KR100711492B1 - Vegetable and fruit cleaner - Google Patents

Abstract

The present invention is an acid capable of producing an alkali buffer system with low bubble generation and excellent cleaning power, so that carbonates and / or bicarbonates, potassium pyrophosphates, and cyclotextins are essential sources of monocarboxylic or polycarboxylic acids and carbonates. It may further contain any binder and any lubricant. The detergent composition of the present invention provides a detergent composition for anhydrous effervescent vegetable fruit of a novel tablet type that increases washing power, has excellent skin safety, and is free from edible problems.

Acids, carbonates, cyclodextrins, effervescent, tablets, detergent compositions

Description

Effervescent tablet-type vegetable and fruit detergent composition {Vegetable and fruit cleaner}

An object of the present invention relates to a foamed tablet vegetables and fruit detergents that are harmless to the human body, which can easily remove dust, microorganisms, pesticides and various contaminations on the surfaces of vegetables and fruits.

The present invention removes residual pesticides, parasites and various contaminants on the surface of vegetable fruits, and is safe for human body and effectively removes microorganisms. Unlike dish detergents, it is environmentally friendly.

Increasing use of chemical fertilizers and pesticides and air pollution are increasing pollution to crops such as vegetables and fruits. In addition, various chemical treatments are applied to crops to maintain the freshness of crops (prevention of corruption) according to the opening of imports, and the contamination caused by this is increasing, and any chemicals left in fruits and vegetables by careless washing are harmful to humans. Might have Of course, fruits such as apples, pears, and persimmons can be eaten relatively safely by simple washing and removal of the skin, but vegetables such as strawberries, grapes, lettuce, and cabbages with or without skins can be eaten with water. Since salts are difficult to wash sufficiently, detergents for washing vegetables and fruits are required.

Vegetable and fruit cleaning detergents require the following conditions.

1) It should be easy to remove pesticides, microorganisms and other contaminants on the surface of vegetables and fruits by simple methods.

2) It should be easily rinsed so that it does not remain and it should be safe even if it remains.

3) It should not be the cause of skin damage and disease.

4) It should not adversely affect the freshness of vegetables and fruits during washing.

5) Do not cause environmental pollution after cleaning.

By the way, most consumers (more than 95%) use only water to remove the contamination of vegetables or fruits, and a few consumers use neutral detergent which is the main ingredient of higher alcohol anionic surfactant. However, it is difficult to rinse because many bubbles are generated to wash fruits, and various types of surfactants and impurities can cause skin irritation and irritation. Therefore, emollients or skin protection agents that reduce toxicity are often added.

Foaming can be defined as bubble generation in liquids. Chapter 6 of Pharmaceutical Dosage Forms; Tablets Volume 1, Second Edition. A. Lieberman. Ed. The effervescent mixtures described in 1989, Marcel Dekker, Inc. have been known for decades and have been used for a variety of applications. Examples of such applications include dental compositions containing enzymes, contact lens cleaners, detergent powders, beverage sweeteners, chewing toothpastes, denture cleaners, surgical disinfectants, foamy candy, as well as pharmaceutical combinations such as analgesics and antibiotics. All. The technology has been found to be applied in various areas, namely laundry detergent compositions, immersion detergent compositions, dishwashing compositions or household detergent compositions, pharmaceutical preparations, dental preparations, foodstuffs and the like. In particular, the present invention relates to a detergent composition for foamable tablet vegetables and fruits, which exhibits excellent detergency against dust, microorganisms, pesticides, and various contaminations on vegetables and fruits, is less foamed, and is safe for human body.

Effervescent tablets include US 1262888, Westlake, US 3962417, Howell, US 4753792, Aberg, and the like. Water-soluble binders are disclosed, and EP 3075834, US Pat. No. 30,425, 31 to Real et al. Discloses the use of lubricants for tableting. Lubricant means a material that can reduce the friction that occurs at the interface between the tablet and the die (DIE) wall during compression and release. The lubricant can be intrinsic or extrinsic. Lubricants used in the form of a film directly on the surface of the tableting means, such as by spraying on the die cavity and / or punch surface, are known as external lubricants. External lubricants provide effective lubrication but their use requires complex application equipment and methods that add cost and reduce productivity. Intrinsic lubricants also delay the decomposition of non-expandable tablets, and the conventional inherent lubricants are hydrogenated and partially hydrogenated vegetable oils, animal fats, polyoxyethylene glycol, polyoxyethylene monostearate, talc, soft minerals. Oils, sodium benzoates, sodium laurate, magnesium oxide, and the like can cause scuming and / or agglomeration.

Accordingly, the present invention has been made to satisfy the conditions of the above-described detergent for vegetables and fruits, and at the same time to solve the problems with the conventional effervescent tablets described above, the object of the present invention is to show excellent cleaning power while generating less bubbles It is possible to maintain the freshness of vegetables and fruits by improving the bactericidal activity against microorganisms. Has distinctive features.

The present invention is an acid capable of producing an alkaline buffer system with low bubble generation and excellent cleaning power, so that carbonate and / or bicarbonate, potassium pyrophosphate, and cyclonetextrin are essential sources of monocarboxylic or polycarboxylic acid and carbonate. It may further contain any binder and any lubricant. The detergent composition of the present invention provides a detergent composition for anhydrous effervescent vegetable fruit of a novel tablet type that increases washing power, has excellent skin safety, and is free from edible problems.

It will be understood that "anhydrous" is substantially free of water, i.e., no water is added or no water other than the moisture of the raw material itself is present. Typically the amount of water is 5% by weight or less, preferably 3% by weight or less, more preferably 1% by weight or less of the total composition.

Anhydrous effervescent tablets produce carbon dioxide very quickly, which promotes the rate of dispersion and decomposition of the tablet composition.

Suitable acids for use in the present invention include solid organic acids, mineral or inorganic acids, salts or derivatives thereof or mixtures thereof. Monoprotonic acid, aprotic acid or triprotonic acid is preferred as the acid. Such acids include mono carboxylic acids or polycarboxylic acids. Preferably citric acid, adipic acid, glutaric acid, triketoglutaric acid, citramal acid, tartaric acid, maleic acid, fumaric acid, malic acid, succinic acid or malonic acid are used. Such acids are preferably used in their acidic form, but may also be used in their anhydrous form or mixtures thereof. By using citric acid, tartaric acid, maleic acid and malic acid as more preferred acids in the effervescent tablets of the present invention. Purifications provide physical and / or chemical stability even for long term storage. In particular, citric acid is most preferred. In order to promote the foaming capacity and to suit the storage stability of the purified product, it is preferable to maintain the amount of citric acid in the foamable anhydrous tablet to 40% by weight or less.

The acid is present in the anhydrous effervescent tablet in the present invention in an amount of 3 to 75%, more preferably 5 to 60% and most preferably 15 to 40% by weight of the total tablet.

Another essential feature of the invention is a carbonate source comprising carbonates, bicarbonates and percarbonates, in particular bicarbonates and / or carbonates. Carbonates suitable for use in the present invention include carbonates and hydrogen carbonates of potassium, lithium, sodium, and the like, of which sodium carbonate and potassium carbonate are preferred. Bicarbonates suitable for use in the present invention include alkali metal salts of bicarbonates of potassium, lithium, sodium, of which sodium bicarbonate and potassium bicarbonate are preferred. Carbonates or bicarbonates or mixtures thereof in anhydrous effervescent tablets may be selected according to the desired pH in an aqueous medium in which the anhydrous effervescent tablets are dissolved. In the present invention, since a relatively high pH is required in the aqueous medium to enhance the cleaning power, it is preferable to use carbonate alone or a mixture of carbonate and bicarbonate.

Carbonates and / or bicarbonates are present in the anhydrous effervescent tablets in the present invention in amounts of 20 to 90% by weight, more preferably 30 to 80% by weight and most preferably 45 to 75% by weight of the total tablet.

In addition, potassium pyrophosphate used in the present invention has 10 to 30 times higher solubility than sodium pyrophosphate or sodium hexametaphosphate, and plays a role of increasing cleaning power due to its excellent performance as an inorganic surfactant and the blocking effect of metal ions. . In 1 wt% or less of potassium pyrophosphate, the detergency is greatly deteriorated. Therefore, it is necessary to use the degreasing agent at a concentration of 1 wt% or more, and at 30 wt% or more, it may cause skin irritation. Potassium pyrophosphate and sodium hydrogen carbonate mentioned above play an important role in increasing the washing power of potassium pyrophosphate as a buffer agent that maintains a constant alkaline pH when washing vegetable fruits. In particular, by maintaining the pH constant in the dilute solution, the effect of improving the cleaning power is given.

Potassium pyrophosphate is present in the anhydrous foam in the present invention in an amount of 1 to 30% by weight, more preferably 3 to 25% by weight and most preferably 5 to 20% by weight of the total tablet.

The water soluble non-complexed cyclodextrins usable in the effervescent tablets of the present invention are known cyclodextrins, such as unsubstituted cyclodextrins having a glucose unit number of 6-12, in particular alpha-cyclodextrins, beta-cyclodextrins, gamma-cyclodextrins. And / or derivatives thereof and / or mixtures thereof. Alpha-cyclodextrin consists of six glucose units, beta-cyclodextrin consists of seven glucose units, and gamma-cyclodextrin consists of eight glucose units arranged in a donut ring. Specific coupling and coordination of glucose units provides the cyclodextrin with a rigid, conical molecular structure having a specific volume of hollow interior. Hydrogen atoms and glycosidic cross-linked oxygen atoms form the "lining" of each internal cavity and therefore the surface is hydrophobic. The unique morphology and physico-chemical properties of the cavity allow the cyclodextrin molecules to absorb organic molecules or parts of the organic molecules that can fit into the cavity. Many undesirable substances and aromatic molecules present in vegetables, fruits may be suitable in the voids. Therefore, cyclodextrins, in particular mixtures of cyclodextrins having cavities of different sizes, can be used to form more water soluble complexes to enhance the removal of undesirable substances and aromas. In particular, complexation between cyclodextrin and organic material occurs rapidly in the presence of water.

The cyclodextrins used in the present invention are preferably highly water soluble, such as alpha-cyclodextrins and / or derivatives thereof, gamma-cyclodextrins and / or derivatives thereof, derivatized beta-cyclodextrins and / or mixtures thereof. Derivatives of cyclodextrins consist primarily of molecules in which some of the OH groups have been converted to OR groups. Examples of cyclodextrin derivatives include those having short-chain alkyl groups in which R is a methyl or ethyl group, such as methylated cyclodextrins and ethylated cyclodextrins; Those having a hydroxy alkyl substituent, such as hydroxypropyl, cyclodextrin and / or hydroxy ethyl cyclodextrin, wherein R is —CH 2 —CH (OH) —CH 3 or —CH 2 CH 2 —OH; Side chain cyclodextrins such as maltose-linked cyclodextrins; Cationic cyclodextrins wherein R is CH 2 -CJ (OH) -CH 2 -N (CH 3) 2, which is cationic at low pH, such as those containing 2-hydroxy-3- (dimethylamino) propyl ether; Quaternary ammonium wherein R is CH 2 -CH (OH) -CH 2 -N (CH 3) 3 Cl, for example the group 2-hydroxy-3- (trimethylammonio) propyl ether chloride; Anionic cyclodextrins such as carboxymethyl cyclodextrin, cyclodextrin sulfate and cyclodextrin succinylate; Amphoteric cyclodextrins such as carboxymethyl / quaternary ammonium cyclodextrins; Cyclodextrins in which at least one glucopyranose unit is a 3-6-anhydro-cyclomalto structure, for example, "Optimal Performances with Minimal Chemical Modification of Cyclodextrins", F. Diedaini-Pilard and B. Perly, The 7 ^th International Cyclodextrin Symposium Abstracts, April 1994, p. Mono-3-6-anhydrocyclodextrin, as described in 49; And mixtures thereof. Other cyclodextrin derivatives are described in the following documents: US Pat. No. 3,426,011 issued to Parmerter et al., Dated Feb. 4, 1969: 3,453,257; No. 3,453,258; 3,453,259; And 3,453,260, all issued by Parmerter et al., July 1, 1969; No. 3,459,731 (Gramera et al., Issued August 5, 1969); No. 3,553,191 (Parmerter et al., Issued January 5, 1971); 3,565,887 (Parmerter et al., Issued February 23, 1971); No. 4,535,152 (Szejtli et al., Issued August 13, 1985); 4,616,008 (Hiral et al., Issued October 7, 1986); No. 4,678,598 (Ogino et al., Issued July 7, 1987); wp4,638,058 (Brand et al., issued January 20, 1987); And 4,746,734 (Tsuchiyama et al., Issued February 4, 1969); All of these patents are incorporated herein by reference.

Examples of preferred water soluble cyclodextrin derivatives suitable for use in the present invention include hydroxypropyl alpha-cyclodextrin, methylated alpha-cyclodextrin, methylated beta-cyclodextrin, hydroxyethyl beta-cyclodextrin, and hydroxypropylbeta. Cyclodextrin. The degree of substitution of the hydroxy alkyl cyclodextrin derivatives is preferably about 1 to about 14, more preferably about 1.5 to about 7, wherein the total number of OR groups per cyclodextrin is defined as the degree of substitution. The degree of substitution of the derivative is typically about 1 to 18, preferably about 3 to about 16. Known methylated beta-cyclodextrins are typically DIMEB (abbreviated for heptakis-2,6-di-O-methyl-beta-cyclodextrin), each glucose unit having about two methyl groups and having a degree of substitution About 14, heptakis-2,6-di-O-methyl-beta-cyclodextrin. Preferred, commercially available methylated beta-cyclodextrins are commonly known as RAMEB (abbreviated for randomly methylated beta-cyclodextrins) and are randomly methylated with different degrees of substitution, typically about 12.6. Beta-cyclodextrin. RAMER is more preferred than DIMEB because DIMEB affects the surfactant activity of a preferred surfactant over RAMEB. Preferred cyclodextrins are described, for example, in Cerestar USA, Inc. And Wacker Chemicals (USA), Inc.

The amount effective to remove the organic residue of the cyclodextrin is from 0.01% to 20% by weight, preferably from 3 to 15% by weight and most preferably from 5 to 10% by weight of the total weight of the composition.

Effervescent tablets of the present invention may comprise any binder or mixtures thereof. The binder serves to bind the raw materials in powder form well at standard temperature and pressure to make the tablets sufficiently hard during tableting, and 0.1 to 10% by weight of the total weight of the composition is used. If less than 0.1% by weight, the bonding strength is weak and easily broken, and if it is 10% by weight or more, it becomes difficult to form a tablet. Typically the effervescent tablets comprise up to about 10% by weight, preferably at most 5% by weight and most preferably at most 2% by weight of the binder and mixtures thereof before. Preferred binders include polymeric materials such as polyvinylpyrrolidone having an average molecular weight of 12000 to 700000 and polyethylene glycol having an average molecular weight of 600 to 10000. Where a binder is required, polyvinylpinolidone having an average molecular weight of 12000 to 700000 is preferred.

Effervescent tablets of the present invention may comprise any lubricant or mixtures thereof. Lubricants are used to make a smooth process in the tableting process to make a foamable tablet form, and 0.1 to 20% by weight of the total weight of the composition is used. Less than 0.1% by weight of the tableting machine is difficult to make a certain type of tablets, and more than 20% by weight of the lubricant usually has a low solubility, which is left as a form of residue during melting, and the price is very high, so the economic disadvantage have. Typically the lubricant is present in the anhydrous expandable tablet in the present invention in an amount ranging from 0.1 to 20% by weight, preferably 0.5 to 7% by weight and most preferably 1 to 5% by weight of the total composition. Lubricants suitable for use in the present invention include L-valine, C8 to C20 sucrose fatty acid esters, sodium benzoate, polyoxyethylene glycol. Particular preference is given to L-valine for the present invention where a lubricant is required.

The present invention has a viscosity of 200 to 1500 centiposie of the conventional dishwashing method and the method of use is generally put the dishwashing detergent in water and write it down by hand to release the detergent or directly wash the dishes and utensils on the sponge or scrubber. However, in the case of washing vegetables or fruits, the same method of using dishwashing detergent is somewhat inconvenient to wash, and a considerable amount of air bubbles are generated. Put the foam tablet into the water, bubbles are automatically generated to wash vegetables and fruits, and in pursuit of convenience of use. In addition, neutral detergents, which are mainly composed of high-alcohol anionic surfactants that have been used by a few consumers to wash vegetables and fruits, can cause skin irritation and irritation due to various surfactants and impurities. All raw materials used in the composition are edible and safe for the skin, so that only the raw materials listed in the food or food additives can be used to obtain better skin safety than the conventional detergents used.

The foaming effect shows excellent cleaning power, very low bubble holding ability, and excellent bactericidal power to maintain the freshness of vegetables and fruits while easily removing dust, microorganisms, pesticides and various contaminations on the surfaces of vegetables and fruits. Harmless and irritant-free detergent composition of the present invention can be applied to the cleaning of food-related products. In particular, it can be used to wash vegetables and fruits.

Hereinafter, the present invention will be described in detail with reference to Examples, but these Examples do not limit the technical scope of the present invention.

Example  1-8

A detergent composition was prepared according to Table 1 below.

   Effervescent Tablet-type Detergent Composition Example Comparative example One 2 3 4 5 6 7 8 One Citric Anhydride 30 30 30 30 30 30 30 30 30 Sodium bicarbonate 65 60 50 45 42 40 41 40 70 Sodium pyrophosphate 5 15 15 15 15 15 15 15 Beta-cyclodextrin 5 10 10 10 10 10 L-valine 3 5 3 3 Polyvinylpyrrolidone One 2

In order to compare with Example, the detergent composition which consists of citric anhydride and sodium hydrogencarbonate was used as the comparative example 1, and the commercial neutral kitchen detergent made from the alkylsulfonate salt (EO) 3 was used as the comparative example 2 and the purified water as the comparative example 3. It was.

The following experiments were carried out using the detergent compositions of Examples 1-8 and Comparative Examples 1-3 as experimental solutions.

Experimental Example  1: pesticide residue evaluation

250 g of crops were immersed in 7 liters of 1.0% by weight of the experimental solution (solutions of Examples 1-8 and Comparative Examples 1-3) for 5 minutes, washed first in a 500 rpm shaker for 3 minutes, and then washed with 3 liters of tap water. After washing for 2 minutes in a shaker of 500rpm for 2 minutes, it is dried at room temperature for 1 day.

After drying, 200 g of the crop is washed with 250 ml of acetone and extracted. The extract is taken up in 10 ml of hexane, filtered and concentrated by reduced pressure. The concentrate is again taken up in 10 ml of hexane and analyzed by GC / FID. The results are shown in Table 2.

  Pesticide Reduction Rate Initial Pesticide Concentration (ppm) 1st wash Secondary cleaning Pesticide Residue (ppm) Removal rate (%) Pesticide Residue (ppm) Removal rate (%) Example 1 15.35 2.86 81.4 2.22 85.5 Example 2 15.32 2.22 85.5 1.61 89.5 Example 3 15.26 2.00 86.9 1.42 90.7 Example 4 15.22 1.92 87.4 1.17 92.3 Example 5 15.36 1.82 88.2 1.09 92.9 Example 6 15.32 1.69 88.5 0.98 93.6 Example 7 15.24 1.59 89.0 0.89 94.2 Example 8 15.34 1.45 90.5 0.80 94.8 Comparative Example 1 15.46 3.03 80.4 2.63 83.0 Comparative Example 2 15.19 1.65 89.1 0.98 93.5 Comparative Example 3 15.68 5.05 67.8 4.61 70.6

As shown in Table 2, the pesticide removal effect on the crop of the detergent composition of Comparative Example 1 is slightly inferior to Examples 1 to 2, which is different in the residual pesticide removal effect by the difference in the content of potassium pyrophosphate To prove that there is. Detergent compositions of Examples 3 to 7 are relatively superior to the pesticide removal effect of citric acid and sodium bicarbonate of Comparative Example 1, but somewhat inferior to the neutral dish detergent of Comparative Example 2. However, Example 8 shows a superior pesticide removal ability than the neutral dish detergent of Comparative Example 2, and shows an overall excellent pesticide removal effect than the pesticide removal effect on the purified water of Comparative Example 3.

Experimental Example  2: cleaning power evaluation

According to the KS M 2716 method, contaminants mainly composed of tallow and soybean oil were prepared and uniformly coated on slide glass, and then washed for 3 minutes using a stirring and mixed cleaning power tester (rotation speed of 100 rpm). Are dissolved and the UV absorbance is measured, respectively, and is determined as the decontamination rate (%). The results are shown in Table 3.

  Detergency rating Detergent composition Cleaning rate (%) Example 1 70 Example 2 80 Example 3 81 Example 4 83 Example 5 86 Example 6 89 Example 7 92 Example 8 95 Comparative Example 1 60 Comparative Example 2 98 Comparative Example 3 35

As can be seen from the above results, the composition of Example 7-8 showed excellent cleaning power.

Experimental Example  3: microbial removal evaluation

In order to measure the effect of removing microorganisms on cucumber and red pepper, 200 g of the standard sample was immersed in 1000 ml of 0.2 wt% of experimental solution (solutions of Examples 1-8 and Comparative Examples 1-3), stirred for 1 minute, and then 200 rpm. After washing with tap water for 30 seconds in a shaker, shake 1000 ml of brine containing 100 g of standard sample for 25 times, and then remove the standard sample remaining in 1 ml of solution to determine the number of living microorganisms remaining in the sample. Evaluate the number of viable microbes per gram. The results are shown in Table 4.

  Living microbial water Detergent composition ＼ sample cucumber pepper Example 1 1613 1548 Example 2 1402 1417 Example 3 862 831 Example 4 664 588 Example 5 475 392 Example 6 351 215 Example 7 305 190 Example 8 295 181 Comparative Example 1 1987 1728 Comparative Example 2 3446 2923 Comparative Example 3 47876 48882

As shown in Table 4, the detergent compositions of Examples 1-8 effectively remove microorganisms. However, Comparative Example 1, which is a detergent composition of citric acid and sodium hydrogen carbonate, and Comparative Example 2, which is a neutral dish detergent, are about half of Examples 3 to 8, which are detergent compositions composed of citric acid, sodium hydrogen carbonate, potassium pyrophosphate, cyclonedextrin, and valine. Only levels of microbes were removed.

Experimental Example  4: Skin irritation evaluation ( Closed cloth  exam)

A patch sample of 2 wt% test solution (solutions of Examples 1-8 and Comparative Examples 1-3) was attached to the inner side of the upper arm, and then elapsed after 48 hours. 4 hours after removing the sample, the degree of erythema is visually determined. The determination criteria are shown in Table 5 below, and the results are shown in Table 6.

  Criteria Visual judgment Judgment code No erythema ◎ Slightly red than the surroundings ○ 1/3 or more red symptoms △ Red, browning, blistering, etc. ×

  Skin irritation evaluation Detergent composition Skin irritation Example 1 ◎ Example 2 ◎ Example 3 ◎ Example 4 ◎ Example 5 ◎ Example 6 ◎ Example 7 ◎ Example 8 ◎ Comparative Example 1 ◎ Comparative Example 2 × Comparative Example 3 ◎

As shown in Table 6, the skin irritation evaluation results for Examples 1 to 8 show that the skin irritation is much better than Comparative Example 2, a neutral kitchen detergent.

The present invention relates to a foamed tablet-type detergent for vegetables and fruits, which is harmless to the human body, which can easily remove dust, microorganisms, pesticides, and various contaminations on the surface of vegetables and fruits. It also helps to maintain the freshness of vegetables and fruits, and is environmentally friendly unlike general dish detergents.

Claims (16)

A carbonate source of an acid, carbonate or bicarbonate of a monocarboxylic acid or a polycarboxylic acid or a mixture thereof, essentially containing potassium pyrophosphate and cyclodextrin, and additionally one selected from L-valine, polyvinylpyrrolidone Detergent composition for anhydrous foamable vegetable fruits of the tablet type containing the above. The method of claim 1, wherein the cyclodextrin is at least one selected from the group consisting of alpha, beta, gamma-cyclodextrin or derivatives thereof. The method of claim 2, wherein the alpha, beta, gamma-cyclodextrin derivative is an anhydrous effervescent vegetable of the tablet type, characterized in that the H of the OH group of the cyclodextrin is substituted with methyl, ethyl, hydroxyethyl or hydroxypropyl. Detergent composition for fruit only. 4. The detergent composition according to any one of claims 1 to 3, wherein the cyclodextrin content effective for removing organic residues is 0.01% to 20% by weight of the total weight of the composition. . 5. The detergent composition according to claim 4, wherein the cyclodextrin content is 5 to 10% by weight of the total composition. The method of claim 1, wherein the monocarboxylic acid or polycarboxylic acid is citric acid, adipic acid, glutaric acid, 3-ketoglutaric acid, citramal acid, tartaric acid, maleic acid, fumaric acid, malic acid, succinic acid or malonic acid Detergent composition for anhydrous foamable vegetable fruit of the tablet type, characterized in that at least one member selected from the group consisting of. 7. The detergent composition according to claim 1 or 6, wherein the monocarboxylic acid or polycarboxylic acid content is 3 to 75% by weight of the total composition. 8. The detergent composition according to claim 7, wherein the monocarboxylic acid or polycarboxylic acid content is 15 to 40% by weight of the total composition. 2. The detergent composition according to claim 1, wherein the carbonate or bicarbonate or a mixture thereof is 20 to 90% by weight of the total composition. 10. The detergent composition according to claim 9, wherein the content of carbonate or bicarbonate or a mixture thereof is 45 to 75% by weight of the total composition. 2. The detergent composition according to claim 1, wherein the potassium pyrophosphate contains 1 to 30% by weight of the total composition. 12. The detergent composition according to claim 11, wherein the potassium pyrophosphate contains 5 to 20% by weight of the total composition. 2. The detergent composition according to claim 1, wherein the polyvinylpyrrolidone contains 0.1% to 10% by weight of the total composition. 15. The detergent composition according to claim 13, wherein the polyvinylpyrrolidone contains 0.1% to 2% by weight of the total composition. 2. The detergent composition according to claim 1, wherein the tablet composition contains 0.1 to 20% by weight of L-valine. 16. The detergent composition according to claim 15, wherein the tablet composition contains only 1% to 5% by weight of L-valine.