CN108350402A

CN108350402A - Hard surface liquid cleaner composition

Info

Publication number: CN108350402A
Application number: CN201680062557.5A
Authority: CN
Inventors: 青野惠太; 渡边义幸; 冈村谕; 西泽伸广
Original assignee: Kao Corp
Current assignee: Kao Corp
Priority date: 2015-12-25
Filing date: 2016-12-20
Publication date: 2018-07-31
Also published as: TWI734721B; HK1257657A1; TW201726904A; EP3395935B1; JP6771952B2; EP3395935A4; JP2017119808A; EP3395935A1

Abstract

The present invention provides a kind of Hard surface liquid cleaner composition, it, which contains (a) specific sulfosuccinate or its salt, (b), has 8 or more and 21 alkyl below of carbon atom number and sulfate group or sulfonic anion surfactant [wherein, (a) except ingredient] 0 mass % is less than 3 mass %, (c) amphoteric surfactant and water, and the mass ratio of (b)/[(a)+(b)+(c)] is 0.3 or less.

Description

Hard surface liquid cleaner composition

Technical field

The present invention relates to a kind of Hard surface liquid cleaner composition, the clean method of hard surface and sprayings to hold Device fills hard surface detergent article.

Background technology

For hand washing dish detergent, it is strongly required the cleaning force to greasy dirt.Especially in plastics sealing container or Lunch box etc. has in the tableware class of hydrophobic surface, including the greasy dirt of the solid fats such as a large amount of butter or lard is difficult to fall off, it is desirable that Higher cleaning force.Thus it is common to use implementing the hot water using about 40 DEG C~45 DEG C or carrying out the clear of the methods such as 2 cleanings Clean method.

A kind of hand washing is disclosed in Japanese Patent Laid-Open 2013-100461 bulletins to be combined with tableware with liquid cleaner Object contains (a) alkyl sulphosuccinates type surfactant with specific content and specific containing ratio, (b) is selected from One or more of alkyl sulfate salt and polyoxyalkylene alkyl sulfuric acid and (c) sulfobetaine type surfactant, And it records and is taken into account at lower temperature (10~35 DEG C) to being attached to tableware class or regulating appliance with hydrophobic surface Deng greasy dirt liquid oil and solid fat cleaning force.

A kind of hand washing is disclosed in Japanese Patent Laid-Open 2013-100462 bulletins to be combined with tableware with liquid cleaner Object, contain (a) alkyl sulphosuccinates or its salt, (b) have carbon atom number 8~21 alkyl and sulfuric ester alkali or 5~35 mass % of anion surfactant [wherein, except (a)] of sulfonate group and (c) sulfobetaine type surface-active Agent, and the duration of foam when showing abundant foaming characteristic and cleaning when tableware cleans is recorded, the foam when rinsing Pop-off is just completed to rinse using a small amount of water.

It has been recorded in Japanese Patent Laid-Open 2013-100461 bulletins, Japanese Patent Laid-Open 2013-100462 bulletins Make hand washing be attached to the flexible materials such as sponge with liquid cleanser composition with tableware to blister, tableware is cleaned.

Invention content

It rubs without using flexible materials such as sponges even if the present invention relates to one kind, that is, even if not applying mechanical force Also it is excellent clean cleaning force can be carried out to the greasy dirt comprising solid fat of the hard surface for the hard article for being attached to plastics etc. The clean method of different Hard surface liquid cleaner composition and hard surface.

The present invention relates to a kind of Hard surface liquid cleaner compositions, contain following (a) ingredient, 0 matter of (b) ingredient % is measured less than 3 mass %, (c) ingredient and water, and (b) quality of ingredient/[(a) ingredient+(b) ingredient+(c) ingredients] Than being 0.3 or less.

＜ (a) ingredients ＞

Sulfosuccinate represented by the following general formula (a1) or its salt

[in formula, R^1a、R^2aIt is each independently 5 or more and 18 alkyl below of carbon atom number；A¹、A²It is each independently carbon original 2 or more and 4 alkylidene below of subnumber, x, y are average addition molal quantity and are each independently 0 or more and 6 or less；M¹For hydrogen original Son or cation.]

＜ (b) ingredients ＞

With 8 or more and 21 alkyl below of carbon atom number and sulfate group or sulfonic anion surfactant [wherein, except (a) ingredient]

＜ (c) ingredients ＞

Amphoteric surfactant selected from one or more of sulfobetaines and carbobetaine

The present invention is in a kind of oil removing Hard surface liquid cleaner composition involved in its one side, containing following (a) ingredient, 0 mass % of (b) ingredient be less than 3 mass %, (c) ingredient and water, and (b) ingredient/[(a) ingredient+(b) at Point+(c) ingredient] mass ratio be 0.3 or less.The hereinafter referred to as feelings of Hard surface liquid cleaner composition of the invention Shape includes the oil removing Hard surface liquid cleaner composition.

＜ (a) ingredients ＞

Sulfosuccinate represented by the following general formula (a1) or its salt

＜ (b) ingredients ＞

＜ (c) ingredients ＞

It is the hard surface liquid for making aforementioned present invention also, the present invention relates to a kind of clean method of hard surface Cleanser compositions are contacted with hard surface.

It is the hard surface liquid for making aforementioned present invention also, the present invention relates to a kind of clean method of hard surface Cleanser compositions are contacted with the hard surface for being attached with greasy dirt.

Also, the present invention relates to a kind of automiser sprays to fill hard surface detergent article, it is make aforementioned present invention hard Matter surface is filled in the container for having sprayer with liquid cleanser composition and forms.

Even if rubbing without using flexible materials such as sponges in accordance with the invention it is possible to provide one kind, that is, even if not applying Add mechanical force also can be clean to the greasy dirt progress comprising solid fat for the article for being attached to the hard surface with plastics etc. The excellent Hard surface liquid cleaner composition of cleaning force, the clean method of hard surface and automiser spray fill hard table Face detergent article.

Specific implementation mode

＜ Hard surface liquid cleaner compositions ＞

The present invention Hard surface liquid cleaner composition by (b) ingredient have 8 or more carbon atom number and The content of 21 alkyl below and sulfate group or sulfonic anion surfactant is provided, can make have 2 (a) ingredient of the higher alkyl of hydrophobicity and the higher sulfate of hydrophily and (c) ingredient as amphoteric surfactant Interaction is stronger.Speculate that surfactant included in Hard surface liquid cleaner composition thus of the invention holds It easily infiltrates into the greasy dirt comprising solid fat, solid fat becomes easy from hard surface and removes, as a result, obtaining cleaning force Promote effect.

Also, in the side for being used to directly contact with hard surface by the Hard surface liquid cleaner composition of the present invention When the situation of method, the concentration of the surfactant applied to hard surface becomes to be above makes itself and hard table using aqueous sponge The situation of face contact.Therefore, the effect generated by the surfactant of the present invention can significantly more be shown.

According to these situations, by using the Hard surface liquid cleaner composition of the present invention, even if using not making It is rubbed, i.e., not applied to the greasy dirt comprising solid fat for being attached to the hard surface of plastics etc. with flexible materials such as sponges The clean method of mechanical force can also obtain excellent cleaning force.

＜ (a) ingredients ＞

(a) ingredient of the present invention is the sulfosuccinate or its salt represented by the following general formula (a1).

[in formula, R^1a、R^2aRespectively 5 or more and 18 alkyl below of carbon atom number；A¹、A²It is each independently carbon atom number 2 Above and 4 alkylidenes below, x, y are average addition molal quantity and are each independently 0 or more and 6 or less；M¹For hydrogen atom or Cation.]

In general formula (a1), R^1a、R^2aBe each independently 5 or more carbon atom number, preferably 6 or more, more preferably 7 or more, simultaneously And 18 or less carbon atom number, preferably 16 or less and then preferably 14 alkyl below, the preferably alkyl of linear chain or branched chain. R^1a、R^2aIndependently, more preferably there is the alkyl of branched structure.

In general formula (a1), A¹、A²It is each independently 2 or more carbon atom number and 4 or less carbon atom number, preferably 3 or less Alkylidene.

In general formula (a1), x, y are average addition molal quantity, for the viewpoint of cleaning force, are each independently 0 or more, simultaneously And 6 or less, preferably 4 or less, more preferably 2 or less, more preferably 0.

Also, x+y is for the viewpoint of cleaning force, preferably 0 or more, and preferably 12 hereinafter, more preferably 6 hereinafter, Preferably 3 hereinafter, be preferably 0 in turn in turn.

In general formula (a1), R^1a、R^2aBe respectively preferably selected from hexyl, octyl, nonyl, decyl, dodecyl, tridecyl, Alkyl in myristyl, 2- ethylhexyls, n-octyl, secondary octyl, isopentyl, isononyl, isodecyl, cyclohexyl, more preferably For the alkyl in n-octyl, secondary octyl, decyl, isodecyl, tridecyl and 2- ethylhexyls, and then more preferably 2- Ethylhexyl, tridecyl, and then more preferably 2- ethylhexyls.

In general formula (a1), M¹For the inorganic cations such as hydrogen atom or sodium ion, ammonium ion, potassium ion, magnesium ion, Dan Yi The organic cations such as hydrochlorate of hydramine, diethanol amine, triethanolamine, morpholine, be preferably selected from sodium ion, ammonium ion, potassium ion, And the inorganic cation in magnesium ion.

It is R as (a) ingredient^1a、R^2aThe preparation method of identical compound, is not particularly limited, such as can refer to the U.S. The method that the 2nd, 028, No. 091 bulletin of patent specification is recorded is manufactured, in addition, R^1a、R^2aDifferent asymmetrical compound examples Japanese Patent Laid-Open No. Sho 58-24555 bulletins are such as can refer to be manufactured.When using the situation of commercially available compound, it can make PELEX OT-P (the R manufactured with flower king (strain)^1a、R^2aBe the compound of 2- ethylhexyls), flower king (strain) manufacture PELEX TR(R^1a、R^2aBe the compound of tridecyl), BASF AG manufacture LuensitA-BO (R^1a、R^2aIt is 2- ethylhexyls Compound), Airrol (エアロー Le) CT-1L (R for manufacturing of eastern nation's chemical industry (strain)^1a、R^2aIt is 2- ethylhexyls Compound), can from Mitsui Cytec Co., Ltd. obtain AEROSOL AY-100 (R^1a、R^2aIt is the chemical combination of amyl Object), can from Mitsui Cytec Co., Ltd. obtain AEROSOL A-196 (R^1a、R^2aIt is the compound of cyclohexyl) etc.. Raw material as (a) ingredient, it is possible to use substance made of the alcohol addition alkylene oxide to specific carbon atom number.

Hard surface liquid cleaner composition about the present invention preferably contains for the viewpoint of cleaning force (a) 0.5 mass % of ingredient or more, more preferably 0.8 mass % or more, and then preferably 1 mass % or more, and then more preferably 1.5 mass % or more, and then more preferably 1.7 mass % or more, also, for reducing the viewpoint of cost of material, preferably Containing 30 mass % of (a) ingredient hereinafter, more preferably 20 mass % are hereinafter, preferably 15 mass % are hereinafter, more excellent in turn in turn 10 mass % are selected as hereinafter, being more preferably 8 mass % in turn hereinafter, being more preferably 5 mass % in turn hereinafter, being more preferably in turn 3 mass % or less.

Furthermore in the present invention, the record (quality % or mass ratio) of the quality in relation to (a) ingredient is set to be based on M¹It is false It is set to the quality (ratio in terms of sodium salt conversion) when sodium.

＜ (b) ingredients ＞

(b) ingredient of the present invention be with 8 or more and 21 alkyl below of carbon atom number, with sulfate group or sulfonic Anion surfactant [wherein, except (a) ingredient].

As the alkyl of (b) ingredient, for the viewpoint of cleaning force, preferably carbon atom number be 8 or more, preferably 10 with Above, 12 or more and 21 or less are more preferably, is preferably 18 or less, more preferably 14 or less and then preferably 12 alkane below Base or aryl.

As the anion surfactant of (b) ingredient, it is preferably selected from alkyl sulfate salt, polyoxyalkylene alkyl sulphur One or more of acid esters salt and alkyl sulfonate.

As the above-mentioned anion surfactant with sulfate group, for the viewpoint of cleaning force, it is however preferred to have Carbon atom number be 8 or more, preferably 10 or more and 21 or less, preferably 18 or less, more preferably 14 or less so that preferably For the alkyl sulfate salt of the alkyl of 12 linear chain or branched chains below.

Also, as the above-mentioned anion surfactant with sulfate group, for the viewpoint of cleaning force, preferably such as Under polyoxyalkylene alkyl sulfuric acid, with carbon atom number be 8 or more, preferably 10 or more and 21 or less, preferably For 18 or less, the alkyl of more preferably 14 or less and then preferably 12 linear chain or branched chains below, and with carbon atom number 2 with Upper and 3 oxyalkylene groups below average addition molal quantitys are preferably 0.1 or more, more preferably 0.3 or more and then are preferably 0.4 or more and preferably 6 or less, 3 or less and then preferably 1.5 polyoxyalkylenes below are more preferably.

Also, being preferably selected from for the viewpoint of cleaning force as with sulfonic above-mentioned anion surfactant Alkylbenzene sulfonate and 8 or more carbon atom number with 6 or more and 15 alkyl below of carbon atom number, preferably 10 or more, simultaneously And 21 or less, preferably 18 or less, more preferably one or more of 14 or less and then preferably 12 alkyl sulfonates below Anion surfactant.

The salt of anion surfactant as (b) ingredient is preferably selected from the nothing of sodium salt, ammonium salt, sylvite, magnesium salts etc. Machine salt, the organic ammonium salt in single ethanol ammonium salt, diethanolammonium salts, tri ethanol ammonium salt, alkylbenzyldimethylasaltsum saltsum etc..

As (b) ingredient, for the viewpoint of fitment stability and foaming characteristic, the preferably chemical combination of the following general formula (b1) Object.

R^1b-O-(R^2bO)_n-SO₃M² (b1)

[in formula, R^1bFor the alkyl of 8 or more and 21 linear chain or branched chain below of carbon atom number, R^2bFor ethylidene and/or Asia Propyl, n are average addition molal quantity and are 0 or more and 6 numbers below；M²It is preferably inorganic or have for hydrogen atom or cation The cation of machine]

In general formula (b1), about R^1b, for the viewpoint of cleaning force, it is 8 or more carbon atom number, is preferably 10 or more, simultaneously And 21 or less, preferably 18 or less, more preferably 14 or less and then preferably 12 linear chain or branched chains below alkyl, preferably For straight chained alkyl.Specifically, R^1bThe alkane being preferably selected from octyl, decyl, dodecyl, tridecyl and myristyl Base, more preferably dodecyl.

In general formula (b1), about n, for the viewpoint of cleaning force, preferably 0.1 or more, more preferably 0.3 or more, into And preferably 0.4 or more and preferably 6 or less, more preferably 3 or less and then preferably 1.5 numbers below.

In general formula (b1), in R^2bFor ethylidene situation when, for the viewpoint of cleaning force, n is preferably 0.1 or more Number, more preferably 0.5 or more, in addition, be preferably 6 or less, more preferably 3 numbers below.

Also, in general formula (b1), in R^2bFor propylidene situation when, for the viewpoint of cleaning force, n is preferably 0.1 or more, More preferably 0.2 or more and then preferably 0.4 or more number, in addition, be preferably 1.5 or less, be more preferably 1.0 or less, Jin Eryou It is selected as 0.8 number below.

Also, in general formula (b1), in R^2bFor the situation of ethylidene and propylidene when, n can respectively be selected from these ranges.

In general formula (b1), M²The inorganic cations such as hydrogen atom or sodium ion, ammonium ion, potassium ion, magnesium ion can be enumerated, The organic cations such as monoethanol ammonium ion, diethanol ammonium ion, triethanol ammonium ion, morpholine, preferably sodium ion, potassium ion, The inorganic cation of ammonium ion, magnesium ion.

The preparation method of compound as general formula (b1), is not particularly limited, such as to R^1bFatty alcohol represented by-OH Depending on the ethylene oxide and/or propylene oxide of purpose addition specific quantity, thereafter, using selected from sulfur trioxide (liquid or gas), contain There is the sulfating agent in the gas, oleum, chlorosulfonic acid of sulfur trioxide to carry out Sulfation, and is carried out using specific alkaline agent It neutralizes and manufactures.The addition reaction of ethylene oxide (hereinafter, being denoted as EO) and/or propylene oxide (hereinafter, being denoted as PO) needs to be catalyzed The alkali metal hydroxides such as NaOH, KOH can be used in agent.Also, can be used described in Japanese Patent Laid-Open 8-323200 bulletins Using magnesia as the catalyst of principal component, the former can obtain addition molal quantity be distributed it is relatively wide polyxyethylated Ether, the latter can obtain the compound being distributed with relatively narrow addition molal quantity.Also, also can be such as Japanese Patent Laid-Open Disclosed in 10-158384 bulletins addition mole is controlled by base catalyst and metal oxide catalyst are used in combination like that Number distribution.

The preferred R in the situation that n is 0 in obtaining general formula (b1)^1bIncluding the compound of the alkyl with branched structure When situation, about the R as raw material^1bAlcohol represented by-OH can be enumerated：By 8 or more and 14 1- alkene below of carbon atom number into The alcohol that row hydroformylation is obtained is (comprising methyl in relative to 15 moles of % or more of alkyl and 70 that OH bases are β progress branches Mole % or less), so that 4 or more and 8 aldehyde below of carbon atom number is condensed after restored and the Guerbet alcohol that obtains (comprising 3 or more and 6 alkyl below of carbon atom number in 100 moles of % of alcohol relative to the structure that OH bases are β progress branches), The dimer of isobutene is subjected to hydroformylation and obtain 3,5,5- trimethyl hexanols, the trimer of isobutene is subjected to hydrogen first It is acylated and obtain multiple-limb tridecanol (branching ratio is 100 moles of %), using oil, coal as the synthol (branching ratio of raw material It is about 20 moles of % or more and 100 mole of % alkyl below).

As (b) ingredient, the preferably compound represented by general formula (b1), and include preferably carbon atom in the present invention 8 or more number and then preferably 10 or more and preferably 18 or less and then preferably 14 or less and then preferably 12 below Straight chained alkyl is as R^1b, including propylidene is as R^2b, n be preferably 0.1 or more and then preferably 0.2 or more so that preferably The compound of 0.4 or more and preferably 1.5 or less and then preferably 1.0 or less and then preferably 0.8 number below.

Furthermore in the present invention, the record (quality % or mass ratio) of the quality in relation to (b) ingredient is set to be based on (b) M in the general formula (b1) of ingredient²It is assumed to the quality (ratio in terms of sodium salt conversion) when sodium.

About the Hard surface liquid cleaner composition of the present invention, for the viewpoint of cleaning force, contain (b) ingredient 0 mass % or more, and it is less than 3 mass %, preferably 2.5 mass % are hereinafter, preferably 2 mass % are hereinafter, excellent in turn in turn 1.5 mass % are selected as hereinafter, preferably 1 mass % is hereinafter, preferably less than 1 mass %, and then preferably 0.5 matter in turn in turn % is measured hereinafter, being preferably less than 0.5 mass % in turn, and then preferably 0.1 mass % hereinafter, be preferably less than 0.1 matter in turn Measure %.(b) content of ingredient is alternatively 0 mass % in the composition.

Also, the Hard surface liquid cleaner composition about the present invention, just uses the present invention's in the form of foam-like For capable of making foam specific volume increased viewpoint when the situation of Hard surface liquid cleaner composition, preferably contain (b) 0.1 mass % of ingredient or more, more preferably 0.3 mass % or more, and then preferably 0.5 mass % or more, and then more preferably 1 Quality % or more.The upper limit value of the situation can be selected from above range.

＜ (c) ingredients ＞

(c) ingredient of the present invention is the amophoteric surface active selected from one or more of sulfobetaines and carbobetaine Agent.For the viewpoint of cleaning force, preferably sulfobetaines.

As sulfobetaines, can enumerate：The carbon atom number of alkyl is preferably 10 or more and preferably 18 or less, more excellent Be selected as 14 N- alkyl-N, N- dimethyl-N-sulfopropyl ammonium sulfobetaines below, the carbon atom number of alkyl be preferably 10 with Upper and preferably 18 or less, more preferably 14 N- alkyl-N, N- dimethyl-N-(2- hydroxyls sulfopropyl) ammonium sulfo group sweet teas below Dish alkali, alkanoyl carbon atom number be preferably 10 or more and preferably 18 or less, more preferably 14 N- alkanoyls amidos below Propyl-N, N- dimethyl-N-sulfopropyl ammonium sulfobetaines, alkanoyl carbon atom number be preferably 10 or more and preferably 18 Below, 14 N- alkanoylaminos propyl-N, N- dimethyl-N-(2- hydroxyls sulfopropyl) ammonium sulfobetaines below are more preferably Alkali.

As carbobetaine, the carbon atom number that can enumerate alkyl is preferably 10 or more and preferably 18 or less, more preferably It is just clear for the compound represented by 14 N- alkyl-N, N- dimethyl-N-carboxymethyl ammonium glycine betaines below or the following general formula (c1) For the viewpoint of clean power, the compound preferably represented by general formula (c1).

(in formula, R^1cIndicate 7 or more and 21 alkyl or alkenyl below of carbon atom number, R^2cIndicate propylidene, R^3cAnd R^4cPoint It is not independent to indicate 1 or more and 3 alkyl below of carbon atom number.)

In general formula (c1), R^1cPreferably 9 or more carbon atom number, more preferably 11 or more and preferably 15 or less, it is more excellent It is selected as 13 alkyl or alkenyls below, preferably nonyl, decyl, undecyl, dodecyl, tridecyl.

In general formula (c1), R^c3And R^c4Independently, preferably methyl.

As the compound represented by general formula (c1), can enumerate：Apricot kernel oil amide groups (almondamido) propyl beet Alkali, wild apricot oleoyl amido (apricotamido) propyl betaine, avocado oleamidopropyl betaine, babassu oil amide groups Propyl betaine, behenyl amido propyl betaine, vegetable seed oleamidopropyl betaine, octyl/caprolactam base propyl sweet tea Dish alkali, COCOAMIDOPROPYL BETAINE, cocounut oil/oleamidopropyl betaine, iso stearin acylaminopropylbetanin, bay Amido propyl betaine, lactoyl amido propyl betaine, ermine oil amido propyl betaine, myristamide propyl beet Alkali, oleamidopropyl betaine, olivamidopropyl base propyl betaine, palmitoleoyl amido (palmamido) propyl beet Alkali, palmityl amido (palmitamido) propyl betaine, ricinoleamide base propyl betaine, sesame oleamidopropyl Glycine betaine, soybean oleamidopropyl betaine, stearoyl amido propyl betaine, butter amido propyl betaine, 11 Octadecenamide base propyl betaine and wheat embryo amido propyl betaine.It is excellent as the compound represented by general formula (c1) It is selected as being selected from lauroyl amido propyl betaine, myristamide propyl betaine, oleamidopropyl betaine and butter One or more of amido propyl betaine.These are the R in general formula (c1)^3cAnd R^4cThe respectively compound of methyl.

Hard surface liquid cleaner composition about the present invention preferably contains for the viewpoint of cleaning force (c) 0.1 mass % of ingredient or more, more preferably 0.3 mass % or more, and then preferably 0.5 mass % or more, and then more preferably For 1 mass % or more, and then more preferably 1.5 mass % or more, also, for reducing the viewpoint of cost of material, preferably Containing 30 mass % of (c) ingredient hereinafter, more preferably 20 mass % are hereinafter, preferably 15 mass % are hereinafter, more excellent in turn in turn 10 mass % are selected as hereinafter, being more preferably 8 mass % in turn hereinafter, being more preferably 5 mass % in turn hereinafter, being more preferably in turn 3 mass % or less.

In the Hard surface liquid cleaner composition of the present invention, about (a) ingredient, (b) ingredient and (c) ingredient Total content, for the viewpoint of cleaning force, preferably 0.6 mass % or more, more preferably 1 mass % or more, and then preferably For 2 mass % or more, and then preferably more than 2 mass %, and then preferably 2.5 mass % or more, and then preferably 3 mass % More than, and then more preferably 4 mass % or more, also, just make the good viewpoint of ejection, reduce the raw material of surfactant at For this viewpoint and the viewpoint of reduction quantity of solvent, preferably 40 mass % are hereinafter, more preferably 35 mass % are hereinafter, excellent in turn 30 mass % are selected as hereinafter, preferably 25 mass % are hereinafter, preferably 20 mass % are hereinafter, be preferably 18 matter in turn in turn in turn % is measured hereinafter, preferably 15 mass % hereinafter, be more preferably 10 mass % or less in turn in turn.The hard surface liquid of the present invention Body cleanser compositions are preferably used for that the present invention of clean method is contacted and carried out with not applying mechanical force with hard surface Hard surface liquid cleaner composition in, can from (a) ingredient, (b) ingredient and (c) ingredient total content remove 0.1 Quality %, 0.64 mass %, 2 mass % and/or 20 mass %.

The present invention Hard surface liquid cleaner composition in, about in all surfaces activating agent (a) ingredient, (b) ingredient and (c) ratio of total content of ingredient, for the viewpoint of cleaning force, preferably 50 mass % or more, more preferably For 60 mass % or more, and then preferably 70 mass % or more, and then more preferably 80 mass % or more, and then more preferably 90 Quality % or more, preferably 100 mass % or less.

In the Hard surface liquid cleaner composition of the present invention, content and (a) ingredient, (b) about (a) ingredient The mass ratio of total content of ingredient and (c) ingredient is the mass ratio of (a) ingredient/[(a) ingredient+(b) ingredient+(c) ingredients], just For the viewpoint of cleaning force, preferably 0.1 or more, more preferably 0.2 or more, and then preferably 0.3 or more, and then preferably 0.35 or more, and then preferably 0.4 or more, also, for identical viewpoint, preferably 0.9 hereinafter, more preferably 0.85 with Under, so preferably 0.8 hereinafter, in turn be preferably 0.75 hereinafter, in turn be preferably 0.7 hereinafter, in turn be preferably 0.65 or less. Furthermore [(a) ingredient+(b) ingredient+(c) ingredients] is that the meaning of (a) ingredient, (b) ingredient and (c) total content of ingredient is (following Mass ratio in it is also identical).

In the Hard surface liquid cleaner composition of the present invention, content and (a) ingredient, (b) about (b) ingredient The mass ratio of total content of ingredient and (c) ingredient is the mass ratio of (b) ingredient/[(a) ingredient+(b) ingredient+(c) ingredients], just It is 0.3 hereinafter, preferably less than 0.3, preferably 0.26 are hereinafter, more preferably 0.2 hereinafter, in turn for the viewpoint of cleaning force Preferably less than 0.2, and then preferably 0.15 hereinafter, be preferably less than 0.15, and then more preferably 0.1 or less in turn.Also, In the Hard surface liquid cleaner composition of the present invention, about (b) ingredient/[(a) ingredient+(b) ingredient+(c) ingredients] Mass ratio can make foam when just in the form of foam-like using the situation of the Hard surface liquid cleaner composition of the present invention It is 0 or more for the viewpoint of the increased foam specific volume of specific volume, preferably 0.03 or more, more preferably 0.05 or more, and then preferably It is 0.07 or more, and then preferably 0.1 or more, and then preferably 0.15 or more, and then preferably 0.2 or more.(b) ingredient/ The mass ratio of [(a) ingredient+(b) ingredient+(c) ingredients] is alternatively 0.

In the Hard surface liquid cleaner composition of the present invention, content and (a) ingredient, (b) about (c) ingredient The mass ratio of total content of ingredient and (c) ingredient is the mass ratio of (c) ingredient/[(a) ingredient+(b) ingredient+(c) ingredients], just For the viewpoint of cleaning force, preferably 0.1 or more, more preferably 0.2 or more, and then preferably 0.3 or more, and then preferably 0.35 or more, and then preferably 0.4 or more, also, for identical viewpoint, preferably 0.9 hereinafter, more preferably 0.85 with Under, so preferably 0.8 hereinafter, in turn be preferably 0.75 hereinafter, in turn be preferably 0.7 hereinafter, in turn be preferably 0.65 or less.

In the Hard surface liquid cleaner composition of the present invention, about the content of (a) ingredient and containing for (c) ingredient The mass ratio of amount is the mass ratio of (a) ingredient/(c) ingredients, for the viewpoint of cleaning force, preferably 0.1 or more, more preferably 0.2 or more, and then preferably 0.3 or more, and then preferably 0.4 or more, and then preferably 0.5 or more, so preferably 0.6 with On, also, for the viewpoint of storage stability and cleaning force, preferably 10 hereinafter, more preferably 8 hereinafter, be preferably 7 in turn Hereinafter, being preferably 6 in turn hereinafter, being preferably 5 in turn hereinafter, being preferably 4 in turn hereinafter, being preferably 3 hereinafter, more excellent in turn in turn 2 are selected as hereinafter, for the viewpoint of storage stability, and then preferably 1 hereinafter, be preferably 0.8 or less in turn.

＜ (d) ingredients ＞

Hard surface liquid cleaner composition about the present invention can contain alkyl for the viewpoint of cleaning force Glycerin ether is used as (d) ingredient.As (d) ingredient, the carbon atom number that can enumerate alkyl is 6 or more and 18 alkyl monoglycerides below Ether.Specifically, it is preferable that for the compound of the following general formula (d1).

R^1d-O-(Gly)_r-H (d1)

[in formula, R^1dIndicate 6 or more and 18 alkyl below of carbon atom number, Gly indicates the structural unit from glycerine, excellent It is selected as indicating to remove residue obtained by 1 hydroxyl and 1 hydrogen atom from glycerine, r indicates 1 or more and 4 numbers below.]

In general formula (d1), R^1dCan enumerate preferably 6 or more carbon atom number, more preferably 8 or more carbon atom number and preferably For 18 or less carbon atom number, more preferably 12 alkyl below of carbon atom number, preferably octyl, 2- ethylhexyls, decyl, 12 Alkyl.R is preferably 1.

Hard surface liquid cleaner composition about the present invention preferably contains for the viewpoint of cleaning force (d) 0.1 mass % of ingredient or more, more preferably 0.2 mass % or more, and then preferably 0.5 mass % or more, and preferably 6 mass % hereinafter, more preferably 4 mass % hereinafter, in turn be preferably 2 mass % or less.

＜ (e) ingredients ＞

About the Hard surface liquid cleaner composition of the present invention, with regard to the viewpoint of cleaning force and fitment stability Speech preferably contains solvent and is used as (e) ingredient.Preferably solvent is preferably 2 or more carbon atom number, more preferably carbon atom number 3 or more and preferably 10 or less carbon atom number, more preferably 8 water-miscible organic solvent below of carbon atom number, as specific Example is more preferably selected from ethyl alcohol, isopropanol, ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, glycerine, isoprene, the third two Alcohol monomethyl ether, dihydroxypropane single-ether, 3- methyl -3- methoxybutanols, phenoxetol, benzoglycols, phenoxy group isopropanol, fourth Water-miscible organic solvent in base diethylene glycol (diethylene glycol monobutyl ether), two butylidene diethylene glycols and benzylalcohol.Wherein, into And the water-miscible organic solvent for one or more of being preferably selected from butyl diglycol, ethyl alcohol and propylene glycol.Herein, so-called water It is 3.5 solvents below that solubleness organic solvent, which refers to Octanol/water Partition Coefficients (LogPow),.

(e) in ingredient, the ratio of butyl diglycol is preferably 25 mass % or more, more preferably 50 mass % or more, Also, preferably 100 mass % or less.

(e) in ingredient, the ratio of ethyl alcohol is preferably 50 mass % hereinafter, more preferably 25 mass % are hereinafter, in turn preferably For 10 mass % or less.

About the Hard surface liquid cleaner composition of the present invention, with regard to the viewpoint of cleaning force and fitment stability Speech preferably contains 0.5 mass % of (e) ingredient or more, more preferably 2 mass % or more, and then preferably 4 mass % or more, Also, preferably 30 mass % hereinafter, more preferably 20 mass % hereinafter, in turn be preferably 10 mass % or less.

When the Hard surface liquid cleaner composition of the present invention contains the situation of (e) ingredient, about (e) ingredient The content mass ratio of total content of ingredient i.e. mass ratio of (e) ingredient/[(a) ingredient+(c) ingredients] with (a) ingredient and (c), For the viewpoint of storage stability and cleaning force, preferably 0.5 or more, more preferably 1 or more, and then preferably 1.2 or more, And then more preferably 1.5 or more, also, with regard to identical viewpoint for, preferably 5 hereinafter, more preferably 4 hereinafter, preferred in turn For 3 hereinafter, being more preferably 2.1 in turn hereinafter, being more preferably 2 or less in turn.

Also, about content and (a) ingredient of (e) ingredient, (b) ingredient and (c) mass ratio of total content of ingredient is (e) The mass ratio of ingredient/[(a) ingredient+(b) ingredient+(c) ingredients], for the viewpoint of storage stability and cleaning force, preferably 0.5 or more, more preferably 1 or more, and then preferably 1.2 or more, and then more preferably 1.5 or more, also, with regard to identical viewpoint For, preferably 5 hereinafter, more preferably 4 hereinafter, in turn be preferably 3 hereinafter, in turn be more preferably 2.1 hereinafter, in turn more preferably It is 2 or less.

＜ (f) ingredients ＞

Hard surface liquid cleaner composition about the present invention can contain for the viewpoint of fitment stability Dissolution aids are used as (f) ingredient.As dissolution aids, toluenesulfonic acid, xylene monosulfonic acid, isopropyl sulfonic acid or these sodium, potassium Or magnesium salts is good, especially p-methyl benzenesulfonic acid or its salt is good.

About the Hard surface liquid cleaner composition of the present invention, for the viewpoint of fitment stability, preferably Containing 0.5 mass % of (f) ingredient or more, more preferably 1 mass % or more, and then preferably 1.5 mass % or more, also, it is excellent 15 mass % are selected as hereinafter, more preferably 10 mass % are hereinafter, be preferably 5 mass % or less in turn.

＜ (g) ingredients ＞

Hard surface liquid cleaner composition about the present invention also may be used for foaming characteristic, the viewpoint of washability Contain 8 or more and 22 aliphatic acid below of carbon atom number or its salt is used as (g) ingredient.

About (g) ingredient of the present invention, with regard to foaming characteristic, washability, cleaning force viewpoint for, preferably carbon atom number 8 Above, 10 or more and preferably 22 or less carbon atom number, more preferably 18 or less and then preferably 14 or less are more preferably Aliphatic acid or its salt.

As (g) ingredient, can enumerate：Octanoic acid, capric acid, lauric acid, myristic acid, palmitic acid, palmitoleic acid, stearic acid, Oleic acid, linoleic acid, leukotrienes and these salt.Also, the fatty acid mixeds such as coconut composition aliphatic acid can also be used.As aliphatic acid Salt, for the inorganic salts selected from sodium salt, sylvite, magnesium salts, ammonium salt, single ethanol ammonium salt, diethanolammonium salts, tri ethanol ammonium salt etc. are organic Amine salt preferably enumerates sodium salt, sylvite, magnesium salts, more preferably sodium salt, sylvite.

As (g) ingredient, preferably capric acid, lauric acid, myristic acid, palmitic acid or these salt, more preferably it is selected from Capric acid, lauric acid, myristic acid or these salt more than one, and then more preferably selected from capric acid, lauric acid or its salt More than one.For the viewpoint of fitment stability, preferably (g) ingredient includes lauric acid or its salt, (g) in ingredient, bay The ratio of acid or its salt is preferably 20 mass % or more, more preferably 50 mass % or more, and then preferably 80 mass % or more, Also, preferably 100 mass % are hereinafter, more preferably 100 mass %.

About the Hard surface liquid cleaner composition of the present invention, for foaming characteristic, the viewpoint of washability, preferably To contain 0 mass % of (g) ingredient or more, also, for the viewpoint of cleaning force, preferably contain 3 mass % of (g) ingredient with Under, more preferably less than 3 mass %, and then preferably 2.5 mass % are hereinafter, preferably 2 mass % are hereinafter, in turn preferably in turn For 1.5 mass % hereinafter, preferably 1 mass % is hereinafter, preferably less than 1 mass %, and then preferably 0.5 matter in turn in turn % is measured hereinafter, being preferably less than 0.5 mass % in turn, and then preferably 0.1 mass % hereinafter, be preferably less than 0.1 matter in turn Measure %.(g) content of ingredient is alternatively 0 mass % in the composition.

Furthermore in the present invention, the record (quality % or mass ratio) of the quality in relation to (g) ingredient is set to be based on aliphatic acid Conversion.

About the Hard surface liquid cleaner composition of the present invention, for foaming characteristic, the viewpoint of washability, preferably Contain (b) ingredient and (g) 0 mass % of ingredient or more to be total, also, for the viewpoint of cleaning force, preferably less than 3 matter % is measured, more preferably 2.5 mass % are hereinafter, preferably 2 mass % are hereinafter, preferably 1.5 mass % are hereinafter, in turn in turn in turn Preferably 1 mass % hereinafter, be preferably less than 1 mass %, and then preferably 0.5 mass % is hereinafter, preferably small in turn in turn In 0.5 mass %, and then preferably 0.1 mass % hereinafter, be preferably less than 0.1 mass % in turn.(b) ingredient and (g) ingredient Total content be alternatively 0 mass % in the composition.

The present invention Hard surface liquid cleaner composition in, about (a) ingredient, (b) ingredient, (c) ingredient and (g) total content of ingredient, for the viewpoint of cleaning force, preferably 0.6 mass % or more, more preferably 1 mass % or more, And then preferably 2 mass % or more, and then preferably 3 mass % or more, and then more preferably 4 mass % or more, also, just drop For the viewpoint of the cost of material of low surfactant and the viewpoint of reduction quantity of solvent, preferably 40 mass % are hereinafter, more preferably For 35 mass % hereinafter, preferably 30 mass % are hereinafter, preferably 25 mass % are hereinafter, be preferably 20 matter in turn in turn in turn % is measured hereinafter, preferably 15 mass % hereinafter, be more preferably 10 mass % or less in turn in turn.

The present invention Hard surface liquid cleaner composition in, about in all surfaces activating agent (a) ingredient, (b) ingredient, (c) ingredient and (g) ratio of total content of ingredient, for the viewpoint of cleaning force, preferably 50 mass % with On, more preferably 60 mass % or more, and then preferably 70 mass % or more, and then more preferably 80 mass % or more, in turn More preferably 90 mass % or more, also, preferably 100 mass % or less.

In the Hard surface liquid cleaner composition of the present invention, content and (a) ingredient, (b) about (a) ingredient Ingredient, (c) ingredient and (g) mass ratio of total content of ingredient be (a) ingredient/[(a) ingredient+(b) ingredient+(c) ingredient+(g) Ingredient] mass ratio, for the viewpoint of cleaning force, preferably 0.1 or more, more preferably 0.2 or more, and then preferably 0.3 More than, and then preferably 0.35 or more, and then preferably 0.4 or more, also, for identical viewpoint, preferably 0.9 with Under, more preferably 0.85 hereinafter, in turn be preferably 0.8 hereinafter, in turn be preferably 0.75 hereinafter, in turn be preferably 0.7 hereinafter, into And preferably 0.65 or less.

In the Hard surface liquid cleaner composition of the present invention, total content about (b) ingredient and (g) ingredient With (a) ingredient, (b) ingredient, (c) ingredient and (g) mass ratio of total content of ingredient be [(b) ingredient+(g) ingredients]/[(a) Ingredient+(b) ingredient+(c) ingredient+(g) ingredients] mass ratio, for the viewpoint of cleaning force, preferably 0.3 hereinafter, more preferably For be less than 0.3, and then preferably 0.26 hereinafter, in turn be preferably 0.2 hereinafter, in turn be preferably less than 0.2, and then preferably 0.15 hereinafter, be preferably less than 0.15, and then more preferably 0.1 or less in turn.Also, the hard surface liquid in the present invention is clear In clean dose of composition, about the mass ratio of [(b) ingredient+(g) ingredients]/[(a) ingredient+(b) ingredient+(c) ingredient+(g) ingredients], Foam specific volume can be made to increase when just in the form of foam-like using the situation of the Hard surface liquid cleaner composition of the present invention It is 0 or more for the viewpoint of big foam specific volume, preferably 0.03 or more, more preferably 0.05 or more, and then preferably 0.07 More than, and then preferably 0.1 or more, and then preferably 0.15 or more, and then preferably 0.2 or more.[(b) ingredient+(g) at Point]/the mass ratio of [(a) ingredient+(b) ingredient+(c) ingredient+(g) ingredients] is alternatively 0.

In the Hard surface liquid cleaner composition of the present invention, content and (a) ingredient, (b) about (c) ingredient Ingredient, (c) ingredient and (g) mass ratio of total content of ingredient be (c) ingredient/[(a) ingredient+(b) ingredient+(c) ingredient+(g) Ingredient] mass ratio, for the viewpoint of cleaning force, preferably 0.1 or more, more preferably 0.2 or more, and then preferably 0.3 More than, and then preferably 0.35 or more, and then preferably 0.4 or more, also, for identical viewpoint, preferably 0.9 with Under, more preferably 0.85 hereinafter, in turn be preferably 0.8 hereinafter, in turn be preferably 0.75 hereinafter, in turn be preferably 0.7 hereinafter, into And preferably 0.65 or less.

The Hard surface liquid cleaner composition of the present invention can contain polyalkylene glycol isogel preventing agent, gather The ingredients such as the tackifier such as acrylic acid, enzyme, fragrance, dyestuff, pigment, fungicide, preservative, pH adjusting agent.

In the Hard surface liquid cleaner composition of the present invention, about the content of solid content ingredient, with regard to cleaning force Viewpoint for, preferably 0.6 mass % or more, more preferably 1 mass % or more, and then preferably 2 mass % or more, in turn Preferably 3 mass % or more, and then more preferably 4 mass % or more, also, just reduce the viewpoint of cost of material and have in using For the viewpoint of ejection when the container of standby sprayer, preferably 60 mass % hereinafter, more preferably 50 mass % hereinafter, into And preferably 45 mass % are hereinafter, preferably 40 mass % are hereinafter, preferably 35 mass % are hereinafter, be preferably in turn in turn in turn 30 mass % hereinafter, be more preferably 28 mass % or less in turn.

Herein, so-called solid content ingredient, be above-mentioned (a)~(c) ingredients and other any ingredients, as other than water at Point.

The Hard surface liquid cleaner composition of the present invention contains water.That is, above-mentioned (a)~(c) ingredients and arbitrarily at Surplus other than point is water.The Hard surface liquid cleaner composition of the present invention preferably contains 30 mass % of water or more, More preferably 50 mass % or more, more preferably 60 mass % or more, and then preferably 70 mass % or more, also, preferably 98 mass % hereinafter, more preferably 95 mass % hereinafter, more preferably 90 mass % or less.Water preferably uses ion exchange Water, sterilization ion exchange water etc..

Hard surface liquid cleaner composition about the present invention is in 25 DEG C of pH value, with regard to the sight of the mildness of opponent Point for, preferably 2 or more, more preferably 4 or more, more preferably 5 or more, also, preferably 10 hereinafter, more preferably 9 with Under, and then preferably 8 or less.

The Hard surface liquid cleaner composition of the present invention is preferably 0.5mPas or more in 20 DEG C of viscosity, more Preferably 1mPas or more, also, preferably 50mPas hereinafter, more preferably 20mPas hereinafter, being preferably in turn 10mPas hereinafter, be more preferably 7mPas hereinafter, being more preferably 5mPas or less in turn in turn.Viscosity can utilize solvent or Dissolution aids etc. are adjusted.

The Hard surface liquid cleaner composition of the present invention is preferably the hard surface use of hard article, and then preferably It is used for the hard surface of the hard article around tableware or kitchen, and then the hard surface of preferably tableware is used.Also, preferably hard The hand washing of the hard surface of matter article is Clean-, and then the hand of the hard surface of the hard article preferably around tableware or kitchen Wash Clean-, and then the hand washing of the preferably hard surface of tableware is Clean-.

Specifically, the Hard surface liquid cleaner composition of the present invention is preferably the hard surface to hard article The detergent of coating, the more preferably detergent to the hard surface coating of the hard article around tableware or kitchen, into And preferably to the detergent of the hard surface coating of tableware.

Also, specifically, the Hard surface liquid cleaner composition of the present invention is preferably the hard to hard article The detergent of surface spray, the more preferably cleaning to the hard surface spraying of the hard article around tableware or kitchen Agent, and then preferably to the detergent of the hard surface spraying of tableware.

As hard article, the food manufacturings machines such as pipe (pipe), part, the hard article around kitchen, meal can be enumerated Tool etc., about the Hard surface liquid cleaner composition of the present invention, for the excellent aspect of the spatter property of solid fat, with Hard article, more preferably tableware around hard article, preferably tableware and kitchen is as cleaning object.

Hard article around kitchen is the article used on the periphery in kitchen, specifically, for foods such as refrigerator, cupboards The place of retention of product, tableware, regulating appliance；The food such as gutter, dressing table, smoke exhaust ventilator, sink, gas oven, micro-wave oven Improve place；And floor or the wall etc. on these periphery.In the present invention, for convenience's sake, these are set as " around kitchen Hard article ".

Also, as tableware, specifically, can enumerate：The so-called tableware such as dish, bowl；Sealing container, bottle etc. preserve container； The regulating appliances such as kitchen knife or chopping board, pot, frying pan, grilled fish frame；What conditioning household electrical appliances such as food processor, mixer etc. were contacted with food materials Component or utensil.In the present invention, for convenience's sake, these are set as " tableware ".

Also, the Hard surface liquid cleaner composition of the present invention is preferably selected from tableware, preserves container, conditioner Tool and conditioning household electrical appliances in article use, and then more preferably selected from dish, bowl, sealing container, bottle, kitchen knife, chopping board, pot, frying pan, Article in grilled fish frame, food processor and mixer is used.

Also, as the hard surface around the hard surface for cleaning object of the invention and then tableware and kitchen and then eating The material of the hard surface of tool can enumerate plastics (comprising silicone resin etc.), metal, pottery, wood and these combination.

The clean method ＞ of ＜ hard surfaces

The clean method of the hard surface of the present invention be make the Hard surface liquid cleaner composition of the present invention with it is hard The clean method of the hard surface of matter surface contact.

That is, being combined with liquid cleaner using the hard surface of the present invention in the clean method of the hard surface of the present invention Object.The preferred mode of the composition is identical as the Hard surface liquid cleaner composition of aforementioned present invention.

The clean method of the hard surface of the present invention can be used as the Hard surface liquid cleaner composition for making the present invention The hard surface contacted with the hard surface for being attached with greasy dirt and then the hard surface that is attached with the greasy dirt comprising solid fat it is clear Clean method and be preferably carried out.

These methods are the Hard surface liquid cleaner composition for making the present invention and the greasy dirt for being attached to hard surface The clean method of the hard surface of contact.

In some way, the present invention provides a kind of clean method of hard surface, is the oil removing for making aforementioned present invention It is contacted with the hard surface for being attached with greasy dirt with Hard surface liquid cleaner composition.

Including the greasy dirt of solid fat is the grease-contained spot of packet, which is in solid under room temperature (such as 20 DEG C).Including It is the greasy dirt comprising solid fat for the greasy dirt typical case of solid fat, and then is the greasy dirt comprising solid fat and liquid oil.With it is above-mentioned The form of the greasy dirt comprising solid fat when Hard surface liquid cleaner composition contacts, which is alternatively, is mixed solid fat And the state of liquid oil.

For the viewpoint of foam specific volume, above-mentioned hard surface liquid can be used in the clean method of hard surface of the invention The mass ratio of (b) ingredient of body cleanser compositions/[(a) ingredient+(b) ingredient+(c) ingredients] is preferably 0.15 or more, more excellent It is selected as 0.2 or more and implements for 0.3 Hard surface liquid cleaner composition below.

Also, for the viewpoint of cleaning force, above-mentioned hard surface can be used to use for the clean method of hard surface of the invention The mass ratio of (b) ingredient of liquid cleanser composition/[(a) ingredient+(b) ingredient+(c) ingredients] be preferably less than 0.2 and Preferably 0 or more Hard surface liquid cleaner composition and implement.

In the clean method of the hard surface of the present invention, make the Hard surface liquid cleaner composition of the present invention with it is hard Matter surface contacts.

Specifically, can enumerate makes above-mentioned Hard surface liquid cleaner composition not dilute and be connect with hard surface Touch, i.e., above-mentioned Hard surface liquid cleaner composition is not diluted and the cleaning side that makes it be contacted with hard surface Method.In turn, it can enumerate and above-mentioned Hard surface liquid cleaner composition be not diluted and makes it and is attached with greasy dirt The clean method of hard surface contact, the cleaning for preferably making it be contacted with the hard surface for being attached with the greasy dirt comprising solid fat Method.

Above-mentioned Hard surface liquid cleaner composition is not diluted and makes it and be attached with comprising solid fat The hard surface contact of greasy dirt refers to making itself and attachment after not purposely being diluted the cleanser compositions using water etc. There is the hard surface contact of the greasy dirt comprising solid fat.For example, making aforesaid liquid cleanser compositions and being attached with water droplet etc. Hard surface adheres to the feelings of water droplet in hard surface after contacting or aforesaid liquid cleanser compositions being made to be contacted with hard surface Shape can be regarded as not being diluted aforesaid liquid cleanser compositions and making it and be attached with the hard of the greasy dirt comprising solid fat Matter surface contacts.

In the present invention, make above-mentioned Hard surface liquid cleaner composition stoste directly, i.e. do not change form and it is attached It in hard surface.For example, make above-mentioned Hard surface liquid cleaner composition be not attached to aqueous sponge and with attachment There is the hard surface contact of the greasy dirt comprising solid fat.After being contacted with hard surface, above-mentioned hard surface cleaning liquid The composition variable of agent composition.That is, being contacted with after hard surface, the group of above-mentioned Hard surface liquid cleaner composition At can be diluted or concentrate.

The present invention hard surface clean method in, also can it is previously prepared the present invention comprising (a) ingredient, (b) ingredient, (c) concentrated composition is diluted and is prepared the hard surface cleaning liquid of the present invention using water by the concentrated composition of ingredient Agent composition, and it is made to be contacted with hard surface.That is, or the present invention is contained (a) ingredient, (b) ingredient, (c) ingredient Concentrated composition using water be diluted and prepare the present invention Hard surface liquid cleaner composition, make the hard surface The clean method of hard surface for not diluted with liquid cleanser composition and being contacted with hard surface.

Also, the present invention hard surface clean method can enumerate make above-mentioned Hard surface liquid cleaner composition with After hard surface contact, mechanical force is not applied and the clean method placed.This method is suitable for hand or tool reaches Position is not easy the cleaning of discreet portions got at.

It is so-called not apply mechanical force and placed, such as refer in addition to the contact of composition, without being used to clean Operation deliberately.For example, the composition of contact is flowed down naturally in the surface of hard surface or shaking not for the purpose of cleaning It is dynamic to be transferred to hard surface etc. and can be regarded as not applying mechanical force and being placed.

That is, the clean method as the present invention, can enumerate without using flexible materials such as sponges, above-mentioned hard surface is made to use Liquid cleanser composition is contacted with hard surface, does not apply mechanical force and the clean method directly placed.

After placement, usually it is rinsed using water.When flushing, applies mechanical force (physical force) using hand etc., also may be used It is rinsed merely with flow.

As the clean method of the present invention, can enumerate makes above-mentioned Hard surface liquid cleaner composition and is attached with packet The hard surface of greasy dirt containing solid fat contacts, and without the cleaning by flexible material, the cleaning by flowing water and passes through Any one of cleaning of ultrasonic wave does not apply mechanical force and the clean method directly placed.That is, as the clear of the present invention Clean method can enumerate the hard table for making above-mentioned Hard surface liquid cleaner composition Yu being attached with the greasy dirt comprising solid fat Face contacts, without using by the frictional force of flexible materials such as sponge, pass through the stream of spray in automatic tableware cleaner etc. Waterpower and any one of vibration by ultrasonic wave do not apply mechanical force and the clean method directly placed.

The present invention hard surface clean method in, preferably make above-mentioned Hard surface liquid cleaner composition with Area 100cm relative to the hard surface as object²Preferably 0.1g or more, more preferably 0.3g or more, Jin Eryou It is selected as 0.4g or more and preferably 5g or less, more preferably 3g or less and then preferably 2g ratios below is contacted, And then it is preferably coated with or sprays.

In the clean method of the hard surface of the present invention, for improving the viewpoint of cleaning force, make hard surface liquid After body cleanser compositions are contacted with hard surface, does not preferably apply mechanical force and place 10 seconds or more, more preferably 20 Second or more, and then preferably 30 seconds or more, and then preferably 40 seconds or more, and then more preferably 50 seconds or more, and then more preferably Be 1 minute or more, also, with regard to shorten cleaning time viewpoint for, preferably 60 minutes hereinafter, more preferably 30 minutes with Under, so preferably 20 minutes hereinafter, more preferably 10 minutes hereinafter, in turn be more preferably 5 minutes or less.When in this respect, The beginning that the time point that above-mentioned composition is initially contacted with hard surface is set as placing.

Furthermore temperature when placement is room temperature, such as can enumerate 10 DEG C or more and 30 DEG C or less.

Also, in the clean method of the hard surface of the present invention, for improving the viewpoint of cleaning force, preferably make above-mentioned liquid Body cleanser compositions contact 10 seconds or more, more preferably 20 seconds or more with the hard surface as cleaning object, and then preferably It is 30 seconds or more, and then preferably 40 seconds or more, and then more preferably 50 seconds or more, and then more preferably 1 minute or more, and And with regard to shorten cleaning time viewpoint for, preferably 60 minutes hereinafter, more preferably 30 minutes hereinafter, in turn be preferably 20 Minute hereinafter, be more preferably 10 minutes hereinafter, more preferably 5 minutes or less in turn.Furthermore the temperature during contact can enumerate room Temperature, such as 10 DEG C or more and 30 DEG C or less.

In the clean method of the hard surface of the present invention, the hard surface for being attached with greasy dirt can also be made to be impregnated in above-mentioned hard The composition is contacted in the liquid cleanser composition of surface, for efficiently improving the viewpoint of cleaning force, preferably The method sprayed or be coated with and contacted with the hard surface for being attached with greasy dirt.

Keep the method that above-mentioned Hard surface liquid cleaner composition is contacted with the hard surface for being attached with greasy dirt preferred To be sprayed or being coated with, droplet-like preferably is made in above-mentioned Hard surface liquid cleaner composition and is sprayed or is made The method being coated at foam-like.Specifically, it is preferable that make above-mentioned hard surface liquid cleaner using spray devices Composition is contacted with the hard surface for being attached with greasy dirt.I.e., it is preferable to use by the hard surface liquid cleaner of the present invention Composition is filled in hard surface detergent article made of having the container of sprayer.The present invention provides a kind of automiser spray Hard surface detergent article is filled, is to be filled in the Hard surface liquid cleaner composition of the present invention to have spraying The container of device forms.Furthermore about the hard surface for being attached with greasy dirt, for playing the viewpoint of effect of the present invention, preferably To be attached with the hard surface for the greasy dirt for including solid fat.

Automiser spray about the present invention fills the hard surface liquid of the filling present invention of hard surface detergent article The container for having sprayer of body cleanser compositions can enumerate trigger-type automiser spray, pump spray container etc. without using spray Hand spraying device, the aerosol etc. using propellant for penetrating agent, are preferably capable content droplet-like or foam is made The trigger sprayer that shape is sprayed or is coated with more preferably has the trigger-type at the mechanism of droplet-like by content spraying Sprayer or the trigger sprayer for having the mechanism (formation of foam mechanism) to form foam.

Hard surface is filled in detergent article in the automiser spray of the present invention, is had the hard table of the present invention using Face sprayed with liquid cleanser composition the situation at the trigger sprayer of the mechanism of droplet-like when, about being put into said combination The injection diameter of the injection nozzle of the automiser spray of object, it is not random, not linear in order to be easy the drop sprayed or sprayed Ground spraying, the area that can be sprayed to be not extremely narrow, preferably 0.1mm or more, more preferably 0.3mm or more and preferably For 2mm or less, more preferably 1mm ranges below.

When using having situation of the spraying at the trigger sprayer of the mechanism of droplet-like, automiser spray of the invention dress Hard surface is preferably 0.1mL or more, more preferably 0.3mL or more with 1 operation spraying with detergent article and is preferably 5mL or less, more preferably 2mL compositions below.

Also, the automiser spray in the present invention fills hard surface in detergent article, has formation of foam mechanism in use Trigger sprayer situation when, preferably the space segment with rotary components and the round in 4~8mm of diameter is provided with The liquid of several rodlike protrusions passes through plate.Herein, so-called rotary components are assigned to the flowing of liquid material by rotary components It rotates and the mechanism finally sprayed from nozzle can refer to Japanese Patent Laid-Open 8-332422 public affairs as its detailed structure Fig. 1 etc. of Fig. 4 (b) of report or Japanese Patent Laid-Open 8-108102 bulletins, Japanese Patent Laid-Open 2002-68265 bulletins.

When using the situation for the trigger sprayer for having formation of foam mechanism, automiser spray of the invention fills hard table Face with detergent article with 1 operation spraying be preferably 0.5mL or more, more preferably 1mL or more and preferably 30mL with Under, more preferably 15mL or less and then preferably 5mL compositions below.

The liquid of another component as formation of foam mechanism by plate the round of 5~7mm of diameter space segment Be provided with preferably 3~8 rodlike protrusions, planar observation by plate situation when, preferably 0.8~1.2mm of width, The rodlike protrusion of the oblong-shaped of 2~4mm of length.Also, rodlike protrusion is relative to the spatial portion in addition to rodlike protrusion Point shared area is preferably 30 area % or more, more preferably 40 area % or more, also, preferably 90 area % hereinafter, More preferably 80 area % are hereinafter, be preferably 70 area % in turn hereinafter, by such liquid being arranged by plate, and foam is to vertical The attachment anelasticity on surface becomes good.

General used container can be used in the container of the automiser spray dress hard surface detergent article of the present invention.Example Such as, it is obtained, can be manufactured by blow molding etc. as raw material using polyethylene or polypropylene, polyethylene terephthalate. About the thickness of container, bottom surface can be different from side, preferably 0.01~2mm, and the capacity of container is preferably 100~1000mL. Be filled in the hard surface liquid agent composition of container amount it is operationally more satisfactory be 200~500mL.Also, liquid is filled out Fill is to reserve in accordance with the gap of common sense and carry out.

The clean method of the hard surface of the present invention is preferably as the hard surface and then tableware of hard article and kitchen The hard surface of the hard article of surrounding and then the clean method of the hard surface of tableware.Also, preferably as hard article The hand washing clean method and then the hand washing clean method of the hard surface of the hard article around tableware and kitchen of hard surface, And then the hand washing clean method of the hard surface of tableware.

The clean method of the hard surface of the present invention with the hard surface of hard article, preferably tableware and kitchen around The hard surface of the hard surface of hard article, more preferably tableware is as cleaning object.

About the hard article around hard article, tableware and kitchen, above-mentioned article can be enumerated.

Also, the clean method of the hard surface of the present invention is preferably to be selected from tableware, preserve container, regulating appliance and tune Keep house electricity article hard surface be object, and then more preferably be selected from dish, bowl, sealing container, bottle, kitchen knife, chopping board, Pot, frying pan, grilled fish frame, food processor and the article in mixer hard surface be object.

The material of the hard surface of the object of clean method about the hard surface as the present invention, can enumerate plastics (including silicone resin etc.), metal, pottery, timber and these combination.

Also, the present invention hard surface clean method can effectively clean be attached to these hard surfaces include The greasy dirt of solid fat.

In the clean method of the hard surface of the present invention, keep the Hard surface liquid cleaner composition of the present invention direct It is contacted with hard surface.Also, due to being placed with the state for contacting above-mentioned composition, in cleaning, without as led to Cross the flexible materials such as sponge cleaned as apply mechanical force operation.Therefore, the clean method of hard surface of the invention The pipe, part and gutter etc. for being equally applicable to food manufacturing machine, refrigerator, cupboard etc. are inconvenient to hand-wash clean adamant The food such as product etc., food, tableware, the place of retention of regulating appliance, dressing table, smoke exhaust ventilator, sink, gas oven, micro-wave oven What the greasy dirt comprising solid fat reached extensively around the kitchens such as the floor or wall on conditioning place and its periphery etc. has hard table The article in face, kitchen knife, skinning machine, parer, slicer, the blade of juicer, food processor the hand washings cleaning such as blade in Be inconvenient to hand-wash clean article and have with dangerous article, water drum, tumbler (tumbler), kettle, tank (pot) etc. The article etc. of complex-shaped part is difficult with clean article of the flexible materials such as sponge etc..Furthermore also can optionally into Row is cleaned.

In turn, the clean method of hard surface of the invention is due to being by the hard surface liquid cleaner group of the present invention It closes object, be preferably the above-mentioned composition of foam-like to be coated on hard surface directly to place, therefore above-mentioned composition can be made Muchly stay in hard surface.

The clean method of the hard surface of the present invention may include utilizing water pair and above-mentioned hard surface liquid cleaner group Hard surface the step of being rinsed of object contact is closed, preferably pair is contacted with above-mentioned Hard surface liquid cleaner composition Hard surface the step of being rinsed after placement using water.

About above-mentioned implementation form, the present invention discloses following Hard surface liquid cleaner composition, hard in turn Clean method, the automiser spray on surface fill hard surface detergent article and purposes.It, can will be of the invention in these modes Hard surface liquid cleaner composition, hard surface clean method and automiser spray fill hard surface detergent Item described in article is mutually suitably applied.

1 ＞ of ＜

A kind of Hard surface liquid cleaner composition, wherein containing following (a) ingredient, 0 mass % of (b) ingredient with Above and it is less than 3 mass %, (c) ingredient and water, and (b) mass ratio of ingredient/[(a) ingredient+(b) ingredient+(c) ingredients] is 0.3 Hereinafter,

＜ (a) ingredients ＞

Sulfosuccinate represented by the following general formula (a1) or its salt,

[in formula, R^1a、R^2aRespectively 5 or more and 18 alkyl below of carbon atom number；A¹、A²It is each independently carbon atom number 2 Above and 4 alkylidenes below, x, y are average addition molal quantity and are each independently 0 or more and 6 or less；M¹For hydrogen atom or Cation ,]

＜ (b) ingredients ＞

With 8 or more and 21 alkyl below of carbon atom number and sulfate group or sulfonic anion surfactant [wherein, except (a) ingredient],

＜ (c) ingredients ＞

Amphoteric surfactant selected from one or more of sulfobetaines and carbobetaine.

2 ＞ of ＜

A kind of oil removing Hard surface liquid cleaner composition, wherein contain following (a) ingredient, 0 matter of (b) ingredient % is measured less than 3 mass %, (c) ingredient and water, and (b) quality of ingredient/[(a) ingredient+(b) ingredient+(c) ingredients] Than for 0.3 hereinafter,

＜ (a) ingredients ＞

Sulfosuccinate represented by the following general formula (a1) or its salt,

＜ (b) ingredients ＞

＜ (c) ingredients ＞

3 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as 2 ＞ of above-mentioned ＜ 1 ＞ or ＜, wherein in general formula (a1), R^1a、R^2aIt is each independently 5 or more carbon atom number, preferably 6 or more, more preferably 7 or more and 18 or less carbon atom number, excellent It is selected as 16 or less and then preferably 14 alkyl below, the preferably alkyl of linear chain or branched chain, the more preferably alkyl of branch.

4 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 1 ＞ of ＜~＜, 3 ＞, wherein general formula (a1) in, A¹、A²It is each independently 2 or more carbon atom number and 4 or less carbon atom number, preferably 3 alkylidenes below.

5 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 1 ＞ of ＜~＜, 4 ＞, wherein general formula (a1) in, x, y are average addition molal quantity, and are each independently 0 or more, also, for 6 hereinafter, preferably 4 hereinafter, more preferably For 2 hereinafter, being more preferably 0 in turn.

6 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 1 ＞ of ＜~＜, 5 ＞, wherein general formula (a1) in, x+y is preferably 0 or more, also, preferably 12 hereinafter, more preferably 6 hereinafter, be preferably 3 hereinafter, in turn more in turn Preferably 0.

7 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 1 ＞ of ＜~＜, 6 ＞, wherein general formula (a1) in, R^1a、R^2aIt is respectively preferably selected from hexyl, octyl, nonyl, decyl, dodecyl, tridecyl, myristyl, 2- The alkyl of ethylhexyl, n-octyl, secondary octyl, isopentyl, isononyl, isodecyl, cyclohexyl, more preferably be selected from n-octyl, The alkyl of secondary octyl, decyl, isodecyl and 2- ethylhexyls, and then preferably 2- ethylhexyls, tridecyl, so it is more excellent It is selected as 2- ethylhexyls.

8 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 1 ＞ of ＜~＜, 7 ＞, wherein general formula (a1) in, M¹Preferably the inorganic cations such as hydrogen atom or sodium ion, ammonium ion, potassium ion, magnesium ion or monoethanolamine, The organic cations such as hydrochlorate of diethanol amine, triethanolamine, morpholine, be more preferably selected from sodium ion, ammonium ion, potassium ion and Inorganic cation in magnesium ion.

9 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 1 ＞ of ＜~＜, 8 ＞, wherein preferably To contain 0.5 mass % of (a) ingredient or more, more preferably 0.8 mass % or more, and then preferably 1 mass % or more, Jin Ergeng Preferably 1.5 mass % or more, and then more preferably 1.7 mass % or more, also, preferably 30 mass % are hereinafter, more preferably For 20 mass % hereinafter, preferably 15 mass % hereinafter, be more preferably 10 mass % hereinafter, being more preferably 8 in turn in turn in turn Quality % hereinafter, be more preferably 5 mass % hereinafter, being more preferably 3 mass % or less in turn in turn.10 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 1 ＞ of ＜~＜, 9 ＞, wherein (b) at Point alkyl be carbon atom number be 8 or more, preferably 10 or more, more preferably 12 or more and 21 or less, preferably 18 with Under, more preferably 14 or less and then preferably 12 alkyl or aryls below.

11 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 1 ＞ of ＜~＜, 10 ＞, wherein (b) Ingredient is the anion selected from one or more of alkyl sulfate salt, polyoxyalkylene alkyl sulfuric acid and alkyl sulfonate Surfactant.

12 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 1 ＞ of ＜~＜, 11 ＞, wherein (b) The anion surfactant that ingredient is a kind chosen from the followings or more：It is 8 or more with carbon atom number, is preferably 10 or more, simultaneously And the alkyl of 21 or less the, alkyl for being preferably 18 or less, being more preferably 14 or less and then preferably 12 linear chain or branched chains below Sulfuric acid；It is 8 or more, preferably 10 or more and 21 or less, preferably 18 or less, more preferably 14 with carbon atom number Below and then the alkyl of preferably 12 linear chain or branched chains below, and there is 2 or more and 3 oxyalkylene below of carbon atom number The average addition molal quantity of base is preferably 0.1 or more, more preferably 0.3 or more and then preferably 0.4 or more and preferably 6 Below, it is more preferably the polyoxyalkylene alkyl sulfuric acid of 3 or less and then preferably 1.5 polyoxyalkylenes below；And it is excellent It is selected as the alkylbenzene sulfonate with 6 or more and 15 alkyl below of carbon atom number；And 8 or more carbon atom number, preferably 10 with It is upper and 21 or less, preferably 18 or less, more preferably 14 or less and then preferably 12 alkyl sulfonates below.

13 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 1 ＞ of ＜~＜, 12 ＞, wherein (b) Ingredient is the compound of the following general formula (b1),

R^1b-O-(R^2bO)_n-SO₃M² (b1)

[in formula, R^1bFor the alkyl of 8 or more and 21 linear chain or branched chain below of carbon atom number, R^2bFor ethylidene and/or Asia Propyl, n are average addition molal quantity and are 0 or more and 6 numbers below；M²It is preferably inorganic or have for hydrogen atom or cation The cation of machine.]

14 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as 13 ＞ of above-mentioned ＜, wherein in general formula (b1), R^1bPreferably 8 or more carbon atom number, more preferably 10 or more and preferably 18 or less, it is more preferably 14 or less and then preferably 12 below The alkyl of linear chain or branched chain, preferably straight chained alkyl.

15 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as 14 ＞ of above-mentioned ＜ 13 ＞ or ＜, wherein in general formula (b1), R^1bFor the alkyl in octyl, decyl, dodecyl, tridecyl and myristyl, preferably dodecyl.

16 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 13 ＞ of ＜~＜, 15 ＞, wherein logical In formula (b1), n is preferably 0.1 or more, is more preferably 0.3 or more and then preferably 0.4 or more and preferably 6 or less, more Preferably 3 or less and then preferably 1.5 numbers below.

17 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 13 ＞ of ＜~＜, 16 ＞, wherein logical In formula (b1), M²For hydrogen atom, inorganic cation or organic cation, preferably hydrogen atom, selected from sodium ion, ammonium ion, potassium Inorganic cation in ion and magnesium ion or selected from monoethanol ammonium ion, diethanol ammonium ion, triethanol ammonium ion, morpholine In organic cation, the more preferably inorganic cation in sodium ion, potassium ion, ammonium ion and magnesium ion.

18 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 1 ＞ of ＜~＜, 17 ＞, wherein contain (b) 0 mass % of ingredient or more, and be less than 3 mass %, preferably 2.5 mass % hereinafter, more preferably 2 mass % hereinafter, into And preferably 1.5 mass % are hereinafter, preferably 1 mass % hereinafter, be preferably less than 1 mass %, and then be preferably in turn in turn 0.5 mass % hereinafter, be preferably less than 0.5 mass %, and then preferably 0.1 mass % hereinafter, be preferably less than in turn in turn 0.1 mass %, or contain 0 mass %.

19 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 1 ＞ of ＜~＜, 18 ＞, wherein preferably To contain 0.1 mass % of (b) ingredient or more, more preferably 0.3 mass % or more, and then preferably 0.5 mass % or more, in turn More preferably 1 mass % or more.

20 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 1 ＞ of ＜~＜, 19 ＞, wherein sulfo group Glycine betaine is sulfobetaines chosen from the followings：The carbon atom number of alkyl is preferably 10 or more, is preferably 18 or less, more preferably 14 N- alkyl-N, N- dimethyl-N-sulfopropyl ammonium sulfobetaines below；The carbon atom number of alkyl is preferably 10 or more, excellent It is selected as 18 or less, more preferably 14 N- alkyl-N, N- dimethyl-N-(2- hydroxyls sulfopropyl) ammonium sulfobetaines below；Alkane The carbon atom number of acyl group is preferably 10 or more, preferably 18 or less, more preferably 14 N- alkanoylaminos propyl-N, N- below Dimethyl-N-sulfopropyl ammonium sulfobetaines；The carbon atom number of alkanoyl is preferably 10 or more, is preferably 18 or less, more preferably For 14 N- alkanoylaminos propyl-N, N- dimethyl-N-(2- hydroxyls sulfopropyl) ammonium sulfobetaines below.

21 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 1 ＞ of ＜~＜, 20 ＞, wherein carbonyl Glycine betaine is that the carbon atom number selected from alkyl is preferably 10 or more, preferably 18 or less, more preferably 14 N- alkyl-N below, The carbobetaine in compound represented by N- dimethyl-N -s carboxymethyl ammonium glycine betaine and the following general formula (c1),

22 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as 21 ＞ of above-mentioned ＜, wherein in general formula (c1), R^1cPreferably 9 or more carbon atom number, more preferably 11 or more and preferably 15 or less, more preferably 13 alkyl or alkenyls below, in turn For nonyl, decyl, undecyl, dodecyl, tridecyl.

23 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as 22 ＞ of above-mentioned ＜ 21 ＞ or ＜, wherein in general formula (c1), R^c3And R^c4Independently, preferably methyl.

24 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 1 ＞ of ＜~＜, 20 ＞, wherein (c) Ingredient is preferably sulfobetaines.

25 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 1 ＞ of ＜~＜, 24 ＞, wherein preferably To contain 0.1 mass % of (c) ingredient or more, more preferably 0.3 mass % or more, and then preferably 0.5 mass % or more, in turn More preferably 1 mass % or more, and then more preferably 1.5 mass % or more, also, preferably 30 mass % are hereinafter, more preferably For 20 mass % hereinafter, preferably 15 mass % hereinafter, be more preferably 10 mass % hereinafter, being more preferably 8 in turn in turn in turn Quality % hereinafter, be more preferably 5 mass % hereinafter, being more preferably 3 mass % or less in turn in turn.

26 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 1 ＞ of ＜~＜, 25 ＞, wherein (a) Ingredient, (b) ingredient and (c) total content of ingredient is preferably 0.6 mass % or more, more preferably 1 mass % or more, Jin Eryou It is selected as 2 mass % or more, and then preferably more than 2 mass %, and then preferably 2.5 mass % or more, and then preferably 3 matter Measure % or more, and then more preferably 4 mass % or more, also, preferably 40 mass % hereinafter, more preferably 35 mass % with Under, and then preferably 30 mass % are hereinafter, preferably 25 mass % are hereinafter, preferably 20 mass % are hereinafter, in turn in turn in turn Preferably 18 mass % are hereinafter, preferably 15 mass % hereinafter, be more preferably 10 mass % hereinafter, preferably can be certainly in turn in turn (a) ingredient, (b) ingredient and (c) total content of ingredient removes 0.1 mass %, 0.64 mass %, 2 mass % and/or 20 matter Measure %.

27 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 1 ＞ of ＜~＜, 26 ＞, wherein all (a) ingredient, (b) ingredient in surfactant and (c) ratio of total content of ingredient is preferably 50 mass % or more, it is more excellent 60 mass % or more, and then preferably 70 mass % or more, and then more preferably 80 mass % or more are selected as, and then more preferably 90 mass % or more, also, preferably 100 mass % or less.

28 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 1 ＞ of ＜~＜, 27 ＞, wherein (a) The mass ratio of ingredient/[(a) ingredient+(b) ingredient+(c) ingredients] is preferably 0.1 or more, and more preferably 0.2 or more, and then preferably Be 0.3 or more, and then preferably 0.35 or more, and then preferably 0.4 or more, also, preferably 0.9 hereinafter, more preferably 0.85 hereinafter, be preferably 0.8 in turn hereinafter, being preferably 0.75 in turn hereinafter, being preferably 0.7 hereinafter, being preferably in turn in turn 0.65 or less.

29 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 1 ＞ of ＜~＜, 28 ＞, wherein (b) The mass ratio of ingredient/[(a) ingredient+(b) ingredient+(c) ingredients] be 0.3 hereinafter, preferably less than 0.3, preferably 0.26 hereinafter, More preferably 0.2 hereinafter, be preferably less than 0.2, and then preferably 0.15 hereinafter, being preferably less than 0.15 in turn, in turn in turn More preferably 0.1 hereinafter, or be 0.

30 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 1 ＞ of ＜~＜, 29 ＞, wherein (b) The mass ratio of ingredient/[(a) ingredient+(b) ingredient+(c) ingredients] be 0 or more, preferably 0.03 or more, more preferably 0.05 with On, and then preferably 0.07 or more, and then preferably 0.1 or more, and then preferably 0.15 or more, and then preferably 0.2 or more, Or it is 0.

31 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 1 ＞ of ＜~＜, 30 ＞, wherein (c) The mass ratio of ingredient/[(a) ingredient+(b) ingredient+(c) ingredients] is preferably 0.1 or more, and more preferably 0.2 or more, and then preferably Be 0.3 or more, and then preferably 0.35 or more, and then preferably 0.4 or more, also, preferably 0.9 hereinafter, more preferably 0.85 hereinafter, be preferably 0.8 in turn hereinafter, being preferably 0.75 in turn hereinafter, being preferably 0.7 hereinafter, being preferably in turn in turn 0.65 or less.

32 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 1 ＞ of ＜~＜, 31 ＞, wherein (a) The mass ratio of ingredient/(c) ingredients is preferably 0.1 or more, and more preferably 0.2 or more, and then preferably 0.3 or more, and then preferably Be 0.4 or more, and then preferably 0.5 or more, and then preferably 0.6 or more, also, preferably 10 hereinafter, more preferably 8 with Under, and then preferably 7 hereinafter, be preferably 6 in turn hereinafter, being preferably 5 in turn hereinafter, being preferably 4 hereinafter, being preferably in turn in turn 3 hereinafter, in turn be more preferably 2 hereinafter, in turn be preferably 1 hereinafter, in turn be preferably 0.8 or less.

33 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 1 ＞ of ＜~＜, 32 ＞, wherein contain Alkyl glycerylether is used as (d) ingredient.

34 ＞ of ＜

The Hard surface liquid cleaner composition that such as 33 ＞ of above-mentioned ＜ are recorded, wherein (d) ingredient is preferably alkyl Carbon atom number is 6 or more and 18 alkyl monoglyceryl ethers below, the more preferably compound of the following general formula (d1),

R^1d-O-(Gly)_r-H (d1)

[in formula, R^1dIndicate that 6 or more and 18 alkyl below of carbon atom number, Gly indicate to remove 1 hydroxyl and 1 from glycerine Residue made of a hydrogen atom, r indicate 1 or more and 4 numbers below.]

35 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as 34 ＞ of above-mentioned ＜, wherein in general formula (d1), R^1dPreferably 6 or more carbon atom number, more preferably 8 or more carbon atom number and preferably 18 or less carbon atom number, more preferably carbon atom number 12 alkyl below.

36 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as 35 ＞ of above-mentioned ＜ 34 ＞ or ＜, wherein in general formula (d1), R^1dThe alkyl being preferably selected from octyl, 2- ethylhexyls, decyl and dodecyl.

37 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 34 ＞ of ＜~＜, 36 ＞, wherein logical In formula (d1), r is preferably 1.

38 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 33 ＞ of ＜~＜, 37 ＞, wherein excellent It is selected as containing 0.1 mass % of (d) ingredient or more, more preferably 0.2 mass % or more, and then preferably 0.5 mass % or more, and And preferably 6 mass % hereinafter, more preferably 4 mass % hereinafter, in turn be preferably 2 mass % or less.

39 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 1 ＞ of ＜~＜, 38 ＞, wherein contain Solvent, preferably water-miscible organic solvent are used as (e) ingredient.

40 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as 39 ＞ of above-mentioned ＜, wherein (e) ingredient is preferably carbon atom 2 or more number, more preferably 3 or more carbon atom number, preferably 10 or less carbon atom number, more preferably 8 water below of carbon atom number Solubleness organic solvent.

41 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of 44 ＞ of above-mentioned ＜ 39 ＞ or ＜, wherein (e) Ingredient is preferably selected from ethyl alcohol, isopropanol, ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, glycerine, isoprene, the third two Alcohol monomethyl ether, dihydroxypropane single-ether, 3- methyl -3- methoxybutanols, phenoxetol, benzoglycols, phenoxy group isopropanol, fourth The water solubility of one or more of base diethylene glycol (diethylene glycol monobutyl ether), two butylidene diethylene glycols and benzylalcohol is organic molten Agent is more preferably selected from the water-miscible organic solvent of one or more of butyl diglycol, ethyl alcohol and propylene glycol, and then preferably For the water-miscible organic solvent selected from one or more of butyl diglycol, ethyl alcohol and propylene glycol.

42 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 39 ＞ of ＜~＜, 41 ＞, wherein excellent It is selected as containing 0.5 mass % of (e) ingredient or more, more preferably 2 mass % or more, and then preferably 4 mass % or more, also, Preferably 30 mass % hereinafter, more preferably 20 mass % hereinafter, in turn be preferably 10 mass % or less.

43 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 39 ＞ of ＜~＜, 42 ＞, wherein (e) The mass ratio of ingredient/[(a) ingredient+(c) ingredients] is preferably 0.5 or more, and more preferably 1 or more, and then preferably 1.2 or more, And then more preferably 1.5 or more, also, preferably 5 hereinafter, more preferably 4 hereinafter, in turn be preferably 3 hereinafter, in turn more preferably For 2.1 hereinafter, being more preferably 2 or less in turn.

44 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 39 ＞ of ＜~＜, 43 ＞, wherein (e) The content of ingredient and (a) ingredient, (b) ingredient and (c) mass ratio of total content of ingredient is (e) ingredient/[(a) ingredient+(b) Ingredient+(c) ingredients] mass ratio be preferably 0.5 or more, more preferably 1 or more, and then preferably 1.2 or more, so more preferably Be 1.5 or more, also, preferably 5 hereinafter, more preferably 4 hereinafter, in turn be preferably 3 hereinafter, in turn be more preferably 2.1 hereinafter, And then more preferably 2 or less.

45 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 1 ＞ of ＜~＜, 44 ＞, wherein contain Dissolution aids are used as (f) ingredient.

46 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as 45 ＞ of above-mentioned ＜, wherein (f) ingredient is preferably toluene sulphur Acid, xylene monosulfonic acid or isopropyl sulfonic acid or these sodium salt, sylvite or magnesium salts, more preferably p-methyl benzenesulfonic acid or Its salt.

47 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as 46 ＞ of above-mentioned ＜ 45 ＞ or ＜, wherein preferably contain (f) 0.5 mass % of ingredient or more, more preferably 1 mass % or more, and then preferably 1.5 mass % or more, and preferably 15 Quality % hereinafter, more preferably 10 mass % hereinafter, in turn be preferably 5 mass % or less.

48 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 1 ＞ of ＜~＜, 47 ＞, wherein contain 8 or more and 22 aliphatic acid below of carbon atom number or its salt are used as (g) ingredient.49 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as 48 ＞ of above-mentioned ＜, wherein (g) ingredient is carbon atom number 8 Above, 10 or more and preferably 22 or less carbon atom number, more preferably 18 or less and then preferably 14 or less are more preferably Aliphatic acid or its salt.

50 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as 49 ＞ of above-mentioned ＜ 48 ＞ or ＜, wherein (g) ingredient is choosing From one or more of capric acid, lauric acid, myristic acid, palmitic acid or these salt, more preferably be selected from capric acid, lauric acid, One or more of myristic acid or these salt, and then more preferably selected from one or more of capric acid, lauric acid or its salt.

51 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 48 ＞ of ＜~＜, 50 ＞, wherein excellent It is selected as containing 0 mass % of (g) ingredient or more, also, preferably 3 mass % are hereinafter, more preferably less than 3 mass %, Jin Eryou 2.5 mass % are selected as hereinafter, preferably 2 mass % are hereinafter, preferably 1.5 mass % are hereinafter, be preferably 1 matter in turn in turn in turn % is measured hereinafter, being preferably less than 1 mass % in turn, and then preferably 0.5 mass % hereinafter, be preferably less than 0.5 matter in turn % is measured, and then preferably 0.1 mass % hereinafter, be preferably less than 0.1 mass %, or contain 0 mass % in turn.

52 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 48 ＞ of ＜~＜, 51 ＞, wherein excellent It is selected as adding up to and contains (b) ingredient and (g) 0 mass % of ingredient or more, also, preferably less than 3 mass %, more preferably 2.5 matter Measure % hereinafter, in turn be preferably 2 mass % hereinafter, in turn be preferably 1.5 mass % hereinafter, in turn be preferably 1 mass % hereinafter, And then preferably less than 1 mass %, and then preferably 0.5 mass % hereinafter, be preferably less than 0.5 mass %, Jin Eryou in turn 0.1 mass % is selected as hereinafter, being preferably less than 0.1 mass % in turn, or contain 0 mass %.

53 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 48 ＞ of ＜~＜, 52 ＞, wherein (a) Ingredient, (b) ingredient, (c) ingredient and (g) total content of ingredient is preferably 0.6 mass % or more, more preferably 1 mass % with On, and then preferably 2 mass % or more, and then preferably 3 mass % or more, and then more preferably 4 mass % or more, also, Preferably 40 mass % hereinafter, more preferably 35 mass % hereinafter, in turn be preferably 30 mass % hereinafter, in turn be preferably 25 matter Measure % hereinafter, in turn be preferably 20 mass % hereinafter, in turn be preferably 15 mass % hereinafter, in turn be more preferably 10 mass % with Under.

54 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 48 ＞ of ＜~＜, 53 ＞, wherein complete (a) ingredient, (b) ingredient, (c) ingredient in portion's surfactant and (g) ratio of total content of ingredient is preferably 50 matter Measure % or more, more preferably 60 mass % or more, and then preferably 70 mass % or more, and then more preferably 80 mass % with On, and then more preferably 90 mass % or more, also, preferably 100 mass % or less.

55 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 48 ＞ of ＜~＜, 54 ＞, wherein (a) The mass ratio of ingredient/[(a) ingredient+(b) ingredient+(c) ingredient+(g) ingredients] is preferably 0.1 or more, and more preferably 0.2 or more, And then preferably 0.3 or more, and then preferably 0.35 or more, and then preferably 0.4 or more, also, preferably 0.9 hereinafter, more Preferably 0.85 hereinafter, be preferably 0.8 in turn hereinafter, being preferably 0.75 in turn hereinafter, being preferably 0.7 hereinafter, excellent in turn in turn It is selected as 0.65 or less.

56 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 48 ＞ of ＜~＜, 55 ＞, wherein The mass ratio of [(b) ingredient+(g) ingredients]/[(a) ingredient+(b) ingredient+(c) ingredient+(g) ingredients] be preferably 0.3 hereinafter, it is preferred that For be less than 0.3, preferably 0.26 hereinafter, more preferably 0.2 hereinafter, in turn be preferably less than 0.2, and then preferably 0.15 with Under, and then preferably less than 0.15, and then more preferably 0.1 hereinafter, also, preferably 0 or more, preferably 0.03 or more, more Preferably 0.05 or more, and then preferably 0.07 or more, and then preferably 0.1 or more, and then preferably 0.15 or more, Jin Eryou It is selected as 0.2 or more, or is 0.

57 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 48 ＞ of ＜~＜, 56 ＞, wherein (c) The mass ratio of ingredient/[(a) ingredient+(b) ingredient+(c) ingredient+(g) ingredients] is preferably 0.1 or more, and more preferably 0.2 or more, And then preferably 0.3 or more, and then preferably 0.35 or more, and then preferably 0.4 or more, also, preferably 0.9 hereinafter, more Preferably 0.85 hereinafter, be preferably 0.8 in turn hereinafter, being preferably 0.75 in turn hereinafter, being preferably 0.7 hereinafter, excellent in turn in turn It is selected as 0.65 or less.

58 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 1 ＞ of ＜~＜, 57 ＞, wherein solid Total content of object ingredient is preferably 0.6 mass % or more, more preferably 1 mass % or more, so preferably 2 mass % with On, and then preferably 3 mass % or more, and then more preferably 4 mass % or more, also, preferably 60 mass % are hereinafter, more excellent 50 mass % are selected as hereinafter, preferably 45 mass % are hereinafter, preferably 40 mass % are hereinafter, be preferably 35 matter in turn in turn in turn % is measured hereinafter, preferably 30 mass % hereinafter, be more preferably 28 mass % or less in turn in turn.

59 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 1 ＞ of ＜~＜, 58 ＞, wherein contain Water.

60 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 1 ＞ of ＜~＜, 59 ＞, wherein preferably To contain 30 mass % of water or more, more preferably 50 mass % or more, more preferably 60 mass % or more, and then preferably 70 matter Measure % or more, also, preferably 98 mass % hereinafter, more preferably 95 mass % hereinafter, more preferably 90 mass % or less.

61 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 1 ＞ of ＜~＜, 60 ＞, wherein in 25 DEG C pH value be preferably 2 or more, more preferably 4 or more, more preferably 5 or more, also, preferably 10 hereinafter, more preferably 9 with Under, and then preferably 8 or less.

62 ＞ of ＜

Such as the Hard surface liquid cleaner composition of any Entries notes Load in above-mentioned 1 ＞ of ＜~＜, 61 ＞, wherein in 20 DEG C viscosity be preferably 0.5mPas or more, more preferably 1mPas or more, also, preferably 50mPas is hereinafter, more excellent 20mPas is selected as hereinafter, preferably 10mPas hereinafter, be more preferably 7mPas hereinafter, being more preferably in turn in turn in turn 5mPas or less.

63 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 1 ＞ of ＜~＜, 62 ＞, wherein be hard The hard surface of matter article is used, and then is the hard surface of the hard article in the hard article around tableware and kitchen With, and then used for the hard surface of tableware, and then the hand washing for the hard surface of hard article is Clean-, and then for selected from tableware And the hand washing of the hard surface of the hard article in the hard article around kitchen is Clean-, and then be the hard surface of tableware It hand-washes Clean-.

64 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 1 ＞ of ＜~＜, 63 ＞, wherein for The detergent of the hard surface coating of hard article, the preferably hard into the hard article around tableware and kitchen The detergent of the hard surface coating of article, the more preferably detergent to the hard surface coating of tableware；Or it is to hard The detergent of the hard surface spraying of matter article, the preferably adamant into the hard article around tableware and kitchen The detergent of the hard surface spraying of product, the more preferably detergent to the hard surface spraying of tableware.

65 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 1 ＞ of ＜~＜, 64 ＞, wherein not dilute Release and directly with the hard surface of the hard article in hard surface, the hard article being preferably selected from around tableware and kitchen, More preferably the hard surface of tableware is contacted and is used.

66 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 1 ＞ of ＜~＜, 65 ＞, wherein with hard The hard article in hard article around matter article, food manufacturings machine, tableware and the kitchen such as be preferably selected from pipe, part, Hard article and then preferably tableware more preferably in the hard article around tableware and kitchen is as cleaning object； Or

With the food such as refrigerator, cupboard, tableware, the place of retention of regulating appliance, gutter, dressing table, smoke exhaust ventilator, water The conditioning place of the food such as slot, gas oven, micro-wave oven and its floor on periphery or wall are as cleaning object；Or

Container, kitchen knife or chopping board are preserved with tableware, preferably so-called tableware, sealing container, bottle such as dish, bowl etc., pot, are decocted The regulating appliances and food processor, mixer etc. such as pot, grilled fish frame improve household electrical appliances as cleaning object；Or

For selected from tableware, preserve the article in container, regulating appliance and conditioning household electrical appliances and use, and then for selected from dish, bowl, close The article sealed in container, bottle, kitchen knife, chopping board, pot, frying pan, grilled fish frame, food processor and mixer is used.

67 ＞ of ＜

The Hard surface liquid cleaner composition recorded such as any one of above-mentioned 1 ＞ of ＜~＜, 66 ＞, wherein hard The material of article is plastics, metal, pottery, timber and these combination.

It, can be from (a) ingredient, (b) ingredient in the Hard surface liquid cleaner composition of above-mentioned 1 ＞ of ＜~＜, 67 ＞ And (c) total content of ingredient removes 0.1 mass %, 0.64 mass % and 2 mass %.

68 ＞ of ＜

A kind of clean method of hard surface, wherein make the hard table recorded such as any one of above-mentioned 1 ＞ of ＜~＜, 67 ＞ Face liquid cleanser composition and hard surface, the hard surface for being preferably attached with greasy dirt are more preferably attached with and include The hard surface of the greasy dirt of solid fat contacts.69 ＞ of ＜

Such as the clean method of 68 ＞ of the above-mentioned ＜ hard surfaces recorded, wherein such as any one of above-mentioned 1 ＞ of ＜~＜, 67 ＞ The quality of (b) ingredient/[(a) ingredient+(b) ingredient+(c) ingredients] for the above-mentioned Hard surface liquid cleaner composition recorded Than being preferably 0.15 or more, more preferably 0.2 or more, and be 0.3 or less.

70 ＞ of ＜

Such as the clean method of 69 ＞ of the above-mentioned ＜ hard surfaces recorded, wherein such as any one of above-mentioned 1 ＞ of ＜~＜, 67 ＞ The quality of (b) ingredient/[(a) ingredient+(b) ingredient+(c) ingredients] for the above-mentioned Hard surface liquid cleaner composition recorded Than being preferably less than 0.2, and preferably 0 or more.71 ＞ of ＜

Such as the clean method of any one of above-mentioned 68 ＞ of ＜~＜, 70 ＞ hard surfaces recorded, wherein make such as above-mentioned ＜ 1 The above-mentioned Hard surface liquid cleaner composition that any one of 67 ＞ of ＞~＜ are recorded is contacted with stoste with hard surface.

72 ＞ of ＜

Such as the clean method of any one of above-mentioned 68 ＞ of ＜~＜, 71 ＞ hard surfaces recorded, wherein make such as above-mentioned ＜ 1 The above-mentioned Hard surface liquid cleaner composition that any one of 67 ＞ of ＞~＜ are recorded is not diluted and is contacted with hard surface.

73 ＞ of ＜

Such as the clean method of any one of above-mentioned 68 ＞ of ＜~＜, 72 ＞ hard surfaces recorded, wherein make such as above-mentioned ＜ 1 And the above-mentioned Hard surface liquid cleaner composition that any one of 67 ＞ of ＞~＜ are recorded does not dilute and is attached with comprising solid The hard surface of the greasy dirt of body fat contacts.

74 ＞ of ＜

Such as the clean method of any one of above-mentioned 68 ＞ of ＜~＜, 73 ＞ hard surfaces recorded, wherein make such as above-mentioned ＜ 1 After the above-mentioned Hard surface liquid cleaner composition that any one of 67 ＞ of ＞~＜ are recorded is contacted with hard surface, do not apply Add mechanical force and is placed.

75 ＞ of ＜

Such as the clean method of any one of above-mentioned 68 ＞ of ＜~＜, 74 ＞ hard surfaces recorded, wherein make such as above-mentioned ＜ 1 The above-mentioned Hard surface liquid cleaner composition that any one of 67 ＞ of ＞~＜ are recorded is with the area relative to hard surface 100cm²Preferably 0.1g or more, more preferably 0.3g or more and then preferably 0.4g or more and preferably 5g or less, more Preferably 3g or less and then preferably 2g ratio contact below, being preferably coated with or spray makes its contact.

76 ＞ of ＜

Such as the clean method of any one of above-mentioned 68 ＞ of ＜~＜, 75 ＞ hard surfaces recorded, wherein make such as above-mentioned ＜ 1 After the above-mentioned Hard surface liquid cleaner composition that any one of 67 ＞ of ＞~＜ are recorded is contacted with hard surface, place Preferably 10 seconds or more, more preferably 20 seconds or more, and then preferably 30 seconds or more, and then preferably 40 seconds or more, Jin Ergeng Preferably 50 seconds or more, and then more preferably 1 minute or more, and preferably 60 minutes hereinafter, more preferably 30 minutes hereinafter, And then preferably 20 minutes hereinafter, in turn be more preferably 10 minutes or less.

77 ＞ of ＜

Such as the clean method of any one of above-mentioned 68 ＞ of ＜~＜, 76 ＞ hard surfaces recorded, wherein make such as above-mentioned ＜ 1 After the above-mentioned Hard surface liquid cleaner composition that any one of 67 ＞ of ＞~＜ are recorded is contacted with hard surface, do not apply Add mechanical force and places preferably 10 seconds or more, more preferably 20 seconds or more, and then preferably 30 seconds or more, and then preferably 40 Second or more, and then more preferably 50 seconds or more, and then more preferably 1 minute or more, and preferably 60 minutes hereinafter, more preferably For 30 minutes hereinafter, in turn be preferably 20 minutes hereinafter, in turn be more preferably 10 minutes hereinafter, in turn be more preferably 5 minutes with Under.

78 ＞ of ＜

Such as the clean method of any one of above-mentioned 68 ＞ of ＜~＜, 77 ＞ hard surfaces recorded, wherein make such as above-mentioned ＜ 1 The above-mentioned Hard surface liquid cleaner composition that any one of 67 ＞ of ＞~＜ are recorded contacts preferably 10 with hard surface Second or more, more preferably 20 seconds or more, and then preferably 30 seconds or more, and then preferably 40 seconds or more, and then more preferably 50 Second or more, and then more preferably 1 minute or more, also, preferably 60 minutes hereinafter, more preferably 30 minutes hereinafter, excellent in turn It is selected as 20 minutes hereinafter, being more preferably 10 minutes in turn hereinafter, more preferably 5 minutes or less.

79 ＞ of ＜

Such as the clean method of any one of above-mentioned 68 ＞ of ＜~＜, 78 ＞ hard surfaces recorded, wherein make hard surface It is impregnated in the above-mentioned Hard surface liquid cleaner composition recorded such as any one of above-mentioned 1 ＞ of ＜~＜, 67 ＞, makes Hard surface liquid cleaner composition is stated to contact with hard surface.

80 ＞ of ＜

Such as the clean method of any one of above-mentioned 68 ＞ of ＜~＜, 79 ＞ hard surfaces recorded, wherein will be such as above-mentioned ＜ 1 Any one of 67 ＞ of ＞~＜ record above-mentioned Hard surface liquid cleaner composition sprayed or be coated with and make its with Hard surface contacts.

81 ＞ of ＜

Such as the clean method of any one of above-mentioned 68 ＞ of ＜~＜, 80 ＞ hard surfaces recorded, wherein will be such as above-mentioned ＜ 1 The above-mentioned Hard surface liquid cleaner composition that any one of 67 ＞ of ＞~＜ are recorded is made droplet-like and is sprayed or made It is coated at foam-like and it is made to be contacted with hard surface.

82 ＞ of ＜

Such as the clean method of any one of above-mentioned 68 ＞ of ＜~＜, 81 ＞ hard surfaces recorded, wherein use will be as above It states the above-mentioned Hard surface liquid cleaner composition that any one of 1 ＞ of ＜~＜, 67 ＞ are recorded and is filled in and have sprayer The detergent article of hard surface made of container, makes above-mentioned Hard surface liquid cleaner composition be connect with hard surface It touches.

83 ＞ of ＜

Such as the clean method of any one of above-mentioned 68 ＞ of ＜~＜, 82 ＞ hard surfaces recorded, wherein above-mentioned hard table Face is the hard surface of hard article, the preferably hard surface of the hard article around tableware or kitchen, more preferably tableware Hard surface；Or

Above-mentioned hard surface is the hard table of the hard article around the food manufacturings such as pipe, part machine, tableware or kitchen The hard surface of hard article around face, preferably tableware or kitchen is more preferably selected from the food such as refrigerator, cupboard, meal The conditioning field of the food such as tool, the place of retention of regulating appliance, gutter, dressing table, smoke exhaust ventilator, sink, gas oven, micro-wave oven The hard surface on the floor or the hard article in wall on institute and its periphery；Or

Above-mentioned hard surface is the hard surface of tableware, is preferably selected from the so-called tableware such as dish, bowl, sealing container, bottle Household electrical appliances are improved Deng the regulating appliances and food processor, mixer etc. such as container, kitchen knife or chopping board, pot, frying pan, grilled fish frame are preserved In tableware hard surface；Or

Above-mentioned hard surface is selected from tableware, preserves container, regulating appliance and the hard table for improving the article in household electrical appliances Face, and then in dish, bowl, sealing container, bottle, kitchen knife, chopping board, pot, frying pan, grilled fish frame, food processor and mixer Article hard surface.

84 ＞ of ＜

Such as the clean method of any one of above-mentioned 68 ＞ of ＜~＜, 83 ＞ hard surfaces recorded, wherein above-mentioned hard table The material in face is plastics, metal, pottery, timber and these combination.

85 ＞ of ＜

Such as the clean method of any one of above-mentioned 68 ＞ of ＜~＜, 84 ＞ hard surfaces recorded, wherein above-mentioned hard table Face is oil removing Hard surface liquid cleaner composition with liquid cleanser composition.

86 ＞ of ＜

A kind of automiser spray fills hard surface detergent article, wherein make as 1 ＞ of above-mentioned ＜~

The Hard surface liquid cleaner composition that any one of 67 ＞ of ＜ are recorded is filled in the container for having sprayer It forms.

87 ＞ of ＜

The hard surface detergent article recorded such as above-mentioned ＜ 86 ＞, wherein the container for having sprayer be without using The hand spraying device of propellant or the aerosol for using propellant, are preferably selected from trigger-type automiser spray and pump spray The hand spraying device without using propellant in container, content can be more preferably made droplet-like or foam-like into The trigger sprayer of row spraying or coating, and then preferably have and spray content spraying at the trigger-type of the mechanism of droplet-like Day with fog or the trigger sprayer for having the mechanism (formation of foam mechanism) to form foam.

88 ＞ of ＜

A kind of composition recorded such as any one of above-mentioned 1 ＞ of ＜~＜, 67 ＞ is as hard surface cleaning liquid Agent, preferably as the hard surface liquid cleaner of the hard article around tableware or kitchen, more preferably as the hard of tableware Purposes in the liquid cleaner of matter surface.

89 ＞ of ＜

A kind of composition recorded such as any one of above-mentioned 1 ＞ of ＜~＜, 67 ＞ is as oil removing hard surface liquid Detergent is more preferably made preferably as the oil removing hard surface liquid cleaner of the hard article around tableware or kitchen For the purposes in the oil removing hard surface liquid cleaner of tableware.

90 ＞ of ＜

A kind of composition recorded such as any one of above-mentioned 1 ＞ of ＜~＜, 67 ＞ as so that the composition is not diluted and with Hard surface contacts and carry out hard surface liquid cleaner used in clean method with not applying mechanical force, preferably makees For the hard surface liquid cleaner of the hard article around tableware or kitchen, more preferably as the hard surface liquid of tableware Purposes in body detergent.

91 ＞ of ＜

A kind of use such as the composition of any one of above-mentioned 1 ＞ of ＜~＜, 67 ＞ records in the clean method of hard surface On the way, wherein this method be make the composition do not dilute and with hard surface, be preferably attached with the hard surface, more excellent of greasy dirt It is selected as being attached with the hard surface contact of the greasy dirt comprising solid fat.

Embodiment

Using following gradation compositions, Hard surface liquid cleaner composition shown in table 1,2 is prepared, and for following Project is evaluated.The composition of table 1,2 is oil removing Hard surface liquid cleaner composition.Show the result in table 1,2. The Hard surface liquid cleaner composition of table 1,2 is to be prepared by conventional method.That is, in suitable ion exchange water Middle addition (a) ingredient~(g) ingredients dissolve under room temperature (25 DEG C), thereafter, add sodium hydroxide or/and hydrochloric acid by pH value (25 DEG C) it is adjusted to 6.Furthermore the quality % of the gradation composition in table 1 is all to be based on a effective amount of numerical value.(b) ingredient expression is based on The quality % of amount in terms of sodium salt, (g) quality % of the ingredient expression based on the amount in terms of acid type compound.Also, (f) ingredient indicates Quality % based on the amount in terms of the compound comprising the crystallization water.

＜ gradation compositions ＞

(a) ingredient

Two -2- ethylhexyls sodium of sulfosuccinic acid (product name " Airrol CT-1L ", eastern nation's chemical industry (strain) system It makes)；In general formula (a1), R^1a、R^2aBe 2- ethylhexyls, x, y it is 0, M¹For the compound of sodium

Sulfosuccinic acid two-tridecane base ester sodium (product name " PELEX TR ", flower king (strain) manufacture)；At general formula (a1) In, R^1a、R^2aBe tridecyl, x, y it is 0, M¹For the compound of sodium

(b) ingredient

PO0.6 lauryl sulfate ester sodium；In general formula (b1), R^1bFor the alkyl (octyl/decyl/ten from natural alcohol The mass ratio of dialkyl group=5/5/90), R^2bFor propylidene, n 0.6, M²For the compound of sodium

Lauryl sulfate ester sodium (product name " Emal 0 ", flower king (strain) manufacture)；In general formula (b1), R^1bFor dodecane Base, n 0, M²For the compound of sodium

EO2 lauryl sulfate esters sodium (product name " Emal 270J ", flower king (strain) manufacture)；In general formula (b1), R^1bFor Dodecyl, R^2bFor ethylidene, n 2, M²For the compound of sodium

(c) ingredient

Lauryl hydroxyl sulfo betaine (product name " AMPHITOL 20HD ", flower king (strain) manufacture)

Lauroyl amido carbonyl propyl base glycine betaine (product name " AMPHITOL 20AB ", flower king (strain) manufacture)

Lauryl betaine (product name " AMPHITOL 20BS ", flower king (strain) manufacture)

(d) ingredient：2- Sensiva SC50s ether (product name " Penetol GE-EH ", flower king (strain) manufacture)

(e) ingredient：Butyl diglycol (product name " BDG-NS ", Japanese emulsifier (strain) manufacture)

(f) ingredient：P-methyl benzenesulfonic acid monohydrate (product name " PTS M-7000 ", bright friend's industry (strain) manufacture)

(g) ingredient：Lauric acid (product name " Lunac L-98 ", flower king (strain) manufacture)

(1) cleaning force (evaluation of solution dipping)

It makes butter and rapeseed oil with 9：The mixture that 1 mass ratio is obtained by mixing (includes as sample spot The sample spot of the greasy dirt of solid fat, same as below).Polypropylene test piece to 30mm (cross) × 80mm (perpendicular) × 1mm (thickness) Quality be measured (x) using a ten thousandth balance.Be produced on the two sides of above-mentioned polypropylene test piece becomes so that two sides is total The mode of 0.02~0.03g is from lower end until test piece is as spot piece made of the highly homogeneously coating sample spot of 50mm. (y) is measured using a ten thousandth balance to the quality of the spot piece.

Hard surface liquid cleaner composition 50g is added to the 50mL containers (circle of internal diameter 35mm × height 68mm Column), then, so that 1 spot piece is stood in the container and contacted with above-mentioned composition.At this point, spot piece is attached with spot Part is all impregnated in the above-mentioned composition in container.

By spot piece to be impregnated in 1 institute of state placement table of the Hard surface liquid cleaner composition in said vesse The time shown takes out above-mentioned spot piece thereafter, and carrying out flowing water using tap water rinses 1 minute.At this point, the condition that flowing water rinses For：The temperature of tap water is 25 DEG C, and flow velocity is about 4L/min, a diameter of about 15mm of the opening portion of tap.With relative to The tap water fallen positioned at the spot piece away from opening portion 5cm vertical lowers keeps spot piece as 45 ° of mode, fixes the angle It is constant to receive flowing water in the unattached upper part for having a spot of spot piece, using flowing through the tap water of spot on piece to cleaning section Single side is divided integrally to be rinsed.At this point, changing within every 10 seconds the positive and back side is alternately carried out flushing.After flushing, make spot Piece is dried, and thereafter, (z) is measured to quality using a ten thousandth balance.Clean rate is found out using following formula.

Clean rate (%)={ (y)-(z) }/{ (y)-(x) } × 100

(2) cleaning force (foam impregnation evaluation)

It makes butter and rapeseed oil with 9：The mixture that 1 mass ratio is obtained by mixing is as sample spot.It is right The quality of the polypropylene test piece of 30mm (cross) × 80mm (perpendicular) × 1mm (thickness) is measured (x) using a ten thousandth balance.System Work is on the two sides of above-mentioned polypropylene test piece from lower end until the height of 5cm is equal in such a way that two sides is total as 0.02~0.03g It is coated with test piece made of sample spot evenly as spot piece.The quality of the spot piece is measured using a ten thousandth balance (y)。

Hard surface liquid cleaner composition is filled in trigger-type automiser spray (Magiclean Handy Spray, flower king (strain) manufacture), it sprays on 5 times in 50mL containers (internal diameter 35mm × height 68mm's is cylindric) interior foam-like State composition.The spray volume of composition adds up to about 5g.

Then, so that 1 spot piece is stood in the container, make the hard table of above-mentioned spot piece and the foam-like in said vesse Face is contacted with liquid cleanser composition.At this point, the part for being attached with spot of spot piece is all impregnated in the foam in container In the above-mentioned composition of shape.By spot piece with the time shown in the state placement table 1 that is impregnated in foam, thereafter, spot is taken out Piece carries out flowing water using tap water and rinses 1 minute.

At this point, the condition that flowing water rinses is：The temperature of tap water is 25 DEG C, and flow velocity is about 4L/min, the opening of tap A diameter of about 15mm in portion.To become 45 ° relative to the tap water fallen positioned at the spot piece away from opening portion 5cm vertical lowers Mode keep spot piece, fix that the angle is constant to receive flowing water in the unattached upper part for having a spot of spot piece, utilize The tap water for flowing through spot on piece is integrally rinsed cleaning part single side.At this point, changing within every 10 seconds front and back side alternating Ground is rinsed.After flushing, so that spot piece is dried, thereafter, (z) is measured to quality using a ten thousandth balance.Profit Clean rate is found out with following formula.

Clean rate (%)={ (y)-(z) }/{ (y)-(x) } × 100

(3) foam specific volume

Hard surface liquid cleaner composition is filled in trigger-type automiser spray (Magiclean Handy Spray, flower king (strain) manufacture), using the abundant foam pattern of said vesse to 200mL graduated cylinders (internal diameter 40mm) internal spraying 10 It is secondary.200mL graduated cylinders quality after spraying is measured using a ten thousandth balance, by the difference of the quality with the graduated cylinder before spraying It is set as foam coating weight (g) (a).Visually to read the volume (mL) (b) of the foam in graduated cylinder.Foam ratio is calculated using following formula Hold.

Foam specific volume (mL/g)=(b)/(a)

If the embodiment 5 of table 1 and the embodiment 14~17 and comparative example 4~5 of table 2 are compared, can confirm： (b) embodiment 5 that the mass ratio of/[(a)+(b)+(c)] is 0 is excellent in terms of cleaning force.On the other hand, can confirm：(b)/ The foam specific volume of the bigger embodiment 14~17 of quality of [(a)+(b)+(c)] is larger.

In the situation of Hard surface liquid cleaner composition contact for making the present invention, if by the embodiment 5 of table 1 It is compared, then can confirm with the embodiment 18,19 of table 2：(a) total content of ingredient+(b) ingredient+(c) ingredients is 5 matter The embodiment 5 for measuring % is better in terms of cleaning force and the balance of the cost of material of surfactant.

In the situation of Hard surface liquid cleaner composition contact for making the present invention, if by the embodiment 2 of table 1 ~8 are compared, then can confirm：(a) embodiment 6 that the mass ratio of ingredient/(c) ingredients is 1.5 is better in terms of cleaning force.

In the situation of Hard surface liquid cleaner composition contact for making the present invention, if by the embodiment of table 1 6, embodiment 9~13 is compared, then can be confirmed：(e) embodiment 10 that the mass ratio of ingredient/[(a)+(c)] is 1.8 is cleaning It is better in terms of power.

Furthermore if observation embodiment 5, embodiment 6, embodiment 16 and embodiment 17, the solution leaching of these embodiments The relationship of clean rate under stain and the relationship of the clean rate under the foam impregnation of these embodiments show identical tendency.According to The situation, it is known that there are incidence relations for the clean rate under clean rate and foam impregnation under solution dipping, in other embodiments, Also can confirm can be according to the value of the clean rate under result (clean rate) the presumption foam impregnation that solution impregnates.

Claims

1. a kind of oil removing Hard surface liquid cleaner composition, wherein

Containing following (a) ingredient, 0 mass % of (b) ingredient less than 3 mass %, (c) ingredient and water, and (b) ingredient/ The mass ratio of [(a) ingredient+(b) ingredient+(c) ingredients] be 0.3 hereinafter,

＜ (a) ingredients ＞

Sulfosuccinate represented by the following general formula (a1) or its salt,

In formula, R^1a、R^2aIt is each independently 5 or more and 18 alkyl below of carbon atom number；A¹、A²It is each independently carbon atom number 2 Above and 4 alkylidenes below, x, y are average addition molal quantity and are each independently 0 or more and 6 or less；M¹For hydrogen atom or Cation,

＜ (b) ingredients ＞

With 8 or more and 21 alkyl below of carbon atom number and with sulfate group or sulfonic anion surface active Agent, wherein except (a) ingredient,

＜ (c) ingredients ＞

2. oil removing Hard surface liquid cleaner composition as described in claim 1, wherein

Contain 0.5 mass % of (a) ingredient or more and 30 mass % or less.

3. oil removing Hard surface liquid cleaner composition as claimed in claim 1 or 2, wherein

Contain 0.1 mass % of (c) ingredient or more and 30 mass % or less.

4. oil removing Hard surface liquid cleaner composition according to any one of claims 1 to 3, wherein

(a) ingredient, (b) ingredient and (c) total content of ingredient be 0.6 mass % or more and 40 mass % or less.

5. oil removing Hard surface liquid cleaner composition as described in any one of claims 1 to 4, wherein

Contain 8 or more and 22 aliphatic acid below of carbon atom number or its 0 mass % of salt or more and 3 mass % or less.

6. such as oil removing Hard surface liquid cleaner composition according to any one of claims 1 to 5, wherein

(a) mass ratio of ingredient/(c) ingredients is 0.1 or more and 10 or less.

7. such as oil removing Hard surface liquid cleaner composition according to any one of claims 1 to 6, wherein

And then contain (e) solvent.

8. such as oil removing Hard surface liquid cleaner composition according to any one of claims 1 to 7, wherein

It is for being contacted with hard surface and carrying out the liquid cleanser composition in clean method with not applying mechanical force.

9. a kind of clean method of hard surface, wherein

Make oil removing Hard surface liquid cleaner composition according to any one of claims 1 to 8 and is attached with greasy dirt Hard surface contact.

10. the clean method of hard surface as claimed in claim 9, wherein

The oil removing is set not diluted with Hard surface liquid cleaner composition and be contacted with the hard surface.

11. the clean method of the hard surface as described in claim 9 or 10, wherein

The oil removing Hard surface liquid cleaner composition is set not apply mechanical force after being contacted with the hard surface And it is placed.

12. the clean method of the hard surface as described in any one of claim 9~11, wherein

Placed 10 seconds after so that the oil removing Hard surface liquid cleaner composition is contacted with the hard surface or more.

13. the clean method of the hard surface as described in any one of claim 9~12, wherein

The oil removing is sprayed or is coated with Hard surface liquid cleaner composition and is contacted with the hard surface.

14. the clean method of hard surface as claimed in claim 13, wherein

Droplet-like is made with Hard surface liquid cleaner composition in the oil removing to sparge the hard surface or be made Foam-like is coated on the hard surface.

15. the clean method of the hard surface as described in any one of claim 9~14, wherein

Greasy dirt is the greasy dirt comprising solid fat.

16. a kind of automiser spray fills hard surface detergent article, wherein

It is to be filled in oil removing according to any one of claims 1 to 8 with Hard surface liquid cleaner composition to have Detergent article made of the container of sprayer.