JP2010536709A - 調節可能な被覆を有するSiO2被覆された二酸化チタン粒子の製造 - Google Patents

調節可能な被覆を有するSiO2被覆された二酸化チタン粒子の製造 Download PDF

Info

Publication number
JP2010536709A
JP2010536709A JP2010522360A JP2010522360A JP2010536709A JP 2010536709 A JP2010536709 A JP 2010536709A JP 2010522360 A JP2010522360 A JP 2010522360A JP 2010522360 A JP2010522360 A JP 2010522360A JP 2010536709 A JP2010536709 A JP 2010536709A
Authority
JP
Japan
Prior art keywords
nano
reaction
outer shell
particles
substance
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP2010522360A
Other languages
English (en)
Japanese (ja)
Other versions
JP2010536709A5 (enExample
Inventor
ゼーバー アレクサンダー
シンドラー ゲッツ−ペーター
フライターク カトリン
クライネ イェーガー フランク
クリンクラー ディルク
ボルクマイアー フリーダー
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of JP2010536709A publication Critical patent/JP2010536709A/ja
Publication of JP2010536709A5 publication Critical patent/JP2010536709A5/ja
Withdrawn legal-status Critical Current

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/39Photocatalytic properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24Stationary reactors without moving elements inside
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/26Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2/00Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic
    • B01J2/003Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic followed by coating of the granules
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2/00Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic
    • B01J2/02Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic by dividing the liquid material into drops, e.g. by spraying, and solidifying the drops
    • B01J2/04Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic by dividing the liquid material into drops, e.g. by spraying, and solidifying the drops in a gaseous medium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08Silica
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/40Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B01J35/45Nanoparticles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/34Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation
    • B01J37/349Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation making use of flames, plasmas or lasers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00Nanotechnology for materials or surface science, e.g. nanocomposites
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G23/00Compounds of titanium
    • C01G23/04Oxides; Hydroxides
    • C01G23/047Titanium dioxide
    • C01G23/07Producing by vapour phase processes, e.g. halide oxidation
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/36Compounds of titanium
    • C09C1/3607Titanium dioxide
    • C09C1/3653Treatment with inorganic compounds
    • C09C1/3661Coating
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/36Compounds of titanium
    • C09C1/3607Titanium dioxide
    • C09C1/3684Treatment with organo-silicon compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00051Controlling the temperature
    • B01J2219/00121Controlling the temperature by direct heating or cooling
    • B01J2219/00123Controlling the temperature by direct heating or cooling adding a temperature modifying medium to the reactants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00051Controlling the temperature
    • B01J2219/00157Controlling the temperature by means of a burner
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00164Controlling or regulating processes controlling the flow
    • B01J2219/00166Controlling or regulating processes controlling the flow controlling the residence time inside the reactor vessel
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00Crystal-structural characteristics
    • C01P2002/80Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
    • C01P2002/85Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by XPS, EDX or EDAX data
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/01Particle morphology depicted by an image
    • C01P2004/04Particle morphology depicted by an image obtained by TEM, STEM, STM or AFM
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/60Particles characterised by their size
    • C01P2004/64Nanometer sized, i.e. from 1-100 nanometer
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/80Particles consisting of a mixture of two or more inorganic phases
    • C01P2004/82Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases
    • C01P2004/84Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases one phase coated with the other
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/80Particles consisting of a mixture of two or more inorganic phases
    • C01P2004/82Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases
    • C01P2004/84Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases one phase coated with the other
    • C01P2004/86Thin layer coatings, i.e. the coating thickness being less than 0.1 time the particle radius
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2991Coated
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2991Coated
    • Y10T428/2993Silicic or refractory material containing [e.g., tungsten oxide, glass, cement, etc.]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Nanotechnology (AREA)
  • Plasma & Fusion (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Composite Materials (AREA)
  • Optics & Photonics (AREA)
  • Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Environmental & Geological Engineering (AREA)
  • Toxicology (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Catalysts (AREA)
JP2010522360A 2007-08-28 2008-08-27 調節可能な被覆を有するSiO2被覆された二酸化チタン粒子の製造 Withdrawn JP2010536709A (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP07115104 2007-08-28
PCT/EP2008/061221 WO2009027433A2 (de) 2007-08-28 2008-08-27 HERSTELLUNG VON SiO2-BESCHICHTETEN TITANDIOXIDPARTIKELN MIT EINSTELLBARER BESCHICHTUNG

Publications (2)

Publication Number Publication Date
JP2010536709A true JP2010536709A (ja) 2010-12-02
JP2010536709A5 JP2010536709A5 (enExample) 2011-10-13

Family

ID=40328678

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2010522360A Withdrawn JP2010536709A (ja) 2007-08-28 2008-08-27 調節可能な被覆を有するSiO2被覆された二酸化チタン粒子の製造

Country Status (5)

Country Link
US (1) US20100304143A1 (enExample)
EP (1) EP2185656A2 (enExample)
JP (1) JP2010536709A (enExample)
CN (1) CN101784342A (enExample)
WO (1) WO2009027433A2 (enExample)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20110089131A (ko) * 2008-10-27 2011-08-04 바스프 에스이 나노미립자 금속 붕소화물의 현탁액의 제조 방법
KR20110120910A (ko) 2009-02-26 2011-11-04 바스프 에스이 자가-세정 중합체
US8545796B2 (en) 2009-07-31 2013-10-01 Cristal Usa Inc. Silica-stabilized ultrafine anatase titania, vanadia catalysts, and methods of production thereof
US9365939B2 (en) * 2011-05-31 2016-06-14 Wisconsin Alumni Research Foundation Nanoporous materials for reducing the overpotential of creating hydrogen by water electrolysis
KR101907106B1 (ko) * 2011-12-16 2018-12-05 삼성전자주식회사 나노다공체를 포함하는 반투성 필름과 분리막 및 이들의 제조방법
KR101282142B1 (ko) * 2012-02-15 2013-07-04 한국과학기술연구원 복합 나노입자의 제조장치 및 제조방법
CN103464220B (zh) * 2013-09-13 2015-01-14 太原理工大学 一种超声雾化改性催化剂的方法
CN108025285A (zh) * 2015-08-28 2018-05-11 沙特基础工业全球技术公司 使用混杂光电子材料制备氢气
DE102016001349A1 (de) * 2016-02-08 2017-08-24 Horst Büchner Verfahren zur thermischen Materialbehandlung
CN105755227A (zh) * 2016-05-24 2016-07-13 江苏金基特钢有限公司 低碳合金钢专用淬火剂
DE102017204488A1 (de) * 2017-03-17 2018-09-20 Technische Universität Berlin Verfahren zur Herstellung von monodispersen Nanopartikeln aus einer flüssigen Mischung
LU100335B1 (en) * 2017-07-18 2019-01-28 Luxembourg Inst Science & Tech List Plasma device for depositing functional composite film comprising crystallized particles embedded in a matrix and method of deposition thereof
CN120205077B (zh) * 2025-05-27 2025-08-08 苏州大学 一种零羟基、微米级二氧化硅颗粒火焰合成方法及装置

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996036441A1 (en) * 1995-05-17 1996-11-21 Kemira Pigments, Inc. COATING OF TiO2 PIGMENT BY GAS-PHASE AND SURFACE REACTIONS
DE60038477T2 (de) * 1999-09-28 2009-06-04 Fujifilm Corp. Antireflexbeschichtung, damit versehene Polarisationsplatte, und Bildanzeigegerät mit der Antireflexbeschichtung oder mit der Polarisationsplatte
JP2001316115A (ja) * 2000-03-28 2001-11-13 Degussa Ag ドーピングされた二酸化チタン
EP1138632B1 (de) * 2000-03-29 2009-10-14 Evonik Degussa GmbH Dotiertes Titandioxid
DE10260718A1 (de) * 2002-12-23 2004-07-08 Degussa Ag Mit Siliziumdioxid umhülltes Titandioxid
US20060116279A1 (en) * 2003-01-09 2006-06-01 Hisao Kogoi Composite particles and method for production thereof and use thereof
US7214363B2 (en) * 2004-10-28 2007-05-08 Seoul National University Industry Foundation Method for preparing composite microparticles
FR2884111B1 (fr) * 2005-04-07 2007-05-18 Saint Gobain Mat Constr Sas Granule biocide, notamment pour la fabrication de bardeau d'asphalte

Also Published As

Publication number Publication date
CN101784342A (zh) 2010-07-21
US20100304143A1 (en) 2010-12-02
WO2009027433A3 (de) 2009-05-14
EP2185656A2 (de) 2010-05-19
WO2009027433A2 (de) 2009-03-05

Similar Documents

Publication Publication Date Title
JP2010536709A (ja) 調節可能な被覆を有するSiO2被覆された二酸化チタン粒子の製造
Naldoni et al. Porous TiO2 microspheres with tunable properties for photocatalytic air purification
US20090093553A1 (en) Method for the production of suspensions of nanoparticulate solids
Johannessen et al. One-step flame synthesis of an active Pt/TiO2 catalyst for SO2 oxidation—a possible alternative to traditional methods for parallel screening
EP1232117A1 (en) Ceria composition and process for preparing same
Kim et al. Cosolvent-assisted spray pyrolysis for the generation of metal particles
KR20180024478A (ko) 중형기공 쉘을 갖는 과산화수소 제조용 나노촉매 및 이를 이용한 과산화수소의 제조방법
US6548169B2 (en) Production process for ultrafine particulate complex oxide containing titanium oxide
Lafaye et al. Synthesis and microscopic characterization of dendrimer-derived Ru/Al2O3 catalysts
JP5114419B2 (ja) ドープ金属酸化物粒子の製造方法
Della Foglia et al. Hydrogen production by photocatalytic membranes fabricated by supersonic cluster beam deposition on glass fiber filters
Liu et al. Photo enhanced catalytic activity for hydrogenation of nitrobenzene over Pt-Au/TiO2 heterojunction
EP1277704A9 (en) Process for producing finely particulate oxide composite containing titanium oxide
JP2009519813A (ja) 脱nox触媒調製法
JP2002293540A (ja) 微粒子状酸化チタン複合体の製造方法
EP2419371B1 (en) A process and apparatus for depositing nanostructured material onto a substrate material
JPH0457602B2 (enExample)
Thoda et al. Parametric optimisation of solution combustion synthesis catalysts and their application for the aqueous hydrogenation of maleic acid
US20100316882A1 (en) Nanomaterial and method for generating nanomaterial
Zhang et al. Flame synthesis of tungsten‐doped t itanium‐dioxide nanoparticles using novel precursor combination of liquid titanium tetra‐isopropoxide and solid tungsten mesh
JP7785280B2 (ja) 結晶質酸化タンタル粒子、及び結晶質酸化タンタル粒子の製造方法
Malekzadeh et al. Laser Pyrolysis
KR100978751B1 (ko) 개선된 광촉매층을 포함하는 오염물질 처리용 광분해 장치및 이를 이용한 오염물질 분해방법
Thoda Investigation of physico-chemical properties of Ni-based catalysts produced by solution combustion synthesis and their catalytic activity in liquid phase hydrogenation
Memon et al. Catalytic oxidation of carbon using TiO2 based nanoparticles prepared using flame synthesis

Legal Events

Date Code Title Description
RD04 Notification of resignation of power of attorney

Free format text: JAPANESE INTERMEDIATE CODE: A7424

Effective date: 20101228

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20110824

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20110824

A761 Written withdrawal of application

Free format text: JAPANESE INTERMEDIATE CODE: A761

Effective date: 20120914