JP2012062449A5 - - Google Patents
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- Publication number
- JP2012062449A5 JP2012062449A5 JP2010210156A JP2010210156A JP2012062449A5 JP 2012062449 A5 JP2012062449 A5 JP 2012062449A5 JP 2010210156 A JP2010210156 A JP 2010210156A JP 2010210156 A JP2010210156 A JP 2010210156A JP 2012062449 A5 JP2012062449 A5 JP 2012062449A5
- Authority
- JP
- Japan
- Prior art keywords
- reaction vessel
- oxygen
- reaction
- gas phase
- mmol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000006243 chemical reaction Methods 0.000 claims description 30
- 238000000034 method Methods 0.000 claims description 27
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 19
- 229910052760 oxygen Inorganic materials 0.000 claims description 19
- 239000001301 oxygen Substances 0.000 claims description 19
- 239000007789 gas Substances 0.000 claims description 13
- 239000012071 phase Substances 0.000 claims description 12
- 239000007791 liquid phase Substances 0.000 claims description 11
- 150000004820 halides Chemical class 0.000 claims description 10
- 239000000178 monomer Substances 0.000 claims description 10
- 238000006116 polymerization reaction Methods 0.000 claims description 10
- 229910052736 halogen Inorganic materials 0.000 claims description 8
- 239000003999 initiator Substances 0.000 claims description 8
- 239000003054 catalyst Substances 0.000 claims description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
- 239000012295 chemical reaction liquid Substances 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 150000002367 halogens Chemical class 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- 230000000379 polymerizing effect Effects 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 150000001721 carbon Chemical group 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 229910052740 iodine Inorganic materials 0.000 claims description 2
- 239000011630 iodine Substances 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 claims description 2
- 238000010526 radical polymerization reaction Methods 0.000 claims description 2
- 239000011541 reaction mixture Substances 0.000 claims description 2
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 6
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- PFHOSZAOXCYAGJ-UHFFFAOYSA-N 2-[(2-cyano-4-methoxy-4-methylpentan-2-yl)diazenyl]-4-methoxy-2,4-dimethylpentanenitrile Chemical compound COC(C)(C)CC(C)(C#N)N=NC(C)(C#N)CC(C)(C)OC PFHOSZAOXCYAGJ-UHFFFAOYSA-N 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- WYGWHHGCAGTUCH-UHFFFAOYSA-N 2-[(2-cyano-4-methylpentan-2-yl)diazenyl]-2,4-dimethylpentanenitrile Chemical compound CC(C)CC(C)(C#N)N=NC(C)(C#N)CC(C)C WYGWHHGCAGTUCH-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 150000001350 alkyl halides Chemical class 0.000 description 1
- 239000003480 eluent Substances 0.000 description 1
- 239000007792 gaseous phase Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2010210156A JP5605945B2 (ja) | 2010-09-17 | 2010-09-17 | リビングラジカル重合法 |
| US13/824,220 US8642711B2 (en) | 2010-09-17 | 2011-09-14 | Living radical polymerization method |
| PCT/JP2011/005180 WO2012035769A1 (ja) | 2010-09-17 | 2011-09-14 | リビングラジカル重合法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2010210156A JP5605945B2 (ja) | 2010-09-17 | 2010-09-17 | リビングラジカル重合法 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2012062449A JP2012062449A (ja) | 2012-03-29 |
| JP2012062449A5 true JP2012062449A5 (https=) | 2013-05-02 |
| JP5605945B2 JP5605945B2 (ja) | 2014-10-15 |
Family
ID=45831255
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2010210156A Active JP5605945B2 (ja) | 2010-09-17 | 2010-09-17 | リビングラジカル重合法 |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US8642711B2 (https=) |
| JP (1) | JP5605945B2 (https=) |
| WO (1) | WO2012035769A1 (https=) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6044199B2 (ja) * | 2012-09-05 | 2016-12-14 | Dic株式会社 | 重合体の製造方法 |
| JP6292807B2 (ja) * | 2013-09-12 | 2018-03-14 | 株式会社日本触媒 | アルカリ可溶性樹脂の製造方法 |
| JP6516319B2 (ja) * | 2014-01-09 | 2019-05-22 | 公立大学法人大阪市立大学 | 熱硬化性多分岐型高分子とその製造方法および硬化多分岐型高分子 |
| JP2017226791A (ja) * | 2016-06-24 | 2017-12-28 | ナンヤン テクノロジカル ユニヴァーシティー | 樹脂組成物 |
| JP6401218B2 (ja) * | 2016-09-16 | 2018-10-10 | 竹本油脂株式会社 | ビニル重合体の水溶液の製造方法 |
| EP3604352B1 (en) * | 2017-03-30 | 2025-02-19 | Godo Shigen Co., Ltd. | Method for producing a polymer using a molecular-weight controlling agent for radical polymerization |
| CN111433227B (zh) * | 2017-12-11 | 2022-07-01 | 竹本油脂株式会社 | 乙烯基聚合物的制造方法 |
| CN111918893A (zh) * | 2018-03-19 | 2020-11-10 | 株式会社大赛璐 | 光致抗蚀剂用树脂、光致抗蚀剂用树脂的制造方法、光致抗蚀剂用树脂组合物、以及图案形成方法 |
| JP7302159B2 (ja) * | 2018-10-29 | 2023-07-04 | 東亞合成株式会社 | 粘着付与剤及び粘着剤組成物 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19813353A1 (de) * | 1998-03-26 | 1999-09-30 | Bayer Ag | Verfahren zur Herstellung von Telechelen, so hergestellte Telechele und ihre Verwendung |
| US7514263B2 (en) * | 2001-04-02 | 2009-04-07 | 3M Innovative Properties Company | Continuous process for the production of combinatorial libraries of materials |
| US6620885B2 (en) * | 2001-08-30 | 2003-09-16 | General Electric Company | Copolymers of functionalized polyphenylene ether resins and blends thereof |
| US6716935B1 (en) * | 2002-12-19 | 2004-04-06 | 3M Innovative Properties Company | Continuous process for the production of controlled architecture materials under high solids loading conditions |
| GB0505367D0 (en) * | 2005-03-16 | 2005-04-20 | Combining Co The Ltd | A method for producing a grafted polymer coating |
| JP4543178B2 (ja) * | 2005-09-01 | 2010-09-15 | 国立大学法人京都大学 | 新規リビングラジカル重合法 |
| JP2007177217A (ja) * | 2005-11-29 | 2007-07-12 | Toray Fine Chemicals Co Ltd | アクリル共重合体の製造方法 |
| JP2010084106A (ja) * | 2008-10-03 | 2010-04-15 | Toray Fine Chemicals Co Ltd | アクリルエマルジョンおよびその製造方法 |
-
2010
- 2010-09-17 JP JP2010210156A patent/JP5605945B2/ja active Active
-
2011
- 2011-09-14 WO PCT/JP2011/005180 patent/WO2012035769A1/ja not_active Ceased
- 2011-09-14 US US13/824,220 patent/US8642711B2/en not_active Expired - Fee Related
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