JP2011051847A5 - - Google Patents
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- Publication number
- JP2011051847A5 JP2011051847A5 JP2009203262A JP2009203262A JP2011051847A5 JP 2011051847 A5 JP2011051847 A5 JP 2011051847A5 JP 2009203262 A JP2009203262 A JP 2009203262A JP 2009203262 A JP2009203262 A JP 2009203262A JP 2011051847 A5 JP2011051847 A5 JP 2011051847A5
- Authority
- JP
- Japan
- Prior art keywords
- temperature
- raw material
- removal
- gas
- reforming
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000007789 gas Substances 0.000 claims description 271
- 239000003054 catalyst Substances 0.000 claims description 234
- 239000002994 raw material Substances 0.000 claims description 218
- 238000002407 reforming Methods 0.000 claims description 134
- 239000001257 hydrogen Substances 0.000 claims description 126
- 229910052739 hydrogen Inorganic materials 0.000 claims description 126
- UFHFLCQGNIYNRP-UHFFFAOYSA-N hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 125
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 90
- 238000001514 detection method Methods 0.000 claims description 51
- 229910004682 ON-OFF Inorganic materials 0.000 claims description 30
- 238000010438 heat treatment Methods 0.000 claims description 30
- 238000001704 evaporation Methods 0.000 claims description 15
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 14
- 150000002430 hydrocarbons Chemical class 0.000 claims description 13
- 239000004215 Carbon black (E152) Substances 0.000 claims description 11
- 238000000629 steam reforming Methods 0.000 claims description 9
- 239000001294 propane Substances 0.000 claims description 5
- IJDNQMDRQITEOD-UHFFFAOYSA-N butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims description 3
- 239000001273 butane Substances 0.000 claims description 3
- 239000000047 product Substances 0.000 description 53
- 239000000446 fuel Substances 0.000 description 30
- 239000002737 fuel gas Substances 0.000 description 27
- 238000002485 combustion reaction Methods 0.000 description 26
- 239000000567 combustion gas Substances 0.000 description 15
- 238000010926 purge Methods 0.000 description 15
- 238000002156 mixing Methods 0.000 description 14
- 238000010586 diagram Methods 0.000 description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 11
- 238000007254 oxidation reaction Methods 0.000 description 9
- UGFAIRIUMAVXCW-UHFFFAOYSA-N carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- 239000004071 soot Substances 0.000 description 7
- 239000000463 material Substances 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 4
- 238000010248 power generation Methods 0.000 description 4
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 3
- 229910052697 platinum Inorganic materials 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 230000001276 controlling effect Effects 0.000 description 2
- 230000000875 corresponding Effects 0.000 description 2
- 230000003247 decreasing Effects 0.000 description 2
- 238000003795 desorption Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005755 formation reaction Methods 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- XXGJRAFLOAKNCC-UHFFFAOYSA-N methane;molecular hydrogen Chemical compound C.[H][H] XXGJRAFLOAKNCC-UHFFFAOYSA-N 0.000 description 2
- 229910000510 noble metal Inorganic materials 0.000 description 2
- 230000000607 poisoning Effects 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 229910052703 rhodium Inorganic materials 0.000 description 2
- 230000000630 rising Effects 0.000 description 2
- 229910052707 ruthenium Inorganic materials 0.000 description 2
- 230000000087 stabilizing Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000001629 suppression Effects 0.000 description 2
- 229910017518 Cu Zn Inorganic materials 0.000 description 1
- 229910017752 Cu-Zn Inorganic materials 0.000 description 1
- 229910017943 Cu—Zn Inorganic materials 0.000 description 1
- 229910017060 Fe Cr Inorganic materials 0.000 description 1
- 229910002544 Fe-Cr Inorganic materials 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 230000003197 catalytic Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000008236 heating water Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2009203262A JP5471192B2 (ja) | 2009-09-03 | 2009-09-03 | 水素発生装置とその起動停止方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2009203262A JP5471192B2 (ja) | 2009-09-03 | 2009-09-03 | 水素発生装置とその起動停止方法 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2011051847A JP2011051847A (ja) | 2011-03-17 |
| JP2011051847A5 true JP2011051847A5 (de) | 2012-05-24 |
| JP5471192B2 JP5471192B2 (ja) | 2014-04-16 |
Family
ID=43941260
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009203262A Expired - Fee Related JP5471192B2 (ja) | 2009-09-03 | 2009-09-03 | 水素発生装置とその起動停止方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP5471192B2 (de) |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05147903A (ja) * | 1991-12-03 | 1993-06-15 | Fuji Electric Co Ltd | 改質装置 |
| JP4130603B2 (ja) * | 2003-04-03 | 2008-08-06 | 東京瓦斯株式会社 | 水素製造システムの運転方法 |
| JP2005206395A (ja) * | 2004-01-20 | 2005-08-04 | Matsushita Electric Ind Co Ltd | 水素生成装置およびその起動方法 |
| JP4917756B2 (ja) * | 2005-03-29 | 2012-04-18 | 株式会社荏原製作所 | 燃料電池システムの起動方法並びに改質装置及び燃料電池システム |
| JP2008105892A (ja) * | 2006-10-25 | 2008-05-08 | Fuji Electric Holdings Co Ltd | 燃料改質装置の停止方法 |
| JP5138324B2 (ja) * | 2007-05-21 | 2013-02-06 | 株式会社荏原製作所 | 改質器及び燃料電池システム |
-
2009
- 2009-09-03 JP JP2009203262A patent/JP5471192B2/ja not_active Expired - Fee Related
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