JP2009537316A - カルボン酸および／またはカルボン酸無水物を製造するための触媒系 - Google Patents
カルボン酸および／またはカルボン酸無水物を製造するための触媒系 Download PDFInfo
- Publication number
- JP2009537316A JP2009537316A JP2009511456A JP2009511456A JP2009537316A JP 2009537316 A JP2009537316 A JP 2009537316A JP 2009511456 A JP2009511456 A JP 2009511456A JP 2009511456 A JP2009511456 A JP 2009511456A JP 2009537316 A JP2009537316 A JP 2009537316A
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- JP
- Japan
- Prior art keywords
- catalyst
- mass
- thickness
- catalyst layer
- active material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 176
- 150000001735 carboxylic acids Chemical class 0.000 title claims abstract description 9
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 title claims abstract description 8
- 239000007789 gas Substances 0.000 claims abstract description 21
- 238000006243 chemical reaction Methods 0.000 claims abstract description 14
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 14
- 230000000694 effects Effects 0.000 claims abstract description 13
- 230000003647 oxidation Effects 0.000 claims abstract description 13
- 238000000034 method Methods 0.000 claims abstract description 12
- 230000008021 deposition Effects 0.000 claims abstract description 10
- 238000004519 manufacturing process Methods 0.000 claims abstract description 9
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 8
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 8
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910001882 dioxygen Inorganic materials 0.000 claims abstract description 6
- 239000011149 active material Substances 0.000 claims description 36
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 13
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 13
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 claims description 12
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 11
- 229910052783 alkali metal Inorganic materials 0.000 claims description 9
- 150000001340 alkali metals Chemical class 0.000 claims description 9
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims description 8
- 239000003513 alkali Substances 0.000 claims description 8
- 229910052792 caesium Inorganic materials 0.000 claims description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 7
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims description 5
- 239000004215 Carbon black (E152) Substances 0.000 claims description 4
- 230000003197 catalytic effect Effects 0.000 claims description 3
- 239000008096 xylene Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 description 10
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 229940078552 o-xylene Drugs 0.000 description 5
- 239000000725 suspension Substances 0.000 description 5
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 4
- 238000001354 calcination Methods 0.000 description 4
- 238000011068 loading method Methods 0.000 description 4
- 229910052720 vanadium Inorganic materials 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 3
- 239000005711 Benzoic acid Substances 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 description 2
- 235000010233 benzoic acid Nutrition 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- SQNZJJAZBFDUTD-UHFFFAOYSA-N durene Chemical compound CC1=CC(C)=C(C)C=C1C SQNZJJAZBFDUTD-UHFFFAOYSA-N 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 2
- 238000007086 side reaction Methods 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- 229910001935 vanadium oxide Inorganic materials 0.000 description 2
- VLDPXPPHXDGHEW-UHFFFAOYSA-N 1-chloro-2-dichlorophosphoryloxybenzene Chemical compound ClC1=CC=CC=C1OP(Cl)(Cl)=O VLDPXPPHXDGHEW-UHFFFAOYSA-N 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- ANSXAPJVJOKRDJ-UHFFFAOYSA-N furo[3,4-f][2]benzofuran-1,3,5,7-tetrone Chemical compound C1=C2C(=O)OC(=O)C2=CC2=C1C(=O)OC2=O ANSXAPJVJOKRDJ-UHFFFAOYSA-N 0.000 description 1
- 238000010574 gas phase reaction Methods 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/20—Vanadium, niobium or tantalum
- B01J23/22—Vanadium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
- B01J27/198—Vanadium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/19—Catalysts containing parts with different compositions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
- C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Catalysts (AREA)
- Furan Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP06114230 | 2006-05-19 | ||
| PCT/EP2007/054621 WO2007135002A1 (de) | 2006-05-19 | 2007-05-14 | Katalysatorsystem zur herstellung von carbonsäuren und/oder carbonsäureanhydriden |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2009537316A true JP2009537316A (ja) | 2009-10-29 |
| JP2009537316A5 JP2009537316A5 (enExample) | 2013-08-22 |
Family
ID=38440253
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009511456A Pending JP2009537316A (ja) | 2006-05-19 | 2007-05-14 | カルボン酸および／またはカルボン酸無水物を製造するための触媒系 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20090163726A1 (enExample) |
| EP (1) | EP2024085A1 (enExample) |
| JP (1) | JP2009537316A (enExample) |
| CN (1) | CN101448571A (enExample) |
| TW (1) | TW200745017A (enExample) |
| WO (1) | WO2007135002A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013537476A (ja) * | 2010-06-30 | 2013-10-03 | ビーエーエスエフ ソシエタス・ヨーロピア | 無水フタル酸を製造するための多層触媒、及び無水フタル酸の製造方法 |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007135104A1 (de) * | 2006-05-19 | 2007-11-29 | Basf Se | Herstellung von phthalsäureanhydrid durch gasphasenoxidation von o-xylol |
| JP5114474B2 (ja) | 2006-05-19 | 2013-01-09 | ビーエーエスエフ ソシエタス・ヨーロピア | 主要反応器および後方反応器中でのｏ−キシロールの気相酸化による無水フタル酸の製造 |
| BRPI0720411A2 (pt) | 2006-12-21 | 2013-12-31 | Basf Se | Processo para oxidação em fase gasosa, e, sistema catalisador para a realização de processos de oxidação em fase gasosa |
| US8492566B2 (en) | 2008-04-07 | 2013-07-23 | Basf Se | Method for starting a gas-phase oxidation reactor |
| EP2274265A1 (de) * | 2008-04-07 | 2011-01-19 | Basf Se | Verfahren zum anfahren eines gasphasenoxidationsreaktors, der eine katalytisch aktive silber-vanadiumoxid-bronze enthält |
| EP2501472A1 (de) * | 2009-11-20 | 2012-09-26 | Basf Se | Mehrlagenkatalysator zur herstellung von carbonsäuren und/oder carbonsäureanhydriden mit vanadiumantimonat in wenigstens einer katalysatorlage und verfahren zur herstellung von phthalsäureanhydrid mit niedriger hotspottemperatur |
| US20110230668A1 (en) * | 2010-03-19 | 2011-09-22 | Basf Se | Catalyst for gas phase oxidations based on low-sulfur and low-calcium titanium dioxide |
| TW201206896A (en) | 2010-04-13 | 2012-02-16 | Basf Se | Process for controlling a gas phase oxidation reactor for preparation of phthalic anhydride |
| US8859459B2 (en) | 2010-06-30 | 2014-10-14 | Basf Se | Multilayer catalyst for preparing phthalic anhydride and process for preparing phthalic anhydride |
| US9212157B2 (en) | 2010-07-30 | 2015-12-15 | Basf Se | Catalyst for the oxidation of o-xylene and/or naphthalene to phthalic anhydride |
| CN110605073B (zh) * | 2018-06-15 | 2022-03-15 | 中国石油化工股份有限公司 | 用于烯烃环氧化工艺的催化剂装填方法及烯烃环氧化方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4876813A (enExample) * | 1972-01-03 | 1973-10-16 | ||
| US4342699A (en) * | 1981-02-23 | 1982-08-03 | Standard Oil Company (Indiana) | Process for production of maleic anhydride |
| WO2005011862A1 (de) * | 2003-08-01 | 2005-02-10 | Basf Aktiengesellschaft | Katalysator für gasphasenoxidationen |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4006935A1 (de) | 1990-03-06 | 1991-09-12 | Wacker Chemie Gmbh | Fliessbettapparatur zum mischen, trocknen und beschichten von pulvrigem, koernigem und geformtem schuettgut |
| DE4013051A1 (de) * | 1990-04-24 | 1991-11-07 | Basf Ag | Verfahren zur herstellung von phthalsaeureanhydrid aus o-xylol |
| DE59808069D1 (de) | 1997-02-27 | 2003-05-28 | Basf Ag | Verfahren zur herstellung von schalenkatalysatoren für die katalytische gasphasenoxidation von aromatischen kohlenwasserstoffen |
| DE19824532A1 (de) | 1998-06-03 | 1999-12-09 | Basf Ag | Verfahren zur Herstellung von Schalenkatalysatoren für die katalytische Gasphasenoxidation von aromatischen Kohlenwasserstoffen und so erhältliche Katalysatoren |
| DE19839001A1 (de) | 1998-08-27 | 2000-03-02 | Basf Ag | Schalenkatalysatoren für die katalytische Gasphasenoxidation von aromatischen Kohlenwasserstoffen |
| DE10206989A1 (de) * | 2002-02-19 | 2003-08-21 | Basf Ag | Verfahren zur Herstellung von Phthalsäureanhydrid |
| DE10323817A1 (de) * | 2003-05-23 | 2004-12-09 | Basf Ag | Verfahren zur Herstellung von Phthalsäureanhydrid |
| DE10323818A1 (de) * | 2003-05-23 | 2004-12-09 | Basf Ag | Katalysatorsysteme zur Herstellung von Phthalsäureanhydrid |
| WO2005030388A1 (de) | 2003-09-26 | 2005-04-07 | Basf Aktiengesellschaft | Verfahren zur herstellung eines katalysators für gasphasenoxidationen durch beschichten von trägermaterial in einer fliessbettapparatur |
| DE102004026472A1 (de) * | 2004-05-29 | 2005-12-22 | Süd-Chemie AG | Mehrlagen-Katalysator zur Herstellung von Phthalsäureanhydrid |
| WO2005115615A1 (de) * | 2004-05-29 | 2005-12-08 | Süd-Chemie AG | Katalysator sowie verfahren zur herstellung von phthalsäureanhydrid |
| CN1616148A (zh) | 2004-09-26 | 2005-05-18 | 刘竖毅 | 四段床苯酐催化剂 |
| DE102005009473A1 (de) * | 2005-03-02 | 2006-09-07 | Süd-Chemie AG | Mehrlagen-Katalysator zur Herstellung von Phthalsäureanhydrid |
-
2007
- 2007-05-14 US US12/301,420 patent/US20090163726A1/en not_active Abandoned
- 2007-05-14 CN CNA2007800181289A patent/CN101448571A/zh active Pending
- 2007-05-14 JP JP2009511456A patent/JP2009537316A/ja active Pending
- 2007-05-14 EP EP07729073A patent/EP2024085A1/de not_active Withdrawn
- 2007-05-14 WO PCT/EP2007/054621 patent/WO2007135002A1/de not_active Ceased
- 2007-05-18 TW TW096117820A patent/TW200745017A/zh unknown
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4876813A (enExample) * | 1972-01-03 | 1973-10-16 | ||
| US4342699A (en) * | 1981-02-23 | 1982-08-03 | Standard Oil Company (Indiana) | Process for production of maleic anhydride |
| WO2005011862A1 (de) * | 2003-08-01 | 2005-02-10 | Basf Aktiengesellschaft | Katalysator für gasphasenoxidationen |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013537476A (ja) * | 2010-06-30 | 2013-10-03 | ビーエーエスエフ ソシエタス・ヨーロピア | 無水フタル酸を製造するための多層触媒、及び無水フタル酸の製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| TW200745017A (en) | 2007-12-16 |
| CN101448571A (zh) | 2009-06-03 |
| US20090163726A1 (en) | 2009-06-25 |
| EP2024085A1 (de) | 2009-02-18 |
| WO2007135002A1 (de) | 2007-11-29 |
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