CN102858932B - Detergent Composition For Dishwashing By Hand - Google Patents
Detergent Composition For Dishwashing By Hand Download PDFInfo
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- CN102858932B CN102858932B CN201180017960.3A CN201180017960A CN102858932B CN 102858932 B CN102858932 B CN 102858932B CN 201180017960 A CN201180017960 A CN 201180017960A CN 102858932 B CN102858932 B CN 102858932B
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/37—Mixtures of compounds all of which are anionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/123—Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Disclosed is a detergent composition for dishwashing by hand which comprises (a) a sulfosuccinic acid di- or monoalkyl ester represented by general formula (1) or (1') or a salt of the ester, (b) 1-50 mass% anionic surfactant (excluding (a)) comprising a C8-21 hydrocarbon group and either a sulfuric ester base or a sulfonic acid base, and (c) an ingredient which is (c1) a C10-18 fatty acid or a salt thereof and/or (c2) an alkyl glyceryl ether in which the alkyl group has 6-18 carbon atoms, wherein the (c)/(a) mass ratio is 0.001-11, and when the ingredient (c) is a C10-18 fatty acid or a salt thereof, then the (b)/[(a)+(c)] mass ratio is 0.01-10.
Description
Technical field
The present invention relates to hand-wash use tableware cleanser compositions.
Background technology
For hand washing dish detergent, foam duration when having abundant foaming characteristic and cleaning in cleaning is pursued.
This foaming characteristic/foam duration is the very important physical property related to cleaning persistence, is substantially carried out foaming all the time
The exploitation of property/excellent cleaning agent of foam duration.
In Japanese Unexamined Patent Application 62-215699, disclose containing sulfosuccinic acid diesters type surfactant and bubble
Property the excellent cleaning agent suitable for wash dishes of high, cleaning capacity technology.In addition, in Japanese Unexamined Patent Application Publication 2008-507611
In disclose the dish detergent containing sulfosuccinic acid diesters type surfactant and other anion surfactants and combine
The technology of thing, and describe in a specific embodiment and can contain fatty acid as builder.In Japanese Unexamined Patent Publication 3-
The liquid detergent combination of the alcohol ester that sulfosuccinate can be used as anion surfactant has been recorded in 207799
Thing, can use fatty acid as its foaming inhibitor.
In addition, recorded in Japanese Unexamined Patent Publication 2004-262955 living containing anion surfactant, amine oxide type surface
Property agent, the liquid cleanser composition of 2- ethylhexyl list glycerin ethers.
In addition, having recorded in Japanese Unexamined Patent Publication 2006-160869 containing anion surfactant, magnesium salt, higher aliphatic
The liquid cleanser composition of acid or its salt.
The content of the invention
The present invention relates under a kind of hand washing uses tableware cleanser compositions, the hand washing tableware cleanser compositions to contain
State composition（a）、（b）、（c）,（a）Following formulas（1）Or（1’）Represented dialkyl sulfosuccinate or sulfosuccinic
Sour monoalkyl ester or its salt are [hereinafter referred to as（a）Composition],（b）1 ~ 50 mass % with carbon number for 8 ~ 21 alkyl and
The anion surfactant of sulfuric ester alkali or sulphonate-base（But,（a）Except）[hereinafter referred to as（b）Composition], and
（c）Carbon number for 10 ~ 18 fatty acid or its salt or alkyl carbon number for 6 ~ 18 alkyl glycerylether [below, claim
For（c）Composition]；（c）In the case that composition is the fatty acid that carbon number is 10 ~ 18 or its salt,（b）/ [（a）+（c）]
Mass ratio be 0.01 ~ 10, and（c）/（a）Mass ratio be 0.001 ~ 11.
[in formula, R1、R2Respectively carbon number for 5 ~ 18 alkyl or hydrogen atom, R1、R2In at least one be that carbon is former
Subnumber is 5 ~ 18 alkyl.A1、A2Separately for carbon number for 2 ~ 4 alkylidene, x, y be average addition molal quantity simultaneously
And separately be 0 ~ 6.In addition, x, y can not be 0 simultaneously.M is inorganic or organic cation.]
In addition, the invention further relates to used the hand washing of the invention described above cleaning solution of tableware cleanser compositions come
Hand washing cleaning tableware, the cleaning method of the tableware being rinsed with water afterwards.
The present invention uses tableware cleanser compositions, said composition to contain following compositions including following hand washing（a）、（b）、
（c）,（a）Dialkyl sulfosuccinate or 2-Sulfosuccinic acid monoalkyl ester or its salt（The carbon number of one alkyl be 5 ~
18）,（b）The anionic surface with the alkyl and sulfuric ester alkali or sulphonate-base that carbon number is 8 ~ 21 of 1 ~ 50 mass %
Activating agent（But,（a）Except）And（c）Carbon number for 10 ~ 18 fatty acid or its salt,（b）/ [（a）+（c）] matter
Amount ratio is 0.01 ~ 10, and（c）/（a）Mass ratio be 0.001 ~ 11.
Present invention additionally comprises following hand washing uses tableware cleanser compositions, said composition to contain following compositions（a）、（b）、
（c）,（a）Dialkyl sulfosuccinate or 2-Sulfosuccinic acid monoalkyl ester or its salt（The carbon number of one alkyl be 5 ~
18）,（b）Anion surfactant with the alkyl and sulfuric ester alkali or sulphonate-base that carbon number is 8 ~ 21（But
It is,（a）Except）, and（c）Alkyl glycerylether with the alkyl that carbon number is 6 ~ 18.
Specific embodiment
In recent years, it is from the purpose for mitigating environmental pressure, effectively utilizes water resource, preferred to reduce used during hand washing is washed
Water amount, expect the flushing water after the cleaning of reduction dish detergent as far as possible.However, general foaming characteristic/foam duration
Excellent cleaning agent must substantial amounts of water in order to complete flushing.Therefore, seek strongly to show abundant foaming characteristic in cleaning
With the persistence of foam, when rinsing, foam disappears in an instant, the hand washing dish detergent for completing to rinse with a small amount of water energy.
In this, in Japanese Unexamined Patent Application 62-215699, Japanese Unexamined Patent Application Publication 2008-507611 and Japanese Unexamined Patent Publication 3-207799
Lather collapse when do not accounted for regard to rinsing completely.
In addition, in Japanese Unexamined Patent Publication 3-207799, the fatty acid of the defoamer enumerated as " foaming inhibitor " be with
For the purpose of low foaming characteristic during cleaning, it is not given at continually forming very abundant foam when cleaning with wink when rinsing
When froth breaking technology contact enlightenment.
Furthermore, it is generally considered that completing for rinsing is lather collapse and tableware does not have soapy feeling.But, foaming characteristic/foam
The excellent cleaning agent of persistence, as its lather collapse is poor, and tableware is satiny all the time, thus, in order to complete to rinse needs
Substantial amounts of water.Therefore, tight demand shows the persistence of abundant foaming characteristic and foam in cleaning, does not instantaneously have when rinsing
There is soapy feeling, the hand washing dish detergent for just completing to rinse with a small amount of water.
In this, in Japanese Unexamined Patent Application 62-215699 and Japanese Unexamined Patent Application Publication 2008-507611 completely without with regard to
The consideration of the improvement of soapy feeling during flushing.Although Japanese Unexamined Patent Publication 3-207799 is the technology for improving soapy feeling and washability, but
It is in recent years, from the purpose for mitigating environmental pressure and effectively utilizes water resource, it is desirable to suppress soapy feeling with lesser amount of water
And the technology rinsed is completed, from this viewpoint, it is desirable to be further improved.
Therefore, the invention reside in offer is a kind of to show abundant foaming characteristic with foam duration when cleaning in cleaning
Property, when rinsing, Flash Lather disappears, the hand washing dish detergent for just completing to rinse with a small amount of water, and/or provides a kind of
Abundant foaming characteristic is shown in cleaning, instantaneous soapy feeling disappears when rinsing, the hand washing for just completing to clean with a small amount of water
Use dish detergent.
According to the present invention it is possible to foam duration when abundant foaming characteristic and cleaning are shown in cleaning is provided,
During flushing, Flash Lather disappears, the hand washing dish detergent for just completing to rinse with a small amount of water.
<（a）Composition>
The present invention's（a）Composition is following formulas（1）Or（1’）Compound.
[in formula, R1、R2Respectively carbon number be 5 ~ 18, be preferably 5 ~ 15, more preferably 5 ~ 13 alkyl or
Hydrogen atom, R1、R2In at least one be carbon number be 5 ~ 18 alkyl.A1、A2Separately for carbon number be 2 ~ 4, it is excellent
Elect 2 ~ 3 alkylidene as, x, y are average addition molal quantity and are separately 0 ~ 6.In addition, x, y can not be 0 simultaneously.M
For inorganic or organic cation.]
（a）In the case that composition is dialkyl sulfosuccinate or its salt, formula（1）Or（1’）In R1、R2
Can be that carbon number is 5 ~ 18, is preferably 5 ~ 15, is more preferably 5 ~ 13 alkyl with identical or different.（a）Composition
For formula（1）In the case of represented dialkyl sulfosuccinate or its salt, A1、A2It is separately carbon number
For 2 ~ 4, be preferably 2 ~ 3 alkylidene, x, y are average addition molal quantity and can not be 0 simultaneously, are 0 ~ 6, preferably 0 or
0.1~2.In addition, x+y is preferably 0.1 ~ 12, more preferably 0.2 ~ 4.In addition,（a）Composition is 2-Sulfosuccinic acid list alkane
In the case of base ester or its salt, formula（1）Or（1’）In R1、R2In one be carbon number be 5 ~ 18, be preferably 5 ~
15th, 5 ~ 13 alkyl is more preferably, another is hydrogen atom.（a）Composition is formula（1）Represented 2-Sulfosuccinic acid
In the case of monoalkyl ester or its salt, A1、A2Separately it is 2 ~ 4, is preferably 2 ~ 3 alkylidene, x, y for carbon number
For average addition molal quantity and can not simultaneously be 0, be 0 ~ 6, preferably 0 or 0.1 ~ 2.In addition, x+y is preferably 0.1 ~ 12, enter
One step is preferably 0.2 ~ 4.R1、R2It is respectively preferably carbon number to be 5 ~ 18, be preferably 5 ~ 15, be more preferably 5 ~ 13 alkane
Base, i.e.（a）Composition is preferably dialkyl sulfosuccinate or its salt.
In addition,（a）Composition is preferably formula（1’）Represented dialkyl sulfosuccinate or 2-Sulfosuccinic acid list
Arrcostab or its salt.
Formula（1）Or（1’）In, R1、R2It is respectively preferably hexyl, octyl group, nonyl, decyl, dodecyl, tridecane
Base, 2- ethylhexyls, n-octyl, secondary octyl, isopentyl, isononyl, isodecyl, cyclohexyl, particularly preferably selected from n-octyl,
Group in secondary octyl, decyl, isodecyl and 2- ethylhexyls.M be selected from hydrion, sodium ion, ammonium ion, potassium from
Son, the inorganic cation in magnesium ion, the organic sun in monoethanolamine, diethanolamine, triethanolamine, the hydrochlorate of morpholine from
Son, the cation being preferably selected from sodium ion, ammonium ion, potassium ion and magnesium ion.
（a）In the case that composition is dialkyl sulfosuccinate or its salt, as modulation R1、R2Identical chemical combination
The method of thing, is not particularly limited, and may be referred to such as United States Patent (USP) 2, the method described in 028,091 being manufactured,
In addition, R1、R2Different asymmetric compounds may be referred to such as Japanese Unexamined Patent Application 58-24555 to be manufactured.Using city
In the case of the compound sold, it is possible to use the PELEX OT-P of Kao Corp's manufacture（R1、R2All it is 2- ethylhexyls
Compound）, Kao Corp manufacture PELEX TR（R1、R2All it is the compound of tridecyl）, BASF AG manufacture
Luensit A-BO（R1、R2All it is the compound of 2- ethylhexyls）, can obtain from Mitsui Cytec Ltd.
AEROSOLAY-100（R1、R2All it is the compound of amyl group）, Mitsui Cytec Ltd. AEROSOLA-196（R1、R2All it is
The compound of cyclohexyl）Deng.As（a）The raw material of composition, can also use the addition on the alcohol of regulation carbon number to have epoxy
The material of alkane.
<（b）Composition>
The present invention's（b）Composition is with the alkyl and sulfate group or sulfonic anion that carbon number is 8 ~ 21
Surfactant（But except（a）Beyond composition）.Known such anion surfactant foaming characteristic is very excellent, more
Specifically, be preferably selected from carbon number be 8 ~ 18, preferred carbon number for 8 ~ 15 alkyl alkyl sulfate salt,
It is 2 and/or 3 with the alkyl and the carbon number with alkylidene that carbon number is 8 ~ 18, preferred carbon number is 8 ~ 15
And the average addition molal quantity of alkylidene be the polyoxyalkylene alkyl sulfuric acid of 0.1 ~ 6 polyoxyalkylenes, it is former with carbon
Subnumber is that the alkylbenzenesulfonate and carbon number of 8 ~ 15 alkyl are lived for the anionic surface in 8 ~ 15 alkane sulfonate
Property agent.As salt, inorganic salt in sodium salt, ammonium salt, potassium salt, magnesium salt is preferably selected from, selected from monoethanolamine salt, diethanolamine
Organic amine salt in salt, triethanolamine salt, alkylbenzyldimethylasaltsum saltsum.
As（b）Composition, from cleaning when foaming characteristic and foam duration and rinse when lather collapse viewpoint
Set out, preferably following formulas（2）Compound.
R3-O-(R4O)n-SO3M （2）
[in formula, R3It is 8 ~ 18, is preferably 8 ~ 15 alkyl, R for carbon number4For ethylidene and/or propylidene, n is flat
Addition molal quantity and for less than more than 06 number, be preferably less than more than 02 number.M for it is inorganic or it is organic sun from
Son.]
In R4In the case of ethylidene, n is preferably less than 1.5 number, in addition, more preferably more than 0.3 number.This
Outward, in R4In the case of propylidene, n is preferably less than 1.5, more preferably less than 1.0 number, in addition, n is preferably 0.1
Above, it is more preferably more than 0.2 number.In addition, in R4In the case of ethylidene and propylidene, n can be from these scopes
It is middle to be selected respectively.
In formula（2）In, in the case where n is 0, compound preferably comprises R3It is the chemical combination of the alkyl with branched structure
Thing.In the case where n is 0, preferred formula（2）Compound branching ratio [have branched alkyl compound total mole number
Relative to formula（2）Compound total mole number ratio] be preferably 15 ~ 100mol%, more preferably 40 ~
The compound of 100mol%, particularly preferably 70 ~ 100mol%.
Formula（2）In M be inorganic cation in sodium ion, ammonium ion, potassium ion, magnesium ion, selected from single second
Organic cation in hydramine, diethanolamine, triethanolamine, the hydrochlorate of morpholine, preferably sodium ion, ammonium ion, potassium ion, magnesium
Ion.
As formula（2）Compound modulator approach, be not particularly limited, for example, according to purpose in R3- OH institutes table
On the fatty alcohol for showing after the oxirane and/or expoxy propane of addition ormal weight, with selected from sulfur trioxide（Liquid or gas
Body）, the gas containing sulfur trioxide, oleum, the sulfating agent in chlorosulfonic acid carry out Sulfation, entered with the alkaline agent of regulation
Row neutralization is manufacturing.Oxirane（Hereinafter, it is expressed as EO）And/or expoxy propane（Hereinafter, it is expressed as PO）Additive reaction need
Catalyst is wanted, catalyst can be using alkali hydroxides such as NaOH, KOH.Further, it is possible to use with Japanese Unexamined Patent Publication 8-323200
Catalyst of the magnesium oxide of record for main component, the former can obtain addition molal quantity be distributed it is relatively wide polyxyethylated
Ether, the latter can obtain the compound being distributed with narrow addition molal quantity.Furthermore it is also possible to pass through such as in Japanese Unexamined Patent Publication
It is disclosed in flat 10-158384 and with base catalyst and metal oxide catalyst come control addition molal quantity distribution.
In formula（2）In n be 0 in the case of obtain preferably comprising R3It is the compound of the alkyl with branched structure
In the case of, as the R of raw material3Alcohol represented by-OH, can enumerate and carbon number is obtained for 8 ~ 14 1- olefin hydroformylations
The alcohol for arriving（Alkyl relative to the methyl branch on the β positions of OH bases contains 15 ~ 70mol%）, be condensed carbon number for 4 ~ 8
Aldehyde after reduced obtained from gerber special type alcohol（Guerbet alcohol）（Relative to carbon atom on the β positions of OH bases
The alcohol of the structure that number has been 3 ~ 6 alkyl branches contains 100mol%）, by 3 obtained from the dimer hydroformylation of isobutene.,
5,5- trimethyl hexanols, by highly branched chain tridecanol obtained from the trimer hydroformylation of isobutene.（Branching ratio is 100mol%）、
Synthol with oil, coal as raw material（Branching ratio is about the alkyl of 20 ~ 100mol%）.
In the present invention, as（b）Composition most preferably formula（2）Represented compound, i.e. R4It is 0.2 for propylidene, n
~ 1.0, the compound of more preferably 0.4 ~ 0.8 number.
<（c）Composition>
The present invention's（c）Composition is（c1）Carbon number for 10 ~ 18 fatty acid or its salt, or（c2）The carbon of alkyl
Atomic number is 6 ~ 18 alkyl glycerylether.（c）Composition is（c1）In the case of composition, specifically can enumerate capric acid, the moon
Cinnamic acid, myristic acid, Palmic acid, palmitoleic acid, stearic acid, Oleic acid, linoleic acid, linolenic acid and their salt.Alternatively, it is also possible to
Using fatty acid mixeds such as Oleum Cocois composition fatty acids.As the salt of fatty acid, can be selected from sodium salt, ammonium salt, potassium salt, magnesium salt
In inorganic salt, selected from organic amine salts such as monoethanolamine salt, diethanolamine salt, triethanolamine salt, alkylbenzyldimethylasaltsum saltsum, can preferably enumerate
Sodium salt, ammonium salt, potassium salt, magnesium salt, can more preferably enumerate sodium salt, ammonium salt, potassium salt.As（c）Composition, more preferably Laurel
Acid, myristic acid, Palmic acid or their salt, further more preferably lauric acid, myristic acid or their salt, most
Preferably myristic acid or its salt.Therefore, from from the viewpoint of foamability and lather collapse, preferably（c）Composition contains
Myristic acid or its salt,（c）In composition, the ratio of myristic acid or its salt is preferably 30 ~ 100 mass %, more preferably
50 ~ 100 mass %, further more preferably 80 ~ 100 mass %.
The present invention's（c）Composition is 6 ~ 18, is preferably 8 ~ 12 alkyl glycerylether for the carbon number of alkyl.It is concrete next
Say, preferably following formulas（3）Compound.
R5-O-（Gly）r-H （3）
[in formula, R5The alkyl that carbon number is 6 ~ 18 is represented, Gly represents the residue that 2 hydrogen atoms are removed from glycerol, r
Represent average addition molal quantity and the number for 1 ~ 4.]
In formula（3）In, R5It is 6 ~ 18, is preferably 7 ~ 12, is more preferably 8 ~ 10 alkyl for carbon number, can makes
With straight chained alkyls such as hexyl, heptyl, octyl group, nonyl, decyls, the viewpoint from the soapy feeling reduced when rinsing goes out in the present invention
Send out, preferably the compound with branched structure, as R5Specific alkyl with branched structure, more preferably selected from 2-
Group in ethylhexyl, secondary octyl, isononyl and isodecyl, more preferably 2- ethylhexyls or isodecyl, it is especially excellent
Elect 2- ethylhexyls as.In formula（3）In, r preferably 1 ~ 3, more preferably 1 ~ 2, the most preferably compound of r=1.It is special
Not preferred compound is R5For 2- ethylhexyls, and the compound of r=1.
Structure represented by Gly is the hydroxy combining of the 1st of glycerol and the 3rd with-CH2CH(OH)CH2The knot of-expression
Structure, or the hydroxy combining of the 1st and the 2nd of glycerol is with-CH (CH2OH)CH2The structure of-expression, according to catalyst or reaction
Condition and it is different.
To obtain formula（3）Compound, can for example use as carbon number for 6 ~ 10 alcohol R5Represented by-OH
Alkanol, use BF3Reacted the epoxides such as epoxyhalopropane or (+)-2,3-Epoxy-1-propanol Deng acid catalyst or Al catalysts
Come the method for manufacturing.
For example, in the case of using 2-Ethylhexyl Alcohol, the 2- ethylhexyl lists glycerin ether for obtaining is can be containing such as day
The mixture of described various products in this JP 2001-49291.
<Tableware cleanser compositions are used in hand washing>
The hand washing of present invention tableware cleanser compositions are by with specified conditions and with foaming characteristic/foam duration
's（b）Composition and（a）Composition and conduct（c）Composition（c1）Composition, so as to the table in the higher clean water of detergent concentration
Reveal very high foaming characteristic and foam duration, by adding flushing water after cleaning terminates, Flash Lather disappears, Ke Yiyong
A small amount of water just completes to rinse.Although its reason does not determine, but it is believed that be by the calcium in tap water and（c1）Composition
Forming salt is insoluble, and due to diluting the fatty acid coagulation, insoluble discharged from micelle, such that it is able to instantaneously eliminate
Foam.Although fatty acid is known as defoamer, using its present invention cleanser compositions cleaning when energy
Abundant foam is obtained, the effect of rapid froth breaking when on the other hand rinsing, can be obtained, this is from the fatty acid as defoamer
Inscrutable unexpected effect in effect.
The hand washing of the present invention is with tableware cleanser compositions by using with foaming characteristic/foam duration（b）Composition,
Very high foaming characteristic can be shown in the higher cleaning agent of the concentration of cleaning agent, but the concentration of cleaning agent is higher,
More it is difficult to remove its soapy feeling when then rinsing.In the system, it is believed that by and with bulky structure（a）Composition and conduct
（c）Composition（c2）Composition, can upset the parcel for adsorbing the surfactant layer in tableware surface（packing）Property, reduce
Soapy feeling during flushing.
The hand washing tableware cleanser compositions of the present invention, in conduct（c）Composition is used（c1）In the case of composition, from
From the viewpoint of bubble ability, the removal of foam and economy, preferably comprise 1 ~ 30 mass %, further preferably 1 ~ 20 matter
Measure %, particularly preferably contain 2 ~ 15 mass %（a）Composition.In addition, containing（b）1 ~ 50 mass % of composition, preferably 4 ~ 40 matter
Amount %, more preferably 10 ~ 30 mass %.In addition, for trying to achieve quality % in the present invention and mass ratio etc.（b）The amount of composition
It is the amount as acid type compound.In addition,（c）Composition preferably comprises 0.1 ~ 20 mass %, more preferably 0.5 ~ 10 mass %,
Particularly preferably 1 ~ 6 mass %.
In addition, in hand washing conduct in tableware cleanser compositions of the present invention（c）Composition is used（c1）The situation of composition
Under, from from the viewpoint of foaming characteristic,（b）Composition/[（a）Composition+（c）Composition] mass ratio be more than 0.01, preferably 0.1
More than, more preferably more than 0.3, more preferably more than 0.45, particularly preferably more than 0.6.On the other hand, from bubble
From the viewpoint of foam elimination property, the mass ratio is less than 10, preferably less than 6, more preferably less than 3, further preferably
For less than 2, particularly preferably less than 1.6.
In addition, in hand washing conduct in tableware cleanser compositions of the present invention（c）Composition is used（c1）The situation of composition
Under, from from the viewpoint of foamability and lather collapse,（c）Composition/（a）The mass ratio of composition is more than 0.001, preferably
More than 0.01, more preferably more than 0.05, more preferably more than 0.07, particularly preferably more than 0.09.The opposing party
Face, the mass ratio are less than 11, preferably less than 5, more preferably less than 3, particularly preferably less than 1.5.
In addition, in hand washing conduct in tableware cleanser compositions of the present invention（c）Composition is used（c1）The situation of composition
Under,（a）Composition/（b）The mass ratio of composition is preferably 0.1 ~ 10, more preferably 0.3 ~ 5, more preferably 0.5 ~ 3.
Conduct in the present invention（c）Composition is used（c1）In the case of composition, from foamability and the removal of foam
Viewpoint is set out,（a）Composition,（b）Composition and（c）Total quality of composition is relative to all surfaces activating agent in compositionss
Content is preferably 50 ~ 100 mass %, and more preferably 70 ~ 100 mass % are even more preferably 80 ~ 100 mass %.
In addition, the hand washing of present invention conduct in tableware cleanser compositions（c）Composition is used（c2）In the case of composition,
From foamability and flushing when remove soapy feeling easy degree from the viewpoint of, preferably comprise 1 ~ 30 mass %（a）Into
Point, more preferably 2 ~ 25 mass %, particularly preferably 6 ~ 20 mass %.In addition,（b）Composition preferably comprises 1 ~ 50 mass %, enters
One step is preferably 5 ~ 40 mass %, particularly preferably 10 ~ 30 mass %.In addition, being used in the present invention asking calculation quality % and mass ratio
Deng（b）The amount of composition is the amount as acid type compound.In addition, the hand washing of present invention tableware cleanser compositions, from punching
From the viewpoint of the easy degree of removal soapy feeling when washing, preferably comprise（c）0.5 ~ 20 mass % of composition, more preferably
1 ~ 10 mass %, is still more preferably 1.5 ~ 5 mass %.
Conduct in the present invention（c）Composition is used（c2）In the case of composition, from foamability and the appearance of removing soapy feeling
Easily from the viewpoint of degree,（a）Composition and（c）Total quality of composition is relative in compositionss（a）Composition,（b）Composition with
And（c）Total quality of composition（[（a）Composition+（c）Composition]/[（a）Composition+（b）Composition+（c）Composition] mass ratio）It is excellent
Elect 0.1 ~ 0.9, more preferably 0.2 ~ 0.8 as, be even more preferably 0.3 ~ 0.7, particularly preferably 0.4 ~ 0.6.
In addition, in the hand washing tableware cleanser compositions conduct of the present invention（c）Composition is used（c2）In the case of composition,
From foamability and from the viewpoint of preventing soapy feeling,（b）Composition/[（a）Composition+（c）Composition] mass ratio be preferably 0.01
More than, more preferably more than 0.1, more preferably more than 0.5, particularly preferably more than 1.In addition, the mass ratio is preferred
For less than 20, more preferably less than 15, more preferably less than 10, particularly preferably less than 5.
In addition, in hand washing of the present invention conduct in tableware cleanser compositions（c）Composition is used（c2）In the case of composition,
From foamability and from the viewpoint of preventing soapy feeling,（c）Composition/（a）The mass ratio of composition is more than 0.01, preferably 0.1
More than, more preferably more than 0.15.In addition, the mass ratio be less than 10, preferably less than 4, more preferably 1.5 with
Under, particularly preferably less than 0.7.
In addition, in hand washing conduct in tableware cleanser compositions of the present invention（c）Composition is used（c2）The situation of composition
Under, from from the viewpoint of foamability and the removal of foam,（a）Composition/（b）The mass ratio of composition is preferably 0.01 ~ 2, enters one
Step is preferably 0.03 ~ 1.5, more preferably 0.1 ~ 1, particularly preferably 0.3 ~ 0.7.
Conduct in the present invention（c）Composition is used（c2）In the case of composition, from foamability, the removal of foam and anti-
From the viewpoint of on-slip soapy feeling,（a）Composition,（b）Composition and（c）Total quality of composition is relative to whole tables in compositionss
The content of face activating agent is preferably 20 ~ 100 mass %, and more preferably 40 ~ 100 mass % are even more preferably 60 ~ 100 matter
Amount %.
The hand washing tableware cleanser compositions of the present invention from rinse when instantaneous soapy feeling disappear, just can be with a small amount of water
From the viewpoint of completing to rinse, as（c）Composition is preferably comprised（c1）Composition and（c2）Composition.
The hand washing tableware cleanser compositions of the present invention strengthen cleaning capacity to improve the emulsifying capacity to greasy dirt,
As（d）Composition contains inorganic compound containing magnesium and/or has Alkylenediamine of the carbon number for 2 ~ 6 alkylidene, preferably
Containing inorganic compound containing magnesium.These compounds are the compound with the structure for playing effect required in this invention, i.e., with（a）
Composition,（b）In composition and other anion surfactants according to contained by hope, at least 2 molecule producing ratios are weaker
Interaction forms coordination compound, used as the common effect/effect of the compound of the interfacial energy for improving emulsifying capacity etc..
As inorganic compound containing magnesium, magnesium salt, the hydrogen-oxygens such as the magnesium chloride such as magnesium chloride, magnesium sulfate, magnesium nitrate can be enumerated
Change magnesium, magnesium oxide etc., more preferably selected from magnesium chloride and the compound of magnesium sulfate, still more preferably magnesium chloride.Separately
Outward, as alkylene diamine compound, preferred ethylenediamine, propane diamine, hexamethylene diamine, cyclohexanediamine, following formula（4）Represented two
Amine, more preferably cyclohexanediamine, 1,3- are double（Aminomethyl）Hexamethylene, more preferably 1,3- are double（Aminomethyl）Hexamethylene.
[in formula, R6~R17Respectively carbon number for 1 ~ 3 alkyl, carbon number for 1 ~ 3 aminoalkyl, or hydrogen is former
Son, and R6~R17In 2 be carbon number for 1 ~ 3 aminoalkyl.]
（d）The content of composition in the composition be preferably 1 ~ 20 mass %, more preferably 1.5 ~ 15 mass %, further more
Plus preferably 1.5 ~ 7 mass %.In addition, these（d）Composition may contain water of crystallization, and the content represented by here is except decrystallizing
The quality of water.
The hand washing tableware cleanser compositions conduct of the present invention（d）The supplement of composition can be used together（d）Beyond composition
Inorganic compound.As inorganic compound, can enumerate Sodium Chloride, potassium chloride, sodium iodide, potassium iodide, sodium sulfate, potassium sulfate,
Alumen etc..
The behavior of foam when cleaning in the present invention and when rinsing is extremely important.In hand washing tableware cleanser compositions
General Study in, it is considered to foaming characteristic/foam duration when cleaning with the surfactant with foam enhancing effect, but
In the present invention, because such surfactant with foam enhancing effect can be big to lather collapse performance generation during flushing
Affect, so should be noted when in use.In the present invention especially to conduct（e）The use of composition is noted that（e）Composition is
Surface in amine oxide type surfactant, carboxy betaine type surfactant and alkylol amide type surfactant
Activating agent.
N- alkanoylamino propyl group-N, N- dimethyl amine can be enumerated as amine oxide type surfactant（As
Alkanoyl is lauroyl or myristoyl）, N- alkyl-N, N- dimethyl amine（As alkyl be lauryl or
Myristyl）.In addition, N- alkanoylamino propyl group-N can be enumerated as carboxy betaine type surfactant, N- dimethyl-
N- carboxymethyl ammonium glycine betaines, N- alkanoylamino propyl group-N, N- dimethyl-N -s（2- hydroxyl sulfopropyls）Ammonium glycine betaine, N- alkyl-
N, N- dimethyl-N-carboxymethyl ammonium glycine betaine, N- alkyl-N, N- dimethyl-N -s（2- hydroxyl sulfopropyls）Ammonium glycine betaine.Enter one
Step, can enumerate the alkanolamines such as monoethanolamine, diethanolamine, methyl monoethanolamine and the moon as alkylol amide type surfactant
The amidate of the fatty acids such as cinnamic acid, myristic acid.
In the present invention, the behavior of foam is extremely important, to giving compositionss foam enhancing effect（e）The use of composition needs note
Meaning, especially,（e）The content of composition is preferably below 5 mass % relative to the content of all surfaces activating agent in compositionss,
Below more preferably 3 mass %, below more preferably 2 mass %, even more preferably for 1 mass % below, further more
Below preferably 0.5 mass %, most preferably do not contain.
Sulfobetaine type surface activity can also be used as the surfactant with foam enhancing effect in the present invention
Agent is [hereinafter referred to as（f）Composition].Sulfobetaine type surfactant improves foaming characteristic/foam duration during cleaning, but
Instantaneous lather collapse performance during flushing is not damaged.As sulfobetaine type surfactant, the carbon atom of preferred alkyl
Count the N- alkyl-N for 10 ~ 18, N- dimethyl-N-sulfopropyl ammonium sulfobetaines, N- alkyl-N, N- dimethyl-N -s（2- hydroxyls
Sulfopropyl）Ammonium sulfobetaines, the N- alkanoylamino propyl group-N that the carbon number of alkanoyl is 10 ~ 18, N- dimethyl-N-sulphurs
Propyl ammonium sulfobetaines, N- alkanoylamino propyl group-N, N- dimethyl-N -s（2- hydroxyl sulfopropyls）Ammonium sulfobetaines.
（f）The content of composition is preferably 0.5 ~ 20 mass % in the composition, and more preferably 1 ~ 15 mass % is especially excellent
Elect 2 ~ 10 mass % as.In addition, from cleaning when foaming characteristic/foam duration raising and rinse when lather collapse sight
Point sets out,（f）Composition/[（a）Composition+（b）Composition] mass ratio be preferably 0.01 ~ 0.2, more preferably 0.02 ~ 0.1.
The hand washing tableware cleanser compositions of the present invention in order to improve storage-stable, preferably comprise hydrotropic solvent [with
Under, referred to as（g）Composition].As hydrotropic solvent, preferred toluenesulfonic acid, xylene monosulfonic acid, isopropyl sulfonic acid or their sodium,
Potassium or magnesium salt, particularly preferred p-methyl benzenesulfonic acid or its salt.（g）The content of composition is preferably 0.5 ~ 15 matter in the composition
Amount %, particularly preferably more preferably 1 ~ 10 mass %, 1.5 ~ 5 mass %.
The hand washing tableware cleanser compositions of the present invention can contain molten to improve storage-stable and adjusting viscosity
Agent is [hereinafter referred to as（h）Composition].As the specific example of solvent, be preferably selected from ethanol, isopropanol, ethylene glycol, Propylene Glycol,
Diethylene glycol, dipropylene glycol, glycerol, isoprene, propylene glycol monomethyl ether, propylene glycol monoethyl, 3- methyl -3- methoxyl groups
Butanol, phenoxyethanol, benzoglycols, phenoxy group isopropanol, butyl diglycol（Diethylene glycol monobutyl ether）, diethylene glycol two
Water-miscible organic solvent in butyl ether, benzylalcohol.Wherein, 1 be preferably selected from butyl, ethanol and Propylene Glycol
Plant the water-miscible organic solvent of the above, more preferably water-miscible organic solvent more than 1 in ethanol and Propylene Glycol kind.
This, water-miscible organic solvent refers to Octanol/water Partition Coefficients（LogPow）For less than 3.5 solvent.（h）The content of composition is in group
3 ~ 30 mass %, particularly preferably more preferably 5 ~ 20 mass %, 10 ~ 15 mass % are preferably in compound.
From from the viewpoint of viscosity adjustment and storage-stable, the hand washing preferably in the present invention is combined with dish detergent
Coordinate polymer for preventing gelation in thing [hereinafter referred to as（i）Composition], such as in Japanese Kohyo 11-513067
That what is recorded prevents gelation polymer, particularly preferably coordinates poly alkylene glycol.As for preventing the polymer of gelation
The specific example of poly alkylene glycol, the weight tried to achieve by gel permeation chromatography when can enumerate with Polyethylene Glycol as standard
Mean molecule quantity for 200 ~ 3,000 polypropylene glycol and weight average molecular weight for 200 ~ 3,000 Polyethylene Glycol.
In addition, conduct（i）Composition, it is also possible to using the alkylene oxide adducts of glycerol.The alkylene oxide adducts of glycerol
For the film of the surfactant for suppressing to be formed on the gas-liquid surface of cleanser compositions is effective, particularly preferably sweet
Addition average out to 5 ~ 120 on oil, be preferably 10 ~ 50mol oxirane material, particularly preferably using weight averaged molecular
Measure the ethylene oxide adduct of the glycerol for 500 ~ 4000.
（i）The content of composition in the composition be preferably 0.05 ~ 10 mass %, more preferably 0.1 ~ 5 mass %, especially
Preferably 0.5 ~ 3 mass %.
The hand washing tableware cleanser compositions of the present invention are preferably mentioned component dissolution/dispersion/be emulsifiable in water
The form of fluid composition, more preferred aqueous solution.The water for using can use the metal ingredient that eliminates oligodynamical from
Sub- exchanged water or distilled water, or dissolved hypochlorous sterilized water of 0.5 ~ 10ppm or so etc..
PH of the hand washing of the present invention with tableware cleanser compositions at 25 DEG C is preferably 4 ~ 9, more preferably 5 ~ 8,
Be adjusted to such pH can using selected from sulphuric acid, hydrochloric acid, the mineral acid of phosphoric acid, selected from citric acid, malic acid, maleic acid, richness
The inorganic alkaline agent such as horse acid, the organic acid of succinic acid, sodium hydroxide, potassium hydroxide, magnesium hydroxide, sodium carbonate, potassium carbonate is carrying out.
In the present invention, from from the viewpoint of foaming characteristic/foam duration, preferred composition has buffer capacity, preferably will be above-mentioned organic
Sour to be used in combination with inorganic alkaline agent, organic acid is preferably citric acid.Organic acid can be matched with compositionss with the form of sodium salt or potassium salt
In.In addition, for adjusting in the compound used by pH, using magnesium hydroxide etc. equivalent to（d）The material conduct of composition（d）
Composition.
Viscosity of the hand washing of the present invention with tableware cleanser compositions at 20 DEG C is preferably 5 ~ 500mPas, further
Preferably 10 ~ 300mPas.Viscosity can be used（g）Composition,（h）Composition,（i）Composition etc. is adjusted.
The hand washing tableware cleanser compositions of the present invention can be containing compositions such as spice, dyestuff, pigment.
<Hand washing clean method>
The hand washing tableware cleanser compositions of the present invention can be used for the hand washing cleaning of tableware.For hand-washing the cleaning of cleaning
Liquid be using the present invention hand washing with tableware cleanser compositions obtained by, it is possible to use the stock solution of compositionss is aqueous
Diluent.As specific hand washing clean method, for example, the compositionss of the present invention are attached on the flexible materials such as aqueous sponge
Cleaning solution is kept, is rubbed with handss and is bubbled for several times, clean tableware.From from the viewpoint of high foaming and foam duration, flexible material
In the cleaning solution kept in material（a）Composition,（b）Composition and（c）Total concentration of composition is preferably 1,000 ~ 30,
000ppm, more preferably 1,000 ~ 20,000ppm, more preferably 2,000 ~ 10,000ppm.
Add water after cleaning terminates and be rinsed, for example, the compositionss used in the present invention relative to 1 mass parts are used
The flushing water of 3.3 ~ 133 mass parts can just make foam fully disappear, and quickly complete flushing.The amount of the flushing water is using existing
Hand washing cleanser compositions in the case of 2/3 ~ 1/10 or so.
Embodiment
The enforcement of the below example narration present invention.Embodiment be to the present invention illustration illustrate, be not for
Limit the present invention.
The hand washing tableware cleanser compositions of table 1 ~ 7 are modulated using following gradation compositions, following each evaluations are carried out.
The results are shown in table 1 ~ 7.In addition, quality % of the gradation composition in table 1 ~ 7 is the numerical value based on whole effective ingredient.
<Gradation composition>
Two（2- ethylhexyls）Sodium sulfosuccinate（1）：Reagent [Kanto Kagaku K. K.]
Two（2- ethylhexyls）Sodium sulfosuccinate（2）：PELEX OT-P [Kao Corp]
2-Sulfosuccinic acid diamyl base ester sodium：AEROSOL AY-100 are [more than 97 mass % of effective ingredient, by Mitsui
Cytec Ltd. are obtained]
2-Sulfosuccinic acid dicyclohexyl maleate sodium：AEROSOL A-196 [93 ~ 95 mass % of effective ingredient, by Mitsui
Cytec Ltd. are obtained]
2-Sulfosuccinic acid double tridecyl ester sodium：PELEX TR [Kao Corp]
2-Sulfosuccinic acid list decyl isoamyl base ester sodium：Reagent [Wako Pure Chemical Industries, Ltd.]
Double Polyethylene oxide -2- ethyl hexyl ester the sodium of 2-Sulfosuccinic acid：Using by 2-Sulfosuccinic acid and Polyethylene oxide -2- second
Material obtained from the esterification of base hexyl ether.Polyethylene oxide -2- ethylhexyl ethers are that the 2-Ethylhexyl Alcohol for 1mol adds
Into obtained from the oxirane of 1mol.
Dialkyl sulfosuccinate sodium（1）：Using by Isalchem123（Alkyl is alkane that carbon number is 12
Base and carbon number are the mixing of 13 alkyl, and branching ratio is the branched-chain alcoho of 94 mass %）With 2-Ethylhexyl Alcohol with mass ratio it is
The mixture of 80/20 mixing and compound obtained from the esterification of 2-Sulfosuccinic acid.（Mean molecule quantity：553）
Dialkyl sulfosuccinate sodium（2）：Using mixed with mass ratio as 80/20 by tridecanol and 2-Ethylhexyl Alcohol
The mixture of conjunction and compound obtained from the esterification of 2-Sulfosuccinic acid.（Mean molecule quantity：559）
·b-1：After to the natural alcohol addition PO of 0.6mol of the alkyl chain of 1mol for C12, entered by sulfur trioxide
Row sulphation, is neutralized with sodium hydroxide（It is 11 to be neutralized to the pH after dilute with water 10%）The material for obtaining.
·b-2：Sodium lauryl sulfate [trade name：EMAL 0, Kao Corp]
·b-3：By positive decyl sodium sulfovinate [Kanto Kagaku K. K.] and sodium lauryl sulfate [trade name：
EMAL 0, Kao Corp] material that mixed with the ratio that mass ratio is 90/10.
·b-4：By sodium lauryl sulfate [trade name：EMAL 0, Kao Corp] and sodium tetradecyl sulfate
The material that [and Gong Chun medicines Industrial Co., Ltd] is mixed with the ratio that mass ratio is 90/10.
·b-5：By n-octyl sodium sulfate and sodium lauryl sulfate [trade name：EMAL 0, Kao Corp] with
Mass ratio is the material that 10/90 ratio is mixed.
·b-6：After the addition PO of 0.4mol on the natural alcohol of the alkyl chain for C12 of 1mol, by sulfur trioxide
Sulphation is carried out, is neutralized with sodium hydroxide（It is 11 to be neutralized to the pH after dilute with water 10%）Material.
·b-7：After the addition PO of 0.8mol on the natural alcohol of the alkyl chain for C12 of 1mol, by sulfur trioxide
Sulphation is carried out, is neutralized with sodium hydroxide（It is 11 to be neutralized to the pH after dilute with water 10%）Material.
·b-8：After the addition PO of 1.0mol on the natural alcohol of the alkyl chain for C12 of 1mol, by sulfur trioxide
Sulphation is carried out, is neutralized with sodium hydroxide（It is 11 to be neutralized to the pH after dilute with water 10%）Material.
·b-9：Alkyl chain is C10:C11:C12:C13=10:35:35:20（Mass ratio）Alkyl benzene sulphonate（After C
Numeral represents carbon number）.
·b-10：Alkane（Carbon number mixes for 14 ~ 17 secondary alkyl）Sodium sulfonate（Trade name is
HOSTAPURSAS60, Clariant company manufactures）.
·b-11：1mol alkyl chain for C12 natural alcohol on addition 0.6mol PO after, entered by sulfur trioxide
Row sulphation, is neutralized with ammonia（It is 11 to be neutralized to the pH after dilute with water 10%）Material.
·b-12：It is C12/C10/C8=90/5/5 in the alkyl chain of 1mol（Mass ratio）Natural alcohol on addition 0.6mol
PO after, sulphation is carried out by sulfur trioxide, is neutralized with sodium hydroxide（The pH being neutralized to after dilute with water 10%
For 11）Material.
·GE-EH：2- ethylhexyl list glycerin ethers（99 mass % of single glycerin ether）
Nonionic 1：Alkyl consists of C12/C14=60/40（Mass ratio）Mixed alkyl and glucoside it is flat
Condensation degree is 1.5 alkyl polyglucoside
Nonionic 2：Softanol 70H（Nippon Shokubai Co., Ltd manufactures）
Nonionic 3：Softanol 33（Nippon Shokubai Co., Ltd manufactures）
·e-1：N- lauryl-N, N- dimethyl-N -s（2- hydroxyl sulfopropyls）Ammonium sulfobetaines（Kao Corp
Manufacture：AMPHITOL 20HD）
·e-2：Lauryl dimethyl amine oxide（Kao Corp, AMPHITOL 20N）
·e-3：Amine oxide：N- decyl-N, N- dimethyls amine/N- myristyl-N, N- dimethyls amine=2/3
（Mass ratio）
Glycerol EO addition products：Weight average molecular weight is the EO addition products of 1,000 glycerol
Polypropylene glycol：Weight average molecular weight is 1,000 polypropylene glycol
·PTS·H2O：1 hydrate of paratoluenesulfonic acid sodium salt
·MgCl2·6H2O：6 hydrate of magnesium chloride
<Foamability（Sclavo is evaluated）>
In the columned glass for adding 20 diameters about a diameter of 5cm of the plastic ball of 9mm, high 13cm
In container, the 3.5 ° of DH hard water of use for adding 40ml are diluted to 0.5 mass %（200 times）Compositionss.Further, add 0.04g yellow
Oil, by temperature adjustment to 20 DEG C in 15 minutes after sealing.Glass container after temperature adjustment is terminated is installed on decantation test
Machine（Suga Test Instruments Co.,Ltd.）, stir 15 minutes in the environment of 20 DEG C, after terminating, take out immediately
The glass container of installation, determines the height of foam in container（mm）.1 compositions are carried out with 2 evaluations, using meansigma methodss as this
The foamability of compositionss（Sclavo is evaluated）.
<Foamability（Initial stage foam volume）And defoaming>
Compositionss are diluted into 30 times with 3.5 ° of DH hard water, by pump bubbling container（1 200 mesh）, in the graduated cylinder of 500ml
The foam of 3g is made, from calibration record its capacity of graduated cylinder, as foamability（Initial stage bubble amount）.Next, by hand-made
Watering can adds 3.5 ° of DH hard water of 100ml in foam, the foam volume after determining 30 seconds.In the case where foam does not disappear,
Further add 3.5 ° of DH hard water of 100ml（Total 200ml）, the foam volume after similarly determining 30 seconds.In addition, for froth breaking
Property, in addition 100ml hard water and 200ml hard water, if the extremely addition 200ml that the foam volume rate of change by shown in following formula is tried to achieve
When foam be changed into less than 30%, then may determine that be by dilution（Rinse）Foam can transient compositionss.
Bubble quantitative change rate（%）=（The bubble amount at the bubble amount/initial stage after addition hard water 100ml or 200ml）×100
In addition, hand-made watering can is by the polypropylene wide mouthed bottle of 250ml（AS ONE Corporation are manufactured, and I-Boy is wide
Mouth bottle）Bottom remove about 1/3rd, fix uniformly being provided with 13 diameters about at the peristome of state for eliminating lid
For 2mm hole thin plastics porous plate being made.
[table 1]
[table 2]
[table 3]
[table 4]
[table 5]
[table 6]
[table 7]
The hand washing tableware cleanser compositions of table 8 are modulated using following gradation compositions, following each evaluations are carried out.Will knot
Fruit is shown in table 8.In addition, quality % of the gradation composition in table 8 is the numerical value based on whole effective ingredient.
<Foamability>
Compositionss are diluted into 30 times with 3.5 ° of DH hard water, by pumping up bubbler（One 200 mesh）Make in the graduated cylinder of 500ml
Make 3g foams, the capacity of foam is read by the scale of graduated cylinder（ml）, as foamability.
<Remove the evaluation of soapy feeling easy degree>
In commercially available sponge（Trade name：KIKULON A, KIKULON CO., LTD.）On pick 1g compositionss and 30g
The tap water handss of homoiothermic to 25 DEG C are rubbed 5 times and are allowed to bubble, and clean 5 a diameter of 23cm's using the sponge for having played foam
The two sides of polypropylene plate.Now, each face carries out 5 scourings.Clean 5 afterwards, immediately in the flowing water of 4L/ minutes（Homoiothermic
To 25 DEG C）In with certain speed with handss clean, and be flushed to each plate lotion soapy feeling disappear when.Will be complete
The time that 5, portion plate soapy feeling disappears（Second）As the index of the easy degree for removing soapy feeling.
[table 8]
Claims (59)
1. tableware cleanser compositions are used in a kind of hand washing, wherein,
The hand washing tableware cleanser compositions contain following compositions (a), (b), (c),
(a) composition：Dialkyl sulfosuccinate or 2-Sulfosuccinic acid monoalkyl ester represented by following formulas (1) or (1 ') or
Its salt；
(b) composition：The anion surface active with the alkyl and sulfuric ester alkali that carbon number is 8～21 in addition to (a)
Agent or the anion surfactant with the alkyl and sulphonate-base that carbon number is 8～21 in addition to (a), (b) composition
Content is 1～50 mass %；And
(c) composition：(c1) carbon number is 10～18 fatty acid or its salt, and/or (c2) are 6～18 with carbon number
The alkyl glycerylether of alkyl,
In the case where (c) composition is the fatty acid that (c1) carbon number is 10～18 or its salt, the mass ratio of (c)/(a) is
0.001～11, and the mass ratio of (b)/[(a)+(c)] is 0.01～10,
In the case where (c) composition with carbon number is 6～18 alkyl glycerylether of alkyl for (c2), the matter of (c)/(a)
Amount is more than 0.1 and less than 10 than the mass ratio for more than 0.15 and less than 4, (b)/[(a)+(c)],
Contain or not contain (e) composition, containing (e) composition in the case of its content relative to the content of all surfaces activating agent be
Below 3 mass %, wherein, (e) composition is selected from amine oxide type surfactant, carboxy betaine type surfactant and alkane
Surfactant in alkylolamides type surfactant,
In formula, R1、R2Respectively carbon number is 5～18 alkyl or hydrogen atom, R1、R2In at least one be that carbon number is
5～18 alkyl；A1、A2It is separately alkylidene that carbon number is 2～4；X, y are average addition molal quantity and divide
0～6 independently is not, and x, y are 0 when different；M is inorganic or organic cation.
2. tableware cleanser compositions are used in hand washing as claimed in claim 1, wherein,
In formula (1) or (1 '), R1、R2N-octyl, secondary octyl, decyl, isodecyl and 2- ethylhexyls are selected from respectively
In group.
3. tableware cleanser compositions are used in hand washing as claimed in claim 1 or 2, wherein,
In the case where (a) composition is dialkyl sulfosuccinate or its salt represented by formula (1), it is 0 when x, y are different
And it is 0 or 0.1～2.
4. tableware cleanser compositions are used in hand washing as claimed in claim 1 or 2, wherein,
In the case where (a) composition is dialkyl sulfosuccinate or its salt represented by formula (1), x+y is 0.2～4.
5. tableware cleanser compositions are used in hand washing as claimed in claim 1 or 2, wherein,
In the case where (c) composition with carbon number is 6～18 alkyl glycerylether of alkyl for (c2), [(a)+(c)]/
The mass ratio of [(a)+(b)+(c)] is 0.1～0.9.
6. tableware cleanser compositions are used in hand washing as claimed in claim 5, wherein,
In the case where (c) composition with carbon number is 6～18 alkyl glycerylether of alkyl for (c2), [(a)+(c)]/
The mass ratio of [(a)+(b)+(c)] is 0.1～0.6.
7. tableware cleanser compositions are used in hand washing as claimed in claim 1 or 2, wherein,
B the mass ratio of ()/[(a)+(c)] is 0.01～10.
8. tableware cleanser compositions are used in hand washing as claimed in claim 1 or 2, wherein,
C the mass ratio of ()/(a) is 0.01～10.
9. tableware cleanser compositions are used in hand washing as claimed in claim 1 or 2, wherein,
In the case where (c1) composition is used as (c) composition, containing 1～30 mass % of (a) composition.
10. tableware cleanser compositions are used in hand washing as claimed in claim 1 or 2, wherein,
In the case where (c1) composition is used as (c) composition, containing 1～20 mass % of (a) composition.
11. tableware cleanser compositions are used in hand washing as claimed in claim 1 or 2, wherein,
In the case where (c1) composition is used as (c) composition, containing 2～15 mass % of (a) composition.
12. tableware cleanser compositions are used in hand washing as claimed in claim 1 or 2, wherein,
In the case where (c1) composition is used as (c) composition, containing 4～40 mass % of (b) composition.
Tableware cleanser compositions are used in 13. hand washings as claimed in claim 1 or 2, wherein,
In the case where (c1) composition is used as (c) composition, containing 10～30 mass % of (b) composition.
Tableware cleanser compositions are used in 14. hand washings as claimed in claim 1 or 2, wherein,
In the case where (c1) composition is used as (c) composition, containing 0.1～20 mass % of (c) composition.
Tableware cleanser compositions are used in 15. hand washings as claimed in claim 1 or 2, wherein,
In the case where (c1) composition is used as (c) composition, containing 0.5～10 mass % of (c) composition.
Tableware cleanser compositions are used in 16. hand washings as claimed in claim 1 or 2, wherein,
In the case where (c1) composition is used as (c) composition, containing 1～6 mass % of (c) composition.
Tableware cleanser compositions are used in 17. hand washings as claimed in claim 1 or 2, wherein,
In the case where (c1) composition is used as (c) composition, (b) mass ratio of composition/[(a) composition+(c) compositions] be 3 with
Under.
Tableware cleanser compositions are used in 18. hand washings as claimed in claim 1 or 2, wherein,
In the case where (c1) composition is used as (c) composition, (b) mass ratio of composition/[(a) composition+(c) compositions] be 2 with
Under.
Tableware cleanser compositions are used in 19. hand washings as claimed in claim 1 or 2, wherein,
In the case where (c1) composition is used as (c) composition, (b) mass ratio of composition/[(a) composition+(c) compositions] is 1.6
Below.
Tableware cleanser compositions are used in 20. hand washings as claimed in claim 1 or 2, wherein,
In the case where (c1) composition is used as (c) composition, (a) mass ratio of composition/(b) compositions is 0.3～5.
Tableware cleanser compositions are used in 21. hand washings as claimed in claim 1 or 2, wherein,
In the case where (c1) composition is used as (c) composition, (a) mass ratio of composition/(b) compositions is 0.5～3.
Tableware cleanser compositions are used in 22. hand washings as claimed in claim 1 or 2, wherein,
In the case where (c2) composition is used as (c) composition, containing 1～30 mass % of (a) composition.
Tableware cleanser compositions are used in 23. hand washings as claimed in claim 1 or 2, wherein,
In the case where (c2) composition is used as (c) composition, containing 2～25 mass % of (a) composition.
Tableware cleanser compositions are used in 24. hand washings as claimed in claim 1 or 2, wherein,
In the case where (c2) composition is used as (c) composition, containing 6～20 mass % of (a) composition.
Tableware cleanser compositions are used in 25. hand washings as claimed in claim 1 or 2, wherein,
In the case where (c2) composition is used as (c) composition, containing 5～40 mass % of (b) composition.
Tableware cleanser compositions are used in 26. hand washings as claimed in claim 1 or 2, wherein,
In the case where (c2) composition is used as (c) composition, containing 10～30 mass % of (b) composition.
Tableware cleanser compositions are used in 27. hand washings as claimed in claim 1 or 2, wherein,
In the case where (c2) composition is used as (c) composition, containing 0.5～20 mass % of (c) composition.
Tableware cleanser compositions are used in 28. hand washings as claimed in claim 1 or 2, wherein,
In the case where (c2) composition is used as (c) composition, containing 1～10 mass % of (c) composition.
Tableware cleanser compositions are used in 29. hand washings as claimed in claim 1 or 2, wherein,
In the case where (c2) composition is used as (c) composition, containing 1.5～5 mass % of (c) composition.
Tableware cleanser compositions are used in 30. hand washings as claimed in claim 1 or 2, wherein,
In the case where (c) composition is the fatty acid that (c1) carbon number is 10～18 or its salt, (a) composition/(b) compositions
Mass ratio is 0.1～10；In the case where the carbon number that (c) composition is (c2) alkyl is 6～18 alkyl glycerylether, (a)
The mass ratio of composition/(b) compositions is 0.01～2.
Tableware cleanser compositions are used in 31. hand washings as claimed in claim 1 or 2, wherein,
In the case where (c) composition is (c1) composition, (c) composition is capric acid, lauric acid, myristic acid, Palmic acid, Petiolus Trachycarpi oil
Acid, stearic acid, Oleic acid, linoleic acid, linolenic acid or their salt.
Tableware cleanser compositions are used in 32. hand washings as claimed in claim 1 or 2, wherein,
In the case where (c) composition is (c2) composition, (c) compound of the composition for following formulas (3),
R5-O-(Gly)r-H (3)
In formula, R5The alkyl that carbon number is 6～18 is represented, Gly represents the residue that 2 hydrogen atoms are removed from glycerol, and r is represented
Average addition molal quantity and the number for 1～4.
33. tableware cleanser compositions are used in hand washing as claimed in claim 1 or 2, wherein,
Further contain (d) inorganic compound containing magnesium and/or the Alkylenediamine with the alkylidene that carbon number is 2～6.
Tableware cleanser compositions are used in 34. hand washings as claimed in claim 33, wherein,
D () inorganic compound containing magnesium is the compound selected from magnesium chloride and magnesium sulfate.
Tableware cleanser compositions are used in 35. hand washings as claimed in claim 33, wherein,
The alkylene diamidogen of (d) with the alkylidene that carbon number is 2～6 be ethylenediamine, propane diamine, hexamethylene diamine, cyclohexanediamine, 1,
Double (aminomethyl) hexamethylene of 3-.
Tableware cleanser compositions are used in 36. hand washings as claimed in claim 33, wherein,
D the content of () composition is 1～20 mass % in the composition.
Tableware cleanser compositions are used in 37. hand washings as claimed in claim 33, wherein,
D the content of () composition is 1.5～15 mass % in the composition.
Tableware cleanser compositions are used in 38. hand washings as claimed in claim 33, wherein,
D the content of () composition is 1.5～7 mass % in the composition.
Tableware cleanser compositions are used in 39. hand washings as claimed in claim 1 or 2, wherein,
(b) be selected from the alkyl sulfate salt with the alkyl that carbon number is 8～18, with carbon number be 8～18 alkane
Base and the carbon number with alkylidene be 2 and/or 3 and the average addition molal quantity of alkylidene be 0.1～6 polyoxyalkylene
The polyoxyalkylene alkyl sulfuric acid of base, with carbon number be 8～15 alkyl alkylbenzenesulfonate and carbon atom
Number is the anion surfactant in 10～15 alkane sulfonate.
Tableware cleanser compositions are used in 40. hand washings as claimed in claim 1 or 2, wherein,
Compound of (b) composition for following formulas (2),
R3-O-(R4O)n-SO3M (2)
In formula, R3For the alkyl that carbon number is 8～18, R4For ethylidene and/or propylidene, n be average addition molal quantity and
For the number below more than 06, M is inorganic or organic cation.
Tableware cleanser compositions are used in 41. hand washings as claimed in claim 1 or 2, wherein,
Compound of (b) composition for following formulas (2),
R3-O-(R4O)n-SO3M (2)
In formula, R3For the alkyl that carbon number is 8～15, R4For ethylidene and/or propylidene, n be average addition molal quantity and
For the number below more than 02, M is inorganic or organic cation.
Tableware cleanser compositions are used in 42. hand washings as claimed in claim 41, wherein,
In formula (2), in R4In the case of propylidene, n is less than 1.5 and more than 0.1 number.
Tableware cleanser compositions are used in 43. hand washings as claimed in claim 41, wherein,
In formula (2), in R4In the case of propylidene, n is less than 1.0 and more than 0.2 number.
Tableware cleanser compositions are used in 44. hand washings as claimed in claim 41, wherein,
When the n in formula (2) is 0, R in the compound represented by formula (2), is included3It is the change of the alkyl with branched structure
Compound.
Tableware cleanser compositions are used in 45. hand washings as claimed in claim 1 or 2, wherein,
Relative to the content of all surfaces activating agent in compositionss, (a) total matter of composition, (b) composition and (c) composition
Measure as 50～100 mass %.
Tableware cleanser compositions are used in 46. hand washings as claimed in claim 1 or 2, wherein,
In the case where (c1) composition is used as (c) composition, relative to the content of all surfaces activating agent in compositionss,
A total quality of () composition, (b) composition and (c) composition is 70～100 mass %.
Tableware cleanser compositions are used in 47. hand washings as claimed in claim 1 or 2, wherein,
In the case where (c1) composition is used as (c) composition, relative to the content of all surfaces activating agent in compositionss,
A total quality of () composition, (b) composition and (c) composition is 80～100 mass %.
Tableware cleanser compositions are used in 48. hand washings as claimed in claim 1 or 2, wherein,
E the content of () composition is below 2 mass % relative to the content of all surfaces activating agent.
Tableware cleanser compositions are used in 49. hand washings as claimed in claim 1 or 2, wherein,
E the content of () composition is below 1 mass % relative to the content of all surfaces activating agent.
Tableware cleanser compositions are used in 50. hand washings as claimed in claim 1 or 2, wherein,
E the content of () composition is below 0.5 mass % relative to the content of all surfaces activating agent.
Tableware cleanser compositions are used in 51. hand washings as claimed in claim 1 or 2, wherein,
(e) composition is not contained.
Tableware cleanser compositions are used in 52. hand washings as claimed in claim 1 or 2, wherein,
Contain 1～15 mass % of sulfobetaine type surfactant in the composition.
Tableware cleanser compositions are used in 53. hand washings as claimed in claim 1 or 2, wherein,
Contain 2～10 mass % of sulfobetaine type surfactant in the composition.
Tableware cleanser compositions are used in 54. hand washings as claimed in claim 1 or 2, wherein,
Sulfobetaine type surfactant for alkyl carbon number be 10～18 N- alkyl-N, N- dimethyl-N -s sulphur third
Base ammonium sulfobetaines, N- alkyl-N, N- dimethyl-N -s (2- hydroxyl sulfopropyls) ammonium sulfobetaines, the carbon atom of alkanoyl
Number is 10～18 N- alkanoylamino propyl group-N, N- dimethyl-N -s sulfopropyl ammonium sulfobetaines or N- alkanoylaminos
Propyl group-N, N- dimethyl-N-(2- hydroxyl sulfopropyls) ammonium sulfobetaines.
55. tableware cleanser compositions are used in hand washing as claimed in claim 1 or 2, wherein,
More than a kind in buiyl diglycol, ethanol and Propylene Glycol containing 3～30 mass % in the composition
Water-miscible organic solvent.
Tableware cleanser compositions are used in 56. hand washings as claimed in claim 1 or 2, wherein,
When in the composition containing with Polyethylene Glycol as standard by the weight average molecular weight that gel permeation chromatography is tried to achieve it is
200～3,000 polypropylene glycol or weight average molecular weight are 200～3,000 0.05～10 mass % of Polyethylene Glycol.
Tableware cleanser compositions are used in 57. hand washings as claimed in claim 1 or 2, wherein,
When in the composition containing with Polyethylene Glycol as standard by the weight average molecular weight that gel permeation chromatography is tried to achieve it is
200～3,000 polypropylene glycol or weight average molecular weight are 200～3,000 0.1～5 mass % of Polyethylene Glycol.
Tableware cleanser compositions are used in 58. hand washings as claimed in claim 1 or 2, wherein,
When in the composition containing with Polyethylene Glycol as standard by the weight average molecular weight that gel permeation chromatography is tried to achieve it is
200～3,000 polypropylene glycol or weight average molecular weight are 200～3,000 0.5～3 mass % of Polyethylene Glycol.
A kind of 59. clean methods of tableware, wherein,
Methods described is with the cleaning for having used the tableware cleanser compositions of the hand washing any one of Claims 1 to 58
Liquid hand washing cleaning tableware, is rinsed with water afterwards.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2010-088316 | 2010-04-07 | ||
| JP2010088316 | 2010-04-07 | ||
| JP2010089350 | 2010-04-08 | ||
| JP2010-089350 | 2010-04-08 | ||
| PCT/JP2011/058675 WO2011126037A1 (en) | 2010-04-07 | 2011-04-06 | Detergent composition for dishwashing by hand |
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| Publication Number | Publication Date |
|---|---|
| CN102858932A CN102858932A (en) | 2013-01-02 |
| CN102858932B true CN102858932B (en) | 2017-05-03 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201180017960.3A Expired - Fee Related CN102858932B (en) | 2010-04-07 | 2011-04-06 | Detergent Composition For Dishwashing By Hand |
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| Country | Link |
|---|---|
| CN (1) | CN102858932B (en) |
| TW (1) | TWI609078B (en) |
| WO (1) | WO2011126037A1 (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5373216B1 (en) * | 2013-04-18 | 2013-12-18 | 株式会社 資生堂 | Cleaning composition for pump former |
| JP6472984B2 (en) * | 2014-11-12 | 2019-02-20 | 花王株式会社 | Dishwashing composition for hand washing |
| JP6549383B2 (en) * | 2015-02-10 | 2019-07-24 | 花王株式会社 | Dishwashing composition for hand washing |
| WO2016191237A1 (en) * | 2015-05-22 | 2016-12-01 | The Procter & Gamble Company | Surfactant and detergent compositions containing ethoxylated glycerine |
| JP6629003B2 (en) * | 2015-08-06 | 2020-01-15 | 花王株式会社 | Liquid dishwashing detergent composition |
| JP6614956B2 (en) * | 2015-12-15 | 2019-12-04 | 花王株式会社 | Solid detergent composition for automatic dishwashers |
| JP6771952B2 (en) * | 2015-12-25 | 2020-10-21 | 花王株式会社 | Liquid cleaning agent composition for hard surfaces |
| JP6707294B2 (en) * | 2016-05-27 | 2020-06-10 | 花王株式会社 | How to clean hard surfaces |
| WO2017204148A1 (en) * | 2016-05-27 | 2017-11-30 | 花王株式会社 | Method for washing hard surface |
| SG11202010460SA (en) * | 2018-06-05 | 2020-12-30 | Kao Corp | Liquid detergent composition for tableware and/or kitchen hard articles |
| WO2019235425A1 (en) * | 2018-06-05 | 2019-12-12 | 花王株式会社 | Liquid detergent composition for tableware and/or rigid kitchen articles |
| CN110713867A (en) * | 2018-07-13 | 2020-01-21 | 花王株式会社 | Liquid detergent composition |
| CN112912458B (en) * | 2018-11-22 | 2023-10-03 | 花王株式会社 | Hydrophilizing agent composition |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1989232A (en) * | 2004-07-23 | 2007-06-27 | 宝洁公司 | Liquid detergent composition for improved low temperature grease cleaning and starch soil cleaning |
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| US5015414A (en) * | 1988-09-08 | 1991-05-14 | Kao Corporation | Low-irritant detergent composition containing alkyl saccharide and sulfosuccinate surfactants |
| JPH0742476B2 (en) * | 1988-09-08 | 1995-05-10 | 花王株式会社 | Hypoallergenic detergent composition |
| US5565146A (en) * | 1991-04-15 | 1996-10-15 | Cologate-Palmolive Co. | Light duty liquid detergent compositions |
| JP3617838B2 (en) * | 2003-01-28 | 2005-02-09 | 花王株式会社 | Liquid detergent composition |
-
2011
- 2011-04-06 WO PCT/JP2011/058675 patent/WO2011126037A1/en active Application Filing
- 2011-04-06 CN CN201180017960.3A patent/CN102858932B/en not_active Expired - Fee Related
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1989232A (en) * | 2004-07-23 | 2007-06-27 | 宝洁公司 | Liquid detergent composition for improved low temperature grease cleaning and starch soil cleaning |
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| Publication number | Publication date |
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| CN102858932A (en) | 2013-01-02 |
| TW201202409A (en) | 2012-01-16 |
| TWI609078B (en) | 2017-12-21 |
| WO2011126037A1 (en) | 2011-10-13 |
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