CN105062712B - A kind of foam type fruits and vegetables dish washing detergent compositions - Google Patents
A kind of foam type fruits and vegetables dish washing detergent compositions Download PDFInfo
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- CN105062712B CN105062712B CN201510459249.3A CN201510459249A CN105062712B CN 105062712 B CN105062712 B CN 105062712B CN 201510459249 A CN201510459249 A CN 201510459249A CN 105062712 B CN105062712 B CN 105062712B
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Abstract
The invention discloses a kind of foam type fruits and vegetables dish washing detergent compositions, its each raw material components contained:Special anionic surfactant magnesium alkylbenzene sulfonate 1% 15%;Other surfaces activating agent 5% 50%;Cosolvent 0.1% 5.0%;Sterilization antiseptic 0.01% 2%;Other components 0.04% 0.1%;Deionized water surplus.The present invention has selected magnesium alkylbenzene sulfonate and the specific combination of other surfaces activating agent and auxiliary agent, to cause the detergent to keep there is no viscosity and stable foam state substantially, detergent is extruded or sprayed with form of foam by push type foam pump head or injecting type foam nozzle, it is different from traditional fruits and vegetables dish washing detergent, directly with pressing or the foam that ejects is cleaned, without detergent is dissolved in the water in advance stir foam after cleaned again.The cleansing composition is mainly used in the cleaning of fruits and vegetables and tableware etc., has the features such as easy to use, quick, potent decontamination.
Description
Technical field
The invention belongs to daily chemical product technical field, is combined more particularly to a kind of foam type fruits and vegetables dish washing detergent
Thing.
Background technology
Fruits and vegetables dish washing detergent is that more daily chemical product is contacted in people's daily life, and its main function is cleaning meal
Tool, melon fruits and vegetables etc., its product appearance, which is generally faint yellow or yellow, has a transparency liquid of certain viscosity, usual during use
It is that cleaning agent is dissolved into water, tableware, melon fruits and vegetables is cleaned after stirring foam.
With the raising that the development in epoch and people live, requirement of the people to fruits and vegetables Dish-Washing Products is also increasingly
Height, in addition to keeping the due washability of fruits and vegetables dish washing detergent, washing feel, its convenience used and convenience also by
The concern of more and more consumers.How to improve the property easy to use of fruits and vegetables dishwashing detergent, while lift its dirt-removing power of deoiling,
It is worth research and inquires into.
At present, conventional fruits and vegetables dish washing detergent compositions Main Ingredients and Appearance is made up of surfactant and other auxiliary agents, table
Face activating agent is combined reach finite concentration after can form micella, these surfactant micellars easily form bar-shaped and net
Shape micelle, so that fruits and vegetables rinse product has certain viscosity;It is and miscellaneous due to containing certain inorganic salts in raw material
Matter, the addition of inorganic salts can compress the double electrical layerses of micelle, and then cause the aggregation number of micelle to increase, and can increase the viscous of product
Degree.
In addition, conventional fruits and vegetables dish washing detergent can also add thickener composition, the addition of thickener can make surface-active
The Jiao-Xin railway increase of agent solution, so as to influence the shape of micelle forma-tion micelle, further increases the viscosity of product, has
The fruits and vegetables dish washing detergent compositions of certain viscosity can not be sprayed with form of foam.
Thus, existing fruits and vegetables dishwashing detergent product can not meet the diversified demand of consumer, it is still necessary to further
Improve necessity of formula.
The content of the invention
It is an object of the invention to provide a kind of foam type fruits and vegetables dish washing detergent compositions, and it has selected special surface work
Property agent and auxiliary combination, to cause the detergent to keep there is no viscosity and stable foam state substantially, pass through push type foam pump
Detergent is extruded or sprayed with form of foam by head or injecting type foam nozzle, is different from traditional fruits and vegetables dish washing detergent,
Cleaning way is more convenient, is directly cleaned with the foam of discharge by pressing, and bubble is stirred without detergent is dissolved in the water in advance
Cleaned again after foam.
A kind of foam type fruits and vegetables dish washing detergent compositions of the present invention, it includes each raw material group of following percentage by weight
Point:
Special anionic surfactant magnesium alkylbenzene sulfonate 1-15%;
Other surfaces activating agent 5-50%;
Chelating agent 0.01-5.0%;
Cosolvent 0.1-20%;
Sterilization antiseptic 0.01-2.0%;
Other components 0.01-0.5%;
Deionized water surplus.
The foam type fruits and vegetables dish washing detergent compositions of the present invention, the other surfaces activating agent is anion surface active
At least one of agent, nonionic surfactant or amphoteric surfactant or two or more mixtures.The alkyl
Benzene sulfonic acid magnesium its be to be formed by alkyl benzene sulphonate and alkaline-earth metal magnesium hydroxide neutralization reaction.The alkyl carbon chain of magnesium alkylbenzene sulfonate
The straight chained alkyl of preferably 10-16 carbon atom.
The foam type fruits and vegetables dish washing detergent compositions of the present invention, the anion surface active in addition to magnesium alkylbenzene sulfonate
Agent be sodium sulfate of polyethenoxy ether of fatty alcohol, AEO carboxylic acid sodium, sodium alkyl sulfate, sodium alkyl benzene sulfonate,
Any of sodium alkyl sulfonate, a- sodium olefin sulfonates, methyl sodiosul foaliphatate, sulfosuccinic acid ester sodium salt are two or more
Mixture.The fatty alcohol alkyl chain of sodium sulfate of polyethenoxy ether of fatty alcohol is preferably the straight chained alkyl of 12-16 carbon atom;Alcohol
The average adduct number of the oxirane of ether is 1-3.The preferred content of anion surfactant is 5.0-20%.
The foam type fruits and vegetables dish washing detergent compositions of the present invention, the nonionic surfactant is fatty alcohol polyoxy second
Alkene ether, collateralization AEO, alkanolamide, alkyl-glucoside, sucrose ester, polyglyceryl fatty acid ester, oxidation
Any or two or more mixture in amine.The preferred content of nonionic surfactant is 0.5-15%.
The fruits and vegetables dish washing detergent compositions of the present invention, the amphoteric surfactant is lauryl alanine diethanol amine
In salt, lauryl alanine sodium, Cocoamidopropyl betaine, alkyl hydroxyl sulfopropyl betaine, imidazoline it is any or
Two or more mixtures.The preferred content of amphoteric surfactant is 0.1-5.0%.
The foam type fruits and vegetables dish washing detergent compositions of the present invention, the cosolvent are to appoint in ethanol, propane diols, glycerine
One or more kinds of mixtures, the preferred content of cosolvent is 0.5~20%.
The present invention foam type fruits and vegetables dish washing detergent compositions, the sterilization antiseptic be sodium benzoate, potassium sorbate,
Any or two or more mixture in methylisothiazolinone, Phenoxyethanol;It is preferred that addition is 0.01-1.0%.
The present invention foam type fruits and vegetables dish washing detergent compositions, described other components be light stabilizer, antioxidant,
Essence, these components are the universaling component of detergent composition, and kind does not do specific limitation, the preferred addition of other components
For 0.04-0.3%.
The foam type fruits and vegetables dish washing detergent compositions of the present invention have the following advantages that and beneficial functional:
1) special surface activating agent magnesium alkylbenzene sulfonate and auxiliary combination have been selected, to cause the detergent to keep not having substantially
There are viscosity and stable foam state, squeezed detergent with form of foam by push type foam pump head or injecting type foam nozzle
Go out or spray, be different from traditional fruits and vegetables dish washing detergent, cleaning way is more convenient, is directly carried out clearly with the foam of discharge by pressing
Wash, without detergent is dissolved in the water in advance stir foam after cleaned again.
2) foam type fruits and vegetables dish washing detergent compositions of the invention, with conventional common fruits and vegetables dish washing detergent compositions
Compare, there is effect of preferably deoiling, particularly with the removal of animal fat.
Embodiment
A kind of the present invention is intended to provide direct discharge by pressing foam type fruits and vegetables dish washing detergent combination containing magnesium alkylbenzene sulfonate
Thing, the technology country still belong to blank.The composition of the present invention is to contain surface-active without viscous liquid, its each raw material components substantially
Agent, cosolvent, chelating agent, sterilization antiseptic and other a small amount of additive and deionized water.The preferred magnesium alkylbenzene sulfonate of the present invention
As important soil release component, obtained foam type fruits and vegetables dish washing detergent compositions product, it is mainly used in fruits and vegetables and tableware etc.
Cleaning, there is easy to use, effect of well deoiling.
The fruits and vegetables dish washing detergent compositions have selected special anionic surfactant magnesium alkylbenzene sulfonate and other tables
Face activating agent and auxiliary combination, to cause the detergent to keep there is no viscosity and stable foam state substantially, steeped by push type
Detergent is extruded or sprayed with form of foam by foam pump head or injecting type foam nozzle, is different from traditional fruits and vegetables dishwashing detergent
Agent, directly with pressing or the foam that ejects is cleaned, without detergent is dissolved in the water in advance stir foam after enter again
Row cleaning.
The present invention is combined by such special surface activating agent so that surfactant micellar is not easy to bar-shaped and netted
Micelle changes, so as to keep liquid without viscosity state, to be easy to spray with form of foam substantially;And conventional fruits and vegetables dish washing detergent is
Making not add thickener can also have certain viscosity be not easy to spray with form of foam.
The present invention is described in further detail below by way of specific preferred embodiment, but the present invention be not limited in it is following
Embodiment.
Embodiment 1
A kind of foam type fruits and vegetables dish washing detergent compositions, raw material components and content comprising table 1 below:
The formula composition of the foam type fruits and vegetables dish washing detergent compositions of the embodiment 1 of table 1
Raw material components | Percentage by weight (%) |
Magnesium hydroxide | 0.45 |
DBSA | 5.0 |
Sodium sulfate of polyethenoxy ether of fatty alcohol | 2.5 |
Sodium olefin sulfonate | 12.0 |
AEO -7 | 5.0 |
Alkyl hydroxyl sulfopropyl betaine | 1.0 |
Glycerine | 2.0 |
Disodium ethylene diamine tetraacetate | 0.1 |
Sodium benzoate | 0.2 |
Methylisothiazolinone | 0.04 |
Deionized water | Surplus (adds to 100%) |
According to the formulation content of table 1, deionized water, magnesium hydroxide and DBSA are put into first, are neutralized complete
Other surfaces activating agent is put into afterwards, and pH is adjusted to 6.5-8.0, input chelating agent, preservative and other auxiliary agents.Qualified products are stood
To basic non-foam, you can filling is finished foam type fruits and vegetables dish washing detergent compositions.
Embodiment 2
A kind of foam type fruits and vegetables dish washing detergent compositions, raw material components and content comprising table 2 below:
The formula composition of the foam type fruits and vegetables dish washing detergent compositions of the embodiment 2 of table 2
Raw material components | Percentage by weight (%) |
Magnesium hydroxide | 0.54 |
C12-14 alkyl benzene sulphonates | 6.0 |
Sodium sulfate of polyethenoxy ether of fatty alcohol | 1.5 |
Sodium olefin sulfonate | 15.0 |
AEO -9 | 4.0 |
Cocoamidopropyl betaine | 1.0 |
Propane diols | 2.0 |
Disodium ethylene diamine tetraacetate | 0.1 |
Sodium benzoate | 0.1 |
Methylisothiazolinone | 0.04 |
Deionized water | Surplus (adds to 100%) |
According to the formulation content of table 2, deionized water, magnesium hydroxide and C12-14 alkyl benzene sulphonates are put into first, has been neutralized
Input other surfaces activating agent after complete, pH are adjusted to 6.5-8.0, input chelating agent, preservative and other auxiliary agents.Qualified products are quiet
Put to basic non-foam, you can filling is finished product fruits and vegetables dish washing detergent compositions.
Embodiment 3
A kind of foam type fruits and vegetables dish washing detergent compositions, raw material components and content comprising table 3 below:
The formula composition of the foam type fruits and vegetables dish washing detergent compositions of the embodiment 3 of table 3
Raw material components | Percentage by weight (%) |
Magnesium hydroxide | 0.63 |
C12-16 alkyl benzene sulphonates | 7.0 |
Sodium sulfate of polyethenoxy ether of fatty alcohol | 0.5 |
Sodium olefin sulfonate | 16.0 |
Isomery AEO -8 | 3.0 |
Lauroylamidopropyl betaine | 1.0 |
Edible alcohol | 2.0 |
Disodium ethylene diamine tetraacetate | 0.1 |
Sodium benzoate | 0.4 |
Methylisothiazolinone | 0.04 |
Deionized water | Surplus (adds to 100%) |
According to the formulation content of table 3, deionized water, magnesium hydroxide and C12-16 alkyl benzene sulphonates are put into first, has been neutralized
Input other surfaces activating agent after complete, pH are adjusted to 6.5-8.0, input chelating agent, preservative and other auxiliary agents.Qualified products are quiet
Put to basic non-foam, you can filling is finished product fruits and vegetables dish washing detergent compositions.
Embodiment 4
A kind of foam type fruits and vegetables dish washing detergent compositions, raw material components and content comprising table 4 below:
The formula composition of the foam type fruits and vegetables dish washing detergent compositions of the embodiment 4 of table 4
Raw material components | Percentage by weight (%) |
Magnesium hydroxide | 0.72 |
C10-16 alkyl benzene sulphonates | 8.0 |
Sodium sulfate of polyethenoxy ether of fatty alcohol | 0.5 |
Sodium olefin sulfonate | 18.0 |
AEO -9 | 2.0 |
Cocamidopropyl propyl amide amine oxide | 1.5 |
Edible alcohol | 5.0 |
Disodium ethylene diamine tetraacetate | 0.1 |
Sodium benzoate | 0.4 |
Methylisothiazolinone | 0.04 |
Deionized water | Surplus (adds to 100%) |
According to the formulation content of table 4, deionized water, magnesium hydroxide and C10-16 alkyl benzene sulphonates are put into first, has been neutralized
Input other surfaces activating agent after complete, pH are adjusted to 6.5-8.0, input chelating agent, preservative and other auxiliary agents.Qualified products are quiet
Put to basic non-foam, you can filling is finished product fruits and vegetables dish washing detergent compositions.
The performance test of the fruits and vegetables dish washing detergent compositions of the present invention is as follows:
1st, fruits and vegetables dish washing detergent compositions remove the assay method of effect to remains of pesticide
Fruits and vegetables dish washing detergent compositions remove efficacy test to remains of pesticide and use the fruits and vegetables dishwashing detergents of GB/T 24691
Remains of pesticide removes the verification method of effect and is measured in appendix A in agent composition.
2nd, the assay method of fruits and vegetables dish washing detergent compositions detergency
The detergency of fruits and vegetables dish washing detergent compositions uses the foam in GB 9985-2000 (detergent for washing dishware with hand)
Position method is tested.
3rd, fruits and vegetables dish washing detergent compositions are to grease removal effect assay method (oil cut rate method is gone in Terg-O-Tometer test)
It is prepared by dirty piece:It is accurate to weigh clean and dried plastic sheet (76mm*25mm) weight m0', and number, by 0.1-
0.3g tests greasy dirt (mixing greasy dirt B) is uniformly applied on plastic sheet, smears position at the center section of plastics length of a film, both ends
Each reserved about 20mm, the greasy dirt on plastic sheet arris is carefully wiped.Room temperature is placed 2 hours or so, weighs the modeling after applying greasy dirt
Tablet weight m1′。
Deoil test:Washing will be prepared in wash stand corresponding to the plastic sheet insertion of the known amount of defiling.Spotter is connected
Power supply, wash temperature are arranged to 25 DEG C, and rotational speed is arranged to 120r/min, and wash time is arranged to 5min.Prepare certain dense
Degree test liquid detergent sample solution (1.5%) 1000ml enters in the washing tube of Terg-O-Tometer, rapidly by the dirty piece of known weight
Accordingly it is put into together with wash stand in washing tube, starts to count soak time after last wash stand is put into washing tube, simultaneously
Agitator is installed rapidly, when soaking 1min, starts spotter, when starting to wash 5min, machine autostop rapidly will stirring
Device is removed, and is taken out wash stand, is fallen liquid detergent solution with tap water rinse, keep flat after drying by dirty piece put it is corresponding weigh frame and weigh be
m2′.Oil cut rate is gone in calculating.It is to wash away greasy dirt f ' mass fraction to go oil cut rate, is represented, is calculated as follows with %:
Carry out parallel test simultaneously.The remains of pesticide to fruits and vegetables cleaning agent and grease, which remove, according to the method described above surveys
Examination, as shown in table 5.
The fruits and vegetables cleaning agent of table 5 removes residues of pesticides, detergency and removes oil cut rate measure table
Note:Greasy dirt A is miscella in the Appendix B in GB 9985;Greasy dirt B is lard:Vegetable oil:Greasy dirt A is 1:1:1
Three mixes greasy dirt.National standard GB 9985-2000 Plays liquid detergents detergencies (dishwashing number) are:3.
The content shown in embodiment 1-4 from above-mentioned table 5, foam type fruits and vegetables cleansing composition pair of the invention
Residues of pesticides, which remove, the effect of preferable, better than common fruits and vegetables cleaning agent;And to grease removal ability, it is significantly better than common fruits and vegetables
Rinse product.
The above described is only a preferred embodiment of the present invention, any formal limitation not is made to the present invention, therefore
It is every without departing from technical solution of the present invention content, what the technical spirit according to the present invention was made to above example any simply repaiies
Change, equivalent variations and modification, in the range of still falling within technical solution of the present invention.
Claims (5)
- A kind of 1. foam type fruits and vegetables dish washing detergent compositions, it is characterised in that:It is each raw material by following percentage by weight Component is made:1.0-30% anion surfactant, and at least containing sodium sulfate of polyethenoxy ether of fatty alcohol, fatty alcohol polyoxy second Any of alkene ether carboxylic acid sodium, a- sodium olefin sulfonates or two or more mixtures;The anion surfactant is at least A kind of magnesium alkylbenzene sulfonate anion surfactant containing 1-15%;The magnesium alkylbenzene sulfonate be by alkyl benzene sulphonate with Alkaline-earth metal magnesium hydroxide neutralization reaction is formed;0.1-15% nonionic surfactant, and the nonionic surfactant at least contains aliphatic alcohol polyethenoxy Any or two or more mixture in ether, collateralization AEO, alkyl-glucoside, amine oxide.0.1-5.0% amphoteric surfactant, the amphoteric surfactant are sodium lauroyl sarcosine, lauryl alanine Any or two or more mixing in sodium, Cocoamidopropyl betaine, alkyl hydroxyl sulfopropyl betaine, imidazoline Thing;Chelating agent 0.01-5.0%;Cosolvent 0.1-20.0%, the cosolvent are mixing any one or more in ethanol, propane diols, glycerine Thing;Sterilization antiseptic 0.01-2.0%;Other components 0.01-0.5%, the other components are one or more in light stabilizer, antioxidant, essence;Deionized water surplus.
- 2. foam type fruits and vegetables dish washing detergent compositions according to claim 1, it is characterised in that:The alkyl benzene sulphonate The alkyl carbon chain of magnesium is the straight chained alkyl of 10-16 carbon atom.
- 3. foam type fruits and vegetables dish washing detergent compositions according to claim 1, it is characterised in that:The fatty alcohol polyoxy The fatty alcohol alkyl chain of ethene ether sodium sulfate is the straight chained alkyl of 12-16 carbon atom;The average adduct number of the oxirane of alcohol ether For 1-3.
- 4. foam type fruits and vegetables dish washing detergent compositions according to claim 1, it is characterised in that:The sterilization antiseptic For mixture any or two or more in sodium benzoate, potassium sorbate, methylisothiazolinone, Phenoxyethanol.
- 5. the preparation method of the foam type fruits and vegetables dish washing detergent compositions any one of claim 1-4, its feature exist In including step:Deionized water, magnesium hydroxide and alkyl benzene sulphonate are put into first, input other surfaces activating agent after neutralizing completely, pH adjustment To 6.5-8.0, input chelating agent, sterilization antiseptic and other auxiliary agents;Qualified products are stood to basic non-foam, you can filling to be Finished foam type fruits and vegetables dish washing detergent compositions.
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