JP2011020933A - Oily base agent, and cosmetic and skin care preparation for external use comprising the same - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide an oily base agent excellent in safety, stability, gloss, water-holding property and adhesion to the skin, and a cosmetic and a skin care preparation for external use comprising the oily base agent. <P>SOLUTION: The oily base agent comprises an ester obtained by allowing a 1-34C monohydric alcohol to react with an ester, obtained by allowing a dimer acid to react with a mixed alcohol of a dimer diol and a 3-10C trihydric or higher hydric alcohol, in an amount of 0.8-1.5 mole equivalent relative to 1 mole equivalent of a carboxy group remaining in the ester. The oily base agent exhibits, as an ingredient of a cosmetic and a skin care preparation for external use, excellent safety, stability, gloss, water-holding property and adhesion to the skin, and can be a liquid oily base agent as well as a pasty oily base agent. <P>COPYRIGHT: (C)2011,JPO&amp;INPIT

Description

  The present invention relates to an oily base excellent in safety, stability, gloss, water repellency, and adhesion to skin, and a cosmetic and a skin external preparation containing these oily bases.

  In recent years, oligomeric esters having dimer acid or dimer diol as the main skeleton (Patent Documents 1 and 2) have been proposed as an oily base excellent in safety, stability, gloss, pigment dispersibility, and feeling of use. Although this oligomer ester is excellent as an oily base, since a carboxyl group or a hydroxyl group that is a polar group always remains at the end of the resulting oligomer ester, compatibility with nonpolar oils such as silicone is not always sufficient. It wasn't. In order to improve such a defect, a terminal-capped oligomer ester (Patent Document 3) in which the end of an oligomer ester having a main skeleton of dimer acid or dimer diol is further esterified with a monohydric alcohol is known. In this ester, not only the terminal polar group is blocked, but also a water-holding property can be imparted by introducing a sterol group at the terminal, and the terminal is a saturated straight chain having 16 to 22 carbon atoms as a solidifying component. It has the characteristic that a paste-like thing can be obtained by introduce | transducing a hydrocarbon group.

JP 2001-072530 A JP 2002-275020 A JP 2004-256515 A

  The present inventors have found that the higher the viscosity of the end-capped oligomer ester having a dimer acid and dimer diol as the main skeleton, the better the adhesion to the skin. It has been found that when viscosity is increased, characteristics such as imparting water repellency and pasting are not sufficiently exhibited. Therefore, the problem to be solved by the present invention is that it has a function equivalent to that of an end-capped oligomer ester having a main skeleton of dimer acid and dimer diol, has high viscosity and excellent adhesion, and has introduced a terminal monohydric alcohol. An object of the present invention is to provide an ester that can sufficiently exhibit the obtained characteristics.

  As a result of intensive studies to solve the above problems, the present inventors have found that an ester obtained by reacting dimer acid with a mixed alcohol composed of dimer diol and a trivalent or higher alcohol having 3 to 10 carbon atoms. It is found that an ester obtained by reacting a monohydric alcohol having 1 to 34 carbon atoms with 0.8 to 1.5 mole equivalents with respect to 1 mole equivalent of the remaining carboxyl group solves the above problems. Completed the invention.

  The ester of the present invention has high viscosity and excellent adhesion as compared with conventional end-capped oligomers, and sufficiently exhibits characteristics such as imparting water repellency and pasting. It can preferably be used as an oily base for the agent.

  In the present invention, the dimer acid, dimer diol, and a mixed alcohol composed of a trihydric or higher alcohol having 3 to 10 carbon atoms react with 1 mol equivalent of the carboxyl group remaining in the ester obtained. An oily base for cosmetics or skin external preparations containing an ester obtained by reacting 1 to 34 monohydric alcohols in an amount of 0.8 to 1.5 molar equivalents, and a cosmetic containing the oily base And an external preparation for skin.

  The dimer acid used in the production of the ester contained in the oil base of the present invention is a known dibasic acid obtained by an intermolecular polymerization reaction of unsaturated fatty acids, and its industrial production process is almost standardized in the industry. For example, dimer acid and / or its lower alcohol ester is obtained by dimerizing an unsaturated fatty acid having 11 to 22 carbon atoms or its lower alcohol ester with a clay catalyst or the like. The dimer acid obtained industrially is mainly composed of a dibasic acid having about 36 carbon atoms, but contains an arbitrary amount of trimer acid and monomer acid depending on the degree of purification. In general, dimer acid content exceeding 70% by weight and dimer acid content increased to 90% or more by molecular distillation are in circulation. In addition, although a double bond remains after the dimerization reaction, a dimer acid that is further hydrogenated to improve oxidation stability, that is, a hydrogenated dimer acid is also on the market. Any dimer acid currently in circulation can be used in the present invention, but hydrogenated dimer acid is more preferable from the viewpoint of oxidation stability. In addition, those derived from animal oils and fats and vegetable oils are distributed among these dimer acids, but those derived from vegetable oils and fats are more preferable. As such dimer acid, for example, PRIPOL 1006, 1009, 1015, 1025, etc. of Croda are commercially available.

  The dimer diol used in the production of the ester contained in the oily base of the present invention is obtained by hydrogenating the dimer acid and / or the lower alcohol ester thereof in the presence of a catalyst, and using the carboxylic acid portion of the dimer acid as an alcohol. The main component is a diol having about 36 carbon atoms. The dimer diol obtained industrially may contain other components, for example, trimer triol, monomer alcohol and ether compound, depending on the degree of purification of dimer acid and / or its lower alcohol ester used as a raw material. The dimer diol content exceeds about 70% by weight, and the dimer diol content exceeds 90% by further purification, and any of them can be used in the present invention. As dimer diols, those derived from animal fats and oils and vegetable fats and oils are distributed, but those derived from vegetable oils and fats are more preferable. As such a dimer diol, PRIPOL 2033 manufactured by CLODA is commercially available.

  Specific examples of the trivalent or higher alcohol having 3 to 10 carbon atoms used for the production of the ester contained in the oily base of the present invention include glycerin, diglycerin, trimethylolpropane, pentaerythritol, ditrimethylolpropane, And dipentaerythritol. Glycerin is most preferable from the viewpoints of economy and physical properties of the resulting ester.

  The monohydric alcohol having 1 to 34 carbon atoms used for the production of the ester contained in the oily base of the present invention is a saturated or unsaturated straight chain, branched, ring-containing or cyclic one having 1 to 34 carbon atoms. Specifically, examples of the saturated linear monohydric alcohol having 1 to 34 carbon atoms include methanol, ethanol, propanol, butanol, pentanol, hexanol, heptanol, octanol, nonanol, decanol, undecanol, Dodecanol, tridecanol, tetradecanol, pentadecanol, hexadecanol, heptadecanol, octadecanol, nonadecanol, eicosanol, docosanol, tetracosanol, tricosanol; and hydrogenated coconut oil alcohol, hydrogenated rapeseed alcohol, hydrogen Additive cheek Natural fatty acid reduction alcohol and the like, such as naturally derived alcohols such as carnauba alcohol. Examples of branched monohydric alcohols having 3 to 34 carbon atoms include isopropyl alcohol, isobutyl alcohol, 2-butanol, isopentyl alcohol, isohexyl alcohol, 4-methyl-2-pentanol, isoheptyl alcohol, 2-ethylhexanol, 6-methyl-2-heptanol, isononyl alcohol, isodecyl alcohol, isoundecyl alcohol, isododecyl alcohol, 2-butyloctanol, isotridecyl alcohol, isotetradecyl alcohol, isopentadecyl alcohol, isohexadecyl alcohol, 2-hexyldecanol, isoheptadecyl alcohol, isostearyl alcohol obtained from dimer acid by-products, isostearyl alcohol obtained by the gerbet method, isonononadecyl Lucol, isoicosyl alcohol, 2-octyldodecanol, isohenicosyl alcohol, 18-methylicosanol, isodocosyl alcohol, 2-decyltetradecanol, 2-dodecylhexadecanol, 2-tetradecylocta Long chain branched alcohol (C12-31) obtained from decanol, 2-hexadecyl icosanol, lanolin, etc. are mentioned. Examples of unsaturated linear or branched monohydric alcohols having 3 to 34 carbon atoms include 2-butenol, prenol, 3-hexenol, 4-methyl-3-hexen-2-ol, 2,7-octadienol, Examples include geraniol, nerol, 10-undecenol, palmitooleyl alcohol, oleyl alcohol, isooleyl alcohol obtained from by-products of dimer acid, elaidyl alcohol, and linoleyl alcohol. Examples of ring-containing or cyclic monohydric alcohols include cyclohexanol, cyclohexanemethanol, tetrahydroabiethyl alcohol; and sitosterol, campesterol, stigmasterol, brassicasterol, ergosterol, and phytosterols that are a mixture thereof, and Sterols such as hydrogenated phytosterol, cholesterol, dihydrocholesterol, desmosterol, lanosterol, dihydrolanosterol, agnosterol, latosterol; benzyl alcohol, benzyloxyethanol and the like.

  Among these monohydric alcohols, saturated linear alcohols having 12 to 22 carbon atoms, such as dodecanol, tetradecanol, hexadecanol, octadecanol, docosanol, etc., from the viewpoint of physical properties, stability, odor and the like of the resulting ester A saturated branched alcohol having 8 to 22 carbon atoms such as isostearyl alcohol, 2-ethylhexanol, 2-hexyldecanol, and 2-octyldodecanol obtained from dimer acid by-products; particularly, sterols such as cholesterol and phytosterol are used. preferable.

  The ester of the present invention can change the properties at room temperature from liquid to paste by selecting the monohydric alcohol to be reacted. In order to obtain pasty oil, it is necessary to use at least one kind of saturated linear monohydric alcohol having 16 or more carbon atoms as the monohydric alcohol to be reacted. Considering physical properties such as the melting point of the resulting ester, it is preferable to use at least one saturated linear monohydric alcohol having 20 or more carbon atoms.

  When the ester of the present invention is used as a pasty oil, the melting point thereof is preferably about 30 ° C. to 36 ° C. as the peak top temperature of the endothermic peak obtained by differential scanning calorimetry. When blended into cosmetics or external preparations for skin, if the temperature is lower than this temperature, the stability of the dosage form may be impaired due to a temperature change near room temperature. Conversely, if the temperature is higher than this temperature, the body temperature does not sufficiently melt on the skin. Therefore, it is not preferable in terms of feel.

  In order to give the ester of the present invention higher hydration properties, it is desirable that at least one of the monohydric alcohols to be reacted is sterols such as phytosterol and cholesterol, and sterols are particularly phytosterols. Most preferred.

  Although the manufacturing method of ester contained in the oil-based base of this invention is not specifically limited, It can manufacture efficiently by performing with the following method. First, an ester of dimer acid and dimer diol and a mixed alcohol composed of a trihydric or higher alcohol having 3 to 10 carbon atoms is obtained, and a carboxyl group remaining in the ester is esterified with a monohydric alcohol, or dimer acid, It can be produced by esterifying dimer diol, trivalent or higher alcohol having 3 to 10 carbon atoms, and monohydric alcohol at a time. Esters of dimer acid, dimer diol, which is an intermediate during production, and mixed alcohols composed of trihydric or higher alcohols having 3 to 10 carbon atoms can be obtained by changing the respective charging ratios to obtain an average esterification degree of the ester. And the average molecular weight can be adjusted. The reaction ratio is preferably 0.4 to 0.8 molar equivalent of the hydroxyl group in the mixed alcohol with respect to 1 molar equivalent of the carboxyl group in the dimer acid, and considering the viscosity of the ester obtained, the carboxyl in the dimer acid The hydroxyl group in the mixed alcohol is more preferably 0.6 to 0.8 molar equivalent relative to 1 molar equivalent of the group. Moreover, it is good to use the usage-amount of the monohydric alcohol made to react 0.8-1.5 mol times with respect to the remaining carboxyl group. Two or more kinds of monohydric alcohols to be reacted may be used. In this case, they can be reacted simultaneously as a mixture of two or more kinds or can be reacted sequentially.

  The mixing ratio of the dimer diol and the trivalent or higher alcohol having 3 to 10 carbon atoms is 0.2 to 3.5 mol of the trivalent or higher alcohol having 3 to 10 carbon atoms with respect to 1 mol of the dimer diol. In consideration of physical properties such as viscosity of the resulting ester, it is more preferable to mix at a ratio of 0.5 to 3.5 mol, most preferably 1.0 to 3.5 mol. .

  The conditions for the esterification reaction are not particularly limited, and the reaction is performed by a commonly used method. For example, paratoluenesulfonic acid, sulfuric acid, hydrochloric acid, methanesulfonic acid, boron trifluoride diethyl ether complex or the like is used as a catalyst, and heptane, hexane, cyclohexane, toluene, xylene or the like is used as a solvent at 50 to 260 ° C. be able to. Alternatively, esterification can be carried out at 100 to 260 ° C. even without solvent and without catalyst.

  The ester of the present invention obtained as described above can be used as it is for an appropriate application, but it can be further purified by an ordinary method and used for various applications as required.

  In order for the oily base of the present invention to exhibit excellent adhesion to the skin, it is preferable that the resulting ester has a viscosity at 60 ° C. of about 1000 to 6000 mPa · s. If it is lower than this, preferable adhesion will not be exhibited, and if it is higher, the feeling such as stickiness will increase.

  The oily base of the present invention may contain components other than the ester of the present invention, such as other oily bases and antioxidants. The ester of the present invention is excellent in oxidation stability, but the oxidation stability can be further improved by adding an antioxidant. As the antioxidant, those usually added to an oily base such as vitamins E, BHT, and BHA can be used, but the use of vitamins E is particularly desirable. Vitamin E was isolated and purified from d-α-tocopherol, d-δ-tocopherol, d, l-α-tocopherol, d-α-tocopherol acetate, d, l-α-tocopherol acetate, soybean and rapeseed. Tocopherol mixtures and the like can be used. Although there is no restriction | limiting in particular in the addition amount of antioxidant, About 10 ppm-10000 ppm are suitable with respect to the weight of the ester of this invention.

  The oily base containing the ester obtained as described above is excellent in safety, stability, gloss, pigment dispersibility, water retention, adhesion to the skin, etc. Since an agent is also obtained, it can be preferably used for cosmetics and skin external preparations. The blending amount of the ester used in the present invention into the cosmetic and the external preparation for skin is not particularly limited, but is preferably about 0.01 to 60% by weight, more preferably 0.05 to 40% by weight. In addition, the cosmetics of the present invention contain water and, as necessary, additive components incorporated in cosmetics and external preparations for skin, such as oil bases, surfactants, alcohols, humectants, polymers, thickeners, and gels. Agent, antioxidant, antiseptic, bactericidal agent, chelating agent, pH adjuster / acid / alkali, UV absorber, whitening agent, solvent, exfoliating / dissolving agent, antipruritic, anti-inflammatory agent, antiperspirant, refreshing Agents, antihistamines, astringents, stimulants, hair growth agents / blood circulation promoters, reducing agents / oxidants, polymer powders, hydroxy acids, vitamins and derivatives thereof, saccharides and derivatives thereof, organic acids, enzymes Nucleic acids, hormones, inorganic powders, fragrances, pigments and the like can be blended.

  Examples of oily bases include cetanol, myristyl alcohol, oleyl alcohol, lauryl alcohol, cetostearyl alcohol, stearyl alcohol, aralkyl alcohol, behenyl alcohol, jojoba alcohol, chimyl alcohol, ceralkyl alcohol, batyl alcohol, hexyldecanol, isostearyl alcohol, Higher alcohols such as 2-octyldodecanol and dimer diol; aralkyl alcohols and derivatives such as benzyl alcohol; lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, behenic acid, undecylenic acid, 12-hydroxystearic acid, Palmitooleic acid, oleic acid, linoleic acid, linolenic acid, erucic acid, docosahexaenoic acid, eicosapentaenoic acid, isohexa Higher fatty acids such as cannic acid, anteisohenicosanoic acid, long-chain branched fatty acid, dimer acid, hydrogenated dimer acid, and metal soaps such as aluminum salts, calcium salts, magnesium salts, zinc salts, potassium, sodium salts, etc. And nitrogen-containing derivatives such as amides; liquid paraffin (mineral oil), heavy liquid isoparaffin, light liquid isoparaffin, α-olefin oligomer, polyisobutene, hydrogenated polyisobutene, polybutene, squalane, olive-derived squalane, squalene, petrolatum, solid Type hydrocarbons such as candelilla wax, carnauba wax, rice wax, wax, beeswax, montan wax, ozokerite, ceresin, paraffin wax, microcrystalline wax, petrolatum, fisher Tropsch wax, polyethylene wax, waxes such as ethylene / propylene copolymer; palm oil, palm oil, palm kernel oil, safflower oil, olive oil, castor oil, avocado oil, sesame oil, tea oil, evening primrose oil, wheat germ oil, macadamia nut Oil, hazelnut oil, cucumber oil, rosehip oil, meadow foam oil, persic oil, tea tree oil, peppermint oil, corn oil, rapeseed oil, sunflower oil, wheat germ oil, linseed oil, cottonseed oil, soybean oil, peanut oil, rice bran Vegetable oils such as oil, cacao butter, shea fat, hydrogenated coconut oil, hydrogenated castor oil, jojoba oil, hydrogenated jojoba oil; animal properties such as beef tallow, milk fat, horse fat, egg yolk oil, mink oil, turtle oil Fats and oils; animal waxes such as whale wax, lanolin, orange luffy oil; liquid lanolin, reduced lanoli Lanolins such as adsorption purified lanolin, lanolin acetate, liquid lanolin acetate, hydroxy lanolin, polyoxyethylene lanolin, lanolin fatty acid, hard lanolin fatty acid, lanolin alcohol, lanolin alcohol acetate, acetic acid (cetyl lanolyl) ester; lecithin, phosphatidylcholine, Phosphatidylethanolamine, phosphatidylserine, phosphatidylglycerol, phosphatidylinositol, sphingophospholipids such as sphingomyelin, phospholipids such as phosphatidic acid, lysolecithin; hydrogenated soybean phospholipid, partially hydrogenated soybean phospholipid, hydrogenated egg yolk phospholipid, Phospholipid derivatives such as partially hydrogenated egg yolk phospholipids; cholesterol, dihydrocholesterol, lanosterol, dihydrolanosterol, phytoster Sterols such as oleol and cholic acid; sapogenins; saponins; cholesteryl acetate, cholesteryl nonanoate, cholesteryl stearate, cholesteryl isostearate, cholesteryl oleate, di-N-lauroyl-L-glutamate (cholesteryl / behenyl / octyldodecyl) ), N-lauroyl-L-glutamate di (cholesteryl / octyldodecyl), N-lauroyl-L-glutamate di (phytosteryl / behenyl / octyldodecyl), N-lauroyl-L-glutamate di (phytosteryl / octyldodecyl), N Acyl sarcosine alkyl esters such as lauroyl sarcosine isopropyl, cholesteryl 12-hydroxystearate, macadamia nut oil fatty acid cholesteryl, macadamia nut oil fatty acid phyto Sterol esters such as steryl, phytosteryl isostearate, soft lanolin fatty acid cholesteryl, hard lanolin fatty acid cholesteryl, long chain branched fatty acid cholesteryl, long chain α-hydroxy fatty acid cholesteryl; phospholipid / cholesterol complex, phospholipid / phytosterol complex, etc. Lipid complex: octyldodecyl myristate, hexyl decyl myristate, octyl dodecyl isostearate, cetyl paritate, octyl dodecyl palmitate, cetyl octanoate, hexyl decyl octanoate, isotridecyl isononanoate, isononyl isononanoate, isononanoate Isotridecyl acid, isodecyl neopentanoate, isotridecyl neopentanoate, isostearyl neopentanoate, octeodecanoate Ludodecyl, oleyl oleate, octyldodecyl oleate, octyldodecyl ricinoleate, lanolin fatty acid octyldodecyl, hexyldecyl dimethyloctanoate, octyldodecyl erucate, isostearic acid hydrogenated castor oil, ethyl oleate, ethyl avocado oil, isopropyl myristate , Isopropyl palmitate, octyl palmitate, isopropyl isostearate, lanolin fatty acid isopropyl, diethyl sebacate, diisopropyl sebacate, dioctyl sebacate, diisopropyl adipate, dibutyl octyl sebacate, diisobutyl adipate, dioctyl succinate, triethyl citrate, etc. Monoalcohol carboxylic acid esters; cetyl lactate, diisostearyl malate, monoisostearyl Oxyacid esters such as acid hydrogenated castor oil; glyceryl trioctanoate, glyceryl trioleate, glyceryl triisostearate, glyceryl diisostearate, glyceryl tri (caprylic / capric), tri (caprylic / capric / myristin) Acid / stearic acid) glyceryl, hydrogenated rosin triglyceride (hydrogenated ester gum), rosin triglyceride (ester gum), glyceryl behenate, trimethylolpropane trioctanoate, trimethylolpropane triisostearate, neopentyl glycol dioctanoate , Neopentyl glycol dicaprate, 2-butyl-2-ethyl-1,3-propanediol dioctanoate, propylene glycol dioleate, pentaerythrtetraoctanoate Chill, hydrogenated rosin pentaerythrityl, triethylhexanoic acid ditrimethylolpropane, (isostearic acid / sebacic acid) ditrimethylolpropane, triethylhexanoic acid pentaerythrityl, (hydroxystearic acid / stearic acid / rosinic acid) dipentaerythrityl, diisostearic acid di Glyceryl, polyglyceryl tetraisostearate, polyglyceryl-10 nonaisostearate, deca (erucic acid / isostearic acid / ricinoleic acid) polyglyceryl-8, (hexyldecanoic acid / sebacic acid) diglyceryl oligoester, glycol distearate (ethylene glycol distearate) , Dineopentanoic acid 3-methyl-1,5-pentanediol, dineopentanoic acid 2,4-diethyl-1,5-pentane Polyhydric alcohol fatty acid esters such as ol; dimer dilinoleate diisopropyl, dimer dilinoleate diisostearyl, dimer dilinoleate di (isostearyl / phytosteryl), dimer dilinoleate (phytosteryl / behenyl), dimer dilinoleate (Phytosteryl / isostearyl / cetyl / stearyl / behenyl), dimer dilinoleic acid dimer dilinoleyl, diisostearic dimer dilinoleyl, dimer dilinoleyl hydrogenated rosin condensate, dimer dilinoleic acid hydrogenated castor oil, hydroxyalkyl die Dimer acid or dimer diol derivative such as merlinoleyl ether; coconut oil fatty acid monoethanolamide (cocamide MEA), coconut oil fatty acid diethanolamide (cocamide DEA), Lauri Acid monoethanolamide (lauramide MEA), lauric acid diethanolamide (lauramide DEA), lauric acid monoisopropanolamide (lauramide MIPA), palmitic acid monoethanolamide (partamide MEA), palmitic acid diethanolamide (partamide DEA), coconut oil Fatty acid alkanolamides such as fatty acid methylethanolamide (cocamidomethyl MEA); dimethicone (dimethylpolysiloxane), highly polymerized dimethicone (highly polymerized dimethylpolysiloxane), cyclomethicone (cyclic dimethylsiloxane, decamethylcyclopentasiloxane), phenyltrimethicone , Diphenyldimethicone, phenyldimethicone, stearoxypropyldimethylamine, (aminoethylaminopropylmethicone / dimethicone) Polymer, dimethiconol, dimethiconol crosspolymer, silicone resin, silicone rubber, amino-modified silicone such as aminopropyl dimethicone and amodimethicone, cation-modified silicone, polyether-modified silicone such as dimethicone copolyol, polyglycerin-modified silicone, sugar-modified silicone, carvone Acid-modified silicone, phosphoric acid-modified silicone, sulfuric acid-modified silicone, alkyl-modified silicone, fatty acid-modified silicone, alkyl ether-modified silicone, amino acid-modified silicone, peptide-modified silicone, fluorine-modified silicone, cation-modified and polyether-modified silicone, amino-modified and poly-modified Ether-modified silicone, alkyl-modified and polyether-modified silicone, polysiloxane-oxyalkylene copolymer Silicones such as body; perfluorodecane, perfluorooctane, fluorine-based oils such as perfluoropolyether may be mentioned as preferred.

  As the humectant / feel improver, glycerin, 1,3-butylene glycol, propylene glycol, 3-methyl-1,3-butanediol, 1,3-propanediol, 2-methyl-1,3-propanediol, Polyols such as trimethylolpropane, pentaerythritol, hexylene glycol, diglycerin, polyglycerin, diethylene glycol, polyethylene glycol, dipropylene glycol, polypropylene glycol, ethylene glycol / propylene glycol copolymer and polymers thereof; diethylene glycol monoethyl ether (Ethoxydiglycol), ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, diethylene glycol dibutyl ether, etc. (Eicosane diacid / tetradecanedioic acid) water-soluble esters such as polyglyceryl-10, tetradecanedioic acid polyglyceryl-10, and cyclohexanedicarboxylic acid bisethoxydiglycol; sugars such as sorbitol, xylitol, erythritol, mannitol, maltitol Alcohols; glucose, fructose, galactose, mannose, threose, xylose, arabinose, fucose, ribose, deoxyribose, maltose, trehalose, lactose, raffinose, gluconic acid, glucuronic acid, cyclodextrins (α-, β-, γ- Cyclodextrins and modified cyclodextrins such as maltosylation and hydroxyalkylation), β-glucan, chitin, chitosan, heparin and derivatives, pectin, arabino Sugars and derivatives thereof such as galactan, dextrin, dextran, glycogen, ethyl glucoside, glucosylethyl methacrylate polymer or copolymer; hyaluronic acid, sodium hyaluronate; sodium chondroitin sulfate; mucoitin sulfate, caroline sulfate, keratosulfate, dermatan Sulfuric acid; white jellyfish extract; white jellyfish polysaccharide; fucoidan; tuberose polysaccharide, naturally derived polysaccharide; organic acids such as citric acid, tartaric acid, lactic acid and their salts; urea; 2-pyrrolidone-5-carboxylic acid and its sodium Salt: betaine (trimethylglycine), proline, hydroxyproline, arginine, lysine, serine, glycine, alanine, phenylalanine, tyrosine, β-alanine, threonine, glutamic acid, glutamine, aspa Amino acids such as gin, aspartic acid, cysteine, cystine, methionine, leucine, isoleucine, valine, tryptophan, histidine, taurine and the salts thereof; collagen, fish-derived collagen, atelocollagen, gelatin, elastin, collagenolytic peptide, hydrolyzed collagen, Hydroxypropylammonium chloride hydrolyzed collagen, elastin degrading peptide, keratin degrading peptide, hydrolyzed keratin, conchiolin degrading peptide, hydrolyzed conchiolin, silk proteolytic peptide, hydrolyzed silk, lauroyl hydrolyzed silk sodium, soy proteolytic peptide, wheat protein Degraded peptides, hydrolyzed wheat protein, casein-degraded peptides, acylated peptides and other protein peptides and their derivatives; palmitoyl oligopeptides , Acylated peptides such as palmitoyl pentapeptide, palmitoyl tetrapeptide; silylated peptides; lactic acid bacteria culture solution, yeast extract, eggshell membrane protein, bovine submandibular gland mucin, hypotaurine, sesameignan glycoside, glutathione, albumin, milk Chin; choline chloride, phosphorylcholine; placenta extract, aerostin, collagen, aloe extract, hamamelis water, loofah water, chamomile extract, licorice extract, comfrey extract, silk extract, Izayoi rose extract, yarrow extract, eucalyptus extract, merirot extract Preferred are ceramides such as animal and plant extract components such as natural ceramides (types 1, 2, 3, 4, 5, 6), hydroxyceramide, pseudoceramide, glycosphingolipid, ceramide, and sugar-ceramide-containing extracts. All It is.

Preferred examples of the surfactant include an anionic surfactant, a nonionic surfactant, a cationic surfactant, an amphoteric surfactant, and a polymer surfactant. There is no restriction | limiting in particular in HLB of surfactant, It can use from about 1 low thing to about 20 high thing, It is also preferable to combine a low thing and a high thing of HLB. Examples of preferable surfactants include fatty acid salts such as potassium laurate and potassium myristate; alkyl sulfates such as sodium lauryl sulfate, triethanolamine lauryl sulfate, and ammonium lauryl sulfate; laureth Polyoxyethylene alkyl sulfates such as sodium sulfate and laureth sulfate triethanolamine; cocoyl methyl taurine sodium, cocoyl methyl taurine potassium, lauroyl methyl taurine sodium, myristoyl methyl taurine sodium, lauroyl methyl alanine sodium, lauroyl sarcosine sodium, lauroyl sarcosine triethanol Acyl N-methyl amino acid salts such as amines and sodium methylalanine lauroylglutamate; Cocoyl Glue Acyl amino acid salts such as sodium phosphate, triethanolamine cocoyl glutamate, sodium lauroyl glutamate, sodium myristoyl glutamate, sodium stearoyl glutamate, ditriethanolamine palmitoyl aspartate, cocoylalanine triethanolamine; polyoxyethylene alkyl ethers such as sodium laureth acetate Acetic acid salt; Succinic acid ester salt such as sodium lauroyl monoethanolamide succinate; Fatty acid alkanolamide ether carboxylate; Acyl lactate; Polyoxyethylene fatty amine sulfate; Fatty acid alkanolamide sulfate; Hardened coconut oil fatty acid sodium glyceryl sulfate Fatty acid glyceride sulfate such as alkylbenzene polyoxyethylene sulfate; α-olefin Olefin sulfonates such as sodium sulfonate; alkylsulfosuccinates such as disodium lauryl sulfosuccinate and dioctyl sodium sulfosuccinate; disodium laureth sulfosuccinate, monolauroyl monoethanolamide polyoxyethylene sodium sulfosuccinate, lauryl polypropylene glycol sulfosuccinic acid Alkyl ether sulfosuccinates such as sodium; alkylbenzene sulfonates such as sodium tetradecylbenzenesulfonate and tetraethanolamine tetraethanol; alkylnaphthalenesulfonates; alkanesulfonates; α-sulfo fatty acid methyl ester salts; Acyl isethionate; alkyl glycidyl ether sulfonate; alkyl sulfoacetate; laurethrin Alkyl ether phosphates such as sodium, sodium dilaureth phosphate, sodium trilaureth phosphate, sodium monooles phosphate; alkyl phosphate salts such as potassium lauryl phosphate; sodium caseinate; alkyl aryl ether phosphate; fatty acid amide ether phosphorus Phospholipids such as phosphatidylglycerol, phosphatidylinositol, and phosphatidic acid; silicone anionic surfactants such as carboxylic acid-modified silicone, phosphate-modified silicone, and sulfate-modified silicone; and nonionic surfactants, laureth (Polyoxyethylene lauryl ether), ceteth (polyoxyethylene cetyl ether), steareth (polyoxyethylene stearyl ether), behenez (polyoxyethylene) Nbehenyl ethers), isosteares (polyoxyethylene isostearyl ethers), octyldecesses (polyoxyethylene octyldodecyl ethers) and other polyoxyethylene alkyl ethers with various polyoxyethylene addition numbers; polyoxyethylene alkylphenyl ethers; Polyoxyethylene hydrogenated castor oil, polyoxyethylene castor oil, polyoxyethylene hydrogenated castor oil monoisostearate, polyoxyethylene hydrogenated castor oil triisostearate, polyoxyethylene hydrogenated castor oil monopyroglutamic acid monoisostearate diester, poly Castor oil such as oxyethylene hydrogenated castor oil maleic acid and hydrogenated castor oil derivatives; polyoxyethylene phytosterol; polyoxyethylene cholesterol; polyoxy Polyoxyethylene lanolin; polyoxyethylene reduced lanolin; polyoxyethylene polyoxypropylene cetyl ether, polyoxyethylene polyoxypropylene 2-decyltetradecyl ether, polyoxyethylene polyoxypropylene monobutyl ether, polyoxyethylene lanolin; Oxyethylene / polyoxypropylene hydrogenated lanolin, polyoxyethylene / polyoxypropylene alkyl ethers such as polyoxyethylene / polyoxypropylene glycerin ether; polyoxyethylene / polyoxypropylene glycol; (poly) such as PPG-9 diglyceryl Glycerin polyoxypropylene glycol; glyceryl stearate, glyceryl isostearate, glyceryl palmitate, myristate group Glyceryl fatty acid partial esters such as ceryl, glyceryl oleate, glyceryl coconut oil fatty acid, glyceryl mono-cotton oil fatty acid glycerin, glyceryl monoerucate, glyceryl sesquioleate, α, α'-oleic acid pyroglutamate glycerin, monostearate glycerin malate; Polyglyceryl stearate-2, 3, 4, 5, 6, 8, 10, polyglyceryl distearate-6, 10, polyglyceryl tristearate, polyglyceryl decastearate-10, polyglyceryl isostearate -2, 3, 4, 5, 6, 8, 10, diglycostyl diisostearate (diglyceryl diisostearate), 3, 10, polyglyceryl-2 triisostearate, polyglyceryl tetraisostearate Ril-2, polyglyceryl-10 decaisostearate, polyglyceryl-2 oleate, 3,4, 5,6, 8,8, dioleate polyglyceryl-6, trioleate polyglyceryl-2, dekaoleic acid Polyglyceryl fatty acid esters such as polyglyceryl-10; ethylene glycol monofatty acid esters such as ethylene glycol monostearate; propylene glycol monofatty acid esters such as propylene glycol monostearate; pentaerythritol partial fatty acid esters; sorbitol partial fatty acid esters; maltitol moieties Fatty acid ester; maltitol ether; sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monos Sorbitan fatty acid esters such as allate, sorbitan sesquioleate, sorbitan trioleate, diglycerol sorbitan penta-2-ethylhexylate, diglycerol sorbitan tetra-2-ethylhexylate; sucrose fatty acid ester, methyl glucoside fatty acid ester, trehalose undecylenate, etc. Partial derivatives of sugar derivatives; alkyl glucosides such as caprylyl glucoside; alkyl polyglycosides; lanolin alcohols; reduced lanolin; polyoxyethylene distearate, polyethylene glycol diisostearate, polyoxyethylene monooleate, polyoxyethylene di- Polyoxyethylene fatty acid mono- and diesters such as oleate; polyoxyethylene propylene glycol fatty acid ester; polyoxyethylene Polyoxyethylene glycerin fatty acid esters such as polyoxyethylene monooleate such as polyglycerin monostearate, polyoxyethylene glycerin monoisostearate, polyoxyethylene glycerin triisostearate; polyoxyethylene sorbitan monooleate, polyoxy Polyoxyethylene sorbitan fatty acid esters such as ethylene sorbitan monostearate, polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan tetraoleate; polyoxyethylene sorbitol monolaurate, polyoxyethylene sorbitol monooleate, polyoxyethylene sorbitol penta Polyoxyethylene sorbitol fatty acid esters such as oleate and polyoxyethylene sorbitol monostearate Polyoxyethylene methyl glucoside fatty acid ester; Polyoxyethylene alkyl ether fatty acid ester; Polyoxyethylene animal and vegetable oils such as polyoxyethylene sorbitol beeswax; Alkyl such as isostearyl glyceryl ether, chimyl alcohol, ceralkyl alcohol, batyl alcohol Glyceryl ethers; polyhydric alcohol alkyl ethers; polyoxyethylene alkylamines; tetrapolyoxyethylene / tetrapolyoxypropylene-ethylenediamine condensates; natural surfactants such as saponins and sophorolipids; polyoxyethylene fatty acid amides; coconut oil Fatty acid monoethanolamide (cocamide MEA), coconut oil fatty acid diethanolamide (cocamide DEA), lauric acid monoethanolamide (laura) De-MEA), lauric acid diethanolamide (lauramide DEA), lauric acid monoisopropanolamide (lauramide MIPA), palmitic acid monoethanolamide (partamid MEA), palmitic acid diethanolamide (partamide DEA), palm oil fatty acid methylethanolamide (cocamidomethyl) Fatty acid alkanolamides such as MEA); alkyldimethylamine oxides such as lauramine oxide, cocamamine oxide, stearamine oxide, and behenamine oxide; alkylethoxydimethylamine oxide; polyoxyethylene alkyl mercaptan; poly such as dimethicone copolyol Silicone such as ether-modified silicone, polysiloxane-oxyalkylene copolymer, polyglycerin-modified silicone, sugar-modified silicone Nonionic surfactants, etc .; for cationic surfactants, alkyltrimethylammonium chlorides such as behentrimonium chloride, steartrimonium chloride, cetrimonium chloride, lauryltrimonium chloride; alkyls such as stearyltrimonium bromide Trialkylammonium bromide; dialkyldimethylammonium chloride such as distearyldimonium chloride and dicocodimonium chloride; fatty acid amidoamines and salts thereof such as stearamidepropyldimethylamine and stearamideethyldiethylamine; alkyl ether amines such as stearoxypropyldimethylamine; Salt or quaternary salt thereof; ethyl sulfate long chain branched fatty acid (12-31) aminopropylethyldimethylammonium, ethyl lanolin sulfate Fatty acid amide-type quaternary ammonium salts such as aminopropylethyldimethylammonium fatty acid; polyoxyethylene alkylamine and its salts or quaternary salts; alkylamine salts; fatty acid amidoguanidinium salts; alkyl etheraminemonium salts; Benzalkonium salt; Pyridinium salt such as cetylpyridinium chloride; Imidazolinium salt; Alkylisoquinolinium salt; Dialkyl morpholinium salt; Polyamine fatty acid derivatives; Aminopropyl dimethicone and amodimethicone Silicone-based cationic surfactants such as amino-modified silicone, cation-modified silicone, cation-modified and polyether-modified silicone, amino-modified and polyether-modified silicone, etc .; amphoteric Surfactants include N-alkyl-N, N-dimethylamino acid betaines such as lauryl betaine (lauryldimethylaminoacetic acid betaine); fatty acid amide alkyl-N, N-dimethylamino acid betaines such as cocamidopropyl betaine and lauramidopropyl betaine. Imidazoline-type betaines such as sodium cocoamphoacetate and sodium lauroamphoacetate; alkylsulfobetaines such as alkyldimethyltaurine; sulfate-type betaines such as alkyldimethylaminoethanol sulfate; phosphate-type betaines such as alkyldimethylaminoethanolphosphate; phosphatidylcholine , Phosphatidylethanolamine, phosphatidylserine, sphingomyelin and other sphingophospholipids, lysolecithin, hydrogenated soybean phospholipid, partially hydrogenated soybean Phospholipids such as phospholipids, hydrogenated egg yolk phospholipids, partially hydrogenated egg yolk phospholipids, and hydroxylated lecithin; silicone-based amphoteric surfactants; polymer surfactants such as polyvinyl alcohol, sodium alginate, starch derivatives, tragacanth gum , Acrylic acid / methacrylic acid alkyl copolymer; and various silicone-based surfactants.

  Polymers, thickeners and gelling agents include guar gum, locust bean gum, queens seed, carrageenan, galactan, arabic gum, tara gum, tamarind, far selelain, karaya gum, troarooi, cara gum, tragacanth gum, pectin, pectic acid and sodium Salt such as salt, salt such as alginic acid and sodium salt, mannan; starch such as rice, corn, potato, wheat; xanthan gum, dextran, succinoglucan, curdlan, hyaluronic acid and its salt, xanthan gum, pullulan, gellan gum, chitin , Chitosan, agar, gypsum extract, chondroitin sulfate, casein, collagen, gelatin, albumin; methylcellulose, ethylcellulose, hydroxyethylcellulose, hydroxypropi Cellulose, carboxymethylcellulose and its salts such as sodium, methylhydroxypropylcellulose, sodium cellulose sulfate, cellulose dialkyldimethylammonium sulfate, crystalline cellulose, cellulose powder such as cellulose powder; soluble starch, carboxymethyl starch, methylhydroxypropyl starch, Starch-based polymers such as methyl starch, starch derivatives such as hydroxypropyltrimonium chloride, octenyl succinate corn starch and aluminum; alginic acid derivatives such as sodium alginate and propylene glycol alginate; polyvinylpyridone (PVP), polyvinyl alcohol (PVA), Vinyl pydridone-vinyl alcohol copolymer, polyvinyl methyl ether Polyethylene glycol, polypropylene glycol, polyoxyethylene / polyoxypropylene copolymer; amphoteric methacrylic acid such as (methacryloyloxyethylcarboxybetaine / alkyl methacrylate) copolymer, (acrylates / stearyl acrylate / ethylamine methacrylate oxide) copolymer, etc. Ester copolymer; (Dimethicone / vinyl dimethicone) crosspolymer, (alkyl acrylate / diacetone acrylamide) copolymer, (alkyl acrylate / diacetone acrylamide) copolymer AMP; Polyvinyl acetate partial saponification product, maleic acid copolymer; Vinylpyrrolidone / dialkylaminoalkyl methacrylate copolymer; acrylic resin alkanolamine; polyester, water-dispersible polyester; Kurylamide; Polyacrylic acid ester copolymer such as polyethyl acrylate, carboxyvinyl polymer, polyacrylic acid and its sodium salt, acrylic acid / methacrylic acid ester copolymer; acrylic acid / alkyl methacrylate Polymer: Cationic cellulose such as polyquaternium-10, diallyldimethylammonium chloride / acrylamide copolymer such as polyquaternium-7, acrylic acid / diallyldimethylammonium chloride copolymer such as polyquaternium-22, and acrylic acid such as polyquaternium-39・ Diallyldimethylammonium chloride / acrylamide copolymer, acrylic acid / cationized methacrylic acid ester copolymer, acrylic acid / cationized methacrylic acid amide copolymer, polyquaternium Acrylic acid / methyl acrylate / methacrylamidopropyltrimethylammonium chloride copolymer such as 47, methacrylic acid choline ester polymer; cationized polysaccharides such as cationized oligosaccharide, cationized dextran, guar hydroxypropyltrimonium chloride; Polyethyleneimine; Cationic polymer; Polymer of 2-methacryloyloxyethyl phosphorylcholine such as polyquaternium-51 and copolymer with butyl methacrylate copolymer; Acrylic resin emulsion, polyethyl acrylate emulsion, polyacrylalkyl ester emulsion, Polymer emulsions such as polyvinyl acetate resin emulsion, natural rubber latex, synthetic latex; nitrocellulose; polyurethanes and various copolymers; various silicones Various silicone-based copolymers such as acrylic-silicone graft copolymers; various fluoropolymers; 12-hydroxystearic acid and its salts; dextrin fatty acid esters such as dextrin palmitate and dextrin myristate; silicic anhydride, Smoke-like silica (ultrafine silicic anhydride), aluminum magnesium silicate, magnesium magnesium silicate, metal soap, dialkyl phosphate metal salt, bentonite, hectorite, organically modified clay mineral, sucrose fatty acid ester, fructooligosaccharide fatty acid ester It is mentioned as preferable.

  Solvents and propellants include ethanol, 2-propanol (isopropyl alcohol), butanol, isobutyl alcohol and other lower alcohols; propylene glycol, 1,3-butylene glycol, diethylene glycol, dipropylene glycol, isopentyl diol and other glycols Diethylene glycol monoethyl ether (ethoxydiglycol), ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, triethylene glycol monoethyl ether, diethylene glycol diethyl ether, diethylene glycol dibutyl ether, propylene glycol monoethyl ether, dipropylene glycol monoethyl ether Glycol ethers such as ethylene glycol monoethyl ether Glycol ether esters such as acetate, diethylene glycol monoethyl ether acetate, propylene glycol monoethyl ether acetate; Glycol esters such as diethoxyethyl succinate, ethylene glycol disuccinate; benzyl alcohol, benzyloxyethanol, propylene carbonate, dialkyl carbonate , Acetone, ethyl acetate, N-methylpyrrolidone; toluene; fluorocarbon, next-generation flon; propellants such as LPG, dimethyl ether, carbon dioxide, and the like are preferable.

  Antioxidants include tocopherol derivatives such as tocopherol (vitamin E) and tocopherol acetate; BHT, BHA; gallic acid derivatives such as propyl gallate; vitamin C (ascorbic acid) and / or derivatives thereof; erythorbic acid and derivatives thereof; Preferred are sulfites such as sodium sulfite; bisulfites such as sodium bisulfite; thiosulfates such as sodium thiosulfate; metabisulfites; thiotaurine, hypotaurine; thioglycerol, thiourea, thioglycolic acid, cysteine hydrochloride As mentioned. Preferred examples of the reducing agent include thioglycolic acid, cysteine, cysteamine and the like. Preferred examples of the oxidizing agent include aqueous hydrogen peroxide, ammonium persulfate, sodium bromate, and percarbonate.

  Antibacterial agents or antiseptics include parabens (hydroxybenzoic acid esters) such as methylparaben, ethylparaben, propylparaben and butylparaben; phenoxyethanol; 1,2-pentanediol, 1,2-hexanediol, 1,2-octane 1,2-alkanediols such as diol; alkyl glyceryl ethers such as 2-ethylhexyl glyceryl ether (ethylhexyl glycerin); salicylic acid; sodium benzoate; isothiazoline derivatives such as methyl chloroisothiazolinone and methylisothiazolinone; Dehydroacetic acid and its salts; phenols; halogenated bisphenols such as triclosan, acid amides, quaternary ammonium salts; trichlorocarbanide, zinc pyrithione, benzoyl chloride Luconium, benzethonium chloride, sorbic acid, chlorhexidine, chlorhexidine gluconate, halocarban, hexachlorophene, hinokitiol; other phenols such as phenol, isopropylphenol, cresol, thymol, parachlorophenol, phenylphenol, sodium phenylphenol; phenylethyl alcohol , Photosensitizers, antibacterial zeolite, and silver ion are preferable, but when used as an antibacterial agent or antiseptic agent for antiseptic purposes, phenoxyethanol; 1 from the viewpoint of safety of cosmetics or skin external preparations; 1,2-alkanediols such as 1,2-pentanediol, 1,2-hexanediol, 1,2-octanediol; alkyl glyceres such as 2-ethylhexyl glyceryl ether It is more preferred to use ethers.

  Examples of chelating agents include edetate (ethylenediaminetetraacetate) such as EDTA, EDTA2Na, EDTA3Na, and EDTA4Na; hydroxyethylethylenediaminetriacetate such as HEDTA3Na; pentetate (diethylenetriaminepentaacetate); phytic acid; Phosphonic acid and its sodium salt; sodium oxalate; polypolyamino acids such as polyaspartic acid and polyglutamic acid; sodium polyphosphate, sodium metaphosphate, phosphoric acid; sodium citrate, citric acid, alanine, dihydroxyethylglycine Gluconic acid, ascorbic acid, succinic acid, and tartaric acid are preferable. pH adjusters / acids / alkalis include citric acid, sodium citrate, lactic acid, sodium lactate, glycolic acid, succinic acid, acetic acid, sodium acetate, malic acid, tartaric acid, fumaric acid, phosphoric acid, hydrochloric acid, sulfuric acid, monoethanol Amine, diethanolamine, triethanolamine, isopropanolamine, triisopropanolamine, 2-amino-2-methyl-1,3-propanediol, 2-amino-2-hydroxymethyl-1,3-propanediol, arginine, hydroxylation Sodium, potassium hydroxide, aqueous ammonia, guanidine carbonate, and ammonium carbonate are preferable.

  Examples of powders include mica, talc, kaolin, sericite, montmorillonite, kaolinite, mica, muscovite, phlogopite, synthetic mica, red mica, biotite, permiculite, magnesium carbonate, calcium carbonate, aluminum silicate, silica Barium acid, calcium silicate, magnesium silicate, strontium silicate, metal tungstate, magnesium, zeolite, barium sulfate, calcined calcium sulfate, calcium phosphate, fluorine apatite, hydroxyapatite, ceramic powder, bentonite, smectite, clay, mud, Metal soap (e.g., zinc myristate, calcium palmitate, aluminum stearate), calcium carbonate, bengara, yellow iron oxide, black iron oxide, ultramarine, bitumen, carbon black, titanium oxide, fine particles and ultrafine Titanium oxide, zinc oxide, fine and ultrafine zinc oxide, alumina, silica, fumed silica (ultrafine silica), titanium mica, fish scale foil, boron nitride, photochromic pigment, synthetic fluorophlogopite, fine particle composite powder Body, gold, aluminum, etc., various sizes and shapes of inorganic powders, and these are treated with various surface treatment agents such as hydrogen silicone, cyclic hydrogen silicone, or other silane or titanium coupling agents Inorganic powders such as hydrophobized or hydrophilized powders; starch, cellulose, nylon powder, polyethylene powder, polymethyl methacrylate powder, polystyrene powder, copolymer resin powder of styrene and acrylic acid, polyester powder, Benzoguanamine resin powder, polyethylene terephthalate, polymethyl Organic powders and surface-treated powders of various sizes and shapes, such as methacrylate powder, polyethylene terephthalate / aluminum / epoxy powder, urethane powder, silicone powder, Teflon (registered trademark) powder, organic-inorganic composite powder Is preferable. Inorganic salts include sodium chloride-containing salts such as salt, common salt, rock salt, sea salt, natural salt; potassium chloride, aluminum chloride, calcium chloride, magnesium chloride, bittern, zinc chloride, ammonium chloride; sodium sulfate, aluminum sulfate, Aluminum sulfate / potassium sulfate (alum), aluminum sulfate / ammonium sulfate, barium sulfate, calcium sulfate, potassium sulfate, magnesium sulfate, zinc sulfate, iron sulfate, copper sulfate; sodium phosphates such as 1Na, 2Na and 3Na phosphates, phosphoric acid Potassium, calcium phosphates and magnesium phosphates are preferred.

  Examples of ultraviolet absorbers include paraaminobenzoic acid, paraaminobenzoic acid monoglycerin ester, N, N-dipropoxyparaaminobenzoic acid ethyl ester, N, N-diethoxyparaaminobenzoic acid ethyl ester, and N, N-dimethylparaaminobenzoic acid ethyl ester. Benzoic acid-based ultraviolet absorbers such as esters, N, N-dimethylparaaminobenzoic acid butyl ester, N, N-dimethylparaaminobenzoic acid ethyl ester; Anthranilic acid-based ultraviolet absorbers such as homomenthyl-N-acetylanthranilate; Salicylic acid And salicylic acid-based purple such as sodium salt, amyl salicylate, menthyl salicylate, homomenthyl salicylate, octyl salicylate, phenyl salicylate, benzyl salicylate, p-isopropanol phenyl salicylate Line absorber: Octyl cinnamate, ethyl-4-isopropyl cinnamate, methyl-2,5-diisopropyl cinnamate, ethyl-2,4-diisopropyl cinnamate, methyl-2,4-diisopropyl cinnamate, propyl-p- Methoxycinnamate, isopropyl-p-methoxycinnamate, isoamyl-p-methoxycinnamate, 2-ethylhexyl p-methoxycinnamate (octyl paramethoxycinnamate), 2-ethoxyethyl-p-methoxycinnamate (sinoxate), Cyclohexyl-p-methoxycinnamate, ethyl-α-cyano-β-phenylcinnamate, 2-ethylhexyl α-cyano-β-phenylcinnamate (octocrine), glyceryl mono-2-ethylhexanoyl-diparamethoxy Cinnamic acid-based UV absorbers such as namate, ferulic acid and derivatives thereof; 2,4-dihydroxybenzophenone, 2,2′-dihydroxy-4-methoxybenzophenone, 2,2′-dihydroxy-4,4′-dimethoxybenzophenone, 2,2 ′, 4,4′-tetrahydroxybenzophenone, 2-hydroxy-4-methoxybenzophenone (oxybenzone-3), 2-hydroxy-4-methoxy-4′-methylbenzophenone, 2-hydroxy-4-methoxybenzophenone -5-sulfonate, 4-phenylbenzophenone, 2-ethylhexyl-4'-phenyl-benzophenone-2-carboxylate, 2-hydroxy-4-n-octoxybenzophenone, 4-hydroxy-3-carboxybenzophenone, etc. Benzophenone purple 3- (4'-methylbenzylidene) -d, l-camphor, 3-benzylidene-d, l-camphor; 2-phenyl-5-methylbenzoxazole; 2,2'-hydroxy-5 2- (2′-hydroxy-5′-t-octylphenyl) benzotriazole; 2- (2′-hydroxy-5′-methylphenylbenzotriazole; dibenzalazine; dianisoylmethane; 5- (3 , 3-dimethyl-2-norbornylidene) -3-pentan-2-one; dibenzoylmethane derivatives such as 4-t-butylmethoxydibenzoylmethane; octyl triazone; urocanic acid derivatives such as urocanic acid and ethyl urocanate; 2- (2′-hydroxy-5′-methylphenyl) benzotriazole, 1- ( , 4-dimethoxyphenyl) -4,4-dimethyl-1,3-pentanedione, dimethoxybenzylidenedioxoimidazolidinepropionate 2-ethylhexyl, etc., hydantoin derivatives, phenylbenzimidazolazosulfonic acid, terephthalylidene dicamphsulfone Preference is given to acids, drometrizole trisiloxane, methyl anthranilate, rutin and its derivatives, oryzanol and its derivatives.

  Examples of whitening agents include hydroquinone glycosides such as arbutin and α-arbutin and esters thereof; ascorbic acid phosphate salts such as ascorbic acid, sodium ascorbate phosphate and magnesium ascorbate phosphate, ascorbic acid Ascorbic acid fatty acid esters such as tetraisopalmitic acid ester, ascorbic acid alkyl ethers such as ascorbic acid ethyl ether, ascorbic acid glucosides such as ascorbic acid-2-glucoside and fatty acid esters thereof, ascorbic acid sulfate ester, tocopheryl ascorbyl phosphate Ascorbic acid derivatives such as kojic acid, ellagic acid, tranexamic acid and its derivatives, ferulic acid and its derivatives, placenta extract, glutathione, oryzanol, butylreso Shinoru, oil-soluble Kamomiraekisu, oil-soluble licorice extract, Nishikawa willow extract, be mentioned as saxifrage extract, and the like plant extracts are preferred.

  Vitamins and their derivatives include vitamin A such as retinol, retinol acetate, retinol palmitate; thiamine hydrochloride, thiamine sulfate, riboflavin, riboflavin acetate, pyridoxine hydrochloride, pyridoxine dioctanoate, pyridoxine dipalmitate, Flavin adenine dinucleotide, cyanocobalamin, folic acid, nicotinic acid such as nicotinic acid amide / benzyl nicotinate, vitamin B group such as choline; vitamin C such as ascorbic acid and its sodium salt; vitamin D; α, Vitamin Es such as β, γ, δ-tocopherol; other vitamins such as pantothenic acid and biotin; ascorbic acid phosphates such as ascorbic acid phosphate sodium salt and ascorbic acid phosphate magnesium salt; Ascorbic acid fatty acid esters such as corobic acid tetraisopalmitic acid ester, ascorbyl stearate, ascorbyl palmitate and ascorbyl dipalmitate, ascorbic acid alkyl ether such as ascorbic acid ethyl ether, ascorbic acid glucoside such as ascorbic acid-2-glucoside and Ascorbic acid derivatives such as fatty acid esters and tocopheryl phosphate ascorbyl; vitamin derivatives such as tocopherol nicotinate, tocopherol acetate, tocopherol acetate, tocopherol linoleate, tocopherol phosphate, tocopherol phosphate etc., tocotrienol, and other various vitamin derivatives Is preferable.

  Anti-inflammatory and anti-inflammatory agents include glycyrrhizic acid and its derivatives, glycyrrhetinic acid derivatives, salicylic acid derivatives, hinokitiol, guaiazulene, allantoin, indomethacin, zinc oxide, hydrocortisone acetate, prednisone, diphedramine hydrochloride, chlorpheniramine maleate; peach leaf extract A plant extract such as a koji leaf extract is preferable. Plant growth and tinctures such as assembly extract, red pepper tincture, ginger tincture, ginger extract, cantalis tincture; capsaicin, nonyl acid valenylamide, gingeron, ictamol, tannic acid Borneol, cyclandelate, cinnarizine, trazoline, acetylcholine, verapamil, cephalanthin, γ-oryzanol, cephalanthin, vitamin E and nicotinic acid tocopherol, acetic acid tocopherol and other derivatives, γ-oryzanol, nicotinic acid, nicotinic acid amide, nicotinic acid benzyl Derivatives such as ester, inositol hexanicotinate, nicotine alcohol, allantoin, photosensitizer 301, photosensitizer 401, capronium chloride, pentadecanoic acid monoglyceride, Preferable examples include flavonol derivatives, stigmasterol or stigmasteranol, its glycosides, and minoxidil. Preferred hormones include estradiol, estrone, ethinyl estradiol, cortisone, hydrocortisone, prednisone and the like. Other remedies such as anti-wrinkle agents, anti-aging agents, squeeze agents, cooling sensations, warming sensation agents, wound healing promoters, irritation relievers, analgesics, cell activators include retinols, retinoic acids, retinoin Acid tocopheryl; derivatives such as lactic acid, glycolic acid, gluconic acid, fruit acid, salicylic acid and glycosides / esterified products thereof, α- or such as hydroxycapric acid, long chain α-hydroxy fatty acid, long chain α-hydroxy fatty acid cholesteryl β-hydroxy acids and derivatives thereof; γ-aminobutyric acid, γ-amino-β-hydroxybutyric acid; carnitine; carnosine; creatine; ceramides, sphingosines; caffeine, xanthine and the like; and coenzyme Q10, carotene, lycopene , Astaxanthin, lutein, α-lipoic acid, platinum nanocolloid, fullerenes, etc. Antioxidant / active oxygen scavengers; catechins; flavones such as quercetin; isoflavones; gallic acid and ester sugar derivatives; polyphenols such as tannin, sesamin, protoanthocyanidin, chlorogenic acid, apple polyphenol; rutin and glycosides, etc. Derivatives of hesperidin and glycosides; lignan glycosides; licorice extract-related substances such as grabrizine, glabrene, liquiritin, and isoliquiritin; lactoferrin; shogaol, gingerol; fragrance substances such as menthol, camphor, cedrol, and derivatives thereof Preferred examples include capsaicin, vanillin and the like and derivatives; insect repellents such as diethyltoluamide; and complexes of physiologically active substances and cyclodextrins.

  Plant / animal / microbe extracts include iris extract, ashitaba extract, asunaro extract, asparagus extract, avocado extract, achacha extract, almond extract, altea extract, arnica extract, aloe extract, apricot extract, apricot kernel extract, ginkgo biloba extract , Incheon extract, Fennel extract, Turmeric extract, Oolong tea extract, Peony extract, Ages extract, Echinacea leaf extract, Enmeo extract, Ogon extract, Oat extract, Auren extract, Barley extract, Panax ginseng extract, Hypericum extract, Odori extract , Dutch mustard extract, orange extract, dried sea water, seaweed extract, oyster leaf extract, oyster extract, hydrolyzed elastin, hydrolyzed wheat powder, hydrolysis Luc, Cascon extract, Chamomile extract, Oil-soluble chamomile extract, Carrot extract, Kawara mugi extract, Oat extract, Calcade extract, Licorice extract, Oil-soluble Licorice extract, Kiwi extract, Kiou extract, Cyprid extract, Quina extract, Cucumber extract, Kiri leaf extract, Guanosine, guava extract, cucumber extract, gardenia extract, kumazasa extract, clara extract, walnut extract, chestnut extract, grapefruit extract, clematis extract, black rice extract, brown sugar extract, black vinegar, chlorella extract, mulberry extract, gentian extract, Gentian pepper extract, tea Extract, yeast extract, kokuboku extract, coffee extract, burdock extract, rice extract, rice fermented extract, rice bran fermented extract, rice germ oil, comfrey extract, Lagen, Cowberry extract, Saishin extract, Psycho extract, Saitai extract, Saffron extract, Salvia extract, Salmon extract, Sasa extract, Hawthorn extract, Sansha extract, Salamander extract, Shiitake extract, Giant extract, Shikon extract, Perilla extract, Linden extract, Shimosukeso Extract, jatoba extract, peonies extract, ginger cucumber extract, ginger root extract, white birch extract, white jellyfish extract, horsetail extract, stevia extract, stevia fermented product, west river willow extract, horse chestnut extract, hawthorn extract, elderberry extract, yarrow extract , Mint extract, sage extract, mallow extract, nematode extract, essence extract, Sakuhakuhi extract, Diou extract, Dai Extract, peanut extract, thyme extract, dandelion extract, lichen extract, tea extract, clove extract, chigaya extract, chimpi extract, tea tree oil, tea tea extract, red pepper extract, red snapper extract, red snapper extract, red spruce extract, red spruce extract, tomato Extract, natto extract, carrot extract, garlic extract, wild rose extract, hibiscus extract, bacmond extract, lotus extract, parsley extract, birch extract, honey, hamamelis extract, parietalia extract, hyacinth extract, bisabolol, cypress extract, bifidobacteria extract, Loquat extract, dandelion extract, burdock extract, bukkuri extract, butcher bloom extract, grape extract, grape seed extract, propolis, loofah extract, Safflower extract, peppermint extract, body extract, button extract, hop extract, squid extract, pine extract, maroonnier extract, mizubasho extract, mukuroji extract, melissa extract, mozuku extract, peach extract, cornflower extract, eucalyptus extract, yukinoshita extract, yuzu extract, lily extract, Yokuinin extract, mugwort extract, lavender extract, green tea extract, eggshell membrane extract, apple extract, rooibos tea extract, litchi extract, lettuce extract, lemon extract, forsythia extract, forsythia extract, rose extract, rosemary extract, roman chamomile extract, royal jelly Extracts such as an extract and a bitumen extract are preferred.

  Examples of the antipruritic agent include diphenhydramine hydrochloride, chlorpheniramine maleate, camphor, substance-P inhibitor, and the like. Examples of the exfoliating / dissolving agent include salicylic acid, sulfur, resorcin, selenium sulfide, pyridoxine and the like. Examples of the antiperspirant include chlorohydroxyaluminum, aluminum chloride, zinc oxide, and zinc paraphenol sulfonate. Examples of the refreshing agent include menthol and methyl salicylate. Examples of the astringent include citric acid, tartaric acid, lactic acid, aluminum sulfate / potassium sulfate, and tannic acid. Examples of enzymes include superoxide dismutase, catalase, lysozyme chloride, lipase, papain, pancreatin, protease, and the like. Preferred nucleic acids include ribonucleic acid and salts thereof, deoxyribonucleic acid and salts thereof, and adenosine triphosphate disodium.

  As perfumes, acetyl cedrene, amylcinnamaldehyde, allyl amyl glycolate, β-ionone, iso-Esuper, isobutyl quinoline, Iris oil, Iron, indole, ylang ylang oil, undecanal, undecenal, γ-undecalactone, Estragole, eugenol, oak moss, opoponax resinoid, orange oil, eugenol, auranthiol, galac solid, carvacrol, L-carvone, camphor, cannon, carrot seed oil, clove oil, methyl cinnamate, geraniol, geranyl nitrile , Isobornyl acetate, geranyl acetate, dimethylbenzyl carvinyl acetate, styrylyl acetate, cedolyl acetate, terpinel acetate, pt-butylcyclohexyl acetate, vetiberyl acetate, benzyl acetate, vinegar Linalyl, isopentyl salicylate, benzyl salicylate, sandalwood oil, santalol, cyclamenaldehyde, cyclopentadecanolide, methyl dihydrojasmonate, dihydromilsenol, jasmine absolute, jasmine lactone, cis-jasmon, citral, citronenol, citronellal, Cinnamon bark oil, 1,8-cineole, cinnamaldehyde, stylax resinoid, cedarwood oil, cedrene, cedrol, celery seed oil, thyme oil, damascon, damacenone, thymol, tuberose absolute, decanal, decalactone, terpineol, γ-terpinene, Tripral, Nellore, Nonanal, 2,6-Nonadienol, Nonalactone, Patchouli alcohol, Vanilla absolute , Vanillin, basil oil, patchouli oil, hydroxycitronellal, α-pinene, piperitone, phenethyl alcohol, phenylacetaldehyde, petitglen oil, hexylcinnamaldehyde, cis-3-hexenol, peruvian valsum, vetiver oil, vetiverol, peppermint oil, Pepper oil, heliotropin, bergamot oil, benzyl benzoate, borneol, milresinoid, musk ketone, methylnonylacetaldehyde, γ-methylyonone, menthol, L-menthol, L-menthol, eucalyptus oil, β-yonone, lime oil, lavender oil, Synthetic and natural fragrances such as D-limonene, linalool, rilal, rireal, lemon oil, rose absolute, rose oxide, rose oil, rosemary oil, various essential oils, and various blended fragrances It is mentioned as preferred.

As pigments / colorants / dyes / pigments, brown 201, black 401, purple 201, purple 401, blue 1, blue 2, blue 201, blue 202, blue 203, blue 204 , Blue 205, Blue 403, Blue 404, Green 201, Green 202, Green 204, Green 205, Green 3, Green 401, Green 402, Red 102, Red 104-1 , Red 105-1, Red 106, Red 2, Red 201, Red 202, Red 203, Red 204, Red 205, Red 206, Red 207, Red 208, Red 213 Red 214, Red 215, Red 218, Red 219, Red 220, Red 221, Red 223, Red 225, Red 226, Red 227, Red 228, Red 230 No. 1, Red 230-2, Red 231, Red 232, Red 3, Red 401, Red 404, Red 405, Red 501, Red 502, Red 503, Red 504, Red 505, red 506, orange 201, orange 203, orange 204, orange 205, orange 206, orange 207, orange 401, orange 402, orange 403, yellow 201, yellow 202- No. 1, yellow 202-2, yellow 203, yellow 204, yellow 205, yellow 4, yellow 401, yellow 402, yellow 403-1, yellow 404, yellow 405, yellow 406 Legal dyes such as Yellow No. 407 and Yellow No. 5; Other acidic dyes such as Acid Red 14; Arianor Sienna Brown, Arianor Madder Red, Arianor
Basic dyes such as Steel Blue and Arianor Straw Yellow; HC Yellow 2, HC Yellow 5, HC Red 3, 4-hydoxypropylamino-3-nitrophenol, N, N'-bis (2-hydroxyethyl) -2-nitro-p-
Nitro dyes such as phenylenediamine, HC Blue 2 and Basic Blue 26; disperse dyes; inorganic white pigments such as titanium dioxide and zinc oxide; inorganic red pigments such as iron oxide (Bengara) and iron titanate; and γ-iron oxide Inorganic brown pigments; inorganic yellow pigments such as yellow iron oxide and ocher; inorganic black pigments such as black iron oxide and low-order titanium oxide; inorganic purple pigments such as mango violet and cobalt violet; chromium oxide and chromium hydroxide Inorganic green pigments such as cobalt titanate; inorganic blue pigments such as ultramarine and bitumen; titanium oxide coated mica, titanium oxide coated bismuth oxychloride, titanium oxide coated talc, colored titanium oxide coated mica, bismuth oxychloride, fish scale foil Pearl powder such as aluminum powder, copper powder, metal powder pigment such as gold; surface treatment inorganic and metal powder pigment; red 01, Red 202, Red 204, Red 205, Red 220, Red 226, Red 228, Red 405, Orange 203, Orange 204, Yellow 205, Yellow 401, Blue 404 Red No. 3, Red No. 104, Red No. 106, Red No. 227, Red No. 230, Red No. 401, Red No. 505, Orange No. 205, Yellow No. 4, Yellow No. 5, Yellow No. 202, Yellow No. 203, Green Organic pigments such as zirconium, barium or aluminum lakes such as No. 3, Blue No. 1; surface-treated organic pigments; anthraquinones such as astaxanthin and alizarin, anthocyanidins, β-carotene, catenal, capsanthin, chalcone, calsamine, quercetin, crocin, Naphthoquinones such as chlorophyll, curcumin, cochineal, shikonin, bixin, flavo Natural pigments and dyes such as amines, betacyanidine, henna, hemoglobin, lycopene, riboflavin, rutin; p-phenylenediamine, toluene-2,5-diamine, o-, m-, or p-aminophenol, m-phenylene Oxidative dye intermediates and couplers such as diamine, 5-amino-2-methylphenol, resorcin, 1-naphthol, 2,6-diaminopyridine and their salts; auto-oxidizing dyes such as indoline; Can be mentioned.

  Preferred examples of water include normal water, purified water, hard water, soft water, natural water, deep sea water, electrolytic alkaline ionized water, electrolytic acidic ionized water, ionic water, and clustered water.

  In addition to these, cosmetic raw material standards, blending ingredient standard by cosmetic varieties, Japan Cosmetic Industry Association ingredient display name list, INCI dictionary (The International Cosmetic Ingredient Dictionary and Handbook), quasi-drug raw material standards, Japanese pharmacopoeia, pharmaceutical additives Ingredients listed in standards, official food additives, etc., and Japanese and foreign patent publications and patent publications (including publications and republications) in which the international patent classification IPC belongs to the classification of A61K7 and A61K8 It is possible to contain known cosmetic ingredients, pharmaceutical ingredients, food ingredients, etc., such as the ingredients described, in known combinations, blending ratios and blending amounts.

  As the types of cosmetics or skin external preparations containing the oily base of the present invention, preferred are skin external preparations such as hair cosmetics, basic cosmetics, makeup cosmetics, aromatic cosmetics, body cosmetics, ointments and the like. As mentioned. The cosmetic / skin external preparation of the present invention can be produced according to a usual method.

  The types of cosmetics or skin external preparations containing the oily base of the present invention will be described in more detail. Examples of hair cosmetics include oil shampoos, cream shampoos, conditioning shampoos, dandruff shampoos, hair color shampoos and rinses. Shampoo such as integrated shampoo; rinse, treatment, hair pack, hair foam, hair mousse, hair spray, hair mist, hair wax, hair gel, water grease, set lotion, color lotion, hair tonic, hair liquid, pomade, tic, hair cream , Hair blow, split hair coat, hair oil, permanent wave agent, straight perm agent, oxidation hair dye, hair bleach, hair color pre-treatment, hair color after-treatment, perm pre-treat Cement, permanent after-treatments, hair manicure, and as hair growth agents are preferred.

  Basic cosmetics include soft lotion, astringent lotion, cleansing lotion, multi-layer lotion, etc .; emollient lotion, moisture lotion, milky lotion, nourishing lotion, nourishing milk, skin moisture, moisturizer -Emulsions such as emulsion, massage lotion, cleansing lotion, protect emulsion, sun protect, sun protector, UV care milk, sunscreen, makeup lotion, horny smoother, elbow lotion, hand lotion, body lotion; emollient cream, nutritional cream, nari Thing cream, burnishing cream, moisture cream, night cream, massage cream, cleansing cream, makeup cream, base cream Cream, sun makeup cream, suntan cream, hair removal cream, deodorant cream, shaving cream, keratin softening cream, etc .; gel such as moisture gel; essence such as moisturizing essence, whitening essence, UV protection essence; liposome Liposome cosmetics such as beauty essence and liposome lotion; Peel-off packs, powder packs, washing packs, oil packs, cleansing masks and other packs and masks; cleansing foams, cleansing creams, cleansing milks, cleansing lotions, cleansing gels, cleansing oils , Cleansing mask, washing powder, face washing powder, etc .; cosmetic soap, transparent soap, medicated soap, liquid soap, shaving soap, synthetic cosmetic soap Soap can be mentioned as preferred.

  Examples of makeup cosmetics that may be preferably used include white powder, dusts, foundations, lipsticks, lip gloss, blushers, eyeliner, mascara, eye shadow, eyebrow, eyebrow, nail enamel, enamel remover, and nail treatment.

  Preferred examples of the aromatic cosmetics include perfume, perfume, parfum, eau de parfum, eau de toilette, eau de cologne, perfumes, fragrance powder, perfume soap, body lotion and bath oil.

  Body cosmetics such as body shampoos; deodorant lotions, deodorant powders, deodorant sprays, deodorant sticks and other deodorant cosmetics; decoloring agents, hair removal / hair removal agents; bathing agents; insect repellents A repeller is preferred.

  Moreover, as a skin external preparation, it can be used with dosage forms, such as an ointment, a patch, a lotion agent, a liniment agent, and a liquid coating agent. It can also be used as an oral cosmetic such as toothpaste and mouthwash.

  The cosmetic or skin external preparation containing the oily base of the present invention includes oil-in-water (O / W) type, water-in-oil (W / O) type, W / O / W type, O / W type. / O type emulsified cosmetics, oily cosmetics, solid cosmetics, liquid cosmetics, paste cosmetics, stick cosmetics, volatile oil cosmetics, powder cosmetics, jelly cosmetics, gels Preferable examples include dosage forms such as cosmetics, pastes, emulsified polymer cosmetics, sheet cosmetics, mist cosmetics, and spray cosmetics.

  EXAMPLES Hereinafter, although this invention is demonstrated in detail using an Example, this invention is not limited to these Examples.

Example 1
In a 500 mL reactor equipped with a stirrer, a thermometer, and a gas introduction tube, 100 g (0.174 mol) of hydrogenated dimer acid (manufactured by Croda, PRIPOL 1006), 45.9 g of dimer diol (manufactured by Croda, PRIPOL 2033) 0.083 mol) and 1.6 g (0.017 mol) of glycerin (Sakamoto Yakuhin Kogyo Co., Ltd.) are charged, heated to 210-220 ° C. in a nitrogen stream, and the esterification reaction is carried out for 5 hours while distilling off the generated water. The intermediate oligomer ester was obtained as a pale yellow high viscosity oil. The acid value of the obtained oligomer ester was 70.0. Furthermore, 46.5 g (0.146 mol) of behenyl alcohol (manufactured by Cognis, STENOL 1822A) was charged, heated to 210 to 220 ° C. in a nitrogen stream, and subjected to esterification reaction for 10 hours while distilling off the generated water. 182 g of was obtained (yield 98%). The resulting ester was a pale yellow pasty oil (hue Gardner 1 or less, acid value 4.5, saponification value 103.9, hydroxyl value 7.9).

Example 2
In a 500 mL reactor equipped with a stirrer, a thermometer, and a gas introduction tube, 100 g (0.174 mol) of hydrogenated dimer acid (manufactured by Croda, PRIPOL 1006), 45.9 g of dimer diol (manufactured by Croda, PRIPOL 2033) 0.083 mol), 1.6 g (0.017 mol) of glycerin (manufactured by Sakamoto Yakuhin Kogyo Co., Ltd.) and 46.5 g (0.146 mol) of behenyl alcohol (manufactured by Cognis, STENOL 1822A) were charged at 210 to 220 ° C. in a nitrogen stream. And the esterification reaction was carried out for 10 hours while distilling off the generated water to obtain 183 g of the desired ester (yield 98%). The obtained ester was a pale yellow pasty oil (hue Gardner 1 or less, acid value 4.0, saponification value 105.8, hydroxyl value 6.3).

Example 3
In a 500 mL reactor equipped with a stirrer, a thermometer, and a gas introduction tube, 100 g (0.174 mol) of hydrogenated dimer acid (manufactured by Croda, PRIPOL 1006), 34.4 g of dimer diol (manufactured by Croda, PRIPOL 2033) ( 0.063 mol), 3.2 g (0.035 mol) of glycerin (manufactured by Sakamoto Yakuhin Kogyo Co., Ltd.) and 43.2 g (0.136 mol) of behenyl alcohol (manufactured by Cognis, STENOL1822A) were charged, and 210 to 220 in a nitrogen stream. The mixture was heated to 0 ° C., and the esterification reaction was carried out for 15 hours while distilling off the generated water to obtain 171 g of the desired ester (yield 98%). The obtained ester was a pale yellow pasty oil (hue Gardner 1 or less, acid value 5.0, saponification value 114.3, hydroxyl value 8.9).

Example 4
In a 500 mL reactor equipped with a stirrer, a thermometer, and a gas introduction tube, 100 g (0.174 mol) of hydrogenated dimer acid (manufactured by Croda, PRIPOL 1006), 22.9 g of dimer diol (manufactured by Croda, PRIPOL 2033) (0 0.042 mol), 4.8 g (0.052 mol) of glycerin (manufactured by Sakamoto Yakuhin Kogyo Co., Ltd.) and 39.9 g (0.125 mol) of behenyl alcohol (manufactured by Cognis, STENOL1822A) were charged at 210 to 220 ° C. in a nitrogen stream. And the esterification reaction was carried out for 15 hours while distilling off the generated water to obtain 158 g of the desired ester (yield 98%). The obtained ester was a light yellow pasty oil (hue Gardner 1 or less, acid value 6.0, saponification value 121.3, hydroxyl value 9.9).

Example 5
In a 500 mL reactor equipped with a stirrer, a thermometer, and a gas introduction tube, 100 g (0.174 mol) of hydrogenated dimer acid (manufactured by Croda, PRIPOL 1006), 11.5 g of dimer diol (manufactured by Croda, PRIPOL 2033) (0 0.021 mol), 6.4 g (0.070 mol) of glycerin (manufactured by Sakamoto Yakuhin Kogyo Co., Ltd.) and 36.6 g (0.115 mol) of behenyl alcohol (manufactured by Cognis, STENOL 1822A) were charged at 210 to 220 ° C. in a nitrogen stream. And the esterification reaction was carried out for 21 hours while distilling off the generated water to obtain 145 g of the desired ester (yield 98%). The obtained ester was a light yellow pasty oil (hue Gardner 1 or less, acid value 3.6, saponification value 132.5, hydroxyl value 7.2).

Comparative Example 1
In a 500 mL reactor equipped with a stirrer, a thermometer, and a gas introduction tube, 100 g (0.174 mol) of hydrogenated dimer acid (manufactured by Croda, PRIPOL1006), 47.6 g of dimerdiol (manufactured by Croda, PRIPOL2033) 0.087 mol) and 60.9 g (0.191 mol) of behenyl alcohol (manufactured by Cognis, STENOL 1822A) are heated to 210-220 ° C. in a nitrogen stream, and the esterification reaction is carried out for 10 hours while distilling off the generated water. This gave 198 g of the desired ester (yield 98%). The obtained ester was a pale yellow pasty oil (hue Gardner 1 or less, acid value 4.4, saponification value 95.5, hydroxyl value 8.8).

Comparative Example 2
In a 500 mL reactor equipped with a stirrer, a thermometer, and a gas introduction tube, 100 g (0.174 mol) of hydrogenated dimer acid (manufactured by Croda, PRIPOL1006), 66.6 g of dimerdiol (manufactured by Croda, PRIPOL2033) .122 mol) and 38.8 g (0.122 mol) of behenyl alcohol (manufactured by Cognis, STENOL 1822A) were heated to 210-220 ° C. in a nitrogen stream, and the esterification reaction was carried out for 10 hours while distilling off the generated water. To obtain 195 g of the desired ester (yield 98%). The obtained ester was a pale yellow pasty oil, but was fluid at about 30 ° C. (hue Gardner 1 or less, acid value 4.5, saponification value 100.3, hydroxyl value 10.1). ).

Comparative Example 3
A 500 mL reactor equipped with a stirrer, a thermometer, and a gas introduction tube was charged with 100 g (0.174 mol) of hydrogenated dimer acid (manufactured by Croda, PRIPOL 1006), 76.1 g of dimer diol (manufactured by Croda, PRIPOL 2033). .139 mol) and 27.7 g (0.087 mol) of behenyl alcohol (manufactured by Cognis, STENOL1822A) were heated to 210-220 ° C. in a nitrogen stream, and the esterification reaction was carried out for 10 hours while distilling off the generated water. To obtain 193 g of the desired ester (yield 98%). The obtained ester was a pale yellow pasty oil but was fluid at about 30 ° C. (hue Gardner 1 or less, acid value 4.5, saponification value 101.3, hydroxyl value 10. 5).

(Refractive index, viscosity, melting point, adhesion evaluation)
About ester obtained in Examples 1-5 and Comparative Examples 1-3, refractive index, a viscosity, melting | fusing point, and the adhesiveness to skin were evaluated. The refractive index was measured at 40 ° C. using an Abbe refractometer (Mode 13 manufactured by ATAGO). The viscosity was measured at 60 ° C. using a cone plate viscometer (Hato Corporation, RotoVisco 1). The melting point was measured using a differential scanning calorimeter (manufactured by Shimadzu Corporation, DSC-50), and the peak top temperature and melting end temperature of the obtained endothermic peak were determined and used as an index of melting point. The adhesion to the skin was evaluated by applying a certain amount of the sample to the back of the left hand and spreading it with the right index finger, and then moving the right index finger in a vertical direction with respect to the application part. The evaluation was performed using the following four grades, and the average value of five panelists was used as the result.

4 points: very close 3 points: close contact 2 points: somewhat close contact 1 point: no close contact

The obtained results are shown in Tables 1 and 2. In addition, the raw material charge ratio of each ester is described. As a result, the higher the viscosity of the esters of Comparative Examples 1 to 3, the better the adhesion, but the melting point was lowered. On the other hand, the esters of Examples 1 to 5 have a melting point that is about the same as that of Comparative Example 1 and that the viscosity is about the same as or higher than that of Comparative Examples 2 and 3, and very excellent in adhesion. It was.

Example 6
In a 500 mL reactor equipped with a stirrer, a thermometer, and a gas introduction tube, 100 g (0.174 mol) of hydrogenated dimer acid (manufactured by Croda, PRIPOL 1006), 22.9 g of dimer diol (manufactured by Croda, PRIPOL 2033) (0 .042 mol), 4.8 g (0.052 mol) of glycerin (manufactured by Sakamoto Yakuhin Kogyo Co., Ltd.), 16.7 g (0.063 mol) of isostearyl alcohol (manufactured by Croda, PRISOLINE3515) and phytosterol (manufactured by ADM) 30 0.7 g (0.063 mol) was charged and heated to 210-220 ° C. in a nitrogen stream, and the esterification reaction was carried out for 15 hours while distilling off the produced water, to obtain 149 g of the desired ester (yield 98%). ). The obtained ester was a pale yellow liquid oil (hue Gardner 1 or less, acid value 6.5, saponification value 129.8, hydroxyl value 11.3).

Comparative Example 4
In a 500 mL reactor equipped with a stirrer, a thermometer, and a gas introduction tube, 100 g (0.174 mol) of hydrogenated dimer acid (manufactured by Croda, PRIPOL 1006), 75.6 g of dimer diol (manufactured by Croda, PRIPOL 2033) (0 139 mol), isostearyl alcohol (Crida, PRISORIINE 3515) 9.6 g (0.035 mol) and phytosterol (ADM) 14.9 g (0.036 mol) were charged in a nitrogen stream at 210 to 220 ° C. And the esterification reaction was carried out for 10 hours while distilling off the generated water to obtain 189 g of the desired ester (yield 98%). The obtained ester was a pale yellow liquid oil, hue Gardner 1 or less, acid value 6.0, saponification value 103.3, hydroxyl value 11.2).

(Refractive index, viscosity, water content, adhesion evaluation)
The esters obtained in Example 6 and Comparative Example 4 were evaluated for refractive index, viscosity, adhesion, and water retention. Refractive index, viscosity, and adhesion were performed in the same manner as described above. The water retention was evaluated by measuring the water content value as an index. The water content was kneaded while adding purified water in an amount of 0.2 ml to 0.5 ml to 10 g of the sample. The point at which water did not enter was taken as the end point, and the amount of purified water dropped was expressed as a percentage of the sample. The results are shown in Table 3. The esters of Example 6 and Comparative Example 4 both have the same viscosity and excellent adhesion, but the ester of Example 6 has a water content value that is twice as high and has excellent water retention. I found out.

  As described above, the ester of the present invention has a high viscosity, excellent adhesion, and high water retention or pasty oil as compared with the conventional end-capped oligomer ester having a main skeleton of dimer acid and dimer diol. The melting point was sufficiently high.

Example 7 Emollient Cream An emollient cream having the following formulation was prepared using the oily base of the present invention. This emollient cream was a glossy and excellent cream moisturizing effect.

Component Blending amount (% by weight)
--------------------------------
1 Ester of Example 5 6.00
2 Hydrogenated palm oil 2.50
3 Behenyl alcohol 2.00
4 Dimethicone (10cs) 1.50
5 Glyceryl stearate 1.50
6 Stearyl alcohol 1.20
7 Stearic acid PG (SE) 1.00
8 PEG-60 glyceryl isostearate 1.00
9 Octyl methoxycinnamate 0.20
10 Ethylparaben 0.10
11 Neosolute-Aqua (Nippon Seika) 0.50
12 1,3-butylene glycol 6.00
13 Glycerin 1.00
14 Phenoxyethanol 0.20
15 Methylparaben 0.15
16 Purified water 75.15
--------------------------------

(Preparation method)
No. 1-10 were added, and it heated and melt | dissolved at about 80 degreeC (A part). No. in a separate container. 11 to 16 were taken, heated to about 80 ° C., and dissolved uniformly (part B). Part B was added to part A, emulsified with a homomixer, and then cooled to 40 ° C.

Example 8 Body Shampoo A body shampoo having the following formulation was prepared using the oily base of the present invention. This body shampoo had good foaming, and the skin after washing and after washing did not become sticky, and had a slippery, moist and moist feeling.

Component Blending amount (% by weight)
--------------------------------
1 Ester of Example 6 0.50
2 Cocoyl Methyl Taurine Na 10.00
3 Lauroyl hydrolyzed silk Na 6.00
4 Lauroylmethylalanine Na 10.00
5 Cocoamphoacetate Na (30%) 4.00
6 Cocamidopropyl betaine (30%) 10.00
7 Cocamide DEA 3.00
8 1,3-butylene glycol 5.00
9 Methylparaben 0.20
10 Purified water Total amount of 100 --------------------------------

(Production method)
No. 1-No. 10 was heated at about 80 ° C. and stirred and mixed uniformly.

Example 9 Lipstick A lipstick having the following formulation was prepared using the oily base of the present invention. This lipstick was glossy, fresh and highly adhesive.

Component Blending amount (% by weight)
--------------------------------
1 Ester of Example 5 27.20
2 LUSPLAN DD-DA7 (Nippon Seika) 7.00
3 Trioctanoin 18.00
4 Dextrin palmitate 0.90
5 Stearoyl lactate Na 0.90
6 Cetyl octanoate 24.00
7 Macadamia nut fatty acid phytosteryl 2.00
8 Ceresin 8.50
9 Candelilla Row 4.00
10 Sorbitan sesquiisostearate 2.00
11 Tocopherol 0.50
12 Iron oxide 2.00
13 Mica 2.00
14 Titanium oxide 1.00
--------------------------------

(Preparation method)
No. 1, 3-11 were heated to about 100-110 ° C. and dissolved uniformly (part A). Next, no. 2, 12-14 were added and mixed with a roll mill (part B). Part A and part B were added, heated to about 80 ° C., uniformly stirred and mixed, then filled into a mold and rapidly cooled.

Example 10 Pasty lipstick Using the oily base of the present invention, a pasty lipstick having the following formulation was prepared. This lipstick was excellent in terms of gloss and odor, and had a smooth and sticky feeling when applied.

Component Blending amount (% by weight)
--------------------------------
1 Ester of Example 5 40.00
2 12-Hydroxystearic acid 8.00
3 Liquid paraffin Amount that totals 100
4 Trioctanoin 15.00
5 Silicic anhydride 0.30
(Aerosil R974 manufactured by Nippon Aerosil Co., Ltd.)
6 Red 202 No.
7 Yellow No. 4 Appropriate amount --------------------------------

(Preparation method)
No. 1-7 are heated and mixed uniformly.

Example 11 Pasty lipstick A pasty lipstick having the following formulation was prepared using the oily base of the present invention. This lipstick was excellent in terms of gloss and odor, and had a smooth and sticky feeling when applied.

Component Blending amount (% by weight)
--------------------------------
1 Ester of Example 5 70.00
2 Silylated ultrafine silica 1.50
(Aerosil R972 manufactured by Nippon Aerosil Co., Ltd.)
3 Dextrin palmitate 1.00
4 Pigment Appropriate amount
5 Liquid paraffin Amount that totals 100 --------------------------------

(Preparation method)
No. 1-5 are heated and mixed uniformly.

Example 12 Lip Gloss A lip gloss having the following formulation was prepared using the oil base of the present invention. This lip gloss was glossy, had a good makeup, and had a high adhesion.

Component Blending amount (% by weight)
--------------------------------
1 Esters of Example 5 55.00
2 LUSPLAN DD-DA7 (Nippon Seika) 15.00
3 Polyethylene wax 0.20
4 12-hydroxystearic acid 1.50
5 Liquid paraffin Amount that totals 100
6 Tocopherol appropriate amount
7 Silylated ultrafine silica 2.00
(Aerosil R972 manufactured by Nippon Aerosil Co., Ltd.)
8 Titanium mica 12.00
--------------------------------

(Preparation method)
No. Nos. 1 to 6 were uniformly heated and mixed, Add 7-8 and mix evenly.

Example 13 Lip Gloss A lip gloss having the following formulation was prepared using the oily base of the present invention. This lip gloss was shiny, fresh and highly adhesive.

Component Blending amount (% by weight)
--------------------------------
1 Ester of Example 5 40.00
2 Dextrin palmitate 10.00
3 Macadamia nut oil fatty acid phytosteryl 10.00
4 Methylphenylpolysiloxane 30.00
5 Trioctanoin 5.00
6 Liquid paraffin 5.00
--------------------------------

(Preparation method)
No. 1 and 2 were heated to 100 to 110 ° C. and dissolved uniformly. Next, no. 3-6 were added and it was made to melt | dissolve uniformly at about 80 degreeC.

Example 14 Transparent Lipstick A transparent lipstick having the following formulation was prepared using the oily base of the present invention. This transparent lipstick was glossy, fresh and highly adhesive.

Component Blending amount (% by weight)
--------------------------------
1 Esters of Example 6 10.00
2 Ester of Example 5 30.00
3 12-Hydroxystearic acid 10.00
4 Heavy liquid isoparaffin 10.00
5 LUSPLAN PI-DA (Nippon Seika) Total amount of 100
6 Castor oil 1.00
7 2-ethylhexyl hydroxystearate 5.00
8 α-olefin oligomer 5.00
9 Refined jojoba oil 5.00
10 Dipropylene glycol 0.10
11 Menthol 0.10
12 Tocopherol 0.10
13 Fragrance Appropriate amount ---------------------------------

(Preparation method)
No. No. 1-12 was added, heated to 90-110 ° C. and uniformly mixed and melted. 13 is added and mixed and dispersed uniformly.

Example 15 Mascara A mascara having the following formulation was produced using the oily base of the present invention. This mascara had good adhesion, good usability, and good stability.

Component Blending amount (% by weight)
---------------------------------
1 Iron oxide (black) 10.00
2 Light isoparaffin 30.00
3 Polyacrylate emulsion 30.00
4 Solid paraffin 8.00
5 Esters of Example 1.20
6 Sorbitan sesquioleate 4.00
7 Preservative appropriate amount
8 Perfume appropriate amount
9 Purified water Total amount of 100 ---------------------------------

(Preparation method)
No. No. 9 no. No. 1 was added and dispersed with a homomixer. 3 was added and heated to 70 ° C (aqueous phase). The other ingredients were mixed and heated to 70 ° C. (oil phase). The aqueous phase was added to the oil phase, and the mixture was uniformly emulsified and dispersed with a homomixer to obtain the desired mascara.

Example 16 Eyeshadow An eye shadow having the following formulation was produced using the oily base of the present invention. This eye shadow had good adhesion and a good feeling of use.

Component Blending amount (% by weight)
---------------------------------
1 Talc 10.00
2 Kaolin 2.00
3 facial 5.00
4 Ester of Example 4 3.00
5 Stearic acid 3.00
6 Isopropyl myristate 5.00
7 Liquid paraffin 5.00
8 Propylene glycol monolaurate 3.00
9 Antioxidant appropriate amount
10 Incense amount
11 1,3-butylene glycol 5.00
12 Glycerin 1.00
13 Preservative appropriate amount
14 Triethanolamine 1.20
15 Suitable amount of sequestering agent
16 Purified water Total amount of 100 ---------------------------------

(Preparation method)
No. 1-3 were mixed with a blender and then processed with a pulverizer (powder part). No. 11 to 16 were heated and dissolved at 70 to 75 ° C. (aqueous phase part). No. 4 to 10 were dissolved by heating at 70 to 80 ° C. (oil phase part). The powder part was added to the aqueous phase part and mixed with stirring. The oil phase was added to this while stirring, dispersed with a homomixer, and stirred and cooled to room temperature to obtain the desired eye shadow.

Example 17 Foundation A foundation having the following formulation was prepared using the oily base of the present invention. This foundation had good adhesion, gloss, excellent color development, and a moist feel.

Component Blending amount (% by weight)
--------------------------------
1 Ester of Example 2 6.00
2 Cyclomethicone 3.50
3 Dimethicone (5cs) 2.00
4 Trimethylsiloxysilicic acid 1.50
5 Octyl methoxycinnamate 1.00
6 Phenoxyethanol 0.40
7 Tocopherol 0.10
8 Mica 39.60
9 Talc 24.00
10 Titanium oxide 20.00
11 Iron oxide 1.90
--------------------------------

(Preparation method)
Each component was stirred at high speed and mixed uniformly.

Example 18 Mild Shampoo A mild shampoo having the following formulation was prepared using the oily base of the present invention. This mild shampoo was a shampoo capable of imparting a moist feeling and gloss to hair and providing smooth fingering.

Component Blending amount (% by weight)
--------------------------------
1 Ester of Example 5 0.50
2 Cocoyl methyl methyl taurine Na (30%) 30.00
3 Cocamidopropyl betaine (30%) 20.00
4 Laureth-12 Na acetate (30%) 5.00
5 1,3-Butylene glycol 1.00
6 Cocamide MEA 2.00
7 Glycol distearate 1.50
8 Polyquaternium-10 0.50
9 Polyquaternium-7 0.30
10 Cationic NH (Nippon Seika) 0.50
11 Sodium benzoate 0.40
12 Phenoxyethanol 0.20
13 Methylparaben 0.20
14 Purified water 37.90
--------------------------------

(Preparation method)
No. 1 to 7 were heated to about 80 ° C. and dissolved (part A). No. in a separate container. 8 to 14 were heated to about 80 ° C. and dissolved (Part B). While stirring Part B into Part A, they were gradually added and mixed uniformly, and then rapidly cooled.

Example 19 Moisturin Using the oily base of the present invention, a moisturin having the following formulation was prepared. This moisturizing was a non-sticky rinse that gave the hair a moist feeling and gloss, and a smooth fingering.

Component Blending amount (% by weight)
--------------------------------
1 Esters of Example 5 0.10
2 Plandool-H (Nippon Seika) 0.50
3 Cetrimonium chloride (30%) 5.20
4 Octild decanol 4.70
5 Cetanol 2.80
6 Steartrimonium chloride (63%) 0.60
7 Cetyl octanoate 0.30
8 Squalane 0.30
9 Myristyl sulfate Na 0.20
10 Seths-40 0.10
11 Ores-5 0.10
12 Cetyl sulfate Na 0.10
13 Citric acid 0.10
14 Methylparaben 0.10
15 Purified water 84.80
--------------------------------

(Preparation method)
No. 1 to 12 were heated to about 80 ° C. and dissolved (part A). No. in a separate container. 14 to 15 were heated to about 80 ° C. and dissolved (Part B). While stirring Part B into Part A, gradually add and mix uniformly. After 13 was added and stirred, it was quenched.

Example 20 Treatment A treatment having the following formulation was prepared using the oily base of the present invention. This treatment was a treatment that could give gloss, supple, moist and smooth feel.

Component Blending amount (% by weight)
--------------------------------
1 Ester of Example 5 2.00
2 Neosolu-Aculio (Nippon Seika) 0.50
3 Glyceryl stearate (SE) 4.50
4 Steerless-10 4.00
5 Cetanol 4.00
6 Steartrimonium chloride (63%) 1.80
7 Hydrolyzed keratin (20%) 1.50
8 Behentrimonium chloride (80%) 1.00
9 Methylparaben 0.20
10 Purified water 80.50
--------------------------------

(Preparation method)
No. No. 10 is heated to about 80 ° C. 9 was added and dissolved (part A). No. in a separate container. 1-8 were added, and it heated and dissolved (part B). Part A was gradually added to part B and mixed uniformly.

Example 21 Hair Cream Wax Using the oily base of the present invention, a hair cream wax having the following formulation was prepared. When this hair cream wax was applied to the hair, it was glossy, non-sticky, did not move even if it was applied, and had high hair tightness due to high adhesion, and was excellent in hairstyle retention.

Component Blending amount (% by weight)
--------------------------------
1 Esters of Example 5 4.00
2 Esters of Example 6 1.00
3 Fatty acid (C18-35) glycol 6.00
4 Dioleic acid PEG-120 methyl glucose 5.00
5 Lanolin fatty acid octyldodecyl 5.00
6 Stearic acid 4.00
7 Candelilla Row 3.00
8 Dimethicone (1000cs) 3.00
9 Diethyl sebacate 2.00
10 Seth-2 2.00
11 Seth-7 2.00
12 SETES-20 1.00
13 Dicocodimonium chloride (75%) 1.00
14 Propylparaben 0.10
15 Polyurethane-4 3.00
16 Triethanolamine 0.30
17 Methylparaben 0.20
18 Purified water 57.40
--------------------------------

(Preparation method)
No. 1-14 was added, it heated at about 80 degreeC, and it was made to melt | dissolve (A part). No. in a separate container. No. 18 and heated to about 80 ° C. 16, 17 was added and dissolved uniformly (part B). Gradually add part B to part A and mix evenly. 15 was added and mixed uniformly. After cooling to room temperature, the pH was adjusted.

Claims (8)

1 to 34 carbon atoms with respect to 1 mole equivalent of the carboxyl group remaining in the ester obtained by reacting dimer acid with dimer diol and a mixed alcohol composed of a trihydric or higher alcohol having 3 to 10 carbon atoms. An oily base for cosmetics or external preparations for skin containing an ester obtained by reacting a monohydric alcohol in an amount of 0.8 to 1.5 molar equivalents. The reaction ratio between the dimer acid and the mixed alcohol is such that the hydroxyl group in the mixed alcohol is 0.4 to 0.8 mole equivalent with respect to 1 mole equivalent of the carboxyl group in the dimer acid. The oily base according to 1. The mixing ratio of the mixed alcohol is such that the trivalent or higher alcohol having 3 to 10 carbon atoms is 0.2 to 3.5 moles per mole of the dimer diol. Oily base. The oily property according to claim 1, wherein the trivalent or higher alcohol having 3 to 10 carbon atoms is selected from glycerin, diglycerin, trimethylolpropane, pentaerythritol, ditrimethylolpropane and dipentaerythritol. Base. The monohydric alcohol having 1 to 34 carbon atoms is selected from saturated linear alcohol having 12 to 22 carbon atoms, saturated branched alcohol having 8 to 22 carbon atoms, cholesterol, and phytosterol. The oil-based base in any one. The oily base according to any one of claims 1 to 5, wherein at least one of the monohydric alcohols is a saturated linear monohydric alcohol having 16 or more carbon atoms and is in a paste form. The oily base according to any one of claims 1 to 6, wherein at least one of the monohydric alcohols is cholesterol or phytosterol. Cosmetics or skin external preparation containing the oil-based base in any one of Claims 1-7.