CN103890156A - Composition for dishwashing liquid for cleaning hands - Google Patents

Composition for dishwashing liquid for cleaning hands Download PDF

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Publication number
CN103890156A
CN103890156A CN201280050578.7A CN201280050578A CN103890156A CN 103890156 A CN103890156 A CN 103890156A CN 201280050578 A CN201280050578 A CN 201280050578A CN 103890156 A CN103890156 A CN 103890156A
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composition
quality
hand washing
carbonatoms
tableware
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CN103890156B (en
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小西祥博
渡边义幸
铃木圭吾
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Kao Corp
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Kao Corp
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/18—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/123—Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/92—Sulfobetaines ; Sulfitobetaines

Abstract

The present invention is a composition for a dishwashing liquid for cleaning hands, containing: (a) a specified sulfosuccinate di- or monoalkyl ester or salt of the same; (b) a hydrocarbon base with a carbon number from 8 to 21, and 5 to 35 mass percent of an anion surfactant having a sulfate base or a sulfonate base (excluding (a)): and (c) a sulfobetaine-type surfactant.

Description

Hand washing tableware cleanser compositions
Technical field
The present invention relates to hand washing tableware cleanser compositions.
Background technology
With in tableware sanitising agent, seek whipability abundant when clean and the persistence of foam when clean in hand washing.This whipability/foam persistence is the very important physical property relevant to cleaning persistence, mainly carries out so far the exploitation of the sanitising agent of whipability/foam persistence excellence.
In Japanese kokai publication sho 62-215699, disclose and contained sulfosuccinic ester, and whipability is high, cleaning capacity excellence, is applicable to the technology of the Clean-sanitising agent of tableware.In addition, in Japanese Unexamined Patent Application Publication 2008-507611, disclose the technology of tableware cleanser compositions that contains dialkyl sulfosuccinate succinate and oxidation amine, and in specification sheets, recorded and can contain lipid acid as washing assistant.In Japanese kokai publication hei 3-207799, record and can use the ethylene oxide condenses of succinic diester salt and fatty alcohol can use lipid acid as foaming inhibitor as the liquid detergent composition of anion surfactant.In Japanese kokai publication hei 3-33197, disclose and can use the aqueous or gelatinous detergent composition of dialkyl sulfosuccinate salt as anion surfactant, and recorded and further can contain trimethyl-glycine and/or amine oxide.In Japanese Unexamined Patent Application Publication 2008-506727, record and contained Di-sodium Sulfo-succinate Mono Est-er, and can give to hair and skin the low irritant cleaning compositions of excellent wettability effect and nursing efficacy.
In the TOHKEMY 2011-231310 that on November 17th, 2011 promulgates, the hand washing tableware cleanser compositions that contains sulfo-succinic acid two or mono alkyl ester or its salt, anion surfactant and lipid acid or its salt is disclosed.
Summary of the invention
The present invention relates to contain the represented sulfosuccinic acid alkyl ester of (a) following general formula (1) or its salt [following, to be called (a) composition]; (b) to have carbonatoms be 8～21 alkyl and sulfuric ester alkali or have the anion surfactant that carbonatoms is 8～21 alkyl and sulphonate alkali [but except (a)] [below, being called (b) composition] 5～35 quality %; (c) the hand washing tableware cleanser compositions of sultaine type tensio-active agent [following, to be called (c) composition].
[in formula, R 1, R 2be respectively carbonatoms and be 5～18 alkyl or hydrogen atom, R 1, R 2at least one alkyl that is 5～18 for carbonatoms., remove R 1and R 2it is the situation of hydrogen atom simultaneously.A 1, A 2the alkylidene group that is 2～4 for carbonatoms independently respectively, x, y are average addition mole number and are respectively 0～6 independently.M 1for positively charged ion.]
In addition, the present invention relates to a kind of cleaning method of tableware, the cleaning method of described tableware cleans tableware with the cleaning liquor hand washing of the hand washing tableware cleanser compositions that has used the invention described above, and water rinses afterwards.
Accompanying drawing explanation
Fig. 1 is the schematic diagram that represents the evaluation method of the lather collapse carrying out in embodiment.
Fig. 2 is the schematic diagram that is illustrated in the punching state of the gatherer (watering can) of the hard water using in the evaluation of lather collapse of embodiment.
Embodiment
In the last few years, from reducing environmental pressure, effectively utilizing the object of water resources, preferably reduce the amount of the clean water used of hand washing, wished to reduce the wash-down water after clean with tableware sanitising agent as far as possible.But the sanitising agent of whipability/foam persistence excellence all needs a large amount of water in order to complete flushing conventionally.Therefore, strongly seek to show abundant whipability and the persistence of foam when clean, when flushing moment lather collapse, just can complete the hand washing tableware sanitising agent of flushing with a small amount of water.
In this, in Japanese kokai publication sho 62-215699, Japanese Unexamined Patent Application Publication 2008-507611, Japanese kokai publication hei 3-207799 and Japanese Unexamined Patent Application Publication 2008-506727, the lather collapse during to flushing is without any consideration.In addition, in Japanese kokai publication hei 3-207799, as the lipid acid as " foaming inhibitor " cited defoamer, that to become low bubble while cleaning be object, form constantly when clean very abundant foam with in the time rinsing moment froth breaking the relation of technology do not provide technology enlightenment.Further, in Japanese kokai publication hei 3-33197, not only do not use the object lesson of sulfosuccinic acid alkyl ester, although have the example that has used carbonyl betaine type amphoteric surfactant as trimethyl-glycine, the object lesson that has used sultaine type tensio-active agent both openly, do not provided to technology enlightenment yet.
Therefore, the invention provides the persistence that shows abundant whipability and the foam when clean when clean, when flushing moment lather collapse, just can complete the hand washing tableware sanitising agent of flushing with a small amount of water.
<(a) composition >
(a) of the present invention composition is the represented sulfosuccinic acid alkyl ester of following general formula (1) or its salt, is preferably sulfo-succinic acid two or mono alkyl ester or its salt.
Figure BDA0000490893250000031
[in formula, R 1, R 2to be respectively carbonatoms be 5～18, be preferably 6～14, more preferably 7～10, or, carbonatoms is more than 5, be preferably more than 6, more preferably more than 7, and be below 18, be preferably below 14, the more preferably alkyl below 10 or hydrogen atom; R 1, R 2at least one for carbonatoms be 5～18, or carbonatoms is the alkyl more than 5 and below 18., remove R 1and R 2it is the situation of hydrogen atom simultaneously.A 1, A 2respectively independently for carbonatoms is 2～4, is preferably 2～3, or carbonatoms is more than 2, and be below 4, be preferably the alkylidene group below 3, x, y be average addition mole number and be respectively 0～6 independently, more preferably 0～3, be more preferably 0～2, further be preferably 0～1, or, be more than 0, and be below 6, more preferably, below 2, more preferably, below 1, be further preferably 0.M 1for positively charged ion, be preferably inorganic or organic positively charged ion.]
In the situation that (a) composition is dialkyl sulfosuccinate or its salt, the R in general formula (1) 1, R 2can be identical or different, the viewpoint of the whipability when clean and the lather collapse while rinsing, for carbonatoms is 5～18, is preferably 6～14, more preferably 7～10, or, for carbonatoms is more than 5, is preferably more than 6, more preferably more than 7, and be below 18, be preferably below 14, be further the alkyl below 10, be preferably the alkyl with branched structure.Carbonatoms is 5 lather collapses can obtain good flushing when above time, and carbonatoms is to obtain good whipability when clean below 18 time.
In addition, in the situation that (a) composition is sulfo-succinic acid mono alkyl ester or its salt, the viewpoint of the whipability when clean and the lather collapse while rinsing, the R in general formula (1) 1, R 2in one be 5～18, be preferably 6～14, more preferably 7～10 for carbonatoms, or, for carbonatoms be more than 5, be preferably more than 6, more preferably more than 7, and be below 18, be preferably below 14, be further the alkyl below 10, another is hydrogen atom.
R in general formula (1) 1, R 2the viewpoint of the whipability when clean and the lather collapse while rinsing, to be respectively carbonatoms be 5～18, be preferably 6～14, more preferably 7～10, or, for carbonatoms be more than 5, be preferably more than 6, more preferably more than 7, and be below 18, be preferably below 14, be more preferably the alkyl below 10,, from the viewpoint of latherability, lather collapse, (a) composition is preferably dialkyl sulfosuccinate or its salt.The viewpoint of the whipability when clean and the lather collapse while rinsing, A 1, A 2respectively independently for carbonatoms is 2～4, is preferably 2～3, or, for carbonatoms is more than 2, and be below 4, be preferably the alkylidene group below 3.X, y are average addition mole numbers, and the viewpoint of the whipability when clean and the lather collapse while rinsing, is respectively 0～6, be preferably 0～3, more preferably 0～2, be more preferably 0～1, or, be more than 0, and be below 6, be preferably below 3, more preferably below 2, be more preferably below 1, be further preferably 0.
In general formula (1), R 1, R 2be respectively specifically hexyl, octyl group, nonyl, decyl, dodecyl, tridecyl, 2-ethylhexyl, n-octyl, secondary octyl, isopentyl, different nonyl, isodecyl, cyclohexyl, more preferably be selected from the group in n-octyl, secondary octyl, decyl, isodecyl and 2-ethylhexyl, be more preferably 2-ethylhexyl.As M 1, can enumerate the inorganic cation being selected from hydrogen ion, sodium ion, potassium ion, magnesium ion, ammonium ion; Be selected from the organic cation in monoethanolamine ammonium ion, di-alcohol ammonium ion, triethanol ammonium ion, be preferably the positively charged ion being selected from sodium ion, potassium ion, magnesium ion and ammonium ion.
In the situation that (a) composition is dialkyl sulfosuccinate or its salt, as R 1, R 2the modulator approach of identical compound, without particular limitation of, for example can be with reference to U.S. Patent bulletin 2,028, the method for recording in 091 is manufactured, in addition, as R 1, R 2the modulator approach of different asymmetrical compounds, for example, can manufacture with reference to Japanese kokai publication sho 58-24555.In the case of using commercially available compound, can use the PELEX OT-P(R of Kao Corp's manufacture 1, R 2all the compound of 2-ethylhexyl), Kao Corp manufacture PELEX TR(R 1, R 2all the compound of tridecyl), BASF AG manufacture LuensitA-BO(R 1, R 2all the compound of 2-ethylhexyl), can be by Mitsui Cytec Co., the Aerosol AY-100(R that Ltd. buys 1, R 2all the compound of amyl group), Mitsui Cytec Co., the Aerosol A-196(R of Ltd. 1, R 2all the compound of cyclohexyl) etc.
<(b) composition >
(b) of the present invention composition is that to have carbonatoms be 8～21 alkyl and sulfate group or to have carbonatoms be 8～21 alkyl and sulfonic anion surfactant [but removing (a) composition].Known such anion surfactant whipability is very excellent, more particularly, be preferably to be selected from and have that carbonatoms is 8～18, preferably carbonatoms is 8～15, or carbonatoms is more than 8 and is below 18, is preferably the alkyl sulfuric ester salt of the alkyl below 15; Having carbonatoms is 8～18, preferably carbonatoms is 8～15, or carbonatoms is more than 8, and be below 18, the average addition mole number of oxyalkylene group that more preferably alkyl below 15 and carbonatoms are 2～3 is 0.1～6, is preferably 0.3～3, more preferably 0.4～1.5, or be more than 0.1, more preferably more than 0.3, be more preferably more than 0.4, and be below 6, more preferably below 3, be more preferably the polyoxyalkylene alkyl vitriol below 1.5; There is carbonatoms and is the alkylbenzene sulfonate of 8～15 alkyl; And anion surfactant in the carbonatoms alkane sulfonate that is 8～15.As salt, be preferably the inorganic salt that are selected from sodium salt, sylvite, magnesium salts, ammonium salt; Be selected from the organic amine salt in monoethanolamine salt, diethanolamine salt, triethanolamine salt.
As (b) composition, the viewpoint of whipability or the foam persistence when clean and the lather collapse while rinsing, the compound of preferred following general formula (2).
R 3-O-(R 4O) n-SO 3M 2 （2）
[in formula, R 3for carbonatoms is 8～18, be preferably 8～15, or, for carbonatoms is more than 8, and be below 18, be further the alkyl below 15; R 4for ethylidene and/or propylidene, n is average addition mole number, it is the number more than 0 and below 6, be preferably the number more than 0.1 and below 2, more preferably more than 0.3 and below 1, or, be more than 0, more preferably more than 0.1, be more preferably more than 0.3, and be below 6, more preferably below 2, be more preferably the number below 1.M 2for positively charged ion, be preferably inorganic or organic positively charged ion.]
At R 4in situation for ethylidene, n is preferably below 1.5, the number below 1 more preferably, in addition, is preferably more than 0.3, more than 0.5 number more preferably.In addition, at R 4in situation for propylidene, n is preferably below 1.5, more preferably below 1, be more preferably the number below 0.8, in addition, be preferably more than 0.1, more preferably more than 0.3, be more preferably more than 0.4 number.In addition, at R 4in situation for ethylidene and propylidene, n can be from selection respectively within the scope of these.
In general formula (2), in the situation that n is 0, is preferably and comprises R 3for thering is the compound of alkyl of branched structure.In the situation that n is 0, the compound of general formula (2) is preferably, side chain rate (having the total mole number of compound of branched-chain alkyl with respect to the ratio of the total mole number of the compound of general formula (2)) is preferably 15～100mol%, more preferably 40～100mol%, is more preferably 70～100mol%, or, more than being preferably 15mol%, more preferably more than 40mol%, more than being more preferably 70mol%, and be preferably the compound below 100mol%.
M in general formula (2) 2for being selected from the inorganic cation in sodium ion, potassium ion, magnesium ion, ammonium ion; Be selected from the organic cation in monoethanolamine ammonium ion, di-alcohol ammonium ion, triethanol ammonium ion, be preferably sodium ion, potassium ion, magnesium ion.
As the modulator approach of the compound of general formula (2), without particular limitation of, for example can be according to object at R 3on fatty alcohol shown in-OH after the ethylene oxide and/or propylene oxide of addition specified amount, carry out sulphating with the sulfating agent being selected from sulphur trioxide (liquid or gas), the gas that contains sulphur trioxide, oleum, chlorsulfonic acid, with in the alkaline agent of regulation and manufacture.The addition reaction of ethylene oxide (following, to be designated as EO) and/or propylene oxide (following, to be designated as PO) needs catalyzer, can use the alkali hydroxide of NaOH, KOH etc.In addition, can use the catalyzer that the magnesium oxide recorded is main component in Japanese kokai publication hei 8-323200, the former can obtain the wider Voranol EP 2001 of addition mole number distribution, and the latter can obtain having the compound that narrow addition mole number distributes.In addition, as disclosed in Japanese kokai publication hei 10-158384, also can distribute by also controlling addition mole number with alkaline catalysts and metal oxide catalyst.
Obtaining in general formula (2) preferably comprising R in the situation that n being 0 3for having in the situation of compound of alkyl of branched structure, as the R of raw material 3alcohol shown in-OH, the alcohol (having the alkyl of methyl to contain 15～70mol% in the β position top set with respect to OH base) that the 1-olefin hydroformylation that can to enumerate carbonatoms be 8～14 obtains; Making carbonatoms is after 4～8 aldehyde condensation, gerber special type alcohol (Guerbet alcohol) that reduction obtains (having carbonatoms in the β position top set with respect to OH base is that the alcohol of the structure of 3～6 alkyl contains 100mol%); The dimer hydroformylation of iso-butylene is obtained 3,5,5-trimethyl hexanol; The higly branched chain tridecanol (side chain rate is 100mol%) that the tripolymer hydroformylation of iso-butylene is obtained; Synthol (side chain rate is about the alkyl of 20～100mol%) using oil, coal as raw material.
In the present invention, as (b) composition, most preferably be the represented compound of general formula (2), and R 4for propylidene, n is 0.1～1.5, more preferably 0.3～1, more preferably 0.4～0.8, or be more than 0.1, more preferably more than 0.3, more preferably more than 0.4 and be below 1.5, more preferably below 1, be more preferably the compound of the number below 0.8.
<(c) composition >
In the present invention, as the tensio-active agent with foam enhancing effect, use the sultaine type tensio-active agent of (c) composition.Sultaine type tensio-active agent improves the whipability/foam persistence while cleaning, can not damage the instantaneous lather collapse while flushing.As sultaine type tensio-active agent; the carbonatoms of preferred alkyl is N-alkyl-N of 10～18; N-dimethyl-N-sulfo group propyl ammonium sultaine, N-alkyl-N; N-alkanoylamino propyl group-N that the carbonatoms of N-dimethyl-N-(2-hydroxyl sulfo group propyl group) ammonium sultaine, alkyloyl is 10～18; N-dimethyl-N-sulfo group propyl ammonium sultaine, N-alkanoylamino propyl group-N, N-dimethyl-N-(2-hydroxyl sulfo group propyl group) ammonium sultaine.
Tableware cleanser compositions > for < hand washing
Hand washing of the present invention tableware cleanser compositions, there is (b) composition of whipability/foam persistence and (c) composition and (a) composition by also using under given conditions, in the higher cleaning water of detergent concentration, show very high whipability and foam persistence, by add wash-down water after clean end, instantaneous lather collapse, can complete flushing with a small amount of water.Its reason is not necessarily clear and definite, but think under the low environment of surfactant concentration in the time rinsing, it is large that the impact that the transport properties of molecules of each molecule produces vacuolar membrane becomes, thereby think and be for example different from, in the interactional situation of anionic group of (c) composition of other trimethyl-glycine (carbonyl trimethyl-glycine) and (a) composition in the position of cation group, formation has the title complex of very large transport properties of molecules, thereby can instantaneous elimination foam.
Hand washing of the present invention tableware cleanser compositions, from the viewpoint of latherability, lather collapse and economy, more than containing (a) composition 1 quality %, more than being preferably 2 quality %, more preferably more than 3 quality %, in addition, contain below (a) composition 30 quality %, more preferably, below 25 quality %, be more preferably below 20 quality %, be further preferably below 15 quality %, for example contain 1～30 quality %, further preferably contain 3～25 quality %, be more preferably and contain 3～20 quality %, further preferably contain 3～15 quality %.
In addition, from the viewpoint of latherability, lather collapse and economy, more than hand washing of the present invention contains (b) composition 5 quality % with tableware cleanser compositions, more than being preferably 7 quality %, more preferably more than 9 quality %, in addition, contain below (b) composition 35 quality %, be preferably below 20 quality %, more preferably below 15 quality %, for example contain 5～35 quality %, further preferably contain 7～20 quality %, be more preferably and contain 9～15 quality %.In addition, be the amount as Na salt for the amount of (b) composition of trying to achieve quality % or mass ratio etc. in the present invention.
In addition, from the viewpoint of latherability, lather collapse and economy, more than hand washing of the present invention contains (c) composition 1 quality % with tableware cleanser compositions, more preferably more than 2 quality %, more than being more preferably 3 quality %, in addition, contain below (c) composition 20 quality %, more preferably below 14 quality %, be more preferably below 12 quality %, for example contain 1～20 quality %, further preferably contain 2～14 quality %, be more preferably and contain 3～12 quality %.
From the viewpoint of latherability, lather collapse and economy, hand washing of the present invention preferably contains (a) composition 1～30 quality % with tableware cleanser compositions, further preferably contains 3～25 quality %.In addition, contain (b) composition 5～35 quality %, be preferably 7～20 quality %, more preferably 9～15 quality %.In addition, be the amount as Na salt for the amount of (b) composition of trying to achieve quality % or mass ratio etc. in the present invention.In addition, (c) content of composition is preferably 1～20 quality % in composition, and more preferably 2～14 quality %, are more preferably 3～12 quality %.
In addition, use in tableware cleanser compositions in hand washing of the present invention, from the viewpoint of latherability and lather collapse, (a) composition/(b) mass ratio of composition is preferably 0.03～2.5, more preferably 0.15～2, be more preferably 0.2～1.5, be further preferably 0.25～1, or, be preferably more than 0.03, more preferably more than 0.15, be more preferably more than 0.2, be further preferably more than 0.25, and be preferably below 2.5, more preferably, below 2, be more preferably below 1.5, be further preferably below 1.In addition, (b) composition/(c) mass ratio of composition is preferably 0.3～6, more preferably 0.5～5, be more preferably 1～4, further be preferably 1.5～3, or be preferably more than 0.3, more preferably more than 0.5, be more preferably more than 1, further be preferably more than 1.5, and be preferably below 6, more preferably below 5, be more preferably below 4, further be preferably below 3, (a) composition/(c) mass ratio of composition is preferably 0.1～5, more preferably 0.3～2.6, be more preferably 0.6～2.3, further be preferably 0.6～1.8, or be preferably more than 0.1, more preferably more than 0.3, be more preferably more than 0.6, and be preferably below 5, more preferably below 2.6, be more preferably below 2.3, further be preferably below 1.8.
In addition, use in tableware cleanser compositions in hand washing of the present invention, the viewpoint of the improvement of the whipability/foam persistence when clean and the lather collapse while rinsing, (c) mass ratio of composition/[(a) composition+(b) composition] is preferably 0.02～2, more preferably 0.1～1.5, be more preferably 0.15～1, further be preferably 0.15～0.5, or be preferably more than 0.02, more preferably more than 0.1, be more preferably more than 0.15, and be preferably below 2, more preferably below 1.5, be more preferably below 1, further be preferably below 0.5.
From the viewpoint of latherability and lather collapse, in the present invention, in composition with respect to (a) composition of the content of all surfaces promoting agent, (b) composition and (c) the total quality optimization of composition be 50～100 quality %, more preferably 60～100 quality %, be more preferably 80～100 quality %, further be preferably 90～100 quality %, or more than being preferably 50 quality %, more preferably more than 60 quality %, more than being more preferably 80 quality %, more than being further preferably 90 quality %, and be preferably below 100 quality %.
From improving the emulsifying capacity to greasy dirt, the object of enhancing cleaning capacity, hand washing of the present invention is with in tableware cleanser compositions, preferably contain containing magnesium mineral compound and/or Alkylenediamine compound (carbonatoms of alkylidene group is 2～6), preferably contain containing magnesium mineral compound as (d) composition.These compounds have effect required for the present invention,, have as with (a) composition, (b) thus composition and according at least 2 molecular ratios of other contained anion surfactant of hope weak interact and form title complex and improve common effect/effect structure of the compound of the surfactivity ability of emulsifying capacity etc.
As containing magnesium mineral compound, be more preferably the magnesium salts, magnesium hydroxide, magnesium oxide of the magnesium muriate, magnesium sulfate, magnesium nitrate etc. of magnesium chloride etc. etc., be further preferably selected from the compound in magnesium chloride and magnesium sulfate, further preferred magnesium chloride.In addition, as Alkylenediamine compound, preferably quadrol, propylene diamine, hexanediamine, cyclohexanediamine, further preferred cyclohexanediamine.
(d) content of composition, in composition, be preferably 0.5～20 quality %, more preferably 0.5～15 quality %, be more preferably 0.5～10 quality %, or, more than being preferably 0.5 quality %, more preferably more than 0.5 quality %, and being preferably below 20 quality %, is further below 15 quality %, is more preferably below 10 quality %.In addition, the situation that has these (d) compositions to comprise crystal water, but be the quality of removing crystal water at the content of this expression.
Hand washing of the present invention tableware cleanser compositions, as the mineral compound beyond auxiliary can be used together (d) composition of (d) composition.As mineral compound, can enumerate sodium-chlor, Repone K, sodium iodide, potassiumiodide, sodium sulfate, potassium sulfate, alum etc.
The movement of the foam while cleaning in the present invention, and while flushing is extremely important.In common research in hand washing with tableware cleanser compositions, consider the whipability/foam persistence while cleaning and use the tensio-active agent with foam enhancing effect, but in the present invention due to such tensio-active agent with foam enhancing effect on rinse time lather collapse can produce large impact, therefore should be noted that the situation of use.Particularly should be noted that in the present invention the operation that is selected from the tensio-active agent in amine oxide type tensio-active agent, carbonyl betaine type amphoteric surfactant and alkylolamide type tensio-active agent as (e) composition.
As amine oxide type tensio-active agent; can enumerate N-alkanoylamino propyl group-N; N-dimethyl oxidation amine (being lauroyl or myristoyl as alkyloyl), N-alkyl-N, N-dimethyl oxidation amine (being lauryl or myristyl as alkyl).In addition, as carbonyl betaine type amphoteric surfactant, can enumerate N-alkanoylamino propyl group-N, N-dimethyl-N-carboxymethyl ammonium trimethyl-glycine, N-alkyl-N, N-dimethyl-N-carboxymethyl ammonium trimethyl-glycine.Further, as alkylolamide type tensio-active agent, can enumerate the amidate of the lipid acid of the alkanolamine of monoethanolamine, diethanolamine, methyl monoethanolamine etc. and lauric acid, tetradecanoic acid etc.
The movement of foam is extremely important in the present invention, in the use of (e) composition that composition is brought to foam enhancing effect, should be noted that, the content of (e) composition in composition is preferably below 5 quality %, more preferably below 3 quality %, be more preferably below 2 quality %, further be preferably below 1 quality %, more more preferably, below 0.5 quality %, most preferably be and do not contain.
Hand washing of the present invention tableware cleanser compositions, from improving the object of washability, as (f) composition, can contain carbonatoms and be 10～18 lipid acid or its salt.Particularly, can enumerate capric acid, lauric acid, tetradecanoic acid, palmitinic acid, Zoomeric acid, stearic acid, oleic acid, linolic acid, linolenic acid and their salt.In addition, can also use the mixed fatty acid of coconut composition lipid acid etc.As the salt of lipid acid, can enumerate the inorganic salt that are selected from sodium salt, sylvite, magnesium salts, ammonium salt; Be selected from the organic amine salt of monoethanolamine salt, diethanolamine salt, triethanolamine salt etc., particular certain cancers, sylvite, magnesium salts, further particular certain cancers, sylvite.As (f) composition, further preferably lauric acid, tetradecanoic acid, palmitinic acid or their salt, further more preferably lauric acid, tetradecanoic acid or their salt, most preferably is tetradecanoic acid or its salt.Therefore,, from the viewpoint of latherability and lather collapse, (f) composition preferably comprises tetradecanoic acid or its salt, in (f) composition, the ratio of tetradecanoic acid or its salt is preferably 20～100 quality %, and more preferably 50～100 quality %, are more preferably 80～100 quality %, or, more than being preferably 20 quality %, more preferably more than 50 quality %, more than being more preferably 80 quality %, and be preferably below 100 quality %, more preferably 100 quality %.
(f) content of composition is preferably below 3 quality % in composition, more preferably, below 2 quality %, is more preferably below 1 quality %, is further preferably below 0.5 quality %, more more preferably, below 0.3 quality %, is also preferably 0 quality %.
During from flushing, instantaneous sticky feeling disappears, the viewpoint that can complete flushing with a small amount of water is set out, hand washing of the present invention tableware cleanser compositions, preferably contain alkyl glycerol base ether (carbonatoms of alkyl is 6～18, is preferably 8～12, or, carbonatoms is more than 6, more preferably more than 8, and be below 18, more preferably below 12) as (g) composition.Particularly, the compound of preferred following general formula (3).
R 5-O-(Gly) r-H （3）
[in formula, R 5represent the carbonatoms alkyl that is 6～18, Gly represents to remove the residue of 2 hydrogen atoms from glycerine, and r represents average addition mole number and is 1～4 number.]
In general formula (3), R 5that carbonatoms is 6～18, is preferably 7～12, more preferably 8～10, or carbon atom is more than 6, more preferably more than 7, be more preferably more than 8, and be below 18, more preferably below 12, be more preferably the alkyl below 10, can use the straight chained alkyl of hexyl, heptyl, octyl group, nonyl, decyl etc., the viewpoint of the sticky feeling during in the present invention from reduction flushing, preferably there is the compound of branched structure, as R 5the concrete alkyl with branched structure, be further preferably selected from the group in 2-ethylhexyl, secondary octyl, different nonyl and isodecyl, more preferably 2-ethylhexyl or isodecyl, is further preferably 2-ethylhexyl.In general formula (3), r is preferably 1～3, and more preferably 1～2, be more preferably the compound of r=1.Further preferred compound is R 5for 2-ethylhexyl, and the compound of r=1.
Structure shown in Gly be 1 of glycerine and 3 hydroxy combining-CH 2cH (OH) CH 2-represented structure, or 1 of glycerine and 2 s' hydroxy combining-CH (CH 2oH) CH 2-represented structure, according to catalyzer or reaction conditions and difference.
In order to obtain the compound of general formula (3), for example, can use and use R 5the alcohol that the represented alkyl alcohol of-OH is 6～10 as carbonatoms, uses BF 3deng acid catalyst or Al catalysts method that the epoxy compounds reaction of epoxyhalopropane or Racemic glycidol etc. is manufactured.
For example, in the situation that using 2-Ethylhexyl Alcohol, the 2-ethylhexyl list glyceryl ether obtaining is the mixture that can contain multiple resultant as what record in TOHKEMY 2001-49291.(g) content of composition is preferably 0.5～20 quality % in composition, more preferably 1～15 quality %, be more preferably 1.5～10 quality %, or, more than being preferably 0.5 quality %, be further more than 1 quality %, more than being more preferably 1.5 quality %, and be preferably below 20 quality %, more preferably, below 15 quality %, be more preferably below 10 quality %.
Hand washing of the present invention tableware cleanser compositions, can be improving storage stability, foam enhancing, clean-up performance while cleaning be as object, uses nonionogenic tenside [removing the material that is equivalent to (g) composition] [hereinafter referred to as (h) composition] in the scope of not damaging washability.As (h) composition, can enumerate the nonionogenic tenside of polyoxyalkylene sorbitan-fatty acid ester, polyoxyalkylene fatty acid ester, polyoxyalkylene alkyl, polyoxyalkylene alkyl phenyl ether, sucrose fatty ester, sorbitan-fatty acid ester, alkyl glycoside etc.Wherein, preferred polyoxyalkylene alkyl and/or alkyl glycoside.
(h) content of composition is preferably 1～20 quality % in composition, more preferably 1.5～15 quality %, be more preferably 2～10 quality %, or more than being preferably 1 quality %, more preferably more than 1.5 quality %, more than being more preferably 2 quality %, and be preferably below 20 quality %, more preferably, below 15 quality %, be more preferably below 10 quality %.
Hand washing of the present invention tableware cleanser compositions, in order to improve storage stability, preferably contains hydrotropic solvent [following, to be called (i) composition].As hydrotropic solvent, preferably toluenesulphonic acids, xylene monosulfonic acid, isopropyl sulfonic acid or their sodium, potassium or magnesium salts, further preferred tosic acid or its salt.(i) the content of composition is 0.5～20 quality %, more preferably 1～15 quality %, be more preferably 1.5～10 quality %, or be more than 0.5 quality %, more than 1 quality %, more than being more preferably 1.5 quality %, and be more preferably below 20 quality %, more preferably, below 15 quality %, be more preferably below 10 quality %.
Hand washing of the present invention tableware cleanser compositions, in order to improve storage stability or adjusting viscosity, can contain solvent [following, to be called (j) composition].As the object lesson of solvent, be preferably selected from the water-miscible organic solvent in ethanol, Virahol, ethylene glycol, propylene glycol, Diethylene Glycol, dipropylene glycol, glycerine, isoamyl glycol, propylene glycol monomethyl ether, propylene glycol list ethyl ether, 3-methyl-3-methoxybutanol, phenoxyethyl alcohol, phenylglycol, phenoxy group Virahol, butyl Diethylene Glycol (Diethylene Glycol single-butyl ether), dibutylene glycol, benzylalcohol.Wherein, be preferably selected from a kind of above water-miscible organic solvent in butyl Diethylene Glycol, ethanol and propylene glycol, be more preferably the a kind of above water-miscible organic solvent being selected from butyl Diethylene Glycol and propylene glycol.At this, water-miscible organic solvent refers to that Octanol/water Partition Coefficients (LogPow) is the solvent below 3.5.(j) content of composition is preferably 1.5～30 quality % in composition, more preferably 2～20 quality %, be more preferably 3～15 quality %, or, more than being preferably 1.5 quality %, more preferably more than 2 quality %, more than being more preferably 3 quality %, and be preferably below 30 quality %, more preferably, below 20 quality %, be more preferably below 15 quality %.
Use in tableware cleanser compositions in hand washing of the present invention, from the viewpoint of viscosity adjustment and storage stability, preferably coordinate the polymkeric substance for preventing gelation [following, be called (k) composition], that for example, in the flat 11-513067 of Japanese Unexamined Patent Application Publication, records prevents gelation polymer, especially polyalkylene glycol.As the object lesson of the polyalkylene glycol of the polymkeric substance for preventing gelation, the weight average molecular weight of trying to achieve by gel permeation chromatography can enumerate take polyoxyethylene glycol as standard time is 200～3,000 polypropylene glycol and weight average molecular weight are 200～3,000 polyoxyethylene glycol.(k) content of composition is preferably 0.05～10 quality % in composition, more preferably 0.1～5 quality %, be more preferably 0.5～3 quality %, or, more than being preferably 0.05 quality %, more preferably more than 0.1 quality %, more than being further preferably 0.5 quality %, and be preferably below 10 quality %, more preferably, below 5 quality %, be more preferably below 3 quality %.
Hand washing of the present invention tableware cleanser compositions, is preferably mentioned component dissolution/dispersion/the be emulsifiable in form of the liquid composition in water, the more preferably aqueous solution.The water using can use deionized water or distilled water or hypochlorous acid is dissolved with 0.5～10ppm degree after hypochlorous acid aqua sterilisa etc.
With tableware cleanser compositions, the pH at 25 ℃ is preferably 4～9 in hand washing of the present invention, and more preferably 4.5～7, be more preferably 5～6.From the viewpoint of low-temperature stability, be preferably more than 4, more preferably more than 4.5, be more preferably more than 5.On the other hand, from the viewpoint of cleaning capacity, be preferably below 10, more preferably, below 9, be more preferably below 8, be further preferably below 7.The adjusting to pH is like this used the mineral acid being selected from sulfuric acid, hydrochloric acid, phosphoric acid; Be selected from the organic acid in citric acid, oxysuccinic acid, toxilic acid, fumaric acid, succsinic acid; The inorganic alkaline agent of sodium hydroxide, potassium hydroxide, magnesium hydroxide, sodium carbonate, salt of wormwood etc. carries out.In the present invention, from the viewpoint of whipability/foam persistence, preferably make composition have surge capability, preferably and with above-mentioned organic acid, be preferably citric acid and inorganic alkaline agent.Organic acid can be matched with in composition with the form of sodium salt or sylvite.In addition, at the compound for pH regulator, the material that magnesium hydroxide etc. are equivalent to (d) composition becomes to assign to use as (d).
With tableware cleanser compositions, the viscosity at 20 ℃ is preferably 5～15 in hand washing of the present invention, 000mPas, more preferably 5～8, 000mPas, be more preferably 5～2, 000mPas, be more preferably 5～500mPas, further 10～300mPas more preferably, in addition, more than being preferably 5mPas, more preferably more than 10mPas, and be preferably 15, below 000mPas, more preferably 8, below 000mPas, be more preferably 2, below 000mPas, further be preferably below 500mPas, more more preferably below 300mPas.Viscosity can be with (i) composition, (j) composition, (k) composition etc. regulate.
Hand washing of the present invention can contain the compositions such as spices, dyestuff, pigment with tableware cleanser compositions.
< hand washing cleaning method >
Hand washing of the present invention is clean for the hand washing of tableware with tableware cleanser compositions.Hand-wash the clean middle cleaning liquor using and use hand washing of the present invention to obtain with tableware cleanser compositions, the stoste that use contains composition or the diluent of water.As concrete hand washing cleaning method, can enumerate the cleaning liquor that has used hand washing of the present invention tableware cleanser compositions is attached on flexible materials, then, and after the clean tableware of this flexible materials hand washing, the cleaning method of the tableware that water rinses.For example, on the flexible materials of moisture sponge etc., adhere to composition of the present invention and make it to keep cleaning liquor, rub for several times and bubble with hand, clean tableware.From the viewpoint of high whipability and foam persistence, (a) composition, (b) composition in the cleaning liquor that flexible materials keeps and (c) the total concentration of composition are preferably 1,000～30,000ppm, more preferably 1,000～20,000ppm, is more preferably 2,000～10,000ppm, or more than being preferably 1,000ppm, more preferably 2, more than 000ppm, and be preferably below 30,000ppm, more preferably 20, below 000ppm, be more preferably below 10,000ppm.After clean end, add water and rinse, for example, using in the present invention the composition that is diluted to clean concentration with respect to 1 mass parts is the fully froth breaking of wash-down water of 3.3～133 mass parts, can promptly finish flushing.The amount of this wash-down water is to use existing hand washing to use 2/3～1/10 left and right in the situation of cleanser compositions.In addition, composition 1 mass parts at this is the concentration that represents composition pure component, no matter about the record of the amount of above-mentioned wash-down water be the concentration representing after dilution, use the hand washing tableware cleanser compositions pure component using in the modulation with respect to the cleaning liquor of 1 mass parts, wash-down water is just abundant froth breakings of 3.3～133 mass parts.
In addition, as other concrete hand washing cleaning method, can be set forth in tableware be impregnated in after in the cleaning liquor after hand washing of the present invention tableware cleanser compositions dilute with water, use the clean tableware of flexible materials hand washing of sponge etc., the cleaning method of the tableware that afterwards, water rinses.The time of dipping tableware, the viewpoint improving from spatter property, is preferably more than 1 minute, more preferably more than 3 minutes, be more preferably more than 5 minutes, be further preferably more than 10 minutes, most preferably be more than 30 minutes, in addition, be preferably below 24 hours, more preferably, below 12 hours, be more preferably below 6 hours, further be preferably below 3 hours, most preferably be below 1 hour.From the viewpoint of high whipability and foam persistence, (a) composition, (b) composition in the cleaning liquor of dipping tableware and (c) more than the total concentration of composition is preferably 100ppm, more preferably more than 200ppm, and be preferably 3, below 000ppm, more preferably 2, below 000ppm, be more preferably below 1,000ppm.After clean end, adding water rinses, for example in the present invention, the wash-down water foam that to use with respect to the hand washing tableware cleanser compositions of the modulation for cleaning liquor of 1 mass parts be 3.3～133 mass parts just can fully disappear, and can promptly complete flushing.
Below illustrate embodiments of the present invention.
<1> hand washing tableware cleanser compositions, it contains: (a) represented sulfosuccinic acid alkyl ester or its salt of following general formula (1), is preferably dialkyl sulfosuccinate or its salt; (b) to have carbonatoms be 8～21 alkyl and sulfuric ester alkali or have the anion surfactant that carbonatoms is 8～21 alkyl and sulphonate-base [but except (a)] 5～35 quality %, be preferably 7～20 quality %, more preferably 9～15 quality %; And (c) sultaine type tensio-active agent,
Figure BDA0000490893250000151
[in formula, R 1, R 2being respectively carbonatoms is 5～18, is preferably 6～14, is more preferably 7～10 alkyl, is preferably alkyl or the hydrogen atom with branched structure, is preferably 2-ethylhexyl, R 1, R 2at least one alkyl that is 5～18 for carbonatoms., remove R 1and R 2it is the situation of hydrogen atom simultaneously.A 1, A 2independently for carbonatoms is 2～4, be preferably 2～3 alkylidene group respectively, x, y are average addition mole number and are 0～6 independently respectively, are preferably 0～3, more preferably 0～2, be more preferably 0～1, and be further preferably 0.M 1for positively charged ion, be preferably organic or organic positively charged ion.]
The hand washing of <2> as described in <1> tableware cleanser compositions, wherein, further contain (d) containing magnesium mineral compound and/or Alkylenediamine (carbon atom of alkylidene group is 2～6), preferably contain the compound being selected from magnesium chloride and magnesium sulfate.
The hand washing tableware cleanser compositions of <3> as described in <1> or <2>, wherein, (e) be selected from amine oxide type tensio-active agent, the content of the tensio-active agent in carbonyl betaine type amphoteric surfactant and alkylolamide type tensio-active agent is below 5 quality % in composition, be preferably below 3 quality %, more preferably below 2 quality %, be more preferably below 1 quality %, further be preferably below 0.5 quality %, further be preferably below 0 quality %.
The hand washing of <4> as described in any one in <1>～<3> tableware cleanser compositions, wherein, (b) there is for being selected from the alkyl sulfuric ester salt that carbonatoms is 8～18 alkyl; The average addition mole number that has carbonatoms and be the oxyalkylene group that 8～18 alkyl and carbonatoms are 2～3 is 0.1～6, more preferably 0.3～3, be more preferably 0.4～1.5 polyoxyalkylene alkyl sulfuric acid; There is carbonatoms and is the alkylbenzene sulfonate of 8～15 alkyl; And anion surfactant in the carbonatoms alkane sulfonate that is 10～15.
The hand washing of <5> as described in any one in <1>～<4> tableware cleanser compositions, wherein, (b) composition is the compound of following general formula (2)
R 3-O-(R 4O) n-SO 3M 2 （2）
[in formula, R 3for carbonatoms is 8～18, be preferably 8～15 alkyl, R 4for ethylidene and/or propylidene, n is average addition mole number and is the number more than 0 and below 6, is preferably the number more than 0.1 and below 2.M 2for positively charged ion, be preferably inorganic or organic positively charged ion.]
The hand washing of <6> as described in any one in <1>～<5> tableware cleanser compositions, wherein, with respect to the content of all surfaces promoting agent in composition, (a) and (b) and total quality (c) are 50～100 quality %, more preferably 60～100 quality %, be more preferably 80～100 quality %, be further preferably 90～100 quality %.
The hand washing of <7> as described in any one in <1>～<6> tableware cleanser compositions, wherein, further in composition, contain lipid acid that (f) carbonatoms is 10～18 or below its salt 3 quality %, more preferably below 2 quality %, be more preferably below 1 quality %, further be preferably below 0.5 quality %, more more preferably 0 quality %.
The hand washing of <8> as described in any one in <1>～<7> tableware cleanser compositions, wherein, (a) composition is dialkyl sulfosuccinate or its salt.
The hand washing of <9> as described in any one in <1>～<8> tableware cleanser compositions, wherein, more than containing (a) composition 1 quality %, more than being preferably 2 quality %, more preferably more than 3 quality %, in addition, contain below (a) composition 30 quality %, more preferably below 25 quality %, be more preferably below 20 quality %, be further preferably below 15 quality %.
The hand washing of <10> as described in any one in <1>～<9> tableware cleanser compositions, wherein, more than containing (b) composition 5 quality %, more than being preferably 7 quality %, more than being more preferably 9 quality %, in addition, contain below (b) composition 35 quality %, more preferably, below 20 quality %, be more preferably below 15 quality %.
The hand washing of <11> as described in any one in <1>～<10> tableware cleanser compositions, wherein, more than containing (c) composition 1 quality %, more than being preferably 2 quality %, more than being more preferably 3 quality %, in addition, contain below (c) composition 20 quality %, more preferably, below 14 quality %, be more preferably below 12 quality %.
The hand washing of <12> as described in any one in <1>～<11> tableware cleanser compositions, wherein, (a) composition/(b) mass ratio of composition is more than 0.03, be preferably more than 0.15, more preferably more than 0.2, further be preferably more than 0.25, in addition, be below 2.5, be preferably below 2, be more preferably below 1.5, be further preferably below 1.
The hand washing of <13> as described in any one in <1>～<12> tableware cleanser compositions, wherein, (b) composition/(c) mass ratio of composition is more than 0.3, more preferably more than 0.5, be more preferably more than 1, further be preferably more than 1.5, in addition, be below 6, more preferably below 5, be more preferably below 4, be further preferably below 3.
The hand washing of <14> as described in any one in <1>～<13> tableware cleanser compositions, wherein, (a) composition/(c) mass ratio of composition is more than 0.1, is preferably more than 0.3, more preferably more than 0.6, in addition, be below 5, be preferably below 3, more preferably below 2.6, be more preferably below 2.3, more more preferably below 1.8.
The hand washing of <15> as described in any one in <1>～<14> tableware cleanser compositions, wherein, (c) mass ratio of composition/[(a) composition+(b) composition] is more than 0.02, more preferably more than 0.1, be more preferably more than 0.15, in addition, be below 2, more preferably, below 1.5, be more preferably below 1, be further preferably below 0.5.
The hand washing of <16> as described in any one in <1>～<15> tableware cleanser compositions, wherein, pH at 25 ℃ is more than 4, more preferably more than 4.5, more than 5, in addition, be more preferably below 9, more preferably, below 7, be more preferably below 6.
The hand washing of <17> as described in any one in <1>～<16> tableware cleanser compositions, wherein, viscosity at 20 ℃ is more than 5mPas, more preferably more than 10mPas, in addition, be 15, below 000mPas, more preferably 8, below 000mPas, be more preferably below 2,000mPas, further be preferably below 500mPas, most preferably be below 300mPas.
The hand washing of <18> as described in any one in <1>～<17> tableware cleanser compositions, wherein, (carbonatoms of alkyl is 6～18 further in composition, to contain alkyl glycerol base ether, be preferably 8～12) more than 0.5 quality %, more than further preferably containing 1 quality %, more than being more preferably and containing 1.5 quality %, in addition, contain below 20 quality %, further preferably contain below 15 quality %, more further preferably contain 10 quality % following as (g) composition.
The hand washing of <19> as described in any one in <1>～<18> tableware cleanser compositions, wherein, further contain hydrotropic solvent 0.5 quality % in composition more than, more than further preferably containing 1 quality %, more than being more preferably and containing 1.5 quality %, in addition, contain below 20 quality %, further preferably contain below 15 quality %, be more preferably and contain (i) composition of the following conduct of 10 quality %.
The hand washing of <20> as described in any one in <1>～<19> tableware cleanser compositions, wherein, further contain solvent 1.5 quality % in composition more than, more than further preferably containing 2 quality %, more than being more preferably and containing 3 quality %, in addition, contain below 30 quality %, further preferably contain below 20 quality %, be more preferably and contain the following conduct of 15 quality % (j) composition.
The hand washing of <21> as described in any one in <1>～<20> tableware cleanser compositions, wherein, further contain polymkeric substance as (k) composition, being preferably and being selected from weight average molecular weight is 200～3, 000 polypropylene glycol, and weight average molecular weight is 200～3, 1 kind or polymkeric substance of more than two kinds in 000 polyoxyethylene glycol, contain 0.05 quality % in composition more than, more preferably more than 0.1 quality %, more than being more preferably 0.5 quality %, in addition, be below 10 quality %, more preferably below 5 quality %, be more preferably below 3 quality %.
The cleaning method of a <22> tableware, wherein, the cleaning method of described tableware is with the clean tableware of cleaning liquor hand washing that has used the tableware of the hand washing described in any one cleanser compositions in <1>～<21>, then, water rinses.
The cleaning method of a <23> tableware, wherein, the cleaning method of described tableware is that the cleaning liquor that has used the tableware of the hand washing described in any one cleanser compositions in <1>～<21> is attached on flexible materials, then, after the clean tableware of described flexible materials hand washing, water rinses.
The cleaning method of a <24> tableware, wherein, the cleaning method of described tableware is that the cleaning liquor that has used the tableware of the hand washing described in any one cleanser compositions in <1>～<21> is attached on flexible materials, then, after the clean tableware of described flexible materials hand washing, water rinses, (a) composition in the cleaning liquor that flexible materials keeps, (b) composition, (c) the total concentration of composition is preferably 1, more than 000ppm, more preferably 2, more than 000ppm, and be preferably 30, below 000ppm, more preferably 20, below 000ppm, be more preferably 10, below 000ppm, use and rinse with the water that tableware cleanser compositions is 3.3～133 mass parts with respect to the hand washing using in the modulation of scavenging solution of 1 mass parts.
The cleaning method of a <25> tableware, wherein, in cleaning liquor by the hand washing described in any one in the tableware <1>～<21> that impregnated in dilute with water with tableware cleanser compositions, after hand washing is clean, water rinses.
The cleaning method of a <26> tableware, wherein, the cleaning method of described tableware is by after in the cleaning liquor of the hand washing tableware cleanser compositions described in any one in the tableware <1>～<21> that impregnated in dilute with water, use flexible materials to clean tableware, and water rinses, the time of dipping tableware is preferably more than 1 minute, more preferably more than 3 minutes, be more preferably more than 5 minutes, further be preferably more than 10 minutes, most preferably be more than 30 minutes, in addition, be preferably below 24 hours, more preferably below 12 hours, be more preferably below 6 hours, further be preferably below 3 hours, most preferably be below 1 hour, (a) composition in the cleaning liquor of dipping tableware, (b) composition, (c) more than the total concentration of composition is preferably 100ppm, more preferably more than 200ppm, and be preferably 3, below 000ppm, more preferably 2, below 000ppm, be more preferably 1, below 000ppm, the water that to use with respect to the hand washing tableware cleanser compositions of the modulation for cleaning liquor of 1 mass parts be 3.3～133 mass parts rinses.
Hand washing in <27><1GreatT.Gre aT.GT～<21> described in any one is the purposes in tableware clean with tableware cleanser compositions, cleaning as cleaning tableware with cleaning liquor hand washing of described tableware, water rinses afterwards.
Embodiment
Following embodiment describes for enforcement of the present invention.Embodiment is the example that example of the present invention is narrated, and is not for limiting the present invention.
The hand washing tableware cleanser compositions that uses table 1 and following gradation composition modulometer 1, carries out following each evaluation.Show the result in table 1.In addition, the quality % of the gradation composition in table 1 is all the numerical value based on effective constituent.
< gradation composition >
A-1: sulfo-succinic acid two-2-ethylhexyl sodium reagent (Kanto Kagaku K. K.)
A-2: sulfo-succinic acid two polyoxyethylene-2-ethylhexyl sodium: use the material obtaining in the esterification of sulfo-succinic acid and polyoxyethylene-2-ethylhexyl ether.Polyoxyethylene-2-ethylhexyl ether obtains by the 2-Ethylhexyl Alcohol addition 1mol ethylene oxide with respect to 1mol.
B-1: Sodium Lauryl Sulphate BP/USP
B-2: the alkyl chain of 1mol be carbonatoms be on 12 natural alcohol average addition after the EO of 1mol, use sulphur trioxide sulfation, regulate pH with aqueous sodium hydroxide solution, dilute the material (pH of the 10 quality % aqueous solution is 11) obtaining simultaneously
B-3: the alkyl chain of 1mol be carbonatoms be on 12 natural alcohol average addition after the PO of 0.6mol, use sulphur trioxide sulfation, regulate pH with aqueous sodium hydroxide solution, dilute the material (pH of the 10 quality % aqueous solution is 11) obtaining simultaneously
B-4: by straight chain/side chain alcohol mixture [it is the alkyl that 12 alkyl and carbonatoms are 13 that the Isalchem123(that Sasol company manufactures contains carbonatoms, and side chain rate is 94mol%)] with sulphur trioxide sulfation and with in sodium hydroxide and after compound (molecular-weight average: 295)
C-1:N-lauryl-N, N-dimethyl-N-(2-hydroxyl sulfo group propyl group) (Kao Corp manufactures ammonium sultaine: AMPHITOL20HD)
C '-1:N-lauroyl aminopropyl-N, (Kao Corp manufactures N-dimethyl-N-carboxymethyl ammonium trimethyl-glycine: AMPHITOL20AB)
D-1:MgCl 26H 2o(magnesium chloride six water salt) although used 6 water salt in cooperation, the numerical value in table 1 is that the use level of having removed crystal water represents.
E-1:N-lauryl-N, (Kao Corp manufactures N-dimethyl oxidation amine: AMPHITOL20N)
< latherability (initial stage bubble amount) and lather collapse >
The tableware cleanser compositions of table 1 is diluted to 3.2 quality % with 3.5 ° of DH hard water, is filled in the pump bubbling container of recording in Fig. 1 of TOHKEMY 2008-260852.At this, foam spues in mechanism, 1 mesh size is installed is the screen cloth of 200/ inch.Next,, by pressing continuously the pump head portion on No. 3 container tops, in the graduated cylinder of 500ml, make the foam of 3g.The speed of pressing in addition, is carried out with the speed of pressing 1 second for every 1 time.Now, by its capacity of calibration summary of graduated cylinder, as initial bubble amount.Whipability is evaluated by this initial bubble amount.
Next, the hard water gatherer (hand-made watering can) by being arranged at graduated cylinder top placed for 10 seconds to 3.5 ° of DH hard water that add 100ml in foam.Repeat this operation until the hard water adding adds up to 300ml.Add last water, measure the bubble amount afterwards in 10 seconds of placing.In addition, for lather collapse, adding in 300ml hard water, tried to achieve by the bubble quantitative change rate shown in following formula, reach more than 70% if be added into 300ml, be judged as and can reach foam by dilution (flushing) and rapidly disappear.
Foam velocity of variation (%)=[1-(adds the bubble amount at the bubble amount/initial stage after 300ml hard water)] × 100
Appearance when hard water is made an addition in graduated cylinder is shown in Fig. 1.In Fig. 1, the 1st, graduated cylinder, the 2nd, foam, the 3rd, the gatherer (hand-made watering can) of hard water, the 4th, the peristome of this gatherer, Fig. 2 is the schematic diagram that represents the punching state of the peristome 4 of the gatherer 3 of hard water.Making method as the hand-made watering can of the gatherer of hard water is as described below.First, the bottom of the wide-necked bottle processed polypropylene of 250ml (AS ONE Corporation manufactures: I-Boy wide-necked bottle) is started to paramount approximately 1/3rd main part excision.Next, the polyethylene making sheet of the thin round shape that is 4cm for diameter, as shown in Figure 2, prepares to have take the interval of 9mm the polyethylene porous plate processed of 13 diameters as the hole of 2mm.Finally, using porous plate processed above-mentioned polyethylene as peristome 4, the cover gab portion (diameter is 4cm) on the wide-necked bottle top after excision is fixed, makes the hand-made watering can of gatherer 3(of hard water).By the hand-made watering can of gatherer 3(of the hard water of making like this), as shown in Figure 1, keep inversion state, and be embedded into the peristome of graduated cylinder 1.Hard water drops into from the cutting side of wide-necked bottle.
[table 1]
Figure BDA0000490893250000221

Claims (14)

1. a hand washing tableware cleanser compositions, wherein,
Contain: (a) represented sulfosuccinic acid alkyl ester or its salt of following general formula (1); (b) carbonatoms that has except (a) is 8～21 alkyl and sulfuric ester alkali or to have carbonatoms be 8～21 alkyl and anion surfactant 5～35 quality % of sulphonate-base; And (c) sultaine type tensio-active agent,
Figure FDA0000490893240000011
In formula, R 1, R 2be respectively carbonatoms and be 5～18 alkyl or hydrogen atom, R 1, R 2at least one alkyl that is 5～18 for carbonatoms, remove R 1and R 2it is the situation of hydrogen atom simultaneously; A 1, A 2the alkylidene group that is 2～4 for carbonatoms independently respectively, x, y are average addition mole number and are respectively 0～6 independently; M 1for positively charged ion.
2. hand washing as claimed in claim 1 tableware cleanser compositions, wherein,
Further contain (d) containing magnesium mineral compound and/or Alkylenediamine, the carbonatoms of described alkylidene group is 2～6.
3. hand washing as claimed in claim 1 or 2 tableware cleanser compositions, wherein,
(e) content that is selected from the tensio-active agent in amine oxide type tensio-active agent, carbonyl betaine type amphoteric surfactant and alkylolamide type tensio-active agent is below 5 quality % in composition.
4. the tableware cleanser compositions of the hand washing as described in any one in claim 1～3, wherein,
(b) to have for being selected from alkyl sulfuric ester salt that carbonatoms is 8～18 alkyl, have carbonatoms be the average addition mole number of 8～18 alkyl and the carbonatoms oxyalkylene group that is 2～3 the polyoxyalkylene alkyl sulfuric acid that is 0.1～6, have carbonatoms is the anion surfactant in the alkylbenzene sulfonate of 8～15 alkyl and alkane sulfonate that carbonatoms is 10～15.
5. the tableware cleanser compositions of the hand washing as described in any one in claim 1～4, wherein,
With respect to the content of all surfaces promoting agent in composition, (a) and (b) and total quality (c) are 50～100 quality %.
6. the tableware cleanser compositions of the hand washing as described in any one in claim 1～5, wherein,
Further in composition, contain lipid acid that (f) carbonatoms is 10～18 or below its salt 0.5 quality %.
7. the tableware cleanser compositions of the hand washing as described in any one in claim 1～6, wherein,
(e) content that is selected from the tensio-active agent in amine oxide type tensio-active agent, carbonyl betaine type amphoteric surfactant and alkylolamide type tensio-active agent is below 2 quality % in composition.
8. the tableware cleanser compositions of the hand washing as described in any one in claim 1～7, wherein,
(a) composition is dialkyl sulfosuccinate or its salt.
9. the tableware cleanser compositions of the hand washing as described in any one in claim 1～8, wherein,
(b) composition is the compound of following general formula (2),
R 3-O-(R 4O) n-SO 3M 2 （2）
In formula, R 3for carbonatoms be 8～18 alkyl, R 4for ethylidene and/or propylidene, n is average addition mole number and is the number more than 0 and below 6, M 2for positively charged ion.
10. the tableware cleanser compositions of the hand washing as described in any one in claim 1～9, wherein,
In composition, contain (a) composition 1～30 quality %, (b) composition 5～35 quality %, (c) composition 1～20 quality %.
11. hand washing tableware cleanser compositions as described in any one in claim 1～10, wherein,
Contain (b) composition 7～20 quality %.
12. hand washing tableware cleanser compositions as described in any one in claim 1～11, wherein,
(a) composition/(b) mass ratio of composition is 0.03～2.5, and (b) composition/(c) mass ratio of composition is 0.3～6, and (a) composition/(c) mass ratio of composition is 0.1～5.
13. hand washing tableware cleanser compositions as described in any one in claim 1～12, wherein,
(c) mass ratio of composition/[(a) composition+(b) composition] is 0.02～2.
The cleaning method of 14. 1 kinds of tablewares, wherein,
With the clean tableware of cleaning liquor hand washing that has used the tableware of the hand washing described in any one cleanser compositions in claim 1～13, then, water rinses.
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