JP2010507697A - ポリマーの原液着色用のモノアゾ着色剤 - Google Patents
ポリマーの原液着色用のモノアゾ着色剤 Download PDFInfo
- Publication number
- JP2010507697A JP2010507697A JP2009533785A JP2009533785A JP2010507697A JP 2010507697 A JP2010507697 A JP 2010507697A JP 2009533785 A JP2009533785 A JP 2009533785A JP 2009533785 A JP2009533785 A JP 2009533785A JP 2010507697 A JP2010507697 A JP 2010507697A
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- Prior art keywords
- alkyl
- formula
- molecular weight
- phenyl
- high molecular
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003086 colorant Substances 0.000 title description 15
- 229920000642 polymer Polymers 0.000 title description 5
- NYGZLYXAPMMJTE-UHFFFAOYSA-M metanil yellow Chemical group [Na+].[O-]S(=O)(=O)C1=CC=CC(N=NC=2C=CC(NC=3C=CC=CC=3)=CC=2)=C1 NYGZLYXAPMMJTE-UHFFFAOYSA-M 0.000 title 1
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- 230000003647 oxidation Effects 0.000 claims abstract description 12
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 12
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract description 12
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 11
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- 150000003624 transition metals Chemical class 0.000 claims abstract description 6
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- 229910052799 carbon Inorganic materials 0.000 claims abstract description 5
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- SWELIMKTDYHAOY-UHFFFAOYSA-N 2,4-diamino-6-hydroxypyrimidine Chemical compound NC1=CC(=O)N=C(N)N1 SWELIMKTDYHAOY-UHFFFAOYSA-N 0.000 description 3
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- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 description 2
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
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- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 239000000025 natural resin Substances 0.000 description 1
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
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- 102000039446 nucleic acids Human genes 0.000 description 1
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- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920005553 polystyrene-acrylate Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
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- 238000007650 screen-printing Methods 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 229940035044 sorbitan monolaurate Drugs 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920005613 synthetic organic polymer Polymers 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- 229920000785 ultra high molecular weight polyethylene Polymers 0.000 description 1
- 229920001862 ultra low molecular weight polyethylene Polymers 0.000 description 1
- 229920001866 very low density polyethylene Polymers 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
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- C09B29/00—Monoazo dyes prepared by diazotising and coupling
- C09B29/34—Monoazo dyes prepared by diazotising and coupling from other coupling components
- C09B29/36—Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds
- C09B29/3604—Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds containing only a nitrogen as heteroatom
- C09B29/3665—Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds containing only a nitrogen as heteroatom containing a six-membered heterocyclic ring with two nitrogen atoms
- C09B29/3669—Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds containing only a nitrogen as heteroatom containing a six-membered heterocyclic ring with two nitrogen atoms from a pyrimidine ring
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0041—Optical brightening agents, organic pigments
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
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- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B29/00—Monoazo dyes prepared by diazotising and coupling
- C09B29/34—Monoazo dyes prepared by diazotising and coupling from other coupling components
- C09B29/36—Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds
- C09B29/3604—Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds containing only a nitrogen as heteroatom
- C09B29/3665—Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds containing only a nitrogen as heteroatom containing a six-membered heterocyclic ring with two nitrogen atoms
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Abstract
Description
[式中、X1は、とりわけアミノであってよく、そしてY1及びZ1は、OH又はNH2であるが、X1、Y1及びZ1は、全てが同時にOHではない]で示されるアゾ顔料を開示している。R1、R2及びR3の定義は、SO3H基もその塩も包含しない。
[式中、
M1は、H、1/2 M2、1/3 M3又はNR4R5R6R7、好ましくはH、1/2 M2又はNR4R5R6R7、特にHであり、
M2は、酸化状態IIのアルカリ土類金属若しくは遷移金属、又は酸化状態IVのオキソ−金属であり、
M3は、Al(III)、酸化状態IIIの遷移金属又は酸化状態Vのオキソ−金属であり、
R1は、H又は非イオン性置換基であり、
R2は、Hであるか、又はR1とは独立に、更なる非イオン性置換基であり、
R3は、H、C1−C6アルキル、フェニル、CO−C1−C6アルキル又はCO−フェニル、好ましくはH又はCO−C1−C6アルキル、特にHであり、そして
R4、R5、R6及びR7は、それぞれ他と独立に、H、又はフェニル、ベンジル若しくはC1−C6アルキル(これらは、非置換であるか、又はヒドロキシ若しくはハロゲンにより置換されていてもよく、そしてC3−C6アルキルの場合には、中断されていないか、又はOにより中断されている)である]で示される化合物又はその互変異性体を、成形前又は成形中に高分子量物質に組み込む方法に関する。
[式中、
M1は、H、1/2 M2、1/3 M3又はNR4R5R6R7、好ましくはH、1/2 M2又はNR4R5R6R7、特にHであり、
R8は、−0.3〜0.6、好ましくは−0.3〜0.3のパラHammett定数σpを有する非イオン性置換基であり、
R9は、Hであるか、又はR8とは独立に、−0.3〜0.6、好ましくは−0.3〜0.3のパラHammett定数σpを有する、更なる非イオン性置換基であり、
R10は、H、C1−C6アルキル、フェニル、CO−C1−C6アルキル又はCO−フェニル、好ましくはH又はCO−C1−C6アルキル、特にHであり、そして
R4、R5、R6及びR7は、それぞれ他と独立に、H、又はフェニル、ベンジル若しくはC1−C6アルキル(これらは、非置換であるか、又はヒドロキシ若しくはハロゲンにより置換されていてもよく、そしてC3−C6アルキルの場合には、中断されていないか、又はOにより中断されている)である]で示される化合物又はその互変異性体に関する。
4−メチルアニリン−2−スルホン酸(99%)7.56gを水160ml中で撹拌して、30%水酸化ナトリウム溶液4mlで溶解した。次に37%塩酸(工業等級)14mlを加えた。この混合物を0〜5℃に冷却して、4N亜硝酸ナトリウム水溶液10mlを滴下により加えた。2時間後、1Nスルファミン酸水溶液4mlをこのジアゾニウム懸濁液に加えた。
で示される生成物6.2gを得たが、これをPVC(カレンダー掛け)及びHDPE(射出成形)の原液着色に使用すると、熱安定性の黄色の着色が得られた。
元素分析: C H N S Na
[%] 40.0 3.9 26.1 9.5 < 1ppm
計算値: 40.7 3.7 25.9 9.9 -
元素分析: C H N S Na
[%] 43.3 4.5 23.3 8.4 < 1ppm
4−メチルアニリン−2−スルホン酸(99%)22.7gを水450ml中で撹拌した。次に37%塩酸(工業等級)30mlを加えた。この混合物を0〜5℃に冷却して、4N亜硝酸ナトリウム水溶液40mlを滴下により加えた。1.5時間後、1Nスルファミン酸水溶液6mlをこのジアゾニウム塩懸濁液に加えた。
元素分析: C H N S Na
[%] 40.4 3.9 26.2 9.6 < 1ppm
計算値: 40.7 3.7 25.9 9.9 -
また、pH値を変化させることにより、ある場合にはM1 +としてアルカリ金属イオン(例えば、Na+、Li+、K+)を含有する、顔料混合物又は固溶体を得ることもできる。
手順は実施例2と同様に行ったが、カップリングが終了したら、スルホン酸を酢酸カルシウム、ストロンチウム又はアンモニウムで中和することにより、以下の構造を有する化合物を得て、これをPVC(カレンダー掛け)及びHDPE(射出成形)の原液着色に使用すると、熱安定性の黄色の着色が得られた:
0.2重量%の実施例1又は2の生成物を押し出し機でポリアミド6(Ultramid(登録商標)B3K、BASF)に組み込み、次に240℃で射出成形により試験板(例えば、30×50×2mm)を製造した。良好な光安定性を有する均質な着色が得られた。
手順は実施例2〜5と同様に行ったが、4−メチルアニリン−2−スルホン酸の代わりに、等量の2−メチルアニリン−4−スルホン酸を使用した。結果は、実施例2〜5のものと非常に類似していた。
手順は実施例2〜5と同様に行ったが、4−メチルアニリン−2−スルホン酸の代わりに、等量のアニリン−4−スルホン酸を使用した。結果は、実施例2〜5のものと非常に類似していたが、わずかに緑色味を帯びた色調であった。
手順は実施例2〜3と同様に行ったが、4−メチルアニリン−2−スルホン酸の代わりに、等量のアニリン−3−スルホン酸を使用し、更にはテクスチャーを改善するために、20重量%(理論的に得られる顔料の量に基づく)のコロホニウム樹脂を加えた。
手順は実施例2〜5と同様に行ったが、4−メチルアニリン−2−スルホン酸の代わりに、等量の2−アミノ−5−クロロ−4−エチルベンゼンスルホン酸を使用した:
手順は実施例2〜5と同様に行ったが、4−メチルアニリン−2−スルホン酸の代わりに、等量の2−アミノ−5−メトキシベンゼンスルホン酸を使用した:
手順は実施例2〜5と同様に行ったが、4−メチルアニリン−2−スルホン酸の代わりに、等量の5−アセトアミノ−2−アミノベンゼンスルホン酸を使用した:
手順は実施例2〜5と同様に行ったが、4−メチルアニリン−2−スルホン酸の代わりに、等量の4−アセトアミノ−2−アミノ−5−(2’−スルホフェニルアゾ)−ベンゼンスルホン酸を使用した:
手順は実施例2〜5と同様に行ったが、2,4−ジアミノ−6−ヒドロキシピリミジンの代わりに、等量の4−アミノ−2−ジメチルアミノ−6−ヒドロキシピリミジンを使用した:
実施例7〜36により得られた顔料を、カレンダー掛けでPVCの原液着色に使用すると、良好な光安定性を有する均質な着色が得られた。
実施例7〜36により得られた顔料を、射出成形プロセスでHDPEの原液着色に使用すると、良好な光安定性を有する均質な着色が得られた。
実施例7〜32により得られた0.2重量%の顔料を、実施例6によりポリアミド6中に組み込み、次に240℃で射出成形により試験板(例えば、30×50×2mm)を製造した。良好な光安定性を有する均質な着色が得られた。
Claims (11)
- 高分子量物質の原液着色の方法であって、式(I):
[式中、
M1は、H、1/2 M2、1/3 M3又はNR4R5R6R7、好ましくはH、1/2 M2又はNR4R5R6R7、特にHであり、
M2は、酸化状態IIのアルカリ土類金属若しくは遷移金属、又は酸化状態IVのオキソ−金属であり、
M3は、Al(III)、酸化状態IIIの遷移金属又は酸化状態Vのオキソ−金属であり、
R1は、H又は非イオン性置換基であり、
R2は、Hであるか、又はR1とは独立に、更なる非イオン性置換基であり、
R3は、H、C1−C6アルキル、フェニル、CO−C1−C6アルキル又はCO−フェニル、好ましくはH又はCO−C1−C6アルキル、特にHであり、そして
R4、R5、R6及びR7は、それぞれ他と独立に、H、又はフェニル、ベンジル若しくはC1−C6アルキル(これらは、非置換であるか、又はヒドロキシ若しくはハロゲンにより置換されていてもよく、そしてC3−C6アルキルの場合には、中断されていないか、又はOにより中断されている)である]で示される化合物又はその互変異性体を、成形前又は成形中に高分子量物質に組み込む方法。 - M2が、Ca、Co、Cu、Fe、Mg、Mn、Sr、TiO、Zn又はZrOであるか、あるいはM3が、Al、Ce、Co、Cr、Fe又はVOである、請求項1記載の方法。
- R1が、−0.3〜0.6のパラHammett定数σpを有する非イオン性置換基であり、そしてR2が、H、又はR1とは独立に、−0.3〜0.6のパラHammett定数σpを有する更なる非イオン性置換基である、請求項1又は2記載の方法。
- 式(I)においてSO3Mが、アゾ橋に対してオルト位にある、請求項1、2又は3記載の方法。
- 式(II):
[式中、
M1は、H、1/2 M2、1/3 M3又はNR4R5R6R7、好ましくはH、1/2 M2又はNR4R5R6R7、特にHであり、
R8は、−0.3〜0.6、好ましくは−0.3〜0.3のパラHammett定数σpを有する非イオン性置換基であり、
R9は、Hであるか、又はR8とは独立に、−0.3〜0.6、好ましくは−0.3〜0.3のパラHammett定数σpを有する、更なる非イオン性置換基であり、
R10は、H、C1−C6アルキル、フェニル、CO−C1−C6アルキル又はCO−フェニル、好ましくはH又はCO−C1−C6アルキル、特にHであり、そして
R4、R5、R6及びR7は、それぞれ他と独立に、H、又はフェニル、ベンジル若しくはC1−C6アルキル(これらは、非置換であるか、又はヒドロキシ若しくはハロゲンにより置換されていてもよく、そしてC3−C6アルキルの場合には、中断されていないか、又はOにより中断されている)である]で示される化合物又はその互変異性体。 - 総着色高分子量物質に基づいて、0.01〜70重量%の請求項1〜7のいずれか1項記載の式(I)、(II)、(III)、(IV)、(V)若しくは(VI)の化合物、又は請求項8記載の混合物若しくは固溶体を含む(高分子量物質中に分布した固体粒子の形で存在するか、又は溶解した形で高分子量物質に均質に浸透している)、原液着色された高分子量物質。
- 高分子量物質が、ポリオレフィンである、請求項9記載の原液着色された高分子量物質。
- 高分子量物質の原液着色における、請求項1〜7のいずれか1項記載の式(I)、(II)、(III)、(IV)、(V)若しくは(VI)の化合物、又は請求項8記載の混合物若しくは固溶体の使用。
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US9896554B2 (en) | 2009-09-29 | 2018-02-20 | Plastipak Packaging, Inc. | Colorant compatible oxygen scavenging polymer compositions and articles made from same |
US10040922B2 (en) | 2009-11-13 | 2018-08-07 | Plastipak Packaging, Inc. | Oxygen scavengers, compositions comprising the scavengers, and articles made from the compositions |
US10059666B2 (en) | 2009-11-13 | 2018-08-28 | Plastipak Packaging, Inc. | Oxygen scavengers, compositions comprising the scavengers, and articles made from the compositions |
US10125096B2 (en) | 2007-05-10 | 2018-11-13 | Plastipak Packaging, Inc. | Oxygen scavenging molecules, articles containing same, and methods of their use |
US10351692B2 (en) | 2014-10-17 | 2019-07-16 | Plastipak Packaging, Inc. | Oxygen scavengers, compositions comprising the scavengers, and articles made from the compositions |
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JPS5773047A (en) * | 1980-08-20 | 1982-05-07 | Ciba Geigy Ag | Method of coloring fiber-formed polyamide |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
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GB727045A (en) * | 1951-05-07 | 1955-03-30 | Bayer Ag | Azo dyestuffs |
CH455986A (de) * | 1965-08-02 | 1968-05-15 | Geigy Ag J R | Verfahren zur Herstellung von in Wasser dispergierbaren schwerlöslichen Azofarbstoffen |
CH480410A (de) * | 1967-01-09 | 1969-10-31 | Geigy Ag J R | Verfahren zur Herstellung von wasserlöslichen Azopyrimidinfarbstoffen |
DE2351294A1 (de) * | 1973-10-12 | 1975-04-24 | Bayer Ag | Azopigmente |
US4340430A (en) * | 1979-08-17 | 1982-07-20 | Ciba-Geigy Corporation | Azo pigments, process for their production and their use |
PL162231B2 (pl) | 1990-10-01 | 1993-09-30 | Univ Lodzki | _ Sposób otrzymywania nowych barwników o,o’ - dihydroksyazowych pochodnych 2,6- diaminopirymidyny PL |
TW243464B (ja) | 1992-09-29 | 1995-03-21 | Ciba Geigy | |
GB9305374D0 (en) | 1993-03-16 | 1993-05-05 | Sandoz Ltd | Improvements in or relating to organic compounds |
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2007
- 2007-10-15 ES ES07821292T patent/ES2388106T3/es active Active
- 2007-10-15 WO PCT/EP2007/060925 patent/WO2008049744A1/en active Application Filing
- 2007-10-15 US US12/446,252 patent/US20100305247A1/en not_active Abandoned
- 2007-10-15 MX MX2009004479A patent/MX2009004479A/es active IP Right Grant
- 2007-10-15 BR BRPI0717624A patent/BRPI0717624B1/pt active IP Right Grant
- 2007-10-15 JP JP2009533785A patent/JP5551441B2/ja active Active
- 2007-10-15 EP EP07821292A patent/EP2079805B1/en active Active
- 2007-10-15 MY MYPI20091502A patent/MY148229A/en unknown
- 2007-10-15 KR KR1020097010580A patent/KR101434322B1/ko active IP Right Grant
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5773047A (en) * | 1980-08-20 | 1982-05-07 | Ciba Geigy Ag | Method of coloring fiber-formed polyamide |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10125096B2 (en) | 2007-05-10 | 2018-11-13 | Plastipak Packaging, Inc. | Oxygen scavenging molecules, articles containing same, and methods of their use |
US11739059B2 (en) | 2007-05-10 | 2023-08-29 | Plastipak Packaging, Inc. | Oxygen scavenging molecules, articles containing same, and methods of their use |
US9896554B2 (en) | 2009-09-29 | 2018-02-20 | Plastipak Packaging, Inc. | Colorant compatible oxygen scavenging polymer compositions and articles made from same |
US10040922B2 (en) | 2009-11-13 | 2018-08-07 | Plastipak Packaging, Inc. | Oxygen scavengers, compositions comprising the scavengers, and articles made from the compositions |
US10059666B2 (en) | 2009-11-13 | 2018-08-28 | Plastipak Packaging, Inc. | Oxygen scavengers, compositions comprising the scavengers, and articles made from the compositions |
US10351692B2 (en) | 2014-10-17 | 2019-07-16 | Plastipak Packaging, Inc. | Oxygen scavengers, compositions comprising the scavengers, and articles made from the compositions |
US11066536B2 (en) | 2014-10-17 | 2021-07-20 | Plastipak Packaging, Inc. | Oxygen scavengers, compositions comprising the scavengers, and articles made from the compositions |
Also Published As
Publication number | Publication date |
---|---|
ES2388106T3 (es) | 2012-10-09 |
BRPI0717624A2 (pt) | 2013-10-29 |
WO2008049744A1 (en) | 2008-05-02 |
EP2079805A1 (en) | 2009-07-22 |
EP2079805B1 (en) | 2012-08-01 |
KR101434322B1 (ko) | 2014-08-27 |
US20100305247A1 (en) | 2010-12-02 |
KR20090088376A (ko) | 2009-08-19 |
MX2009004479A (es) | 2009-05-12 |
JP5551441B2 (ja) | 2014-07-16 |
BRPI0717624B1 (pt) | 2017-03-14 |
MY148229A (en) | 2013-03-29 |
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