JP2010513612A5 - - Google Patents
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- Publication number
- JP2010513612A5 JP2010513612A5 JP2009541824A JP2009541824A JP2010513612A5 JP 2010513612 A5 JP2010513612 A5 JP 2010513612A5 JP 2009541824 A JP2009541824 A JP 2009541824A JP 2009541824 A JP2009541824 A JP 2009541824A JP 2010513612 A5 JP2010513612 A5 JP 2010513612A5
- Authority
- JP
- Japan
- Prior art keywords
- solution
- thiophene derivative
- leaving groups
- reacting
- polymerization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 238000006116 polymerization reaction Methods 0.000 claims description 7
- 239000003054 catalyst Substances 0.000 claims description 5
- 238000009826 distribution Methods 0.000 claims description 4
- 150000003577 thiophenes Chemical class 0.000 claims 9
- 239000000178 monomer Substances 0.000 claims 4
- 239000002184 metal Substances 0.000 claims 3
- 238000000034 method Methods 0.000 claims 3
- 150000002902 organometallic compounds Chemical class 0.000 claims 2
- 230000000379 polymerizing effect Effects 0.000 claims 2
- 229920000123 polythiophene Polymers 0.000 claims 2
- 150000001350 alkyl halides Chemical class 0.000 claims 1
- 238000010924 continuous production Methods 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 238000010992 reflux Methods 0.000 description 8
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- NSYFIAVPXHGRSH-UHFFFAOYSA-N 2,5-dibromo-3-hexylthiophene Chemical compound CCCCCCC=1C=C(Br)SC=1Br NSYFIAVPXHGRSH-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- NXPHGHWWQRMDIA-UHFFFAOYSA-M magnesium;carbanide;bromide Chemical compound [CH3-].[Mg+2].[Br-] NXPHGHWWQRMDIA-UHFFFAOYSA-M 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- LVEYOSJUKRVCCF-UHFFFAOYSA-N 1,3-Bis(diphenylphosphino)propane Substances C=1C=CC=CC=1P(C=1C=CC=CC=1)CCCP(C=1C=CC=CC=1)C1=CC=CC=C1 LVEYOSJUKRVCCF-UHFFFAOYSA-N 0.000 description 1
- QZVHYFUVMQIGGM-UHFFFAOYSA-N 2-Hexylthiophene Chemical compound CCCCCCC1=CC=CS1 QZVHYFUVMQIGGM-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 125000006165 cyclic alkyl group Chemical group 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 125000001072 heteroaryl group Chemical group 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102006061966A DE102006061966A1 (de) | 2006-12-21 | 2006-12-21 | Verfahren zur Darstellung von Thiophenen |
| PCT/EP2007/010710 WO2008080512A1 (de) | 2006-12-21 | 2007-12-08 | Verfahren zur darstellung von thiophenen |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2010513612A JP2010513612A (ja) | 2010-04-30 |
| JP2010513612A5 true JP2010513612A5 (enExample) | 2011-01-13 |
Family
ID=38973131
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009541824A Pending JP2010513612A (ja) | 2006-12-21 | 2007-12-08 | チオフェンの合成方法 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US20110105717A1 (enExample) |
| EP (1) | EP2121798A1 (enExample) |
| JP (1) | JP2010513612A (enExample) |
| KR (1) | KR20090101919A (enExample) |
| CN (1) | CN101563390A (enExample) |
| CA (1) | CA2673415A1 (enExample) |
| DE (1) | DE102006061966A1 (enExample) |
| TW (1) | TW200835773A (enExample) |
| WO (1) | WO2008080512A1 (enExample) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102007033343A1 (de) * | 2007-07-09 | 2009-01-15 | Bayer Technology Services Gmbh | Verfahren zur Synthese von Oligo/Polythiophenen nach einem "Eintopf"-Syntheseweg |
| DE102007038449A1 (de) * | 2007-08-14 | 2009-02-19 | Bayer Technology Services Gmbh | Verfahren zur Herstellung von Thiophenoligomeren |
| JP2010043217A (ja) * | 2008-08-18 | 2010-02-25 | Tokyo Institute Of Technology | π共役系高分子及びその製造方法、並びに電荷輸送材料及び有機電子デバイス |
| DE102010062961A1 (de) | 2010-12-13 | 2012-06-14 | Bayer Technology Services Gmbh | Carboxylierung von Poly-/Oligothiophenen |
| US8642719B2 (en) * | 2011-02-28 | 2014-02-04 | Corning Incorporated | Solvent mixture for molecular weight control |
| EP2731974A1 (en) * | 2011-07-15 | 2014-05-21 | The University of Melbourne | Process for the synthesis of conjugated polymers |
| US8901544B2 (en) | 2011-12-06 | 2014-12-02 | Corning Incorporated | Organic thin film transistor with ion exchanged glass substrate |
| JP2014070066A (ja) * | 2012-10-02 | 2014-04-21 | Sanko Kagaku Kogyo Kk | 電子伝導性オリゴマー、その製造方法、該電子伝導性オリゴマーを含む塗料、制電性被覆物、および電子部材、並びに電子伝導性組成物 |
| CN109651600A (zh) * | 2018-11-12 | 2019-04-19 | 深圳烯湾科技有限公司 | 一种聚3-己基噻吩的制备方法 |
| CN112125879A (zh) * | 2020-09-29 | 2020-12-25 | 浙江永太科技股份有限公司 | 一种卡格列净中间体2-(4-氟苯基)噻吩的制备方法 |
| CN113929881A (zh) * | 2021-11-08 | 2022-01-14 | 上海交通大学 | 一种基于连续流微反应器合成共轭光电高分子的制备方法 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US247420A (en) * | 1881-09-20 | sanford- | ||
| US5204423A (en) * | 1988-06-13 | 1993-04-20 | Solvay & Cie | Process for the preparation of polythiophenes by use of ferric salts and alkyl halides |
| AU2787892A (en) * | 1992-02-04 | 1993-09-01 | Board Of Regents Of The University Of Nebraska, The | Highly reactive forms of zinc and reagents thereof |
| US5556706A (en) * | 1993-10-06 | 1996-09-17 | Matsushita Electric Industrial Co., Ltd. | Conductive layered product and method of manufacturing the same |
| US6611172B1 (en) * | 2001-06-25 | 2003-08-26 | Sirenza Microdevices, Inc. | Thermally distributed darlington amplifier |
| US6602974B1 (en) * | 2001-12-04 | 2003-08-05 | Carnegie Mellon University | Polythiophenes, block copolymers made therefrom, and methods of forming the same |
| DE10304006B3 (de) * | 2003-02-01 | 2004-08-19 | Merck Patent Gmbh | Verfahren zur Herstellung von Grignard-Addukten |
| JP4125658B2 (ja) * | 2003-09-30 | 2008-07-30 | Ｊｆｅケミカル株式会社 | 炭化水素の製造方法 |
| US7262264B2 (en) * | 2005-01-12 | 2007-08-28 | Honeywell International Inc. | Halogenated thiophene monomer for the preparation of regioregular polythiophenes |
| US7795359B2 (en) * | 2005-03-04 | 2010-09-14 | Novartis Ag | Continuous process for production of polymeric materials |
| KR101275449B1 (ko) * | 2005-04-01 | 2013-06-14 | 카네기 멜론 유니버시티 | 위치규칙성 중합체, 폴리티오펜 및 블록 공중합체를포함하는 전도성 중합체의 리빙 합성 |
-
2006
- 2006-12-21 DE DE102006061966A patent/DE102006061966A1/de not_active Withdrawn
-
2007
- 2007-08-12 US US12/517,235 patent/US20110105717A1/en not_active Abandoned
- 2007-12-08 CA CA002673415A patent/CA2673415A1/en not_active Abandoned
- 2007-12-08 EP EP07856486A patent/EP2121798A1/de not_active Withdrawn
- 2007-12-08 JP JP2009541824A patent/JP2010513612A/ja active Pending
- 2007-12-08 KR KR1020097014229A patent/KR20090101919A/ko not_active Ceased
- 2007-12-08 CN CNA2007800473997A patent/CN101563390A/zh active Pending
- 2007-12-08 WO PCT/EP2007/010710 patent/WO2008080512A1/de not_active Ceased
- 2007-12-20 TW TW096148847A patent/TW200835773A/zh unknown
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