JP2010513673A - アンモニアとイオン液体との混合物 - Google Patents
アンモニアとイオン液体との混合物 Download PDFInfo
- Publication number
- JP2010513673A JP2010513673A JP2009542893A JP2009542893A JP2010513673A JP 2010513673 A JP2010513673 A JP 2010513673A JP 2009542893 A JP2009542893 A JP 2009542893A JP 2009542893 A JP2009542893 A JP 2009542893A JP 2010513673 A JP2010513673 A JP 2010513673A
- Authority
- JP
- Japan
- Prior art keywords
- group
- ionic liquid
- composition
- ammonia
- substituted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 title claims abstract description 131
- 239000002608 ionic liquid Substances 0.000 title claims abstract description 85
- 229910021529 ammonia Inorganic materials 0.000 title claims abstract description 64
- 239000000203 mixture Substances 0.000 title claims abstract description 56
- 238000010521 absorption reaction Methods 0.000 claims abstract description 36
- 150000001450 anions Chemical class 0.000 claims description 40
- 150000001768 cations Chemical class 0.000 claims description 29
- 150000001336 alkenes Chemical class 0.000 claims description 21
- 229910052731 fluorine Inorganic materials 0.000 claims description 19
- NJMWOUFKYKNWDW-UHFFFAOYSA-N 1-ethyl-3-methylimidazolium Chemical compound CCN1C=C[N+](C)=C1 NJMWOUFKYKNWDW-UHFFFAOYSA-N 0.000 claims description 18
- 229910052757 nitrogen Inorganic materials 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 16
- 125000001072 heteroaryl group Chemical group 0.000 claims description 14
- 125000005842 heteroatom Chemical group 0.000 claims description 14
- 229910052794 bromium Inorganic materials 0.000 claims description 13
- 229910052801 chlorine Inorganic materials 0.000 claims description 13
- 150000001924 cycloalkanes Chemical class 0.000 claims description 12
- 229910052717 sulfur Inorganic materials 0.000 claims description 12
- 229910052740 iodine Inorganic materials 0.000 claims description 10
- IQQRAVYLUAZUGX-UHFFFAOYSA-N 1-butyl-3-methylimidazolium Chemical compound CCCCN1C=C[N+](C)=C1 IQQRAVYLUAZUGX-UHFFFAOYSA-N 0.000 claims description 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 9
- 235000019000 fluorine Nutrition 0.000 claims description 9
- 229910052739 hydrogen Inorganic materials 0.000 claims description 9
- 239000001257 hydrogen Substances 0.000 claims description 9
- 125000003118 aryl group Chemical group 0.000 claims description 8
- 125000003107 substituted aryl group Chemical group 0.000 claims description 8
- 239000006096 absorbing agent Substances 0.000 claims description 7
- 125000003342 alkenyl group Chemical group 0.000 claims description 7
- 125000004122 cyclic group Chemical group 0.000 claims description 6
- RAXXELZNTBOGNW-UHFFFAOYSA-O Imidazolium Chemical compound C1=C[NH+]=CN1 RAXXELZNTBOGNW-UHFFFAOYSA-O 0.000 claims description 5
- 229910052736 halogen Inorganic materials 0.000 claims description 5
- 150000002367 halogens Chemical class 0.000 claims description 5
- 229910052760 oxygen Inorganic materials 0.000 claims description 5
- 229910016467 AlCl 4 Inorganic materials 0.000 claims description 4
- 229910021591 Copper(I) chloride Inorganic materials 0.000 claims description 4
- -1 N, N-dimethylammonium ethanol cation Chemical class 0.000 claims description 4
- 125000002619 bicyclic group Chemical group 0.000 claims description 4
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 claims description 4
- 125000001424 substituent group Chemical group 0.000 claims description 4
- 229910018286 SbF 6 Inorganic materials 0.000 claims description 3
- 125000001153 fluoro group Chemical group F* 0.000 claims description 3
- HVVRUQBMAZRKPJ-UHFFFAOYSA-N 1,3-dimethylimidazolium Chemical compound CN1C=C[N+](C)=C1 HVVRUQBMAZRKPJ-UHFFFAOYSA-N 0.000 claims description 2
- FYZZJDABXBPMOG-UHFFFAOYSA-N ethanol;n-methylmethanamine Chemical compound CCO.CNC FYZZJDABXBPMOG-UHFFFAOYSA-N 0.000 claims description 2
- 125000000129 anionic group Chemical group 0.000 claims 1
- 239000012809 cooling fluid Substances 0.000 abstract description 2
- 239000007789 gas Substances 0.000 description 13
- 239000002250 absorbent Substances 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 238000003556 assay Methods 0.000 description 8
- 239000007788 liquid Substances 0.000 description 8
- 239000003507 refrigerant Substances 0.000 description 8
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 7
- 235000011114 ammonium hydroxide Nutrition 0.000 description 7
- 239000000460 chlorine Substances 0.000 description 7
- 239000011737 fluorine Substances 0.000 description 7
- 239000011829 room temperature ionic liquid solvent Substances 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 230000002745 absorbent Effects 0.000 description 6
- 238000004364 calculation method Methods 0.000 description 6
- 238000007906 compression Methods 0.000 description 6
- 238000001816 cooling Methods 0.000 description 6
- 238000010586 diagram Methods 0.000 description 6
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 5
- 230000006835 compression Effects 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 239000012071 phase Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 239000012530 fluid Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 238000001179 sorption measurement Methods 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical class [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 239000003463 adsorbent Substances 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 230000003993 interaction Effects 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- XIYUIMLQTKODPS-UHFFFAOYSA-M 1-ethyl-3-methylimidazol-3-ium;acetate Chemical compound CC([O-])=O.CC[N+]=1C=CN(C)C=1 XIYUIMLQTKODPS-UHFFFAOYSA-M 0.000 description 2
- RVEJOWGVUQQIIZ-UHFFFAOYSA-N 1-hexyl-3-methylimidazolium Chemical compound CCCCCCN1C=C[N+](C)=C1 RVEJOWGVUQQIIZ-UHFFFAOYSA-N 0.000 description 2
- NKRASMXHSQKLHA-UHFFFAOYSA-M 1-hexyl-3-methylimidazolium chloride Chemical compound [Cl-].CCCCCCN1C=C[N+](C)=C1 NKRASMXHSQKLHA-UHFFFAOYSA-M 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 229910001615 alkaline earth metal halide Inorganic materials 0.000 description 2
- 239000000908 ammonium hydroxide Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- LRESCJAINPKJTO-UHFFFAOYSA-N bis(trifluoromethylsulfonyl)azanide;1-ethyl-3-methylimidazol-3-ium Chemical compound CCN1C=C[N+](C)=C1.FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F LRESCJAINPKJTO-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 150000001923 cyclic compounds Chemical class 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- CCIVGXIOQKPBKL-UHFFFAOYSA-M ethanesulfonate Chemical compound CCS([O-])(=O)=O CCIVGXIOQKPBKL-UHFFFAOYSA-M 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 238000005086 pumping Methods 0.000 description 2
- 238000005057 refrigeration Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000011555 saturated liquid Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- PYVOHVLEZJMINC-UHFFFAOYSA-N trihexyl(tetradecyl)phosphanium Chemical compound CCCCCCCCCCCCCC[P+](CCCCCC)(CCCCCC)CCCCCC PYVOHVLEZJMINC-UHFFFAOYSA-N 0.000 description 2
- 239000012855 volatile organic compound Substances 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- BGGUZIZLOYTWFU-UHFFFAOYSA-M 1,1,2,3,3,3-hexafluoropropane-1-sulfonate;tributyl(tetradecyl)phosphanium Chemical compound [O-]S(=O)(=O)C(F)(F)C(F)C(F)(F)F.CCCCCCCCCCCCCC[P+](CCCC)(CCCC)CCCC BGGUZIZLOYTWFU-UHFFFAOYSA-M 0.000 description 1
- VFKJFIDWVGPBDV-UHFFFAOYSA-M 1-butyl-2,3-dimethylimidazol-3-ium;1,1,2,2-tetrafluoroethanesulfonate Chemical compound [O-]S(=O)(=O)C(F)(F)C(F)F.CCCC[N+]=1C=CN(C)C=1C VFKJFIDWVGPBDV-UHFFFAOYSA-M 0.000 description 1
- MXDXOYOYMBHGQD-UHFFFAOYSA-M 1-butyl-3-methylimidazol-3-ium;1,1,2,3,3,3-hexafluoropropane-1-sulfonate Chemical compound CCCC[N+]=1C=CN(C)C=1.[O-]S(=O)(=O)C(F)(F)C(F)C(F)(F)F MXDXOYOYMBHGQD-UHFFFAOYSA-M 0.000 description 1
- ZIPFNZZMKGEBFU-UHFFFAOYSA-M 1-butyl-3-methylimidazol-3-ium;1,1,2-trifluoro-2-(1,1,2,2,2-pentafluoroethoxy)ethanesulfonate Chemical compound CCCC[N+]=1C=CN(C)C=1.[O-]S(=O)(=O)C(F)(F)C(F)OC(F)(F)C(F)(F)F ZIPFNZZMKGEBFU-UHFFFAOYSA-M 0.000 description 1
- BGHQBDVUMIWVAR-UHFFFAOYSA-M 1-dodecyl-3-methylimidazol-3-ium;1,1,2,2-tetrafluoroethanesulfonate Chemical compound [O-]S(=O)(=O)C(F)(F)C(F)F.CCCCCCCCCCCC[N+]=1C=CN(C)C=1 BGHQBDVUMIWVAR-UHFFFAOYSA-M 0.000 description 1
- VRFOKYHDLYBVAL-UHFFFAOYSA-M 1-ethyl-3-methylimidazol-3-ium;ethyl sulfate Chemical compound CCOS([O-])(=O)=O.CCN1C=C[N+](C)=C1 VRFOKYHDLYBVAL-UHFFFAOYSA-M 0.000 description 1
- VASPYXGQVWPGAB-UHFFFAOYSA-M 1-ethyl-3-methylimidazol-3-ium;thiocyanate Chemical compound [S-]C#N.CCN1C=C[N+](C)=C1 VASPYXGQVWPGAB-UHFFFAOYSA-M 0.000 description 1
- MCZWGKAIQPGCBP-UHFFFAOYSA-M 1-hexyl-3-methylimidazol-3-ium;1,1,2,2-tetrafluoroethanesulfonate Chemical compound [O-]S(=O)(=O)C(F)(F)C(F)F.CCCCCC[N+]=1C=CN(C)C=1 MCZWGKAIQPGCBP-UHFFFAOYSA-M 0.000 description 1
- FONRKAHEKCCJDV-UHFFFAOYSA-M 1-methyl-3-octadecylimidazol-1-ium;1,1,2,2-tetrafluoroethanesulfonate Chemical compound [O-]S(=O)(=O)C(F)(F)C(F)F.CCCCCCCCCCCCCCCCCC[N+]=1C=CN(C)C=1 FONRKAHEKCCJDV-UHFFFAOYSA-M 0.000 description 1
- LOZOAPSBGHOALW-UHFFFAOYSA-N 1h-imidazol-1-ium;1,1,2,2-tetrafluoroethanesulfonate Chemical compound [NH2+]1C=CN=C1.[O-]S(=O)(=O)C(F)(F)C(F)F LOZOAPSBGHOALW-UHFFFAOYSA-N 0.000 description 1
- NXEVRPVZRBQJKJ-UHFFFAOYSA-N 3-butyl-2-methyl-1h-imidazol-3-ium;1,1,2,2-tetrafluoroethanesulfonate Chemical compound CCCC[N+]=1C=CNC=1C.[O-]S(=O)(=O)C(F)(F)C(F)F NXEVRPVZRBQJKJ-UHFFFAOYSA-N 0.000 description 1
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- 241000208199 Buxus sempervirens Species 0.000 description 1
- JSDLUHDNGXVAFF-UHFFFAOYSA-L C(C)[N+]1=CN(C=C1)C.FC(C(F)F)(S(=O)(=O)[O-])F.C(C)[N+]1=CN(C=C1)C.FC(C(F)F)(S(=O)(=O)[O-])F Chemical compound C(C)[N+]1=CN(C=C1)C.FC(C(F)F)(S(=O)(=O)[O-])F.C(C)[N+]1=CN(C=C1)C.FC(C(F)F)(S(=O)(=O)[O-])F JSDLUHDNGXVAFF-UHFFFAOYSA-L 0.000 description 1
- 101100283604 Caenorhabditis elegans pigk-1 gene Proteins 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229920001774 Perfluoroether Polymers 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 235000019257 ammonium acetate Nutrition 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000005388 borosilicate glass Substances 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 150000005827 chlorofluoro hydrocarbons Chemical class 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 125000004428 fluoroalkoxy group Chemical group 0.000 description 1
- 125000003709 fluoroalkyl group Chemical group 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- BVZFTIYNEUGOHK-UHFFFAOYSA-M potassium;1,1,2,2-tetrafluoroethanesulfonate Chemical compound [K+].[O-]S(=O)(=O)C(F)(F)C(F)F BVZFTIYNEUGOHK-UHFFFAOYSA-M 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- ZPHRQLVXRDQUPM-UHFFFAOYSA-M sodium;1,1,2,3,3,3-hexafluoropropane-1-sulfonate Chemical compound [Na+].[O-]S(=O)(=O)C(F)(F)C(F)C(F)(F)F ZPHRQLVXRDQUPM-UHFFFAOYSA-M 0.000 description 1
- 238000007655 standard test method Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000002277 temperature effect Effects 0.000 description 1
- BJQWBACJIAKDTJ-UHFFFAOYSA-N tetrabutylphosphanium Chemical compound CCCC[P+](CCCC)(CCCC)CCCC BJQWBACJIAKDTJ-UHFFFAOYSA-N 0.000 description 1
- UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical compound OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 239000002918 waste heat Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C1/00—Ammonia; Compounds thereof
- C01C1/003—Storage or handling of ammonia
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C1/00—Ammonia; Compounds thereof
- C01C1/02—Preparation, purification or separation of ammonia
- C01C1/10—Separation of ammonia from ammonia liquors, e.g. gas liquors
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
- C09K5/047—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for absorption-type refrigeration systems
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C11/00—Use of gas-solvents or gas-sorbents in vessels
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Thermal Sciences (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Analytical Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Sorption Type Refrigeration Machines (AREA)
- Gas Separation By Absorption (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/615,394 US20080153697A1 (en) | 2006-12-22 | 2006-12-22 | Mixtures of ammonia and ionic liquids |
| PCT/US2007/025952 WO2008082561A2 (en) | 2006-12-22 | 2007-12-19 | Mixtures of ammonia and ionic liquids |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2010513673A true JP2010513673A (ja) | 2010-04-30 |
| JP2010513673A5 JP2010513673A5 (enExample) | 2011-01-27 |
Family
ID=39415118
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009542893A Pending JP2010513673A (ja) | 2006-12-22 | 2007-12-19 | アンモニアとイオン液体との混合物 |
Country Status (6)
| Country | Link |
|---|---|
| US (3) | US20080153697A1 (enExample) |
| EP (1) | EP2118230A2 (enExample) |
| JP (1) | JP2010513673A (enExample) |
| KR (1) | KR20090101359A (enExample) |
| CN (1) | CN101573426A (enExample) |
| WO (1) | WO2008082561A2 (enExample) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103388541A (zh) * | 2012-05-10 | 2013-11-13 | 株式会社电装 | 燃料汽化器 |
| JP2015221741A (ja) * | 2014-05-23 | 2015-12-10 | 株式会社豊田中央研究所 | アンモニア吸蔵放出装置 |
| JP2017154074A (ja) * | 2016-03-01 | 2017-09-07 | 国立研究開発法人産業技術総合研究所 | 塩基性ガス吸収剤及び塩基性ガス分離回収方法 |
| JP2019517654A (ja) * | 2016-05-26 | 2019-06-24 | 矢崎総業株式会社 | 吸収式冷凍機におけるグアニジニウム系イオン液体 |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8715521B2 (en) * | 2005-02-04 | 2014-05-06 | E I Du Pont De Nemours And Company | Absorption cycle utilizing ionic liquid as working fluid |
| AR058054A1 (es) * | 2005-09-22 | 2008-01-23 | Du Pont | Utilizacion de liquidos ionicos para la separacion de hidrofluorocarburos |
| US8506839B2 (en) * | 2005-12-14 | 2013-08-13 | E I Du Pont De Nemours And Company | Absorption cycle utilizing ionic liquids and water as working fluids |
| JP5371747B2 (ja) * | 2006-05-31 | 2013-12-18 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | イオン性液体を圧縮器潤滑剤として用いる蒸気圧縮 |
| US8313558B2 (en) | 2006-11-08 | 2012-11-20 | E I Du Pont De Nemours And Company | Process for separation of tetrafluoroethylene from carbon dioxide using ionic liquids |
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| KR101110171B1 (ko) * | 2010-05-06 | 2012-02-09 | 경희대학교 산학협력단 | 암모니아-물 흡수식 냉각 시스템의 흡수제 및 이의 제조방법 |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005113702A1 (de) * | 2004-05-21 | 2005-12-01 | Basf Aktiengesellschaft | Neue arbeitsstoffpaare für absorptionswärmepumpen, absorptionskältemaschinen und wärmetransformatoren |
| JP2006150346A (ja) * | 2004-09-23 | 2006-06-15 | Air Products & Chemicals Inc | ガスの貯蔵及び搬送用のイオン液体をベースにした混合物 |
| WO2006084262A1 (en) * | 2005-02-04 | 2006-08-10 | E.I. Dupont De Nemours And Company | Absorption cycle utilizing ionic liquid as working fluid |
| WO2006134015A1 (de) * | 2005-06-17 | 2006-12-21 | Evonik Degussa Gmbh | Neuartige arbeitsmedien für kälteprozesse |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4031712A (en) * | 1975-12-04 | 1977-06-28 | The University Of Delaware | Combined absorption and vapor-compression refrigeration system |
| US4810403A (en) * | 1987-06-09 | 1989-03-07 | E. I. Du Pont De Nemours And Company | Halocarbon blends for refrigerant use |
| US5643492A (en) * | 1990-12-17 | 1997-07-01 | E. I. Du Pont De Nemours And Company | Constant boiling compositions of HFC-32, HFC-125 and HFC-134 A |
| US6001273A (en) * | 1994-03-11 | 1999-12-14 | Minor; Barbara Haviland | Binary azeotropes of difluoromethane and hydrocarbons |
| CA2154109C (en) * | 1994-07-19 | 2004-06-29 | Katsuya Takigawa | Fluid compositon comprising hfc refrigerant and alkylbenzene-based refrigerator oil |
| DE10027995A1 (de) * | 2000-06-09 | 2001-12-13 | Merck Patent Gmbh | Ionische Flüssigkeiten II |
| DE10316418A1 (de) * | 2003-04-10 | 2004-10-21 | Basf Ag | Verwendung einer ionischen Flüssigkeit |
| US7404845B2 (en) * | 2004-09-23 | 2008-07-29 | Air Products And Chemicals, Inc. | Ionic liquid based mixtures for gas storage and delivery |
| US7638058B2 (en) * | 2005-04-07 | 2009-12-29 | Matheson Tri-Gas | Fluid storage and purification method and system |
| RU2007146973A (ru) * | 2005-05-18 | 2009-06-27 | Е.И.Дюпон де Немур энд Компани (US) | Гибридный парокомпрессионно-абсорбционный цикл |
| AR058054A1 (es) * | 2005-09-22 | 2008-01-23 | Du Pont | Utilizacion de liquidos ionicos para la separacion de hidrofluorocarburos |
| GB0519898D0 (en) * | 2005-09-30 | 2005-11-09 | Bioniqs Ltd | Liquids |
| US8506839B2 (en) * | 2005-12-14 | 2013-08-13 | E I Du Pont De Nemours And Company | Absorption cycle utilizing ionic liquids and water as working fluids |
| US8075777B2 (en) * | 2007-05-16 | 2011-12-13 | E. I. Du Pont De Nemours And Company | Process for the separation of diastereomers |
| US7964760B2 (en) * | 2007-05-25 | 2011-06-21 | E.I. Du Pont De Nemours And Company | Process for the separation of fluorocarbons using ionic liquids |
-
2006
- 2006-12-22 US US11/615,394 patent/US20080153697A1/en not_active Abandoned
-
2007
- 2007-12-19 EP EP07863115A patent/EP2118230A2/en not_active Withdrawn
- 2007-12-19 WO PCT/US2007/025952 patent/WO2008082561A2/en not_active Ceased
- 2007-12-19 CN CNA2007800471120A patent/CN101573426A/zh active Pending
- 2007-12-19 JP JP2009542893A patent/JP2010513673A/ja active Pending
- 2007-12-19 KR KR1020097015480A patent/KR20090101359A/ko not_active Ceased
-
2010
- 2010-01-15 US US12/688,151 patent/US20100155660A1/en not_active Abandoned
-
2014
- 2014-06-03 US US14/295,100 patent/US20140286849A1/en not_active Abandoned
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005113702A1 (de) * | 2004-05-21 | 2005-12-01 | Basf Aktiengesellschaft | Neue arbeitsstoffpaare für absorptionswärmepumpen, absorptionskältemaschinen und wärmetransformatoren |
| JP2006150346A (ja) * | 2004-09-23 | 2006-06-15 | Air Products & Chemicals Inc | ガスの貯蔵及び搬送用のイオン液体をベースにした混合物 |
| WO2006084262A1 (en) * | 2005-02-04 | 2006-08-10 | E.I. Dupont De Nemours And Company | Absorption cycle utilizing ionic liquid as working fluid |
| WO2006134015A1 (de) * | 2005-06-17 | 2006-12-21 | Evonik Degussa Gmbh | Neuartige arbeitsmedien für kälteprozesse |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103388541A (zh) * | 2012-05-10 | 2013-11-13 | 株式会社电装 | 燃料汽化器 |
| JP2013234626A (ja) * | 2012-05-10 | 2013-11-21 | Denso Corp | 燃料気化器 |
| CN103388541B (zh) * | 2012-05-10 | 2015-12-02 | 株式会社电装 | 燃料汽化器 |
| JP2015221741A (ja) * | 2014-05-23 | 2015-12-10 | 株式会社豊田中央研究所 | アンモニア吸蔵放出装置 |
| JP2017154074A (ja) * | 2016-03-01 | 2017-09-07 | 国立研究開発法人産業技術総合研究所 | 塩基性ガス吸収剤及び塩基性ガス分離回収方法 |
| JP2019517654A (ja) * | 2016-05-26 | 2019-06-24 | 矢崎総業株式会社 | 吸収式冷凍機におけるグアニジニウム系イオン液体 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101573426A (zh) | 2009-11-04 |
| US20080153697A1 (en) | 2008-06-26 |
| US20100155660A1 (en) | 2010-06-24 |
| WO2008082561A2 (en) | 2008-07-10 |
| US20140286849A1 (en) | 2014-09-25 |
| WO2008082561A3 (en) | 2008-08-21 |
| EP2118230A2 (en) | 2009-11-18 |
| KR20090101359A (ko) | 2009-09-25 |
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