JP2011529777A5 - - Google Patents
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- Publication number
- JP2011529777A5 JP2011529777A5 JP2011521118A JP2011521118A JP2011529777A5 JP 2011529777 A5 JP2011529777 A5 JP 2011529777A5 JP 2011521118 A JP2011521118 A JP 2011521118A JP 2011521118 A JP2011521118 A JP 2011521118A JP 2011529777 A5 JP2011529777 A5 JP 2011529777A5
- Authority
- JP
- Japan
- Prior art keywords
- reaction mixture
- antimony
- compound
- compounds
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 36
- 239000011541 reaction mixture Substances 0.000 claims description 30
- 239000003054 catalyst Substances 0.000 claims description 26
- 238000000034 method Methods 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 18
- 239000002243 precursor Substances 0.000 claims description 14
- 239000010955 niobium Substances 0.000 claims description 12
- 150000001463 antimony compounds Chemical class 0.000 claims description 11
- 150000003682 vanadium compounds Chemical class 0.000 claims description 11
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 claims description 10
- 239000005078 molybdenum compound Substances 0.000 claims description 9
- 150000002752 molybdenum compounds Chemical class 0.000 claims description 9
- 229910052787 antimony Inorganic materials 0.000 claims description 8
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 8
- 239000007789 gas Substances 0.000 claims description 8
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 6
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 6
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 6
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 239000003607 modifier Substances 0.000 claims description 6
- 229910052750 molybdenum Inorganic materials 0.000 claims description 6
- 239000011733 molybdenum Substances 0.000 claims description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- 229910052760 oxygen Inorganic materials 0.000 claims description 5
- 239000001301 oxygen Substances 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 5
- 229910052684 Cerium Inorganic materials 0.000 claims description 4
- 229910052779 Neodymium Inorganic materials 0.000 claims description 4
- 229910000410 antimony oxide Inorganic materials 0.000 claims description 4
- 229910052758 niobium Inorganic materials 0.000 claims description 4
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 4
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims description 4
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 claims description 4
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 3
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 claims description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000000470 constituent Substances 0.000 claims description 3
- 239000001282 iso-butane Substances 0.000 claims description 3
- 150000002822 niobium compounds Chemical class 0.000 claims description 3
- FXADMRZICBQPQY-UHFFFAOYSA-N orthotelluric acid Chemical compound O[Te](O)(O)(O)(O)O FXADMRZICBQPQY-UHFFFAOYSA-N 0.000 claims description 3
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 3
- 239000001294 propane Substances 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- 239000010936 titanium Substances 0.000 claims description 3
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 3
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 3
- AHBGXHAWSHTPOM-UHFFFAOYSA-N 1,3,2$l^{4},4$l^{4}-dioxadistibetane 2,4-dioxide Chemical compound O=[Sb]O[Sb](=O)=O AHBGXHAWSHTPOM-UHFFFAOYSA-N 0.000 claims description 2
- 229910052693 Europium Inorganic materials 0.000 claims description 2
- 229910052783 alkali metal Inorganic materials 0.000 claims description 2
- 150000001340 alkali metals Chemical class 0.000 claims description 2
- 229910000411 antimony tetroxide Inorganic materials 0.000 claims description 2
- SZXAQBAUDGBVLT-UHFFFAOYSA-H antimony(3+);2,3-dihydroxybutanedioate Chemical compound [Sb+3].[Sb+3].[O-]C(=O)C(O)C(O)C([O-])=O.[O-]C(=O)C(O)C(O)C([O-])=O.[O-]C(=O)C(O)C(O)C([O-])=O SZXAQBAUDGBVLT-UHFFFAOYSA-H 0.000 claims description 2
- DSXCPKFPLVABHA-UHFFFAOYSA-N antimony;oxalic acid Chemical compound [Sb].OC(=O)C(O)=O DSXCPKFPLVABHA-UHFFFAOYSA-N 0.000 claims description 2
- 150000001495 arsenic compounds Chemical class 0.000 claims description 2
- 150000001639 boron compounds Chemical class 0.000 claims description 2
- 150000001785 cerium compounds Chemical class 0.000 claims description 2
- 229910000420 cerium oxide Inorganic materials 0.000 claims description 2
- 229910052732 germanium Inorganic materials 0.000 claims description 2
- 150000002291 germanium compounds Chemical class 0.000 claims description 2
- YBMRDBCBODYGJE-UHFFFAOYSA-N germanium oxide Inorganic materials O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 claims description 2
- OLQSNYOQJMTVNH-UHFFFAOYSA-N germanium(4+);oxygen(2-) Chemical compound [O-2].[O-2].[Ge+4] OLQSNYOQJMTVNH-UHFFFAOYSA-N 0.000 claims description 2
- 229910052735 hafnium Inorganic materials 0.000 claims description 2
- 150000002642 lithium compounds Chemical class 0.000 claims description 2
- 229910003455 mixed metal oxide Inorganic materials 0.000 claims description 2
- 150000002798 neodymium compounds Chemical class 0.000 claims description 2
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 2
- 150000002910 rare earth metals Chemical class 0.000 claims description 2
- 229910052701 rubidium Inorganic materials 0.000 claims description 2
- 229940065287 selenium compound Drugs 0.000 claims description 2
- 150000003343 selenium compounds Chemical class 0.000 claims description 2
- 150000003482 tantalum compounds Chemical class 0.000 claims description 2
- 229910052718 tin Inorganic materials 0.000 claims description 2
- 150000003658 tungsten compounds Chemical class 0.000 claims description 2
- 229910052727 yttrium Inorganic materials 0.000 claims description 2
- 229910052726 zirconium Inorganic materials 0.000 claims description 2
- 150000003755 zirconium compounds Chemical class 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims 4
- 229920006395 saturated elastomer Polymers 0.000 claims 4
- 229930195734 saturated hydrocarbon Natural products 0.000 claims 4
- 229930195735 unsaturated hydrocarbon Natural products 0.000 claims 4
- 230000003647 oxidation Effects 0.000 claims 3
- 238000007254 oxidation reaction Methods 0.000 claims 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 2
- 229910044991 metal oxide Inorganic materials 0.000 claims 2
- 150000004706 metal oxides Chemical class 0.000 claims 2
- 150000002978 peroxides Chemical class 0.000 claims 2
- AXIFGFAGYFPNFC-UHFFFAOYSA-I 2-hydroxy-2-oxoacetate;niobium(5+) Chemical compound [Nb+5].OC(=O)C([O-])=O.OC(=O)C([O-])=O.OC(=O)C([O-])=O.OC(=O)C([O-])=O.OC(=O)C([O-])=O AXIFGFAGYFPNFC-UHFFFAOYSA-I 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims 1
- 229910021529 ammonia Inorganic materials 0.000 claims 1
- 229940058905 antimony compound for treatment of leishmaniasis and trypanosomiasis Drugs 0.000 claims 1
- XFHGGMBZPXFEOU-UHFFFAOYSA-I azanium;niobium(5+);oxalate Chemical compound [NH4+].[Nb+5].[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O XFHGGMBZPXFEOU-UHFFFAOYSA-I 0.000 claims 1
- 229940093920 gynecological arsenic compound Drugs 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 150000002825 nitriles Chemical class 0.000 claims 1
- 150000007524 organic acids Chemical class 0.000 claims 1
- 125000004430 oxygen atom Chemical group O* 0.000 claims 1
- 238000005502 peroxidation Methods 0.000 claims 1
- 150000003018 phosphorus compounds Chemical class 0.000 claims 1
- 238000010992 reflux Methods 0.000 claims 1
- 239000008247 solid mixture Substances 0.000 claims 1
- 229910052714 tellurium Inorganic materials 0.000 claims 1
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 claims 1
- 150000003609 titanium compounds Chemical class 0.000 claims 1
- -1 Sb 6 O 13 Chemical compound 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 150000003498 tellurium compounds Chemical class 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13771608P | 2008-08-01 | 2008-08-01 | |
| US61/137,716 | 2008-08-01 | ||
| PCT/US2009/004355 WO2010014206A1 (en) | 2008-08-01 | 2009-07-28 | Method of making mixed metal oxide catalysts for ammoxidation and/or oxidation of lower alkane hydrocarbons |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2011529777A JP2011529777A (ja) | 2011-12-15 |
| JP2011529777A5 true JP2011529777A5 (enExample) | 2012-09-13 |
| JP5611206B2 JP5611206B2 (ja) | 2014-10-22 |
Family
ID=41066426
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011521118A Expired - Fee Related JP5611206B2 (ja) | 2008-08-01 | 2009-07-28 | 低級アルカン系炭化水素のアンモ酸化及び／又は酸化のための混合金属酸化物触媒の製造方法 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US8658817B2 (enExample) |
| EP (1) | EP2310123A1 (enExample) |
| JP (1) | JP5611206B2 (enExample) |
| KR (1) | KR20110039478A (enExample) |
| CN (1) | CN102176966B (enExample) |
| BR (1) | BRPI0916583A2 (enExample) |
| MX (1) | MX2011001164A (enExample) |
| RU (1) | RU2495720C2 (enExample) |
| WO (1) | WO2010014206A1 (enExample) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5663902B2 (ja) * | 2010-03-05 | 2015-02-04 | 三菱レイヨン株式会社 | メタクリル酸製造用触媒の製造方法 |
| WO2012158418A1 (en) * | 2011-05-13 | 2012-11-22 | Evernu Technology Llc | Gas phase heterogeneous catalytic oxidation of alkanes to aliphatic ketones and/or other oxygenates |
| MY169922A (en) * | 2012-10-01 | 2019-06-17 | Asahi Kasei Chemicals Corp | Method for stopping ammoxidation |
| US9409156B2 (en) | 2012-10-19 | 2016-08-09 | Instituto Mexicano Del Petroleo | Oxidative dehydrogenation of ethane to ethylene and preparation of multimetallic mixed oxide catalyst for such process |
| FR3004713B1 (fr) * | 2013-04-17 | 2015-05-15 | Centre Nat Rech Scient | Procede de production de nitriles mettant en oeuvre un catalyseur a base d'antimoine et de fer. |
| KR101876656B1 (ko) * | 2014-03-06 | 2018-07-09 | 아사히 가세이 가부시키가이샤 | 산화물 촉매 및 그의 제조 방법, 및 불포화 니트릴의 제조 방법 |
| MY178728A (en) * | 2014-03-31 | 2020-10-20 | Asahi Chemical Ind | Method for producing oxide catalyst, and method for producing unsaturated nitrile |
| JP6310751B2 (ja) * | 2014-04-04 | 2018-04-11 | 旭化成株式会社 | 複合酸化物及びその製造方法 |
| ES2851907T3 (es) | 2016-01-09 | 2021-09-09 | Ascend Performance Mat Operations Llc | Composiciones catalizadoras y procesos de amoxidación |
| EP3495043B1 (en) * | 2016-08-02 | 2020-09-09 | Asahi Kasei Kabushiki Kaisha | Process for producing oxide catalyst and process for producing unsaturated nitrile |
| CN109689210B (zh) * | 2016-09-13 | 2022-04-15 | 旭化成株式会社 | 氧化物催化剂的制造方法及不饱和腈的制造方法 |
| EP4098362A4 (en) * | 2020-01-31 | 2023-07-19 | Asahi Kasei Kabushiki Kaisha | COMPOSITION FOR PRODUCTION OF CATALYST, METHOD FOR PRODUCTION OF COMPOSITION FOR PRODUCTION OF CATALYST, AND PRODUCTION METHOD FOR PRODUCTION OF OXIDE CATALYST |
| CN119633800A (zh) * | 2023-09-18 | 2025-03-18 | 中国石油化工股份有限公司 | 脱硝催化剂及其制备方法 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2105757C1 (ru) * | 1993-09-02 | 1998-02-27 | Стандарт Ойл Компани | Способ парофазного аммоксидирования с3 - с5-моноолефинов |
| US6156920A (en) * | 1998-03-26 | 2000-12-05 | The Standard Oil Company | Molybdenum promoted vanadium-antimony-oxide based catalyst for selective paraffin ammoxidation |
| AU5445599A (en) * | 1998-08-28 | 2000-03-21 | Asahi Kasei Kabushiki Kaisha | Method for producing oxide catalyst for use in producing acrylonitrile or methacrylonitrile from propane or isobutane |
| KR100407528B1 (ko) * | 2000-09-18 | 2003-11-28 | 아사히 가세이 가부시키가이샤 | 산화 또는 가암모니아산화용 산화물 촉매의 제조 방법 |
| JP4530595B2 (ja) * | 2000-12-13 | 2010-08-25 | 旭化成ケミカルズ株式会社 | 酸化またはアンモ酸化用酸化物触媒 |
| US6642173B2 (en) | 2001-04-25 | 2003-11-04 | Rohm And Haas Company | Catalyst |
| JP4667674B2 (ja) * | 2001-09-06 | 2011-04-13 | 旭化成ケミカルズ株式会社 | 酸化またはアンモ酸化用触媒の製造方法 |
| US20050054869A1 (en) * | 2003-06-06 | 2005-03-10 | Lugmair Claus G. | Mixed metal oxide catalysts for propane and isobutane oxidation and ammoxidation, and methods of preparing same |
| CN100400157C (zh) * | 2003-06-09 | 2008-07-09 | 旭化成化学株式会社 | 氧化或氨氧化催化剂 |
| JP5392806B2 (ja) * | 2005-10-26 | 2014-01-22 | 旭化成ケミカルズ株式会社 | 酸化物触媒の製造方法 |
| EP2111295A1 (en) * | 2007-02-16 | 2009-10-28 | Ineos USA, LLC | Process for the ammoxidation of propane and isobutane using mixed metal oxide catalysts |
| US8697596B2 (en) * | 2007-04-03 | 2014-04-15 | Ineos Usa Llc | Mixed metal oxide catalysts and catalytic conversions of lower alkane hydrocarbons |
| JP5219249B2 (ja) * | 2008-02-07 | 2013-06-26 | 旭化成ケミカルズ株式会社 | 複合酸化物の製造方法、及び不飽和酸又は不飽和ニトリルの製造方法 |
-
2009
- 2009-07-28 JP JP2011521118A patent/JP5611206B2/ja not_active Expired - Fee Related
- 2009-07-28 CN CN200980136188.XA patent/CN102176966B/zh not_active Expired - Fee Related
- 2009-07-28 MX MX2011001164A patent/MX2011001164A/es active IP Right Grant
- 2009-07-28 KR KR1020117004762A patent/KR20110039478A/ko not_active Ceased
- 2009-07-28 BR BRPI0916583A patent/BRPI0916583A2/pt not_active IP Right Cessation
- 2009-07-28 EP EP09789017A patent/EP2310123A1/en not_active Withdrawn
- 2009-07-28 RU RU2011107438/04A patent/RU2495720C2/ru not_active IP Right Cessation
- 2009-07-28 US US12/737,604 patent/US8658817B2/en not_active Expired - Fee Related
- 2009-07-28 WO PCT/US2009/004355 patent/WO2010014206A1/en not_active Ceased
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