to 10% by mass in the composition from the viewpoint of cleaning performance.
本発明では、（ｅ）成分として、（ｅ１）両性界面活性剤〔以下、（ｅ１）成分という〕、アルカノールアミド型界面活性剤〔以下、（ｅ２）成分という〕及びアミンオキシド型界面活性剤〔以下、（ｅ３）成分という〕から選ばれる１種以上の界面活性剤を本発明の効果を損なわない範囲で配合することができる。（ｅ）成分は、炭素数８〜１８のアルキル基を有するものが好ましい。 In the present invention, as the component (e), (e1) an amphoteric surfactant (hereinafter referred to as component (e1)), an alkanolamide surfactant (hereinafter referred to as component (e2)) and an amine oxide surfactant ( Hereinafter, it may be blended with one or more surfactants selected from (e3) component within a range not impairing the effects of the present invention. The component (e) preferably has an alkyl group having 8 to 18 carbon atoms.
本発明では増泡効果のある界面活性剤として（ｅ１）成分を使用してもよい。（ｅ１）成分として、スルホベタイン型界面活性剤、カルボベタイン型界面活性剤、及びイミダゾリン型界面活性剤が挙げられる。 In the present invention, the component (e1) may be used as a surfactant having a foam increasing effect. Examples of the component (e1) include sulfobetaine surfactants, carbobetaine surfactants, and imidazoline surfactants.
洗浄時の起泡性及び泡持続性を改善するが、すすぎ時の瞬時の泡消え性を損なうことがない点で、スルホベタイン型界面活性剤が好ましい。スルホベタイン型界面活性剤としては、アルキル基の炭素数が１０〜１８のＮ−アルキル−Ｎ，Ｎ−ジメチル−Ｎ−スルホプロピルアンモニウムスルホベタイン、アルキル基の炭素数が１０〜１８のＮ−アルキル−Ｎ，Ｎ−ジメチル−Ｎ−（２−ヒドロキシスルホプロピル）アンモニウムスルホベタイン、アルカノイル基の炭素数が１０〜１８のＮ−アルカノイルアミノプロピル−Ｎ，Ｎ−ジメチル−Ｎ−スルホプロピルアンモニウムスルホベタイン、アルカノイル基の炭素数が１０〜１８のＮ−アルカノイルアミノプロピル−Ｎ，Ｎ−ジメチル−Ｎ−（２−ヒドロキシスルホプロピル）アンモニウムスルホベタインが好適である。（ｅ１）成分の含有量は、組成物中に好ましくは０．５〜２０質量％、より好ましくは１〜１５質量％、更に好ましくは２〜１０質量％である。また（ｅ１）成分／〔（ａ）成分＋（ｅ１）成分〕の質量比は、洗浄時の起泡性／泡持続性の向上とすすぎ時の泡消え性の観点から、好ましくは０．０１〜０．２、より好ましくは０．０２〜０．１である。 A sulfobetaine-type surfactant is preferred in that it improves foaming properties and foam persistence during washing, but does not impair instantaneous foam disappearance during rinsing. Examples of the sulfobetaine surfactant include N-alkyl-N, N-dimethyl-N-sulfopropylammonium sulfobetaine having an alkyl group having 10 to 18 carbon atoms, and N-alkyl having an alkyl group having 10 to 18 carbon atoms. -N, N-dimethyl-N- (2-hydroxysulfopropyl) ammonium sulfobetaine, N-alkanoylaminopropyl-N, N-dimethyl-N-sulfopropylammonium sulfobetaine whose alkanoyl group has 10 to 18 carbon atoms, N-alkanoylaminopropyl-N, N-dimethyl-N- (2-hydroxysulfopropyl) ammonium sulfobetaine having an alkanoyl group having 10 to 18 carbon atoms is preferred. (E1) Content of a component becomes like this. Preferably it is 0.5-20 mass% in a composition, More preferably, it is 1-15 mass%, More preferably, it is 2-10 mass%. Further, the mass ratio of (e1) component / [(a) component + (e1) component] is preferably 0.01 from the viewpoint of improvement in foamability / foam persistence during washing and foam extinction during rinsing. It is -0.2, More preferably, it is 0.02-0.1.
本発明では増泡効果のある界面活性剤として（ｅ２）成分を使用してもよい。（ｅ２）成分としては、モノエタノールアミン、ジエタノールアミン、メチルモノエタノールアミンなどのアルカノールアミンとラウリン酸、ミリスチン酸などの脂肪酸とのアミド化物が挙げられる。（ｅ２）成分の含有量はすすぎ時の消泡効果の観点で、組成物中、０〜１０質量％、更に０〜５質量％、より更に０〜１質量％が好ましく、実質的に含まないことが特に好ましい。 In the present invention, the component (e2) may be used as a surfactant having a foam increasing effect. Examples of the component (e2) include amidated products of alkanolamines such as monoethanolamine, diethanolamine, and methylmonoethanolamine with fatty acids such as lauric acid and myristic acid. The content of the component (e2) is preferably 0 to 10% by mass, more preferably 0 to 5% by mass, and still more preferably 0 to 1% by mass in the composition from the viewpoint of the defoaming effect at the time of rinsing. It is particularly preferred.
本発明では増泡効果のある界面活性剤として（ｅ３）成分を使用してもよい。（ｅ３）成分としては、Ｎ−アルカノイルアミノプロピル−Ｎ，Ｎ−ジアミノメチルオキシド（アルカノイルとしてはラウロイル又はミリスチロイル）、Ｎ−アルキル−Ｎ，Ｎ−ジアミノメチルオキシド（アルキル基としてはラウリル基又はミリスチル基）が挙げられる。（ｅ３）成分の含有量はすすぎ時の消泡効果の観点で、組成物中、０〜１０質量％、更に０〜５質量％、より更に０〜１質量％が好ましく、実質的に含まないことが特に好ましい。 In the present invention, the component (e3) may be used as a surfactant having a foam increasing effect. As the component (e3), N-alkanoylaminopropyl-N, N-diaminomethyl oxide (lauroyl or myristoyl as alkanoyl), N-alkyl-N, N-diaminomethyl oxide (lauryl group or myristyl group as alkyl group) ). The content of the component (e3) is preferably 0 to 10% by mass, more preferably 0 to 5% by mass, and still more preferably 0 to 1% by mass in the composition from the viewpoint of the defoaming effect at the time of rinsing. It is particularly preferred.
本発明の手洗い用食器洗浄剤組成物は、油汚れに対する乳化力を高め、洗浄力を増強する目的から、（ｆ）成分として、含マグネシウム無機化合物を含有することが好ましい。これらの化合物は、本発明に必要な効果、すなわち（ａ）成分、（ｂ）成分、及び所望により含有される他の陰イオン界面活性剤の少なくとも２分子と比較的弱く相互作用しコンプレックスを形成させ、乳化力などの界面活性能を向上させる化合物として共通の効果／作用機構を有するものである。 The dishwashing composition for hand washing of the present invention preferably contains a magnesium-containing inorganic compound as the component (f) for the purpose of enhancing the emulsifying power against oil stains and enhancing the cleaning power. These compounds interact relatively weakly with at least two molecules of the effect necessary for the present invention, ie, component (a), component (b), and other anionic surfactants optionally contained to form a complex. And has a common effect / action mechanism as a compound that improves the surface activity such as emulsifying power.
含マグネシウム無機化合物としては、塩化マグネシウム等のマグネシウム塩化物、硫酸マグネシウム、硝酸マグネシウム等のマグネシウム塩、水酸化マグネシウム、酸化マグネシウム等が挙げられるが、塩化マグネシウム及び硫酸マグネシウムから選ばれる化合物がより好ましく、塩化マグネシウムが更により好ましい。 Examples of the magnesium-containing inorganic compound include magnesium chloride such as magnesium chloride, magnesium salts such as magnesium sulfate and magnesium nitrate, magnesium hydroxide, magnesium oxide, and the like, more preferably a compound selected from magnesium chloride and magnesium sulfate. Even more preferred is magnesium chloride.
（ｆ）成分の含有量は、油汚れに対する乳化力を高め、洗浄力を増強する観点から、組成物中、好ましくは１〜２０質量％、より好ましくは２〜１５質量％、更に好ましくは３〜１０質量％である。なお、これら（ｆ）成分は結晶水を含む場合があるが、ここで示す含有量は、結晶水を除いた質量である。 The content of the component (f) is preferably 1 to 20% by mass, more preferably 2 to 15% by mass, and still more preferably 3 in the composition from the viewpoint of enhancing emulsifying power against oil stains and enhancing detergency. -10 mass%. In addition, although these (f) components may contain crystal water, content shown here is the mass except crystal water.
本発明の手洗い用食器洗浄剤組成物は、（ｆ）成分の補助として（ｆ）成分以外の無機化合物を併用してもよい。無機化合物としては、塩化ナトリウム、塩化カリウム、ヨウ化ナトリウム、ヨウ化カリウム、硫酸ナトリウム、硫酸カリウム、ミョウバン等が挙げられる。 In the dishwashing composition for hand washing of the present invention, an inorganic compound other than the component (f) may be used in combination with the component (f). Examples of inorganic compounds include sodium chloride, potassium chloride, sodium iodide, potassium iodide, sodium sulfate, potassium sulfate, alum and the like.
本発明では、手洗い用食器洗浄剤組成物の貯蔵安定性を向上させる効果がある添加剤として、ハイドロトロープ剤〔以下、（ｇ）成分という〕を使用してもよい。ハイドロトロープ剤としては、トルエンスルホン酸、キシレンスルホン酸、クメンスルホン酸又はこれらのナトリウム、カリウムあるいはマグネシウム塩が良好であり、特にｐ−トルエンスルホン酸又はその塩が良好である。（ｇ）成分の含有量は貯蔵安定性の観点から、組成物中に好ましくは０．５〜１５質量％、より好ましくは１〜１０質量％、特に好ましくは１．５〜５質量％である。 In this invention, you may use a hydrotrope agent (henceforth (g) component) as an additive which has the effect of improving the storage stability of the dishwashing composition for hand-washing. As the hydrotrope, toluenesulfonic acid, xylenesulfonic acid, cumenesulfonic acid or a sodium, potassium or magnesium salt thereof is preferable, and p-toluenesulfonic acid or a salt thereof is particularly preferable. The content of the component (g) is preferably 0.5 to 15% by mass, more preferably 1 to 10% by mass, and particularly preferably 1.5 to 5% by mass in the composition from the viewpoint of storage stability. .
本発明の手洗い用食器洗浄剤組成物は、貯蔵安定性の改善や粘度調節の目的で、溶剤〔以下、（ｈ）成分という〕を含有することができる。溶剤の具体的例としては、エタノール、イソプロピルアルコール、エチレングリコール、プロピレングリコール、ジエチレングリコール、ジプロピレングリコール、グリセリン、イソプレングリコール、プロピレングリコールモノメチルエーテル、プロピレングリコールモノエチルエーテル、３−メチル−３−メトキシブタノール、フェノキシエタノール、フェニルグリコール、フェノキシイソプロパノール、ブチルジグリコール（ジエチレングリコールモノブチルエーテル）、ジブチレンジグリコール、ベンジルアルコールから選ばれる水溶性有機溶媒が好ましい。なかでも、ブチルジグリコール、エタノール、及びプロピレングリコールから選ばれる１種以上の水溶性有機溶剤が好ましく、エタノール、及びプロピレングリコールから選ばれる１種以上の水溶性有機溶剤が更に好ましい。ここで、水溶性有機溶剤とは、オクタノール／水分配係数（ＬｏｇＰｏｗ）が３．５以下の溶剤を指すものとする。（ｈ）成分の含有量は、組成物中に好ましくは３〜３０質量％、より好ましくは５〜２０質量％、特に好ましくは１０〜１５質量％である。 The dishwashing composition for hand washing of the present invention can contain a solvent [hereinafter referred to as component (h)] for the purpose of improving storage stability and adjusting viscosity. Specific examples of the solvent include ethanol, isopropyl alcohol, ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, glycerin, isoprene glycol, propylene glycol monomethyl ether, propylene glycol monoethyl ether, 3-methyl-3-methoxybutanol, A water-soluble organic solvent selected from phenoxyethanol, phenyl glycol, phenoxyisopropanol, butyl diglycol (diethylene glycol monobutyl ether), dibutylene glycol, and benzyl alcohol is preferred. Among these, one or more water-soluble organic solvents selected from butyl diglycol, ethanol, and propylene glycol are preferable, and one or more water-soluble organic solvents selected from ethanol and propylene glycol are more preferable. Here, the water-soluble organic solvent refers to a solvent having an octanol / water partition coefficient (LogPow) of 3.5 or less. The content of the component (h) is preferably 3 to 30% by mass, more preferably 5 to 20% by mass, and particularly preferably 10 to 15% by mass in the composition.
本発明では、手洗い用食器洗浄剤組成物のゲル化防止のために重合体〔以下、（ｉ）成分という〕、例えば特表平１１−５１３０６７号公報に記載されているゲル化防止重合体を使用してもよい。とりわけポリアルキレングリコールを配合することが粘度調節及び貯蔵安定性の点から好ましい。ゲル化防止のための重合体としてのポリアルキレングリコールの具体例としては、ポリエチレングリコールを標準としたときのゲルパーミエーションクロマトグラフィーによって求められた重量平均分子量が２００〜３，０００のポリプロピレングリコール、及び重量平均分子量が２００〜３，０００のポリエチレングリコールを挙げることができる。（ｉ）成分の含有量は、組成物中に好ましくは０．０５〜１０質量％、より好ましくは０．１〜５質量％、特に好ましくは０．５〜３質量％である。 In the present invention, in order to prevent gelation of a dishwashing detergent composition for hand washing, a polymer (hereinafter referred to as component (i)), for example, a gelation-preventing polymer described in JP-T-11-513067 is used. May be used. In particular, blending of polyalkylene glycol is preferable from the viewpoint of viscosity control and storage stability. Specific examples of the polyalkylene glycol as a polymer for preventing gelation include polypropylene glycol having a weight average molecular weight of 200 to 3,000 determined by gel permeation chromatography using polyethylene glycol as a standard, and Examples include polyethylene glycol having a weight average molecular weight of 200 to 3,000. (I) Content of a component becomes like this. Preferably it is 0.05-10 mass% in a composition, More preferably, it is 0.1-5 mass%, Most preferably, it is 0.5-3 mass%.
本発明の手洗い用食器洗浄剤組成物は、上記成分を水に溶解／分散／乳化させた液体組成物の形態が好ましく、水溶液がより好ましい。水としては脱イオン水や蒸留水、或いは次亜塩素酸を０．５〜１０ｐｐｍ程度溶解させた次亜塩素酸滅菌水などを使用することができる。 The dishwashing composition for hand washing of the present invention is preferably in the form of a liquid composition in which the above components are dissolved / dispersed / emulsified in water, and more preferably an aqueous solution. As water, deionized water, distilled water, or hypochlorous acid sterilized water in which about 0.5 to 10 ppm of hypochlorous acid is dissolved can be used.
水を含有する液体組成物の場合、本発明の手洗い用食器洗浄剤組成物の２５℃におけるｐＨは洗浄力及び貯蔵安定性の観点から、好ましくは４〜９、より好ましくは５〜８であり、このようなｐＨへの調整は、硫酸、塩酸、リン酸から選ばれる無機酸、クエン酸、りんご酸、マレイン酸、フマール酸、コハク酸から選ばれる有機酸、水酸化ナトリウム、水酸化カリウム、水酸化マグネシウム、炭酸ナトリウム、炭酸カリウムなどの無機アルカリ剤を用いて行われる。本発明では、組成物に緩衝能を持たせることが起泡性／泡持続性の点から好ましく、上記有機酸、好ましくはクエン酸と、無機アルカリ剤とを併用することが好適である。有機酸はナトリウム塩やカリウム塩の形態で組成物に配合しても差し支えない。なお、ｐＨ調整のために用いた化合物のうち、水酸化マグネシウム等、（ｆ）成分に該当するものは、（ｆ）成分として取り扱うものとする。 In the case of a liquid composition containing water, the pH of the dishwashing composition for hand washing of the present invention at 25 ° C. is preferably 4 to 9, more preferably 5 to 8, from the viewpoints of detergency and storage stability. In order to adjust the pH, an inorganic acid selected from sulfuric acid, hydrochloric acid, and phosphoric acid, an organic acid selected from citric acid, malic acid, maleic acid, fumaric acid, and succinic acid, sodium hydroxide, potassium hydroxide, It is carried out using an inorganic alkaline agent such as magnesium hydroxide, sodium carbonate or potassium carbonate. In the present invention, it is preferable that the composition has a buffering ability from the viewpoint of foamability / foam persistence, and it is preferable to use the organic acid, preferably citric acid, and an inorganic alkaline agent in combination. The organic acid may be added to the composition in the form of sodium salt or potassium salt. Of the compounds used for pH adjustment, those corresponding to component (f), such as magnesium hydroxide, are handled as component (f).
本発明の手洗い用食器洗浄剤組成物の２０℃における粘度は、好ましくは５〜５００ｍＰａ・ｓ、より好ましくは１０〜３００ｍＰａ・ｓである。粘度は（ｇ）成分、（ｈ）成分、（ｉ）成分などで調整することができる。 The viscosity at 20 ° C. of the dishwashing composition for hand washing of the present invention is preferably 5 to 500 mPa · s, more preferably 10 to 300 mPa · s. Viscosity can be adjusted with (g) component, (h) component, (i) component, etc.
本発明の手洗い用食器洗浄剤組成物は、香料、染料、顔料などの成分を含有することができる。 The dishwashing composition for hand-washing of this invention can contain components, such as a fragrance | flavor, dye, and a pigment.
本発明の手洗い用食器洗浄剤組成物は、食器の手洗い洗浄に用いられる。手洗い洗浄に用いられる洗浄液は、本発明の手洗い用食器洗浄剤組成物を用いて得られたものであり、組成物の原液又は水を含む希釈液が用いられる。具体的な手洗い洗浄方法としては、例えば、水を含んだスポンジなどの可撓性材料に本発明の組成物を付着させ洗浄液を保持させて、手で数回揉みながら泡立てて、食器をこすり洗いする。可撓性材料が保持する洗浄液中の（ａ）成分、（ｂ）成分、（ｃ）成分及び（ｄ）成分の合計濃度は、好ましくは１，０００〜３０，０００ｐｐｍ、より好ましくは１，０００〜２０，０００ｐｐｍ、更に好ましくは２，０００〜１０，０００ｐｐｍであることが、高い起泡性と泡持続性の点から好ましい。洗浄終了後には水を加えてすすぎを行うが、例えば、本発明では使用した組成物１質量部に対してすすぎ水３．３〜１３３質量部で泡が消え、すすぎを速やかに完了することができる。このすすぎ水の量は、従来の手洗い用洗浄剤組成物を用いた場合の２／３〜１／１０である。 The dishwashing composition for handwashing of the present invention is used for handwashing dishes. The cleaning liquid used for hand-washing is obtained using the dishwashing detergent composition for hand-washing of the present invention, and a stock solution of the composition or a diluted solution containing water is used. As a specific hand-washing method, for example, the composition of the present invention is attached to a flexible material such as a sponge containing water to hold the cleaning liquid, and foamed while squeezing several times by hand to rub the dishes. To do. The total concentration of component (a), component (b), component (c) and component (d) in the cleaning liquid held by the flexible material is preferably 1,000 to 30,000 ppm, more preferably 1,000. From 20,000 to 10,000 ppm, more preferably from 2,000 to 10,000 ppm, from the viewpoint of high foamability and foam persistence. After completion of washing, water is added to perform rinsing. For example, in the present invention, bubbles disappear with 3.3 to 133 parts by mass of rinsing water with respect to 1 part by mass of the composition used, and rinsing can be completed quickly. it can. The amount of the rinsing water is 2/3 to 1/10 when a conventional hand washing detergent composition is used.
表１、２及び下記の配合成分を用いて表１、２の手洗い用食器洗浄剤組成物を調製し、下記の各評価を行った。結果を表１、２に示す。なお、表１、２中の配合成分の質量％は、全て有効分に基づく数値である。 Using Tables 1 and 2 and the following blending components, the tableware detergent compositions for hand washing shown in Tables 1 and 2 were prepared and subjected to the following evaluations. The results are shown in Tables 1 and 2. In addition, the mass% of the compounding component in Tables 1 and 2 is a numerical value based on all the effective components.
＜配合成分＞
・ＡｐＳ−Ｎａ：アルキル鎖がＣ８／Ｃ１０／Ｃ１２＝５／５／９０（質量比、Ｃの次の数字は炭素数を意味する）の天然アルコール１モルにプロピレンオキシドを０．６モル付加して得られたものを三酸化イオウにより硫酸化したのち、水酸化ナトリウム水溶液で中和した（水で１０％希釈したもののｐＨが１１になるまで中和した）もの（平均分子量３４３）。
・Ｃ１２−１３ＡＳ：炭素数１２〜１３の１級アルコール（商品名ＮＥＯＤＯＬ ２３、Ｓｈｅｌｌ社製）を三酸化イオウにより硫酸化し、水酸化ナトリウム水溶液でｐＨ調整と同時に希釈したもの（１０質量％水溶液のｐＨは１１）（平均分子量：２９６、分岐率２０モル％）
・ＬＡＳ：アルキル鎖がＣ１０／Ｃ１１／Ｃ１２／Ｃ１３＝１０／３５／３５／２０（質量比）のアルキルベンゼンスルホン酸ナトリウム（Ｃの次の数字は炭素数を意味する）（平均分子量：３４６）
・ＳＡＳ６０：アルカン（炭素数１４〜１７第二アルキル基混合）スルホン酸ナトリウム（商品名HOSTAPUR SAS 60、Clariant社製）（平均分子量：３３１）
・ＤＡＳＳ：スルホコハク酸ジ−２−エチルヘキシルナトリウム〔関東化学（株）〕
・１，３−ＢＡＣ：１，３−ビス（アミノメチル）シクロヘキサン
・ＰＧ：プロピレングリコール：品名「プロピレングリコール工業グレード」（ザ・ダウ・ケミカル・カンパニー）
・ＢＤＧ：ジエチレングリコールモノブチルエーテル（品名：ＢＤＧ−ＮＳ〔日本乳化剤（株）〕）
<Blending ingredients>
ApS-Na: 0.6 mol of propylene oxide was added to 1 mol of natural alcohol having an alkyl chain of C8 / C10 / C12 = 5/5/90 (mass ratio, the number after C means the number of carbon atoms). The product obtained was sulfated with sulfur trioxide, and then neutralized with an aqueous sodium hydroxide solution (neutralized until diluted to 10% with water until the pH was 11) (average molecular weight 343).
C12-13AS: a primary alcohol having 12 to 13 carbon atoms (trade name NEODOL 23, manufactured by Shell) sulfated with sulfur trioxide and diluted with sodium hydroxide aqueous solution at the same time as pH adjustment (10% by weight aqueous solution) pH is 11) (average molecular weight: 296, branching rate: 20 mol%)
LAS: Sodium alkylbenzenesulfonate having an alkyl chain of C10 / C11 / C12 / C13 = 10/35/35/20 (mass ratio) (the number after C means the number of carbon atoms) (average molecular weight: 346)
SAS60: alkane (mixed with 14 to 17 carbon atoms, secondary alkyl group) sodium sulfonate (trade name HOSTAPUR SAS 60, manufactured by Clariant) (average molecular weight: 331)
DASS: di-2-ethylhexyl sodium sulfosuccinate [Kanto Chemical Co., Ltd.]
・ 1,3-BAC: 1,3-bis (aminomethyl) cyclohexane PG: Propylene glycol: Product name “Propylene glycol industrial grade” (The Dow Chemical Company)
・ BDG: Diethylene glycol monobutyl ether (Product name: BDG-NS [Nippon Emulsifier Co., Ltd.])
＜起泡力（初期泡量）及び泡消え性＞
組成物を３．５°ｄＨ硬水で３０倍希釈し、ポンプフォーマー（２００メッシュ１枚）により、３ｇの泡を５００ｍｌのメスシリンダーに作製し、メスシリンダーの目盛りからその容量を記録し、起泡力（初期泡量）とした。
<Foaming power (initial foam amount) and foam disappearance>
Dilute the composition 30 times with 3.5 ° dH hard water, make 3 g of foam into a 500 ml graduated cylinder with a pump former (one 200 mesh), record the volume from the graduated scale and record the volume. The foam power (initial foam amount) was used.
次に、手製のジョウロの下面を上記メスシリンダーの上端に設置して、当該ジョウロに３．５°ｄＨ硬水１００ｍｌを瞬時に満たして、そのままジョウロを通じて硬水を泡に添加し、３０秒後、再び当該ジョウロに３．５°ｄＨ硬水１００ｍｌを瞬時に満たして、そのままジョウロを通じて硬水を泡に添加し、３０秒後の泡量（硬水２００ｍｌ添加後の泡量）を確認し、次式で示す泡量変化率を求めた。尚、泡量変化率が５０％以下であれば希釈（すすぎ）による速やかな泡消えが達成できるものと判断できる。
泡量変化率（％）＝（硬水２００ｍｌ添加後の泡量／初期の泡量）×１００
Next, the lower surface of the handmade water heater is installed at the upper end of the graduated cylinder, and the water is immediately filled with 100 ml of 3.5 ° dH hard water, and hard water is added to the foam as it is through the water heater. Fill the water with 100 ml of 3.5 ° dH hard water instantly, add the hard water to the foam as it is through the water, check the amount of foam after 30 seconds (the amount of foam after adding 200 ml of hard water), and the following formula: The amount change rate was determined. If the rate of change in the amount of foam is 50% or less, it can be determined that rapid foam disappearance by dilution (rinsing) can be achieved.
Foam amount change rate (%) = (foam amount after addition of 200 ml of hard water / initial foam amount) × 100
なお、ポンプフォーマーは市販の「キュキュットクエン酸効果泡タイプ」（花王（株）製：２００７年製造）のポンプフォーマーを水で十分洗浄・乾燥させたものを用いた。手製のジョウロは、２５０ｍｌのポリプロピレン製広口びん（アズワン製：アイボーイ広口びん）の底部約３分の１を除去し、フタを外した状態の開口部に、均一に１３個の直径約２ｍｍの穴を開けた薄いプラスチック製の多孔板を固定して作製した。上部から水を注ぐと下端面の穴から水が放出される。 As the pump former, a commercially available pump former of “Cucut citric acid effect foam type” (manufactured by Kao Corporation: manufactured in 2007) was sufficiently washed with water and dried. The hand-made water bottle is made by removing about one-third of the bottom of a 250 ml polypropylene wide-mouthed bottle (Aswan: Eyeboy wide-mouthed bottle), and uniformly opening 13 holes with a diameter of about 2 mm in the opening with the lid removed. A thin plastic perforated plate with the opening opened was fixed. When water is poured from the top, water is released from the hole at the lower end.
表１、２の結果から、実施例１、３、４と比較例１〜６を比較すると（ｂ）成分に加えて（ｃ）成分を含有することで泡消え性が発現することが分かった。また、実施例９と比較例７及び８と比較すると、（ｂ）／（ｃ）質量比が所定の範囲内にあると優れた泡消え性が発現することが分かった。 From the results of Tables 1 and 2, when Examples 1, 3, 4 and Comparative Examples 1 to 6 were compared, it was found that the foam disappearance was expressed by containing the component (c) in addition to the component (b). . Moreover, when Example 9 and Comparative Examples 7 and 8 were compared, it was found that when the mass ratio (b) / (c) was within a predetermined range, excellent foam disappearance was exhibited.
本発明の手洗い用食器洗浄剤組成物は、洗浄時には豊かな泡立ちと洗浄時の泡の持続性を示すが、すすぎ時には瞬時に泡が消え、少量の水ですすぎが完了する手洗い用食器洗浄剤組成物として適している。 The dishwashing composition for hand washing of the present invention exhibits rich foaming during washing and the persistence of foaming during washing, but the foam disappears instantly during rinsing and the rinsing with a small amount of water is completed. Suitable as a composition.
Claims (8)
〔式中、Ｒ1c〜Ｒ12cはそれぞれ、炭素数１〜３のアルキル基、炭素数１〜３のアミノアルキル基、アミノ基又は水素原子であり、かつ、Ｒ1c〜Ｒ12cの中の２つがアミノ基及び炭素数１〜３のアミノアルキル基から選ばれる基である。〕 (C) is organic diamine of a following formula (c1), The dishwashing agent composition for hand-washing in any one of Claims 1-4.
[Wherein, R 1c to R 12c are each an alkyl group having 1 to 3 carbon atoms, an aminoalkyl group having 1 to 3 carbon atoms, an amino group, or a hydrogen atom, and 2 in R 1c to R 12c One is a group selected from an amino group and an aminoalkyl group having 1 to 3 carbon atoms. ]
Ｒ1a−Ｏ−〔（ＰＯ）m／（ＥＯ）n〕−ＳＯ3Ｍ （ａ１）
〔式中、Ｒ1aは、炭素数８〜１８のアルキル基であり、ＰＯとＥＯはそれぞれプロピレンオキシ基とエチレンオキシ基であり、ｍ、ｎはＰＯ又はＥＯの付加モル数を示し、それぞれ０〜１．５となる数である。Ｍは無機又は有機の陽イオンである。ＰＯとＥＯの付加順序は問わない。また、“／”は、ＰＯとＥＯの付加形態がブロックでもランダムでもよいことを意味する。〕 (A) is (a1) the compound of the following general formula (a1), The dishwashing composition for hand-washing of any one of Claims 1-6.
R 1a -O - [(PO) m / (EO) n ] -SO 3 M (a1)
[Wherein, R 1a is an alkyl group having 8 to 18 carbon atoms, PO and EO are a propyleneoxy group and an ethyleneoxy group, respectively, m and n represent the added mole number of PO or EO, It is a number which becomes -1.5. M is an inorganic or organic cation. The order of addition of PO and EO does not matter. “/” Means that the addition form of PO and EO may be block or random. ]
Ｒ1a−Ｏ−〔（ＰＯ）m／（ＥＯ）n〕−ＳＯ3Ｍ （ａ１）
〔式中、Ｒ1aは、炭素数８〜１８のアルキル基であり、ＰＯとＥＯはそれぞれプロピレンオキシ基とエチレンオキシ基であり、ｍ、ｎはＰＯ又はＥＯの付加モル数を示し、それぞれ０〜１．５となる数である。Ｍは無機又は有機の陽イオンである。ＰＯとＥＯの付加順序は問わない。また、“／”は、ＰＯとＥＯの付加形態がブロックでもランダムでもよいことを意味する。〕 (A) is (a1) a compound of the following general formula (a1), and (a2) monoalkyl sulfosuccinate (the alkyl group has 5 to 18 carbon atoms) ester salt and dialkyl sulfosuccinate (the alkyl group has 5 to 5 carbon atoms, respectively) 18) A sulfosuccinic acid ester salt type surfactant selected from ester salts, The dishwashing composition for hand washing according to any one of claims 1 to 7.
R 1a -O - [(PO) m / (EO) n ] -SO 3 M (a1)
[Wherein, R 1a is an alkyl group having 8 to 18 carbon atoms, PO and EO are a propyleneoxy group and an ethyleneoxy group, respectively, m and n represent the added mole number of PO or EO, It is a number which becomes -1.5. M is an inorganic or organic cation. The order of addition of PO and EO does not matter. “/” Means that the addition form of PO and EO may be block or random. ]
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011001264A JP5875766B2 (en) | 2011-01-06 | 2011-01-06 | Dishwashing composition for hand washing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011001264A JP5875766B2 (en) | 2011-01-06 | 2011-01-06 | Dishwashing composition for hand washing |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2012140572A true JP2012140572A (en) | 2012-07-26 |
| JP5875766B2 JP5875766B2 (en) | 2016-03-02 |
Family
ID=46677179
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011001264A Active JP5875766B2 (en) | 2011-01-06 | 2011-01-06 | Dishwashing composition for hand washing |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP5875766B2 (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2013054635A1 (en) * | 2011-10-12 | 2013-04-18 | 花王株式会社 | Composition for dishwashing liquid for cleaning hands |
| WO2013054636A1 (en) * | 2011-10-12 | 2013-04-18 | 花王株式会社 | Detergent composition for hand washing dishes |
| JP2017513986A (en) * | 2014-04-30 | 2017-06-01 | ザ プロクター アンド ギャンブル カンパニー | Cleaning composition |
| JP2018532854A (en) * | 2015-10-29 | 2018-11-08 | ザ プロクター アンド ギャンブル カンパニー | Cleaning product |
| JP2018532855A (en) * | 2015-10-29 | 2018-11-08 | ザ プロクター アンド ギャンブル カンパニー | Liquid detergent composition |
| JP7568608B2 (en) | 2021-12-23 | 2024-10-16 | 花王株式会社 | Foam suppressor composition |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3613835A1 (en) | 2018-08-24 | 2020-02-26 | The Procter & Gamble Company | Treatment compositions comprising a surfactant system and an oligoamine |
| EP3613834A1 (en) | 2018-08-24 | 2020-02-26 | The Procter & Gamble Company | Treatment compositions comprising low levels of an oligoamine |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08503732A (en) * | 1992-11-30 | 1996-04-23 | ザ、プロクター、エンド、ギャンブル、カンパニー | Highly foaming detergent composition containing special soap |
| JP2001507727A (en) * | 1996-12-20 | 2001-06-12 | ザ、プロクター、エンド、ギャンブル、カンパニー | Dishwashing detergent composition containing organic diamine |
| JP2001515100A (en) * | 1997-08-29 | 2001-09-18 | ザ、プロクター、エンド、ギャンブル、カンパニー | Concentrated liquid dishwashing detergent composition containing organic diamine |
| JP2001520304A (en) * | 1997-10-23 | 2001-10-30 | ザ、プロクター、エンド、ギャンブル、カンパニー | Fatty acids, soaps, surfactant systems and consumer products based on them |
| JP2002517549A (en) * | 1998-06-02 | 2002-06-18 | ザ、プロクター、エンド、ギャンブル、カンパニー | Dishwashing detergent composition containing organic diamine |
| JP2002535443A (en) * | 1999-01-20 | 2002-10-22 | ザ、プロクター、エンド、ギャンブル、カンパニー | Dishwashing composition comprising an alkylbenzene sulfonate surfactant |
| JP2004203989A (en) * | 2002-12-25 | 2004-07-22 | Lion Corp | Liquid detergent composition for tableware washing |
| JP2006160869A (en) * | 2004-12-07 | 2006-06-22 | Kao Corp | Liquid detergent composition |
| JP2008520767A (en) * | 2004-11-15 | 2008-06-19 | ザ プロクター アンド ギャンブル カンパニー | Liquid detergent composition for improved low temperature oil cleaning |
-
2011
- 2011-01-06 JP JP2011001264A patent/JP5875766B2/en active Active
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08503732A (en) * | 1992-11-30 | 1996-04-23 | ザ、プロクター、エンド、ギャンブル、カンパニー | Highly foaming detergent composition containing special soap |
| JP2001507727A (en) * | 1996-12-20 | 2001-06-12 | ザ、プロクター、エンド、ギャンブル、カンパニー | Dishwashing detergent composition containing organic diamine |
| JP2001515100A (en) * | 1997-08-29 | 2001-09-18 | ザ、プロクター、エンド、ギャンブル、カンパニー | Concentrated liquid dishwashing detergent composition containing organic diamine |
| JP2001520304A (en) * | 1997-10-23 | 2001-10-30 | ザ、プロクター、エンド、ギャンブル、カンパニー | Fatty acids, soaps, surfactant systems and consumer products based on them |
| JP2002517549A (en) * | 1998-06-02 | 2002-06-18 | ザ、プロクター、エンド、ギャンブル、カンパニー | Dishwashing detergent composition containing organic diamine |
| JP2002535443A (en) * | 1999-01-20 | 2002-10-22 | ザ、プロクター、エンド、ギャンブル、カンパニー | Dishwashing composition comprising an alkylbenzene sulfonate surfactant |
| JP2004203989A (en) * | 2002-12-25 | 2004-07-22 | Lion Corp | Liquid detergent composition for tableware washing |
| JP2008520767A (en) * | 2004-11-15 | 2008-06-19 | ザ プロクター アンド ギャンブル カンパニー | Liquid detergent composition for improved low temperature oil cleaning |
| JP2006160869A (en) * | 2004-12-07 | 2006-06-22 | Kao Corp | Liquid detergent composition |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2013054635A1 (en) * | 2011-10-12 | 2013-04-18 | 花王株式会社 | Composition for dishwashing liquid for cleaning hands |
| WO2013054636A1 (en) * | 2011-10-12 | 2013-04-18 | 花王株式会社 | Detergent composition for hand washing dishes |
| JP2013100461A (en) * | 2011-10-12 | 2013-05-23 | Kao Corp | Detergent composition for hand-washing dish |
| CN103890156A (en) * | 2011-10-12 | 2014-06-25 | 花王株式会社 | Composition for dishwashing liquid for cleaning hands |
| JP2017513986A (en) * | 2014-04-30 | 2017-06-01 | ザ プロクター アンド ギャンブル カンパニー | Cleaning composition |
| JP2019112650A (en) * | 2014-04-30 | 2019-07-11 | ザ プロクター アンド ギャンブル カンパニーＴｈｅ Ｐｒｏｃｔｅｒ ＆ Ｇａｍｂｌｅ Ｃｏｍｐａｎｙ | Cleaning composition |
| JP2018532854A (en) * | 2015-10-29 | 2018-11-08 | ザ プロクター アンド ギャンブル カンパニー | Cleaning product |
| JP2018532855A (en) * | 2015-10-29 | 2018-11-08 | ザ プロクター アンド ギャンブル カンパニー | Liquid detergent composition |
| JP2020169330A (en) * | 2015-10-29 | 2020-10-15 | ザ プロクター アンド ギャンブル カンパニーＴｈｅ Ｐｒｏｃｔｅｒ ＆ Ｇａｍｂｌｅ Ｃｏｍｐａｎｙ | Liquid detergent composition |
| JP7068387B2 (en) | 2015-10-29 | 2022-05-16 | ザ プロクター アンド ギャンブル カンパニー | Liquid detergent composition |
| JP7568608B2 (en) | 2021-12-23 | 2024-10-16 | 花王株式会社 | Foam suppressor composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JP5875766B2 (en) | 2016-03-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5875766B2 (en) | Dishwashing composition for hand washing | |
| JP5775788B2 (en) | Dishwashing composition for hand washing | |
| JP5654537B2 (en) | Dishwashing composition for hand washing | |
| TWI609078B (en) | Hand wash food detergent composition | |
| JP5642598B2 (en) | Dishwashing composition for hand washing | |
| JP5659038B2 (en) | Detergent composition for dishwashing | |
| JP5774315B2 (en) | Dishwashing composition for hand washing | |
| JP5642599B2 (en) | Dishwashing composition for hand washing | |
| US6172024B1 (en) | High foaming grease cutting light duty liquid detergent comprising a poly (oxyethylene) diamine | |
| JP5700523B2 (en) | Dishwashing composition for hand washing | |
| JP5700553B2 (en) | Cleaning composition for hard surface | |
| JP6549383B2 (en) | Dishwashing composition for hand washing | |
| JP5722692B2 (en) | Dishwashing composition for hand washing | |
| US6495507B1 (en) | High foaming, grease cutting light duty liquid detergent | |
| JP5875827B2 (en) | Dishwashing composition for hand washing | |
| JP2016132689A (en) | Detergent composition for washing dishes by hand | |
| JP5805493B2 (en) | Dishwashing composition for hand washing | |
| JP5957198B2 (en) | Dishwashing composition for hand washing | |
| JP5844223B2 (en) | Surfactant mixture | |
| JP5592781B2 (en) | Dishwashing composition for hand washing | |
| JP5802612B2 (en) | Liquid detergent for kitchen | |
| JP6549379B2 (en) | Dishwashing composition for hand washing | |
| JP5809006B2 (en) | Dishwashing composition for hand washing | |
| JP6472984B2 (en) | Dishwashing composition for hand washing | |
| JP2018184496A (en) | Tableware detergent |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20131216 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20140911 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20141028 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20141222 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20150630 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20150806 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20160112 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20160120 |
|
| R151 | Written notification of patent or utility model registration |
Ref document number: 5875766 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R151 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |