JP2010502636A5 - - Google Patents
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- Publication number
- JP2010502636A5 JP2010502636A5 JP2009526843A JP2009526843A JP2010502636A5 JP 2010502636 A5 JP2010502636 A5 JP 2010502636A5 JP 2009526843 A JP2009526843 A JP 2009526843A JP 2009526843 A JP2009526843 A JP 2009526843A JP 2010502636 A5 JP2010502636 A5 JP 2010502636A5
- Authority
- JP
- Japan
- Prior art keywords
- alkylation
- catalyst
- alkylation catalyst
- preliminary
- exhaust stream
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000029936 alkylation Effects 0.000 claims 61
- 238000005804 alkylation reaction Methods 0.000 claims 61
- 239000003054 catalyst Substances 0.000 claims 49
- 229910004298 SiO 2 Inorganic materials 0.000 claims 12
- 229910021536 Zeolite Inorganic materials 0.000 claims 11
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims 11
- 239000010457 zeolite Substances 0.000 claims 11
- 229940100198 alkylating agent Drugs 0.000 claims 10
- 239000002168 alkylating agent Substances 0.000 claims 10
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims 9
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 9
- -1 alkyl aromatic hydrocarbon Chemical class 0.000 claims 9
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims 9
- 150000001875 compounds Chemical class 0.000 claims 9
- 238000000034 method Methods 0.000 claims 7
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 claims 6
- 239000002808 molecular sieve Substances 0.000 claims 6
- 239000002574 poison Substances 0.000 claims 6
- 231100000614 poison Toxicity 0.000 claims 6
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims 6
- 239000007791 liquid phase Substances 0.000 claims 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 3
- 239000005977 Ethylene Substances 0.000 claims 3
- 239000012041 precatalyst Substances 0.000 claims 3
- 230000008929 regeneration Effects 0.000 claims 3
- 238000011069 regeneration method Methods 0.000 claims 3
- 229910052684 Cerium Inorganic materials 0.000 claims 2
- 239000002253 acid Substances 0.000 claims 2
- 150000001336 alkenes Chemical class 0.000 claims 2
- 125000000217 alkyl group Chemical group 0.000 claims 2
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 claims 2
- 239000012071 phase Substances 0.000 claims 2
- 230000007420 reactivation Effects 0.000 claims 2
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- 230000002378 acidificating effect Effects 0.000 claims 1
- 229930195733 hydrocarbon Natural products 0.000 claims 1
- 150000002430 hydrocarbons Chemical class 0.000 claims 1
- 238000006116 polymerization reaction Methods 0.000 claims 1
- 239000000758 substrate Substances 0.000 claims 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/515,679 US20080058566A1 (en) | 2006-09-05 | 2006-09-05 | Processes for reduction of alkylation catalyst deactivation utilizing low silica to alumina ratio catalyst |
| US11/515,679 | 2006-09-05 | ||
| PCT/US2007/076872 WO2008030722A2 (en) | 2006-09-05 | 2007-08-27 | Processes for the reduction of alkylation catalyst deactivation utilizing low silica to alumina ratio catalyst |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2010502636A JP2010502636A (ja) | 2010-01-28 |
| JP2010502636A5 true JP2010502636A5 (enExample) | 2011-03-24 |
| JP5486306B2 JP5486306B2 (ja) | 2014-05-07 |
Family
ID=39152703
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009526843A Expired - Fee Related JP5486306B2 (ja) | 2006-09-05 | 2007-08-27 | 低いシリカ対アルミナ比の触媒を使用する、アルキル化触媒の失活の減少法 |
Country Status (8)
| Country | Link |
|---|---|
| US (5) | US20080058566A1 (enExample) |
| EP (1) | EP2064168A4 (enExample) |
| JP (1) | JP5486306B2 (enExample) |
| KR (3) | KR101586629B1 (enExample) |
| CN (2) | CN102153435A (enExample) |
| CA (1) | CA2661021C (enExample) |
| MX (2) | MX374947B (enExample) |
| WO (1) | WO2008030722A2 (enExample) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080192226A1 (en) * | 2004-06-07 | 2008-08-14 | Nikon Corporation | Stage Unit, Exposure Apparatus, and Exposure Method |
| US7645913B2 (en) | 2007-01-19 | 2010-01-12 | Exxonmobil Chemical Patents Inc. | Liquid phase alkylation with multiple catalysts |
| US8134036B2 (en) * | 2008-03-13 | 2012-03-13 | Fina Technology Inc | Process for liquid phase alkylation |
| US8865958B2 (en) * | 2008-09-30 | 2014-10-21 | Fina Technology, Inc. | Process for ethylbenzene production |
| US8697208B2 (en) * | 2009-07-24 | 2014-04-15 | Fina Technology, Inc. | Polystyrene nanocomposites for blow molding applications |
| US8455383B2 (en) | 2009-09-28 | 2013-06-04 | Fina Technology, Inc. | Process for catalyst regeneration and extended use |
| KR101574384B1 (ko) | 2010-05-20 | 2015-12-03 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 개선된 알킬화 공정 |
| US20120296142A1 (en) * | 2011-05-22 | 2012-11-22 | Fina Technology, Inc. | Addition of basic nitrogen to alkylation reactions |
| US8785706B2 (en) * | 2011-05-22 | 2014-07-22 | Fina Technology, Inc. | Addition of a base to enhance product yield in alkylation reactions |
| CN105709815B (zh) * | 2014-12-02 | 2018-06-19 | 中国石油化工股份有限公司 | 一种甲苯与乙烯选择性烷基化催化剂及其制备方法 |
| EP3416933B1 (en) * | 2016-02-17 | 2020-06-03 | Badger Licensing LLC | Process for producing ethylbenzene |
| KR102235872B1 (ko) * | 2016-10-06 | 2021-04-06 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 방향족 탄화수소의 메틸화 방법 |
| KR102235874B1 (ko) | 2016-10-06 | 2021-04-06 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 벤젠 및/또는 톨루엔의 메틸화에 의해 파라크실렌을 생성시키기 위한 촉매의 선택화 방법 |
| KR20190040081A (ko) | 2016-10-06 | 2019-04-16 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 벤젠 및/또는 톨루엔의 메틸화에 의한 파라크실렌의 제조 방법 |
| US11673849B2 (en) | 2016-12-21 | 2023-06-13 | Exxonmobil Chemical Patents Inc. | Process for selectivating catalyst for producing paraxylene by methylation of benzene and/or toluene |
Family Cites Families (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3308069A (en) | 1964-05-01 | 1967-03-07 | Mobil Oil Corp | Catalytic composition of a crystalline zeolite |
| US4185040A (en) | 1977-12-16 | 1980-01-22 | Union Oil Company Of California | Alkylation of aromatic hydrocarbons |
| US4358362A (en) * | 1981-01-15 | 1982-11-09 | Mobil Oil Corporation | Method for enhancing catalytic activity |
| US4642226A (en) | 1984-04-16 | 1987-02-10 | Mobil Oil Corporation | Process for the preparation of zeolite Beta using dibenzyldimethylammonium ions and the product produced |
| US5081323A (en) * | 1987-12-17 | 1992-01-14 | Chevron Research And Technology Company | Liquid phase alkylation or transalkylation process using zeolite beta |
| US4992606A (en) | 1988-10-06 | 1991-02-12 | Mobil Oil Corp. | Process for preparing short chain alkyl aromatic compounds |
| US5535817A (en) * | 1989-07-28 | 1996-07-16 | Uop | Sorption cooling process and apparatus |
| US5334795A (en) * | 1990-06-28 | 1994-08-02 | Mobil Oil Corp. | Production of ethylbenzene |
| US5258565A (en) | 1992-05-04 | 1993-11-02 | Mobil Oil Corp. | Process for preparing short chain alkylaromatic compounds |
| US5362697A (en) | 1993-04-26 | 1994-11-08 | Mobil Oil Corp. | Synthetic layered MCM-56, its synthesis and use |
| KR960703102A (ko) | 1993-06-16 | 1996-06-19 | 택 케이.성 | 액상 에틸벤젠 합성방법(Liquid phase ethylbenzene synthesis) |
| WO1998007673A1 (en) * | 1996-08-20 | 1998-02-26 | The Dow Chemical Company | Process for the production of alkylated benzenes |
| JP4275739B2 (ja) * | 1996-09-06 | 2009-06-10 | エクソンモービル・ケミカル・パテンツ・インク | ゼオライトβを用いるアルキル化方法 |
| US5998687A (en) * | 1997-07-29 | 1999-12-07 | Uop Llc | Ethylbenzene process using stacked reactor loading of beta and Y zeolites |
| US6057485A (en) * | 1998-11-17 | 2000-05-02 | Fina Technology, Inc. | Gas phase alkylation with split load of catalyst |
| US6617482B1 (en) * | 2000-08-16 | 2003-09-09 | Exxonmobil Chemical Patents Inc. | Removable of polar contaminants from aromatic feedstocks |
| US20020042548A1 (en) * | 2001-07-11 | 2002-04-11 | Dandekar Ajit B. | Process for producing cumene |
| FR2832144B1 (fr) * | 2001-11-15 | 2004-09-24 | Inst Francais Du Petrole | Procede de production de phenylalcanes utilisant une combinaison de deux catalyseurs |
| JP2005519103A (ja) * | 2002-02-28 | 2005-06-30 | ストーン アンド ウェブスター インコーポレーテッド | アルキル芳香族化合物の製造 |
| US6933418B2 (en) * | 2002-10-04 | 2005-08-23 | Fina Technology, Inc. | Critical phase alkylation process |
| US20040138511A1 (en) * | 2003-01-10 | 2004-07-15 | James Butler | Aromatic alkylation process with direct recycle |
| KR20130087575A (ko) * | 2003-03-24 | 2013-08-06 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 공급물 전처리 |
| US6894201B1 (en) * | 2003-12-19 | 2005-05-17 | Uop Llc | Process and apparatus for the removal of nitrogen compounds from a fluid stream |
| US20060194991A1 (en) * | 2005-02-25 | 2006-08-31 | Fina Technology, Inc. | Treatment of alkylation catalyst poisons |
| US20060192985A1 (en) | 2005-02-25 | 2006-08-31 | Konica Minolta Systems Laboratory, Inc. | Printing system |
| US7476774B2 (en) * | 2005-02-28 | 2009-01-13 | Exxonmobil Research And Engineering Company | Liquid phase aromatics alkylation process |
| US7501547B2 (en) * | 2006-05-10 | 2009-03-10 | Exxonmobil Chemical Patents Inc. | Alkylaromatics production |
| US7645913B2 (en) * | 2007-01-19 | 2010-01-12 | Exxonmobil Chemical Patents Inc. | Liquid phase alkylation with multiple catalysts |
-
2006
- 2006-09-05 US US11/515,679 patent/US20080058566A1/en not_active Abandoned
-
2007
- 2007-08-27 JP JP2009526843A patent/JP5486306B2/ja not_active Expired - Fee Related
- 2007-08-27 KR KR1020147005870A patent/KR101586629B1/ko not_active Expired - Fee Related
- 2007-08-27 CN CN2011100463851A patent/CN102153435A/zh active Pending
- 2007-08-27 KR KR1020097006770A patent/KR101542785B1/ko not_active Expired - Fee Related
- 2007-08-27 MX MX2014007499A patent/MX374947B/es unknown
- 2007-08-27 CA CA2661021A patent/CA2661021C/en active Active
- 2007-08-27 EP EP07841389A patent/EP2064168A4/en not_active Ceased
- 2007-08-27 MX MX2009002350A patent/MX2009002350A/es active IP Right Grant
- 2007-08-27 KR KR1020147005866A patent/KR101587786B1/ko not_active Expired - Fee Related
- 2007-08-27 CN CNA2007800324598A patent/CN101511753A/zh active Pending
- 2007-08-27 WO PCT/US2007/076872 patent/WO2008030722A2/en not_active Ceased
-
2011
- 2011-08-18 US US13/212,234 patent/US9556083B2/en not_active Expired - Fee Related
-
2013
- 2013-04-16 US US13/863,722 patent/US8552238B2/en not_active Expired - Fee Related
- 2013-08-29 US US14/014,098 patent/US8680354B2/en active Active
-
2014
- 2014-01-14 US US14/154,422 patent/US9556084B2/en not_active Expired - Fee Related
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