JP2011256383A - ジアルデヒドから製造された5−および6−員環式エナミン化合物からの速硬化性熱硬化性物質 - Google Patents
ジアルデヒドから製造された5−および6−員環式エナミン化合物からの速硬化性熱硬化性物質 Download PDFInfo
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- JP2011256383A JP2011256383A JP2011120927A JP2011120927A JP2011256383A JP 2011256383 A JP2011256383 A JP 2011256383A JP 2011120927 A JP2011120927 A JP 2011120927A JP 2011120927 A JP2011120927 A JP 2011120927A JP 2011256383 A JP2011256383 A JP 2011256383A
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L79/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
- C08L79/02—Polyamines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
- C08G12/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
- C08G12/34—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds and acyclic or carbocyclic compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J161/00—Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
- C09J161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C09J161/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J161/00—Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
- C09J161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C09J161/32—Modified amine-aldehyde condensates
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Phenolic Resins Or Amino Resins (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
【解決手段】ビスエナミンおよびジもしくはより高次の官能性エナミンをはじめとする1種以上の環式エナミン、場合によって水可溶性もしくは分散性第1級アミン化合物を含む熱硬化性水性バインダー組成物を提供する。このバインダーは少なくとも実質的にホルムアルデヒドを含まず、ポリカルボキシルもしくはポリカルボキシラート成分を必要とせず、並びに使用において1分以下の短い時間で硬化されるときに優れたホットメルト引張強さ。
【選択図】なし
Description
さらに、本発明は、基材を水性バインダー組成物で処理し、次いで、乾燥させ、熱硬化させる方法を提供する。
さらに、本発明は、本発明の方法に従って処理された基材を含む物品を提供する。
本明細書において使用される場合、語句「エマルションポリマー」とは、水もしくは水性溶媒と一緒にされるときに分散相を形成するポリマーをいう。
2.0.087g亜硫酸水素塩で分散されたArcher Daniels Midland325(米国、イリノイ州、デカター)。
Claims (10)
- 1種以上の環式エナミン化合物および/またはそのオリゴマーと、アンモニア、水酸化アンモニウムまたはアンモニア塩とを含む熱硬化性水性バインダー組成物。
- 前記環式エナミンもしくはオリゴマーがビスエナミンもしくはそのオリゴマーを含む、請求項1に記載のバインダー組成物。
- 前記ビスエナミンもしくはオリゴマーが1,4−ジヒドロピリジンもしくはオリゴ(1,4−ジヒドロピリジン)である、請求項2に記載のバインダー組成物。
- 1種以上の水可溶性もしくは分散性不揮発性アミンをさらに含む、請求項1に記載のバインダー組成物。
- 環式エナミン化合物および水可溶性もしくは分散性不揮発性アミンを、環式エナミン基:アミン基のモル比0.1:1〜15:1で含む、請求項4に記載のバインダー組成物。
- 水可溶性もしくは分散性不揮発性アミンが1以上の第1級アミン基を有する脂肪族ヒドロキシアミン、1以上の第1級アミン基を有する芳香族アミン、アミン官能性ポリマー、タンパク質、ゼラチン、アミノ酸、アミノ糖、ポリペプチド、尿素、第1級アミンとポリオールとの混合物、並びに第1級アミンと炭水化物との混合物から選択される第1級アミンである、請求項4に記載のバインダー組成物。
- 水可溶性もしくは分散性不揮発性アミンが2以上の第1級アミン基を有するポリ(第1級アミン)である、請求項6に記載のバインダー組成物。
- 場合によって、1種以上のポリオール、炭水化物もしくは糖アルコールをさらに含む、請求項1に記載のバインダー組成物。
- 1種以上の環式エナミン化合物またはそのオリゴマーが、過剰なアンモニア、水酸化アンモニウムもしくはアンモニア塩の存在下のジアルデヒドから生じた、請求項1に記載のバインダー組成物。
- 2以上のアルデヒド基を有するジアルデヒドもしくはアルデヒドオリゴマーの1種以上を過剰なアンモニア、水酸化アンモニウムもしくはアンモニア塩に、アンモニア基:アルデヒド基のモル比1.5以上:1で添加することを含む、請求項1に記載のバインダー組成物を製造する方法。
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US35393810P | 2010-06-11 | 2010-06-11 | |
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JP2011120927A Active JP5616291B2 (ja) | 2010-06-11 | 2011-05-30 | ジアルデヒドから製造された5−および6−員環式エナミン化合物からの速硬化性熱硬化性物質 |
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US (1) | US8592518B2 (ja) |
EP (1) | EP2395035B1 (ja) |
JP (1) | JP5616291B2 (ja) |
CN (1) | CN102516910B (ja) |
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JP2018518603A (ja) * | 2015-05-20 | 2018-07-12 | ケーシーシー コーポレーション | バインダー組成物及びこれを用いて繊維状材料を結束する方法 |
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JP5616291B2 (ja) | 2014-10-29 |
US8592518B2 (en) | 2013-11-26 |
EP2395035B1 (en) | 2016-11-30 |
EP2395035A1 (en) | 2011-12-14 |
US20110306726A1 (en) | 2011-12-15 |
CN102516910A (zh) | 2012-06-27 |
CN102516910B (zh) | 2014-07-09 |
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