CN102858932A - Detergent Composition For Dishwashing By Hand - Google Patents

Detergent Composition For Dishwashing By Hand Download PDF

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Publication number
CN102858932A
CN102858932A CN2011800179603A CN201180017960A CN102858932A CN 102858932 A CN102858932 A CN 102858932A CN 2011800179603 A CN2011800179603 A CN 2011800179603A CN 201180017960 A CN201180017960 A CN 201180017960A CN 102858932 A CN102858932 A CN 102858932A
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composition
carbonatoms
alkyl
hand washing
salt
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CN102858932B (en
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小西祥博
丸田一成
铃木政宏
青野惠太
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Kao Corp
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Kao Corp
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/37—Mixtures of compounds all of which are anionic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/123—Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

Abstract

Disclosed is a detergent composition for dishwashing by hand which comprises (a) a sulfosuccinic acid di- or monoalkyl ester represented by general formula (1) or (1') or a salt of the ester, (b) 1-50 mass% anionic surfactant (excluding (a)) comprising a C8-21 hydrocarbon group and either a sulfuric ester base or a sulfonic acid base, and (c) an ingredient which is (c1) a C10-18 fatty acid or a salt thereof and/or (c2) an alkyl glyceryl ether in which the alkyl group has 6-18 carbon atoms, wherein the (c)/(a) mass ratio is 0.001-11, and when the ingredient (c) is a C10-18 fatty acid or a salt thereof, then the (b)/[(a)+(c)] mass ratio is 0.01-10.

Description

Hand washing tableware cleanser compositions
Technical field
The present invention relates to hand washing tableware cleanser compositions.
Background technology
For hand washing tableware sanitising agent, pursue the foam persistence that abundant whipability is arranged and cleaning when when cleaning.This whipability/foam persistence is the very important physical property relevant with the cleaning persistence, mainly carries out the exploitation of the sanitising agent of whipability/foam persistence excellence all the time.
In Japanese kokai publication sho 62-215699, the technology that is applicable to the sanitising agent that wash dishes uses that contains that sulfosuccinic acid diesters type tensio-active agent and whipability are high, cleaning capacity is excellent is disclosed.In addition, in Japanese Unexamined Patent Application Publication 2008-507611, disclose the technology of the tableware cleanser compositions that contains sulfosuccinic acid diesters type tensio-active agent and other anion surfactant, and in embodiment, put down in writing as washing assistant and can contain lipid acid.In Japanese kokai publication hei 3-207799, put down in writing the liquid detergent composition that can use the alcohol ester of sulfosuccinate as anion surfactant, can use lipid acid as its foaming inhibitor.
In addition, in TOHKEMY 2004-262955, put down in writing the liquid cleanser composition that contains anion surfactant, amine oxide type tensio-active agent, 2-ethylhexyl list glyceryl ether.
In addition, in TOHKEMY 2006-160869, put down in writing the liquid cleanser composition that contains anion surfactant, magnesium salts, higher fatty acid or its salt.
Summary of the invention
The present invention relates to a kind of hand washing tableware cleanser compositions, described hand washing contains following compositions (a) with the tableware cleanser compositions, (b), (c), (a) represented dialkyl sulfosuccinate of following general formula (1) or (1 ') or sulfo-succinic acid mono alkyl ester or its salt [below, be called (a) composition], (b) carbonatoms that has of 1 ~ 50 quality % is 8 ~ 21 alkyl, with the anion surfactant of sulfuric ester alkali or sulphonate-base (still, (a) except) [below, be called (b) composition], and (c) carbonatoms is 10 ~ 18 lipid acid or its salt, perhaps the carbonatoms of alkyl is 6 ~ 18 alkyl glycerylether [below, be called (c) composition]; Be that carbonatoms is that mass ratio (b)/[(a)+(c)] is 0.01 ~ 10, and mass ratio (c)/(a) is 0.001 ~ 11 in the situation of 10 ~ 18 lipid acid or its salt at (c) composition.
Figure BDA00002228787200021
[in the formula, R 1, R 2Be respectively carbonatoms and be 5 ~ 18 alkyl or hydrogen atom, R 1, R 2In at least one is that carbonatoms is 5 ~ 18 alkyl.A 1, A 2Be respectively 2 ~ 4 alkylidene group independently for carbonatoms, x, y are average addition mole number and are respectively 0 ~ 6 independently.In addition, x, y can not be 0 simultaneously.M is inorganic or organic positively charged ion.]
In addition, the invention still further relates to the hand washing of having used the invention described above and hand-wash the cleaning tableware with the cleaning liquor of tableware cleanser compositions, afterwards the purging method of the tableware that washes of water.
The present invention includes following hand washing tableware cleanser compositions, said composition contains following compositions (a), (b), (c), (a) dialkyl sulfosuccinate or sulfo-succinic acid mono alkyl ester or its salt (carbonatoms of an alkyl is 5 ~ 18), (b) carbonatoms that has of 1 ~ 50 quality % is 8 ~ 21 alkyl, with the anion surfactant of sulfuric ester alkali or sulphonate-base (still, (a) except) and (c) carbonatoms be 10 ~ 18 lipid acid or its salt, (b)/[(a)+(c)] mass ratio is 0.01 ~ 10, and mass ratio (c)/(a) is 0.001 ~ 11.
The present invention also comprises following hand washing tableware cleanser compositions, said composition contains following compositions (a) and (b), (c), (a) dialkyl sulfosuccinate or sulfo-succinic acid mono alkyl ester or its salt (carbonatoms of an alkyl is 5 ~ 18), (b) have carbonatoms be 8 ~ 21 alkyl and sulfuric ester alkali or sulphonate-base anion surfactant (still, (a) except), and (c) have an alkyl glycerylether that carbonatoms is 6 ~ 18 alkyl.
Embodiment
In recent years, from alleviating environmental pressure, effectively utilize the purpose of water resources, the preferred amount that reduces water used in the hand washing washing, the expectation reduce is with the wash-down water after the tableware sanitising agent cleaning.Yet the sanitising agent of general whipability/foam persistence excellence is in order to finish the essential a large amount of water of flushing.Therefore, strongly seek to show abundant whipability and the persistence of foam when cleaning, foam disappears in an instant when flushing, can finish the hand washing tableware sanitising agent of flushing with a small amount of water.Lather collapse when in this, in Japanese kokai publication sho 62-215699, Japanese Unexamined Patent Application Publication 2008-507611 and Japanese kokai publication hei 3-207799, not having fully to consider about flushing.
In addition, in Japanese kokai publication hei 3-207799, the lipid acid of the defoamer of enumerating as " foaming inhibitor " be low whipability when cleaning be purpose, be not given in the enlightenment that contacts of the technology of instantaneous froth breaking when forming constantly very abundant foam with flushing when cleaning.
In addition, it has been generally acknowledged that finishing of flushing is that lather collapse and tableware do not have soapy feeling.But, the sanitising agent of whipability/foam persistence excellence, because its lather collapse is poor, and tableware is satiny all the time, thereby, need a large amount of water in order to finish flushing.Therefore, tight demand shows abundant whipability and the persistence of foam when cleaning, and instantaneous when flushing do not have a soapy feeling, just finishes the hand washing tableware sanitising agent of flushing with a small amount of water.
The consideration of the improvement of soapy feeling when in this, in Japanese kokai publication sho 62-215699 and Japanese Unexamined Patent Application Publication 2008-507611, not having about flushing fully.Although Japanese kokai publication hei 3-207799 is the technology of improving soapy feeling and washability, but in recent years, from alleviating environmental pressure and effectively utilizing the purpose of water resources, require with the water inhibition soapy feeling of less amount and finish the technology of flushing, from this viewpoint, wish to be further improved.
Therefore, the invention reside in provides a kind of and shows abundant whipability and the foam persistence when cleaning when cleaning, instantaneous lather collapse when flushing, just finish the hand washing tableware sanitising agent of flushing with a small amount of water, and/or provide a kind of abundant whipability that when cleaning, shows, instantaneous soapy feeling disappears when flushing, just finishes the hand washing tableware sanitising agent of cleaning with a small amount of water.
According to the present invention, can be provided in the foam persistence that shows abundant whipability when cleaning and cleaning when, instantaneous lather collapse when flushing is just finished the hand washing tableware sanitising agent of flushing with a small amount of water.
＜(a) composition 〉
(a) of the present invention composition is the compound of following general formula (1) or (1 ').
Figure BDA00002228787200041
[in the formula, R 1, R 2To be respectively carbonatoms be 5 ~ 18, be preferably 5 ~ 15, more preferably 5 ~ 13 alkyl or hydrogen atom, R 1, R 2In at least one is that carbonatoms is 5 ~ 18 alkyl.A 1, A 2Independently for carbonatoms is 2 ~ 4, is preferably 2 ~ 3 alkylidene group, x, y are average addition mole number and are respectively 0 ~ 6 independently respectively.In addition, x, y can not be 0 simultaneously.M is inorganic or organic positively charged ion.]
Be in the situation of dialkyl sulfosuccinate or its salt at (a) composition, general formula (1) or the R in (1 ') 1, R 2Can be identical or different, for carbonatoms is 5 ~ 18, is preferably 5 ~ 15, more preferably 5 ~ 13 alkyl.Be in the situation of the represented dialkyl sulfosuccinate of general formula (1) or its salt at (a) composition, A 1, A 2Independently for carbonatoms is 2 ~ 4, is preferably 2 ~ 3 alkylidene group, x, y are average addition mole number and can not are 0 simultaneously, are 0 ~ 6, are preferably 0 or 0.1 ~ 2 respectively.In addition, x+y is preferably 0.1 ~ 12, and more preferably 0.2 ~ 4.In addition, be in the situation of sulfo-succinic acid mono alkyl ester or its salt at (a) composition, general formula (1) or the R in (1 ') 1, R 2In one for carbonatoms is 5 ~ 18, is preferably 5 ~ 15, is more preferably 5 ~ 13 alkyl, another one is hydrogen atom.Be in the situation of the represented sulfo-succinic acid mono alkyl ester of general formula (1) or its salt at (a) composition, A 1, A 2Independently for carbonatoms is 2 ~ 4, is preferably 2 ~ 3 alkylidene group, x, y are average addition mole number and can not are 0 simultaneously, are 0 ~ 6, are preferably 0 or 0.1 ~ 2 respectively.In addition, x+y is preferably 0.1 ~ 12, and more preferably 0.2 ~ 4.R 1, R 2To be preferably respectively carbonatoms be 5 ~ 18, be preferably 5 ~ 15, more preferably 5 ~ 13 alkyl, that is, (a) composition is preferably dialkyl sulfosuccinate or its salt.
In addition, (a) composition is preferably the represented dialkyl sulfosuccinate of general formula (1 ') or sulfo-succinic acid mono alkyl ester or its salt.
General formula (1) or in (1 '), R 1, R 2Be preferably respectively hexyl, octyl group, nonyl, decyl, dodecyl, tridecyl, 2-ethylhexyl, n-octyl, secondary octyl, isopentyl, different nonyl, isodecyl, cyclohexyl, be particularly preferably the group that is selected from n-octyl, secondary octyl, decyl, isodecyl and the 2-ethylhexyl.M is selected from inorganic cation in hydrogen ion, sodium ion, ammonium ion, potassium ion, the magnesium ion, is selected from the organic cation in the hydrochlorate of monoethanolamine, diethanolamine, trolamine, morpholine, is preferably the positively charged ion that is selected from sodium ion, ammonium ion, potassium ion and the magnesium ion.
Be in the situation of dialkyl sulfosuccinate or its salt at (a) composition, as modulation R 1, R 2The method of identical compound limits especially, can reference example such as United States Patent (USP) 2,028,091 in the method for record make, in addition, R 1, R 2Different asymmetric compounds can reference example such as Japanese kokai publication sho 58-24555 make.In the situation of using commercially available compound, the PELEX OT-P(R that can use Kao Corp to make 1, R 2All be the compound of 2-ethylhexyl), the PELEX TR(R that makes of Kao Corp 1, R 2All be the compound of tridecyl), the Luensit A-BO(R that makes of BASF AG 1, R 2All be the compound of 2-ethylhexyl), the AEROSOLAY-100(R that can obtain from Mitsui Cytec Ltd. 1, R 2All be the compound of amyl group), the AEROSOLA-196(R of Mitsui Cytec Ltd. 1, R 2All be the compound of cyclohexyl) etc.As the raw material of (a) composition, can also use on the alcohol of regulation carbonatoms addition that the material of epoxy alkane is arranged.
＜(b) composition 〉
(b) of the present invention composition is 8 ~ 21 alkyl and sulfate group or sulfonic anion surfactant (but except (a) composition) for having carbonatoms.Known such anion surfactant whipability is very excellent, more specifically, be preferably and be selected from that to have carbonatoms be 8 ~ 18, preferred carbonatoms is the alkyl sulfuric ester salt of 8 ~ 15 alkyl, having carbonatoms is 8 ~ 18, preferred carbonatoms be 8 ~ 15 alkyl and the carbonatoms with alkylidene group be 2 and/or 3 and the average addition mole number of alkylidene group be the polyoxyalkylene alkyl sulfuric acid of 0.1 ~ 6 polyoxyalkylenes, has carbonatoms and is the alkylbenzene sulfonate of 8 ~ 15 alkyl, and carbonatoms is the anion surfactant in 8 ~ 15 the alkane sulfonate.As salt, be preferably the inorganic salt that are selected from sodium salt, ammonium salt, sylvite, the magnesium salts, be selected from the organic amine salt in monoethanolamine salt, diethanolamine salt, triethanolamine salt, the alkylbenzyldimethylasaltsum saltsum.
As (b) composition, the viewpoint of the lather collapse the when whipability when cleaning and foam persistence and flushing is preferably the compound of following general formula (2).
R 3-O-(R 4O) n-SO 3M （2）
[in the formula, R 3For carbonatoms is 8 ~ 18, is preferably 8 ~ 15 alkyl, R 4Be ethylidene and/or propylidene, n be average addition mole number and be the number below 6 more than 0, be preferably the number below 2 more than 0.M is inorganic or organic positively charged ion.]
At R 4In the situation for ethylidene, n is preferably the number below 1.5, in addition, is more preferably the number more than 0.3.In addition, at R 4In the situation for propylidene, n is preferably below 1.5, is more preferably the number below 1.0, and in addition, n is preferably more than 0.1, be more preferably the number more than 0.2.In addition, at R 4In the situation for ethylidene and propylidene, n can select respectively from these scopes.
In general formula (2), be that compound preferably comprises R in 0 the situation at n 3Compound for alkyl with branched structure.Be in 0 the situation at n, the branching ratio of the compound of preferred formula (2) [having the total mole number of compound of branched-chain alkyl with respect to the ratio of the total mole number of the compound of general formula (2)] is preferably 15 ~ 100mol%, 40 ~ 100mol% more preferably is particularly preferably the compound of 70 ~ 100mol%.
M in the general formula (2) is selected from inorganic cation in sodium ion, ammonium ion, potassium ion, the magnesium ion, is selected from the organic cation in the hydrochlorate of monoethanolamine, diethanolamine, trolamine, morpholine, is preferably sodium ion, ammonium ion, potassium ion, magnesium ion.
As the modulator approach of the compound of general formula (2), limit especially, for example, according to purpose at R 3On the represented Fatty Alcohol(C12-C14 and C12-C18) of-OH after the oxyethane and/or propylene oxide of addition specified amount, carry out sulphating with the sulfating agent that is selected from sulphur trioxide (liquid or gas), the gas that contains sulphur trioxide, oleum, the chlorsulfonic acid, neutralize to make with the alkaline agent of stipulating.The addition reaction of oxyethane (below, be expressed as EO) and/or propylene oxide (below, be expressed as PO) needs catalyzer, and catalyzer can use the alkali hydroxides such as NaOH, KOH.In addition, can use with the magnesium oxide put down in writing among the Japanese kokai publication hei 8-323200 catalyzer as main component, the former can obtain the wider Voranol EP 2001 of addition mole number distribution, and the latter can obtain having the compound that narrow addition mole number distributes.In addition, can also by as disclosed and control addition mole number distribution with alkaline catalysts and metal oxide catalyst in Japanese kokai publication hei 10-158384.
N in general formula (2) is preferably comprised R in 0 the situation 3In the situation for the compound of alkyl with branched structure, as the R of raw material 3The alcohol that-OH is represented; can enumerate with carbonatoms be the alcohol that obtains of 8 ~ 14 1-olefin hydroformylation (with respect to the methyl branch on the β position of OH base alkyl contain 15 ~ 70mol%); condensation carbonatoms be to reduce the gerber special type alcohol (Guerbet alcohol) that obtains (alcohol of the structure that is 3 ~ 6 alkyl branch with respect to carbonatoms on the β position of OH base contains 100mol%) after 4 ~ 8 the aldehyde; with the dimer hydroformylation of iso-butylene and obtain 3; 5,5-trimethyl hexanol; with the tripolymer hydroformylation of iso-butylene and the higly branched chain tridecanol (branching ratio is 100mol%) that obtains; with oil; coal is the synthol (branching ratio is about the alkyl of 20 ~ 100mol%) of raw material.
In the present invention, as (b) composition most preferably represented compound of general formula (2), i.e. R 4It is the compound of 0.2 ~ 1.0, more preferably 0.4 ~ 0.8 number for propylidene, n.
＜(c) composition 〉
(c) of the present invention composition is that (c1) carbonatoms is 10 ~ 18 lipid acid or its salt, and perhaps the carbonatoms of (c2) alkyl is 6 ~ 18 alkyl glycerylether.Be in the situation of (c1) composition at (c) composition, can enumerate specifically capric acid, lauric acid, tetradecanoic acid, palmitinic acid, Zoomeric acid, stearic acid, oleic acid, linolic acid, linolenic acid and their salt.In addition, also can use Oleum Cocois to form the mixed fatty acids such as lipid acid.Salt as lipid acid, can be for being selected from the inorganic salt in sodium salt, ammonium salt, sylvite, the magnesium salts, be selected from the organic amine salts such as monoethanolamine salt, diethanolamine salt, triethanolamine salt, alkylbenzyldimethylasaltsum saltsum, preferably can enumerate sodium salt, ammonium salt, sylvite, magnesium salts, be more preferably and to enumerate sodium salt, ammonium salt, sylvite.As (c) composition, be more preferably lauric acid, tetradecanoic acid, palmitinic acid or their salt, further be more preferably lauric acid, tetradecanoic acid or their salt, most preferably be tetradecanoic acid or its salt.Therefore, from the viewpoint of latherability and lather collapse, preferred (c) composition contains tetradecanoic acid or its salt, and (c) ratio of tetradecanoic acid or its salt is preferably 30 ~ 100 quality % in the composition, be more preferably 50 ~ 100 quality %, further be more preferably 80 ~ 100 quality %.
(c) of the present invention composition is that the carbonatoms of alkyl is 6 ~ 18, is preferably 8 ~ 12 alkyl glycerylether.Specifically, be preferably the compound of following general formula (3).
R 5-O-（Gly） r-H （3）
[in the formula, R 5The expression carbonatoms is 6 ~ 18 alkyl, and Gly represents to remove the residue of 2 hydrogen atoms from glycerine, and r represents average addition mole number and is 1 ~ 4 number.]
In general formula (3), R 5For carbonatoms is 6 ~ 18, is preferably 7 ~ 12, is more preferably 8 ~ 10 alkyl, can use the straight chained alkyls such as hexyl, heptyl, octyl group, nonyl, decyl, the viewpoint of the soapy feeling when reducing flushing in the present invention preferably has the compound of branched structure, as R 5Concrete alkyl with branched structure more preferably is selected from the group in 2-ethylhexyl, secondary octyl, different nonyl and the isodecyl, is more preferably 2-ethylhexyl or isodecyl, is particularly preferably the 2-ethylhexyl.In general formula (3), r is preferably 1 ~ 3, and more preferably 1 ~ 2, most preferably be the compound of r=1.Particularly preferred compound is R 5Be the 2-ethylhexyl, and the compound of r=1.
The represented structure of Gly is that the 1st of glycerine and the 3rd 's hydroxy combining is with-CH 2CH (OH) CH 2The structure of-expression, perhaps the 1st of glycerine the and the 2nd 's hydroxy combining is with-CH (CH 2OH) CH 2The structure of-expression is according to catalyzer or reaction conditions and difference.
For obtaining the compound of general formula (3), for example can use as carbonatoms is 6 ~ 10 alcohol R 5The alkanol that-OH is represented is used BF 3The method that makes the epoxy compoundss such as epoxyhalopropane or Racemic glycidol react to make Deng acid catalyst or Al catalysts.
For example, in the situation of using 2-Ethylhexyl Alcohol, the 2-ethylhexyl list glyceryl ether that obtains is for containing the mixture just like the multiple resultant of putting down in writing among the TOHKEMY 2001-49291.
＜hand washing tableware cleanser compositions 〉
Hand washing of the present invention with the tableware cleanser compositions by with specified conditions and with having (b) composition of whipability/foam persistence and (a) composition and as (c1) composition of (c) composition, thereby in the higher cleaning water of detergent concentration, show very high whipability and foam persistence, after finishing in cleaning, add wash-down water, instantaneous lather collapse can just be finished flushing with a small amount of water.Although its reason is determined, thinks that composition formation salt is insoluble by the calcium in tap water with (c1), and because the lipid acid aggegation that dilution discharges from micella, insoluble, thereby can be at instantaneous elimination foam.Although lipid acid is known as defoamer, but the foam that the cleanser compositions of the present invention that uses it can obtain enriching when cleaning, can obtain the effect of rapid froth breaking when washing on the other hand, this is from as inscrutable unexpected effect the effect of the lipid acid of defoamer.
Hand washing of the present invention has (b) composition of whipability/foam persistence by use with the tableware cleanser compositions, show very high whipability in can be at the concentration ratio of the sanitising agent higher sanitising agent, but the concentration of sanitising agent is higher, more is difficult to remove its soapy feeling when then washing.In this system, think by and with (a) composition with bulky structure with as (c2) composition of (c) composition, can upset parcel (packing) property of the surfactant layer that is adsorbed on the tableware surface, the soapy feeling when reducing flushing.
Hand washing of the present invention tableware cleanser compositions, using as (c) composition in the situation of (c1) composition, from the viewpoint of latherability, the removal of foam and economy, preferably contain 1 ~ 30 quality %, further preferably contain 1 ~ 20 quality %, particularly preferably contain (a) composition of 2 ~ 15 quality %.In addition, contain (b) composition 1 ~ 50 quality %, be preferably 4 ~ 40 quality %, be more preferably 10 ~ 30 quality %.In addition, the amount that is used for trying to achieve (b) composition of the present invention's quality % and mass ratio etc. is the amount as the acid type compound.In addition, (c) composition preferably contains 0.1 ~ 20 quality %, and more preferably 0.5 ~ 10 quality % is particularly preferably 1 ~ 6 quality %.
In addition, use in the situation of conduct (c) composition use (c1) composition in the tableware cleanser compositions in hand washing of the present invention, viewpoint from whipability, (b) mass ratio of composition/[(a) composition+(c) composition] is more than 0.01, be preferably more than 0.1, more preferably more than 0.3, more preferably more than 0.45, be particularly preferably more than 0.6.On the other hand, from the viewpoint of the removal of foam, this mass ratio is below 10, is preferably below 6, more preferably below 3, more preferably below 2, is particularly preferably below 1.6.
In addition, use in the situation of conduct (c) composition use (c1) composition in the tableware cleanser compositions in hand washing of the present invention, viewpoint from latherability and lather collapse, (c) composition/(a) mass ratio of composition is more than 0.001, be preferably more than 0.01, more preferably more than 0.05, more preferably more than 0.07, be particularly preferably more than 0.09.On the other hand, this mass ratio is below 11, is preferably below 5, is more preferably below 3, is particularly preferably below 1.5.
In addition, use in the situation of (c1) composition as (c) composition in the tableware cleanser compositions in hand washing of the present invention, (a) composition/(b) mass ratio of composition is preferably 0.1 ~ 10, and more preferably 0.3 ~ 5, be more preferably 0.5 ~ 3.
Use in the situation of (c1) composition as (c) composition in the present invention, viewpoint from latherability and the removal of foam, (a) composition, (b) composition and (c) the total quality of composition be preferably 50 ~ 100 quality % with respect to the content of all surfaces promoting agent in the composition, be more preferably 70 ~ 100 quality %, further 80 ~ 100 quality % more preferably.
In addition, hand washing of the present invention is with using in the situation of (c2) composition as (c) composition in the tableware cleanser compositions, remove the viewpoint of the easy degree of soapy feeling during from latherability and flushing, (a) composition that preferably contains 1 ~ 30 quality %, more preferably 2 ~ 25 quality % are particularly preferably 6 ~ 20 quality %.In addition, (b) composition preferably contains 1 ~ 50 quality %, and more preferably 5 ~ 40 quality % are particularly preferably 10 ~ 30 quality %.In addition, be used in the present invention asking the amount of (b) composition of calculating quality % and mass ratio etc. to be the amount as the acid type compound.In addition, hand washing of the present invention tableware cleanser compositions, the viewpoint of the easy degree of the removal soapy feeling during from flushing preferably contains (c) composition 0.5 ~ 20 quality %, and more preferably 1 ~ 10 quality % further is preferably 1.5 ~ 5 quality %.
Use in the situation of (c2) composition as (c) composition in the present invention, from latherability and the viewpoint of removing the easy degree of soapy feeling, (a) composition and (c) composition the total quality with respect to (a) composition in the composition, (b) composition and (c) the total quality of composition (mass ratio of [(a) composition+(c) composition]/[(a) composition of composition+(b)+(c) composition]) be preferably 0.1 ~ 0.9, more preferably 0.2 ~ 0.8, further more preferably 0.3 ~ 0.7, be particularly preferably 0.4 ~ 0.6.
In addition, use in the situation of (c2) composition in hand washing of the present invention as (c) composition with the tableware cleanser compositions, from latherability and the viewpoint that prevents soapy feeling, (b) mass ratio of composition/[(a) composition+(c) composition] is preferably more than 0.01, more preferably more than 0.1, be more preferably more than 0.5, be particularly preferably more than 1.In addition, this mass ratio is preferably below 20, more preferably below 15, is more preferably below 10, is particularly preferably below 5.
In addition, use in the situation of (c2) composition as (c) composition in the present invention hand-washes with the tableware cleanser compositions, from latherability and the viewpoint that prevents soapy feeling, (c) composition/(a) mass ratio of composition is more than 0.01, be preferably more than 0.1, be more preferably more than 0.15.In addition, this mass ratio is below 10, is preferably below 4, more preferably below 1.5, is particularly preferably below 0.7.
In addition, use in the situation of conduct (c) composition use (c2) composition in the tableware cleanser compositions in hand washing of the present invention, viewpoint from latherability and the removal of foam, (a) composition/(b) mass ratio of composition is preferably 0.01 ~ 2, more preferably 0.03 ~ 1.5, be more preferably 0.1 ~ 1, be particularly preferably 0.3 ~ 0.7.
Use in the situation of (c2) composition as (c) composition in the present invention, from latherability, the removal of foam and the viewpoint that prevents soapy feeling, (a) composition, (b) composition and (c) the total quality of composition be preferably 20 ~ 100 quality % with respect to the content of all surfaces promoting agent in the composition, be more preferably 40 ~ 100 quality %, further 60 ~ 100 quality % more preferably.
Hand washing of the present invention with the tableware cleanser compositions from when flushing instantaneous soapy feeling disappear, just can finish the viewpoint of flushing with a small amount of water, preferably contain (c1) composition and (c2) composition as (c) composition.
Hand washing of the present invention with the tableware cleanser compositions in order to improve the emulsifying capacity to greasy dirt, strengthen cleaning capacity, contain the magnesium mineral compound and/or have the Alkylenediamine that carbonatoms is 2 ~ 6 alkylidene group as (d) composition, preferably contain the magnesium mineral compound.These compounds are the compound with the structure that plays effect required in this invention, namely with (a) composition, (b) composition and produce more weak interaction according at least 2 molecules in other contained anion surfactant of hope and form title complexs, as the common effect of the compound of the interfacial energy of raising emulsifying capacity etc./effect.
As containing the magnesium mineral compound, can enumerate the magnesium salts such as magnesium muriate, sal epsom, magnesium nitrate, magnesium hydroxide, the magnesium oxide etc. such as magnesium chloride, more preferably be selected from the compound of magnesium chloride and sal epsom, further preferred magnesium chloride.In addition, as the Alkylenediamine compound, preferred quadrol, propylene diamine, hexanediamine, cyclohexanediamine, the represented diamines of following formula (4), cyclohexanediamine, 1 more preferably, two (aminomethyl) hexanaphthenes of 3-are more preferably two (aminomethyl) hexanaphthenes of 1,3-.
[in the formula, R 6~ R 17Be respectively carbonatoms and be 1 ~ 3 alkyl, carbonatoms is 1 ~ 3 aminoalkyl, perhaps hydrogen atom, and R 6~ R 17In 2 be 1 ~ 3 aminoalkyl for carbonatoms.]
(d) content of composition is preferably 1 ~ 20 quality % in composition, is more preferably 1.5 ~ 15 quality %, further is more preferably 1.5 ~ 7 quality %.In addition, these (d) compositions may contain crystal water, are the quality of removing crystal water at this represented content.
Hand washing of the present invention with the tableware cleanser compositions as the mineral compound beyond additional may be used (d) composition of (d) composition.As mineral compound, can enumerate sodium-chlor, Repone K, sodium iodide, potassiumiodide, sodium sulfate, vitriolate of tartar, alum etc.
The behavior of the foam among the present invention when when cleaning and flushing is extremely important.In the general Study of hand washing with the tableware cleanser compositions, whipability when considering cleaning/foam persistence is also used the tensio-active agent with foam enhancing effect, but in the present invention, because such tensio-active agent with foam enhancing effect can produce large impact to the lather collapse performance in when flushing, so should be noted that in use.Especially the use as (e) composition be it is noted that (e) composition is the tensio-active agent that is selected from amine oxide type tensio-active agent, carboxybetaine type tensio-active agent and the alkylolamide type tensio-active agent in the present invention.
Can enumerate N-alkanoylamino propyl group-N as the amine oxide type tensio-active agent; N-dimethyl oxidation amine (be lauroyl or myristoyl as alkyloyl), N-alkyl-N, N-dimethyl oxidation amine (be lauryl or myristyl as alkyl).In addition; can enumerate N-alkanoylamino propyl group-N as carboxybetaine type tensio-active agent; N-dimethyl-N-carboxymethyl ammonium trimethyl-glycine, N-alkanoylamino propyl group-N; N-dimethyl-N-(2-hydroxyl sulfopropyl) ammonium trimethyl-glycine, N-alkyl-N; N-dimethyl-N-carboxymethyl ammonium trimethyl-glycine, N-alkyl-N, N-dimethyl-N-(2-hydroxyl sulfopropyl) the ammonium trimethyl-glycine.Further, can enumerate the amidate of the lipid acid such as the alkanolamines such as monoethanolamine, diethanolamine, methyl monoethanolamine and lauric acid, tetradecanoic acid as alkylolamide type tensio-active agent.
The behavior of foam is extremely important among the present invention, use to (e) composition of giving composition foam enhancing effect should be noted that, especially, (e) content of composition is preferably below the 5 quality % with respect to the content of all surfaces promoting agent in the composition, more preferably below the 3 quality %, be more preferably below the 2 quality %, further more preferably below the 1 quality %, further more preferably below the 0.5 quality %, most preferably be and do not contain.
Also can use sultaine type tensio-active agent [hereinafter referred to as (f) composition] as the tensio-active agent with foam enhancing effect in the present invention.Whipability when sultaine type tensio-active agent improves cleaning/foam persistence, but the instantaneous lather collapse performance when not damaging flushing.As sultaine type tensio-active agent; the carbonatoms of preferred alkyl is N-alkyl-N of 10 ~ 18; N-dimethyl-N-sulfopropyl ammonium sultaine, N-alkyl-N; N-dimethyl-N-(2-hydroxyl sulfopropyl) carbonatoms of ammonium sultaine, alkyloyl is N-alkanoylamino propyl group-N of 10 ~ 18; N-dimethyl-N-sulfopropyl ammonium sultaine, N-alkanoylamino propyl group-N, N-dimethyl-N-(2-hydroxyl sulfopropyl) the ammonium sultaine.
(f) content of composition is preferably 0.5 ~ 20 quality % in composition, and more preferably 1 ~ 15 quality % is particularly preferably 2 ~ 10 quality %.In addition, the viewpoint of the lather collapse the when raising of the whipability when cleaning/foam persistence and flushing, (f) mass ratio of composition/[(a) composition+(b) composition] is preferably 0.01 ~ 0.2, and more preferably 0.02 ~ 0.1.
Hand washing of the present invention in order to improve storage stability, preferably contains hydrotropic solvent [below, be called (g) composition] with the tableware cleanser compositions.As hydrotropic solvent, preferred toluenesulphonic acids, xylene monosulfonic acid, isopropyl sulfonic acid or their sodium, potassium or magnesium salts, particularly preferably tosic acid or its salt.(g) content of composition is preferably 0.5 ~ 15 quality % in composition, and more preferably 1 ~ 10 quality % is particularly preferably 1.5 ~ 5 quality %.
Hand washing of the present invention in order to improve storage stability and adjusting viscosity, can contain solvent [below, be called (h) composition] with the tableware cleanser compositions.As the object lesson of solvent, be preferably the water-miscible organic solvent that is selected from ethanol, Virahol, ethylene glycol, propylene glycol, Diethylene Glycol, dipropylene glycol, glycerine, isoamyl glycol, propylene glycol monomethyl ether, propylene glycol list ethyl ether, 3-methyl-3-methoxybutanol, Phenoxyethanol, benzoglycols, phenoxy group Virahol, butyl Diethylene Glycol (Diethylene Glycol single-butyl ether), dibutyl ethylene glycol ether, the benzylalcohol.Wherein, be preferably the water-miscible organic solvent more than a kind that is selected from Diethylene Glycol butyl ether, ethanol and the propylene glycol, more preferably be selected from the water-miscible organic solvent more than a kind in ethanol and the propylene glycol.At this, water-miscible organic solvent refers to that Octanol/water Partition Coefficients (LogPow) is the solvent below 3.5.(h) content of composition is preferably 3 ~ 30 quality % in composition, and more preferably 5 ~ 20 quality % are particularly preferably 10 ~ 15 quality %.
Viewpoint from viscosity adjustment and storage stability, preferably hand washing of the present invention cooperate to be used for preventing in the tableware cleanser compositions gelation polymkeric substance [below, be called (i) composition], that for example puts down in writing in the flat 11-513067 of Japanese Unexamined Patent Application Publication prevents gelation polymer, especially preferably cooperates polyalkylene glycol.Object lesson as the polyalkylene glycol of the polymkeric substance that is used for preventing gelation, the weight average molecular weight of trying to achieve by gel permeation chromatography in the time of can enumerating take polyoxyethylene glycol as standard is 200 ~ 3,000 polypropylene glycol and weight average molecular weight are 200 ~ 3,000 polyoxyethylene glycol.
In addition, as (i) composition, also can use the alkylene oxide adducts of glycerine.The alkylene oxide adducts of glycerine is effective for the film of the tensio-active agent that suppresses to form at the gas-liquid surface of cleanser compositions, particularly preferably in addition on the glycerine average out to 5 ~ 120, be preferably the material of the oxyethane of 10 ~ 50mol, particularly preferably the operating weight molecular-weight average is the ethylene oxide adduct of 500 ~ 4000 glycerine.
(i) content of composition is preferably 0.05 ~ 10 quality % in composition, and more preferably 0.1 ~ 5 quality % is particularly preferably 0.5 ~ 3 quality %.
Hand washing of the present invention is preferably mentioned component dissolution/dispersion/be emulsifiable in the form of the liquid composition in the water with the tableware cleanser compositions, is more preferably the aqueous solution.The water that uses can use ion exchanged water or the distilled water of the metal ingredient of having removed oligodynamical, has perhaps dissolved hypochlorous sterilized water about 0.5 ~ 10ppm etc.
Hand washing of the present invention is preferably 4 ~ 9 with the pH of tableware cleanser compositions under 25 ℃, more preferably 5 ~ 8, being adjusted to such pH can carry out with inorganic alkaline agents such as the mineral acid that is selected from sulfuric acid, hydrochloric acid, phosphoric acid, the organic acid that is selected from citric acid, oxysuccinic acid, toxilic acid, fumaric acid, succsinic acid, sodium hydroxide, potassium hydroxide, magnesium hydroxide, yellow soda ash, salt of wormwood.In the present invention, from the viewpoint of whipability/foam persistence, preferred composition has buffer capacity, and preferably with above-mentioned organic acid and inorganic alkaline agent and usefulness, organic acid is preferably citric acid.Organic acid can be matched with in the composition with the form of sodium salt or sylvite.In addition, be used for regulating the employed compound of pH, use magnesium hydroxide etc. is equivalent to the material of (d) composition as (d) composition.
Hand washing of the present invention is preferably 5 ~ 500mPas with the viscosity of tableware cleanser compositions under 20 ℃, more preferably 10 ~ 300mPas.Viscosity can become to grade with (g) composition, (h) composition, (i) and regulate.
Hand washing of the present invention can contain the compositions such as spices, dyestuff, pigment with the tableware cleanser compositions.
＜hand washing cleaning method 〉
Hand washing of the present invention can be used for the hand washing cleaning of tableware with the tableware cleanser compositions.The cleaning liquor that is used for the hand washing cleaning is to use hand washing of the present invention resulting with the tableware cleanser compositions, can use the stoste of composition or moisture diluent.As concrete hand washing cleaning method, such as composition of the present invention being attached to the liquid that keeps clean on the flexible materials such as moisture sponge, rubbing for several times with hand and bubble, clean tableware.From the viewpoint of high whipability and foam persistence, (a) composition in the cleaning liquor that keeps in the flexible materials, (b) composition and (c) the total concentration of composition be preferably 1,000 ~ 30,000ppm, more preferably 1,000 ~ 20,000ppm, be more preferably 2,000 ~ 10,000ppm.
Add water and wash after cleaning end, for example, the composition that uses among the present invention with respect to 1 mass parts just can make foam fully disappear with the wash-down water of 3.3 ~ 133 mass parts, finishes rapidly flushing.The amount of this wash-down water is for using existing hand washing about 2/3 ~ 1/10 in the situation of cleanser compositions.
Embodiment
Following embodiment narrates enforcement of the present invention.Embodiment describes illustration of the present invention, is not in order to limit the present invention.
Use the hand washing tableware cleanser compositions of following gradation composition modulometer 1 ~ 7, carry out following each and estimate.The results are shown in table 1 ~ 7.In addition, the quality % of the gradation composition in table 1 ~ 7 is based on the numerical value of whole effective constituents.
＜gradation composition 〉
Two (2-ethylhexyl) sodium sulfosuccinates (1): reagent [Kanto Kagaku K. K.]
Two (2-ethylhexyl) sodium sulfosuccinates (2): PELEX OT-P[Kao Corp]
Sulfo-succinic acid diamyl ester sodium: more than the AEROSOL AY-100[effective constituent 97 quality %, obtained by Mitsui Cytec Ltd.]
Sulfo-succinic acid two cyclohexyl sodium: AEROSOL A-196[effective constituent 93 ~ 95 quality % are obtained by Mitsui Cytec Ltd.]
Sulfo-succinic acid double tridecyl ester sodium: PELEX TR[Kao Corp]
Sulfo-succinic acid list decyl isopentyl ester sodium: reagent [Wako Pure Chemical Industries, Ltd.]
Sulfo-succinic acid double focusing oxygen ethene-2-(ethyl hexyl) ester sodium: use the material that is obtained by the esterification of sulfo-succinic acid and polyoxyethylene-2-ethylhexyl ether.Polyoxyethylene-2-ethylhexyl ether obtains for the oxyethane for the 2-Ethylhexyl Alcohol addition 1mol of 1mol.
Dialkyl sulfosuccinate sodium (1): using by the Isalchem123(alkyl is that 12 alkyl and carbonatoms are the mixing of 13 alkyl as carbonatoms, and branching ratio is the branched-chain alcoho of 94 quality %) and the compound that obtains of the esterification of 2-Ethylhexyl Alcohol take mass ratio as 80/20 mixture that mixes and sulfo-succinic acid.(molecular-weight average: 553)
Dialkyl sulfosuccinate sodium (2): use the compound that the esterification take mass ratio as 80/20 mixture that mixes and sulfo-succinic acid obtains by tridecanol and 2-Ethylhexyl Alcohol.(molecular-weight average: 559)
B-1: to the alkyl chain of 1mol be C12 the natural alcohol addition after the PO of 0.6mol, carry out sulfation by sulphur trioxide, with the sodium hydroxide material that (pH that is neutralized to after the dilute with water 10% is 11) obtain that neutralizes.
B-2: lauryl sulfate ester sodium [trade name: EMAL 0, Kao Corp]
B-3: the material that positive decyl sodium sulfovinate [Kanto Kagaku K. K.] and lauryl sulfate ester sodium [trade name: EMAL 0, Kao Corp] are mixed take the ratio of mass ratio as 90/10.
B-4: the material that lauryl sulfate ester sodium [trade name: EMAL 0, Kao Corp] and Trombovar [with the pure pharmaceutical worker's industry of worker Co., Ltd.] are mixed take the ratio of mass ratio as 90/10.
B-5: the material that n-octyl sodium sulfate and lauryl sulfate ester sodium [trade name: EMAL 0, Kao Corp] are mixed take the ratio of mass ratio as 10/90.
B-6: the alkyl chain of 1mol be on the natural alcohol of C12 addition after the PO of 0.4mol, carry out sulfation by sulphur trioxide, with the neutralize material of (pH that is neutralized to after the dilute with water 10% is 11) of sodium hydroxide.
B-7: the alkyl chain of 1mol be on the natural alcohol of C12 addition after the PO of 0.8mol, carry out sulfation by sulphur trioxide, with the neutralize material of (pH that is neutralized to after the dilute with water 10% is 11) of sodium hydroxide.
B-8: the alkyl chain of 1mol be on the natural alcohol of C12 addition after the PO of 1.0mol, carry out sulfation by sulphur trioxide, with the neutralize material of (pH that is neutralized to after the dilute with water 10% is 11) of sodium hydroxide.
B-9: alkyl chain is the C10:C11:C12:C13=10:35:35:20(mass ratio) alkyl benzene sulphonate (ABS) (C after numeral carbonatoms).
B-10: alkane (carbonatoms is 14 ~ 17 secondary alkyl mixing) sodium sulfonate (trade name is that HOSTAPURSAS60, Clariant company make).
B-11: after the alkyl chain of 1mol is the PO of addition 0.6mol on the natural alcohol of C12, carry out sulfation by sulphur trioxide, with the neutralize material of (pH that is neutralized to after the dilute with water 10% is 11) of ammoniacal liquor.
B-12: the alkyl chain at 1mol is the C12/C10/C8=90/5/5(mass ratio) natural alcohol on after the PO of addition 0.6mol, carry out sulfation by sulphur trioxide, with the neutralize material of (pH that is neutralized to after the dilute with water 10% is 11) of sodium hydroxide.
GE-EH:2-ethylhexyl list glyceryl ether (single glyceryl ether 99 quality %)
Nonionic 1: alkyl consist of the C12/C14=60/40(mass ratio) mixed alkyl and the average condensation degree of glucoside be 1.5 alkyl glycoside
Nonionic 2:Softanol 70H(Nippon Shokubai Co., Ltd makes)
Nonionic 3:Softanol 33(Nippon Shokubai Co., Ltd makes)
E-1:N-lauryl-N, N-dimethyl-N-(2-hydroxyl sulfopropyl) (Kao Corp makes the ammonium sultaine: AMPHITOL 20HD)
E-2: lauryl dimethyl amine oxide (Kao Corp, AMPHITOL 20N)
E-3: amine oxide: N-decyl-N, N-dimethyl oxidation amine/N-myristyl-N, N-dimethyl oxidation amine=2/3(mass ratio)
Glycerine EO affixture: weight average molecular weight is the EO affixture of 1,000 glycerine
Polypropylene glycol: weight average molecular weight is 1,000 polypropylene glycol
PTSH 2O: paratoluenesulfonic acid sodium salt 1 hydrate
MgCl 26H 2O: magnesium chloride 6 hydrates
＜latherability (Sclavo evaluation) 〉
Be in the columned Glass Containers of 5cm, high 13cm having added the diameter that 20 diameters are about the plastic ball of 9mm, the usefulness 3.5 ° of DH hard water that add 40ml are diluted to 0.5 quality %(200 doubly) composition.Further, add the 0.04g butter, after the sealing in 15 minutes with temperature regulation to 20 ℃.Glass Containers after the temperature regulation end is installed on washing testing machine (Suga Test Instruments Co., Ltd.), under 20 ℃ environment, stirred 15 minutes, after the end, take out immediately the Glass Containers of installing, measure the height (mm) of foam in the container.1 composition is carried out 2 times estimate, with the latherability (Sclavo evaluation) of mean value as said composition.
＜latherability (initial stage foam volume) and defoaming 〉
With 30 times of composition dilutions, by pumping up bubble container (1 200 order), in the graduated cylinder of 500ml, make the foam of 3g, from its capacity of calibration summary of graduated cylinder, as latherability (initial stage bubble amount) with 3.5 ° of DH hard water.Next, add 3.5 ° of DH hard water of 100ml in the foam by hand-made watering can, measure the foam volume after 30 seconds.In the situation that does not have to disappear at foam, further add 3.5 ° of DH hard water (adding up to 200ml) of 100ml, similarly measure the foam volume after 30 seconds.In addition, for defoaming, in adding 100ml hard water and 200ml hard water, if the foam when adding 200ml of being tried to achieve by the foam volume velocity of variation shown in the following formula becomes below 30%, then can be judged as by the transient composition of dilution (flushing) foam energy.
Bubble quantitative change rate (%)=(adding hard water 100ml or the 200ml bubble amount at bubble amount/initial stage afterwards) * 100
In addition, hand-made watering can is that (AS ONE Corporation makes with the polypropylene of 250ml wide-necked bottle processed, the I-Boy wide-necked bottle) it is about 1/3rd that remove bottom, fixingly at the peristome place of the state of having removed lid evenly has the thin plastics porous plate that 13 diameters are about the hole of 2mm and make.
[table 1]
Figure BDA00002228787200181
[table 2]
Figure BDA00002228787200191
[table 3]
Figure BDA00002228787200201
[table 4]
Figure BDA00002228787200211
[table 5]
Figure BDA00002228787200221
[table 6]
Figure BDA00002228787200222
[table 7]
Figure BDA00002228787200231
Use the hand washing tableware cleanser compositions of following gradation composition modulometer 8, carry out following each and estimate.The results are shown in Table 8.In addition, the quality % of the gradation composition in the table 8 is based on the numerical value of whole effective constituents.
＜latherability 〉
Composition with 30 times of 3.5 ° of DH hard water dilutions, is made the 3g foam by pump bubbler (200 orders) in the graduated cylinder of 500ml, read the capacity (ml) of foam by the scale of graduated cylinder, as latherability.
The evaluation of the easy degree of＜removal soapy feeling 〉
In commercially available sponge (trade name: KIKULON A, KIKULON CO., LTD.) tap water that picks 1g composition and 30g temperature adjustment to 25 ℃ on is rubbed with hand and is made it for 5 times to bubble, and uses this sponge that has played foam to clean the two sides that 5 diameters are the polypropylene plate of 23cm.At this moment, each face carries out 5 scourings.After cleaning 5, in 4L/ minute flowing water (temperature adjustment to 25 ℃), clean with hand with certain speed immediately, and the lotion soapy feeling that is flushed to each plate is when disappearing.The time (second) that whole 5 plate soapy feelings are disappeared is as the index of the easy degree of removing soapy feeling.
[table 8]
Figure BDA00002228787200241

Claims (9)

1. hand washing tableware cleanser compositions, wherein,
Described hand washing contains following compositions (a) and (b), (c) with the tableware cleanser compositions,
(a) composition: the dialkyl sulfosuccinate that following general formula (1) or (1 ') are represented or sulfo-succinic acid mono alkyl ester or its salt;
(b) composition: the carbonatoms that has except (a) of 1 ~ 50 quality % is 8 ~ 21 alkyl and the anion surfactant of sulfuric ester alkali or sulphonate-base; And
(c) composition: (c1) carbonatoms is 10 ~ 18 lipid acid or its salt and/or (c2) has an alkyl glycerylether that carbonatoms is 6 ~ 18 alkyl,
Be that mass ratio (c)/(a) is 0.001 ~ 11 in the situation of 10 ~ 18 lipid acid or its salt for (c1) carbonatoms at (c) composition, and mass ratio (b)/[(a)+(c)] is 0.01 ~ 10,
Figure FDA00002228787100011
In the formula, R 1, R 2Be respectively carbonatoms and be 5 ~ 18 alkyl or hydrogen atom, R 1, R 2In at least one is that carbonatoms is 5 ~ 18 alkyl; A 1, A 2Be respectively 2 ~ 4 alkylidene group independently for carbonatoms; X, y are average addition mole number and are respectively 0 ~ 6 independently, and x, y are not 0 simultaneously; M is inorganic or organic positively charged ion.
2. hand washing as claimed in claim 1 tableware cleanser compositions, wherein,
The mass ratio of [(a)+(c)]/[(a)+(b)+(c)] is 0.1 ~ 0.9.
3. hand washing as claimed in claim 1 or 2 tableware cleanser compositions, wherein,
(b)/[(a)+(c)] mass ratio is 0.01 ~ 20.
4. such as each described hand washing tableware cleanser compositions in the claim 1 ~ 3, wherein,
(c)/(a) mass ratio is 0.01 ~ 10.
5. such as each described hand washing tableware cleanser compositions in the claim 1 ~ 4, wherein,
Be that (a) composition/(b) mass ratio of composition is 0.1 ~ 10 in the situation of 10 ~ 18 lipid acid or its salt for (c1) carbonatoms at (c) composition; Be that (a) composition/(b) mass ratio of composition is 0.01 ~ 2 in the situation of 6 ~ 18 alkyl glycerylether for the carbonatoms of (c2) alkyl at (c) composition.
6. such as each described hand washing tableware cleanser compositions in the claim 1 ~ 5, wherein,
Further containing (d) contains the magnesium mineral compound and/or has the Alkylenediamine that carbonatoms is 2 ~ 6 alkylidene group.
7. such as each described hand washing tableware cleanser compositions in the claim 1 ~ 6, wherein,
(b) have alkyl sulfuric ester salt that carbonatoms is 8 ~ 18 alkyl for being selected from, have carbonatoms be 8 ~ 18 alkyl and the carbonatoms with alkylidene group be 2 and/or 3 and the average addition mole number of alkylidene group be 0.1 ~ 6 polyoxyalkylenes the polyoxyalkylene alkyl sulfuric acid, to have alkylbenzene sulfonate that carbonatoms is 8 ~ 15 alkyl and carbonatoms be anion surfactant in 10 ~ 15 the alkane sulfonate.
8. such as each described hand washing tableware cleanser compositions in the claim 1 ~ 7, wherein,
With respect to the content of all surfaces promoting agent in the composition, (a) composition, (b) composition and (c) the total quality of composition be 50 ~ 100 quality %.
9. the cleaning method of a tableware, wherein,
Described method is that usefulness has used the cleaning liquor hand washing of each described hand washing usefulness tableware cleanser compositions in the claim 1 ~ 8 to clean tableware, and water washes afterwards.
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