JP2012102025A - 乳化型毛髪用化粧料 - Google Patents
乳化型毛髪用化粧料 Download PDFInfo
- Publication number
- JP2012102025A JP2012102025A JP2010249388A JP2010249388A JP2012102025A JP 2012102025 A JP2012102025 A JP 2012102025A JP 2010249388 A JP2010249388 A JP 2010249388A JP 2010249388 A JP2010249388 A JP 2010249388A JP 2012102025 A JP2012102025 A JP 2012102025A
- Authority
- JP
- Japan
- Prior art keywords
- hair
- fatty acid
- acid ester
- cosmetic
- sucrose
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 210000004209 hair Anatomy 0.000 title claims abstract description 149
- 239000002537 cosmetic Substances 0.000 title claims abstract description 57
- 239000000839 emulsion Substances 0.000 title abstract description 7
- -1 sucrose fatty acid ester Chemical class 0.000 claims abstract description 128
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 85
- 239000000194 fatty acid Substances 0.000 claims abstract description 85
- 229930195729 fatty acid Natural products 0.000 claims abstract description 85
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 43
- 229930006000 Sucrose Natural products 0.000 claims abstract description 35
- 239000005720 sucrose Substances 0.000 claims abstract description 35
- KIUKXJAPPMFGSW-DNGZLQJQSA-N (2S,3S,4S,5R,6R)-6-[(2S,3R,4R,5S,6R)-3-Acetamido-2-[(2S,3S,4R,5R,6R)-6-[(2R,3R,4R,5S,6R)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylic acid Chemical class CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 KIUKXJAPPMFGSW-DNGZLQJQSA-N 0.000 claims abstract description 12
- 239000003093 cationic surfactant Substances 0.000 claims abstract description 11
- 238000002156 mixing Methods 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 10
- 150000002191 fatty alcohols Chemical class 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 13
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 abstract description 7
- 238000013329 compounding Methods 0.000 abstract description 7
- 229920000223 polyglycerol Polymers 0.000 abstract description 6
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 abstract description 3
- 239000000600 sorbitol Substances 0.000 abstract description 3
- 239000003676 hair preparation Substances 0.000 description 24
- 238000011282 treatment Methods 0.000 description 22
- 230000000694 effects Effects 0.000 description 13
- 239000002253 acid Substances 0.000 description 11
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 8
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 8
- 150000004665 fatty acids Chemical class 0.000 description 7
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- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 5
- 150000001298 alcohols Chemical class 0.000 description 5
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- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 4
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 4
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- 229920002907 Guar gum Polymers 0.000 description 4
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- 239000005642 Oleic acid Substances 0.000 description 4
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 4
- 239000002738 chelating agent Substances 0.000 description 4
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 239000003925 fat Substances 0.000 description 4
- 235000010417 guar gum Nutrition 0.000 description 4
- 239000000665 guar gum Substances 0.000 description 4
- 229960002154 guar gum Drugs 0.000 description 4
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 4
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 4
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- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 4
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000005639 Lauric acid Substances 0.000 description 3
- 241001465754 Metazoa Species 0.000 description 3
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- 239000004359 castor oil Substances 0.000 description 3
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- 239000003795 chemical substances by application Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 3
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- 239000003755 preservative agent Substances 0.000 description 3
- 230000002335 preservative effect Effects 0.000 description 3
- 239000008117 stearic acid Substances 0.000 description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 description 3
- 239000008158 vegetable oil Substances 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- FRPZMMHWLSIFAZ-UHFFFAOYSA-N 10-undecenoic acid Chemical compound OC(=O)CCCCCCCCC=C FRPZMMHWLSIFAZ-UHFFFAOYSA-N 0.000 description 2
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 2
- WNWHHMBRJJOGFJ-UHFFFAOYSA-N 16-methylheptadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 description 2
- ASKIVFGGGGIGKH-UHFFFAOYSA-N 2,3-dihydroxypropyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(O)CO ASKIVFGGGGIGKH-UHFFFAOYSA-N 0.000 description 2
- 229940100555 2-methyl-4-isothiazolin-3-one Drugs 0.000 description 2
- LEEDMQGKBNGPDN-UHFFFAOYSA-N 2-methylnonadecane Chemical compound CCCCCCCCCCCCCCCCCC(C)C LEEDMQGKBNGPDN-UHFFFAOYSA-N 0.000 description 2
- 235000021357 Behenic acid Nutrition 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N Caprylic acid Natural products CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 2
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 235000021314 Palmitic acid Nutrition 0.000 description 2
- 229920002385 Sodium hyaluronate Polymers 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- ZPVGIKNDGJGLCO-VGAMQAOUSA-N [(2s,3r,4s,5s,6r)-2-[(2s,3s,4s,5r)-3,4-dihydroxy-2,5-bis(hydroxymethyl)oxolan-2-yl]-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl] hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)O[C@@]1([C@]2(CO)[C@H]([C@H](O)[C@@H](CO)O2)O)O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O ZPVGIKNDGJGLCO-VGAMQAOUSA-N 0.000 description 2
- SZYSLWCAWVWFLT-UTGHZIEOSA-N [(2s,3s,4s,5r)-3,4-dihydroxy-5-(hydroxymethyl)-2-[(2r,3r,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxolan-2-yl]methyl octadecanoate Chemical compound O([C@@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)[C@]1(COC(=O)CCCCCCCCCCCCCCCCC)O[C@H](CO)[C@@H](O)[C@@H]1O SZYSLWCAWVWFLT-UTGHZIEOSA-N 0.000 description 2
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- 239000003963 antioxidant agent Substances 0.000 description 2
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- 235000013871 bee wax Nutrition 0.000 description 2
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- 229940116226 behenic acid Drugs 0.000 description 2
- KHAVLLBUVKBTBG-UHFFFAOYSA-N caproleic acid Natural products OC(=O)CCCCCCCC=C KHAVLLBUVKBTBG-UHFFFAOYSA-N 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
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- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
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- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
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- MVLVMROFTAUDAG-UHFFFAOYSA-N ethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC MVLVMROFTAUDAG-UHFFFAOYSA-N 0.000 description 2
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Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
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Abstract
【解決手段】 脂肪族アルコール、カチオン性界面活性剤、ショ糖脂肪酸エステル、ポリグリセリン脂肪酸エステルおよびポリオキシエチレンソルビット脂肪酸エステルが配合されていることを特徴とする乳化型毛髪用化粧料により、上記課題を解決する。本発明の乳化型毛髪用化粧料においては、ショ糖脂肪酸エステルおよびポリグリセリン脂肪酸エステルの配合量の合計A(質量%)とポリオキシエチレンソルビット脂肪酸エステルの配合量B(質量%)との比が1:1〜8:1であることが好ましく、また、ヒアルロン酸誘導体が更に配合されていることが好ましい。
【選択図】 なし
Description
実施例1〜7および比較例1〜4の毛髪用化粧料を、表1〜表3に示す組成で調製した。なお、実施例1〜7および比較例1〜4の毛髪用化粧料は、これらの調製後に、いずれも良好に乳化していた。
被験者5名の頭髪を、それぞれ別の専門の評価者5名が洗髪し、続いて実施例および比較例の毛髪用化粧料を塗布して仕上げ、その際の毛髪用化粧料の毛髪への塗布性と、処理後の毛髪のおさまりのよさとを、上記専門の評価者5名が評価した。まず、被験者の頭髪を表4に示す組成のシャンプー6gを用いて洗髪し、その後に実施例および比較例の毛髪用化粧料各6gを毛髪に付け、しっかりと毛髪を揉み込んだ後に温水で洗い流し、乾燥させた。そして、上記専門の評価者5名のそれぞれが、被験者の毛髪に毛髪用化粧料を付け、その毛髪を揉み込んだ際の毛髪用化粧料の塗布性と、処理後(乾燥後)の毛髪のおさまりのよさとを、下記の評価基準に従って点数付けした。
よい 2点、
ややよい 1点、
普通 0点、
やや悪い −1点、
悪い −2点。
上記被験者のうち、最も毛髪のくせの強い者1名から、上記の毛髪への塗布性および処理後の毛髪のおさまりのよさを評価する前(洗髪前)の毛髪(すなわち、毛髪用化粧料での処理前の毛髪)0.5gと、各毛髪用化粧料で処理した後(乾燥後)の毛髪各0.5gとを採取した。次に、これらの毛髪を25℃、相対湿度50%の環境下で24時間以上保管した後に、各毛髪約0.01gを採取してアルミホイルに精秤し、カールフィッシャー水分測定装置を用いて各毛髪中の水分量を測定した。そして、各毛髪用化粧料で処理した後の毛髪の水分量から、毛髪用化粧料での処理前の毛髪の水分量を引いて、これらの差を求めた。
Claims (3)
- 脂肪族アルコール、カチオン性界面活性剤、ショ糖脂肪酸エステル、ポリグリセリン脂肪酸エステルおよびポリオキシエチレンソルビット脂肪酸エステルが配合されていることを特徴とする乳化型毛髪用化粧料。
- ショ糖脂肪酸エステルの配合量とポリグリセリン脂肪酸エステルの配合量との合計をA(質量%)、ポリオキシエチレンソルビット脂肪酸エステルの配合量をB(質量%)としたとき、A:Bが1:1〜8:1である請求項1に記載の乳化型毛髪用化粧料。
- ヒアルロン酸誘導体が更に配合されている請求項1または2に記載の乳化型毛髪用化粧料。
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JPH1179943A (ja) * | 1997-09-04 | 1999-03-23 | Mirubon:Kk | 毛髪保護剤 |
JP2009280530A (ja) * | 2008-05-23 | 2009-12-03 | Milbon Co Ltd | 乳化型毛髪化粧料 |
JP2009292732A (ja) * | 2008-05-02 | 2009-12-17 | Milbon Co Ltd | 乳化型毛髪化粧料 |
JP2009292733A (ja) * | 2008-05-08 | 2009-12-17 | Milbon Co Ltd | 乳化型毛髪化粧料 |
JP2010235567A (ja) * | 2009-03-31 | 2010-10-21 | Kose Corp | 水中油乳化型毛髪化粧料 |
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JPH04235114A (ja) * | 1990-05-24 | 1992-08-24 | Unilever Nv | 化粧品エマルジョン |
JPH1179943A (ja) * | 1997-09-04 | 1999-03-23 | Mirubon:Kk | 毛髪保護剤 |
JP2009292732A (ja) * | 2008-05-02 | 2009-12-17 | Milbon Co Ltd | 乳化型毛髪化粧料 |
JP2009292733A (ja) * | 2008-05-08 | 2009-12-17 | Milbon Co Ltd | 乳化型毛髪化粧料 |
JP2009280530A (ja) * | 2008-05-23 | 2009-12-03 | Milbon Co Ltd | 乳化型毛髪化粧料 |
JP2010235567A (ja) * | 2009-03-31 | 2010-10-21 | Kose Corp | 水中油乳化型毛髪化粧料 |
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JP2016175874A (ja) * | 2015-03-20 | 2016-10-06 | 株式会社ミルボン | シャンプー組成物 |
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