JP2009503243A - ラジカル重合用触媒 - Google Patents

ラジカル重合用触媒 Download PDF

Info

Publication number
JP2009503243A
JP2009503243A JP2008525230A JP2008525230A JP2009503243A JP 2009503243 A JP2009503243 A JP 2009503243A JP 2008525230 A JP2008525230 A JP 2008525230A JP 2008525230 A JP2008525230 A JP 2008525230A JP 2009503243 A JP2009503243 A JP 2009503243A
Authority
JP
Japan
Prior art keywords
polymer
lithium
molecular weight
group
carborane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2008525230A
Other languages
English (en)
Japanese (ja)
Other versions
JP2009503243A5 (https=
Inventor
ジョセフ マイクル,
カメシュ ヴャカラナム,
ステファニー コルベ,
Original Assignee
ザ リージェンツ オブ ザ ユニヴァーシティー オブ コロラド, ア ボディー コーポレイト
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ザ リージェンツ オブ ザ ユニヴァーシティー オブ コロラド, ア ボディー コーポレイト filed Critical ザ リージェンツ オブ ザ ユニヴァーシティー オブ コロラド, ア ボディー コーポレイト
Publication of JP2009503243A publication Critical patent/JP2009503243A/ja
Publication of JP2009503243A5 publication Critical patent/JP2009503243A5/ja
Pending legal-status Critical Current

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/46Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals
    • C08F4/48Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals selected from lithium, rubidium, caesium or francium
    • C08F4/484Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals selected from lithium, rubidium, caesium or francium an alkali metal bound to a cyclic carbon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/08Butenes
    • C08F110/10Isobutene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/14Monomers containing five or more carbon atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polymerization Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
JP2008525230A 2005-08-04 2006-08-04 ラジカル重合用触媒 Pending JP2009503243A (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US70564805P 2005-08-04 2005-08-04
US74389606P 2006-03-29 2006-03-29
PCT/US2006/030470 WO2007016700A2 (en) 2005-08-04 2006-08-04 Catalysts for radical polymerization

Publications (2)

Publication Number Publication Date
JP2009503243A true JP2009503243A (ja) 2009-01-29
JP2009503243A5 JP2009503243A5 (https=) 2009-09-10

Family

ID=37709382

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2008525230A Pending JP2009503243A (ja) 2005-08-04 2006-08-04 ラジカル重合用触媒

Country Status (6)

Country Link
US (2) US7737234B2 (https=)
EP (1) EP1915400A4 (https=)
JP (1) JP2009503243A (https=)
KR (1) KR20080064801A (https=)
CA (1) CA2618051A1 (https=)
WO (1) WO2007016700A2 (https=)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2022530670A (ja) * 2019-04-30 2022-06-30 ダウ グローバル テクノロジーズ エルエルシー アルケン官能化活性化剤

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20080064801A (ko) * 2005-08-04 2008-07-09 더 리젠츠 오브 더 유니버시티 오브 콜로라도, 어 바디 코포레이트 라디칼 중합 촉매
ATE534675T1 (de) * 2007-04-27 2011-12-15 Basf Se Verfahren zur herstellung von en-addukten mittels mikrowellenstrahlung
US8503539B2 (en) * 2010-02-26 2013-08-06 Bao Tran High definition personal computer (PC) cam
KR20160045702A (ko) 2013-08-22 2016-04-27 헨켈 아이피 앤드 홀딩 게엠베하 높은 올레핀 함량을 갖는 높은 분자량의 중합체
WO2017139572A1 (en) 2016-02-11 2017-08-17 Henkel IP & Holding GmbH Olefin-acrylate copolymers with pendant hydroxyl functionality and use thereof
EP3414270B1 (en) 2016-02-11 2022-09-14 Henkel AG & Co. KGaA Olefin-acrylate copolymers with pendant hydroxyl functionality and use thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08114916A (ja) * 1994-10-13 1996-05-07 Konica Corp 平版印刷版作成用感光性材料及び平版印刷版の作成方法
JPH09500921A (ja) * 1993-07-23 1997-01-28 ミネソタ マイニング アンド マニュファクチャリング カンパニー 重合用触媒および開始剤
JP2001518883A (ja) * 1997-04-03 2001-10-16 コロラド ステート ユニバーシティ リサーチ ファンデーション ポリハロゲン化モノヘテロボランアニオン組成物
JP2006523766A (ja) * 2003-04-17 2006-10-19 ザ ユニバーシティ オブ アクロン ビス(ボラン)共開始剤を使用する、炭化水素媒体中でのi−ブテンの重合

Family Cites Families (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2531196A (en) * 1942-10-20 1950-11-21 Du Pont Vinyl polymers and process for producing the same
US2534095A (en) * 1948-03-31 1950-12-12 Standard Oil Dev Co Hydrocarbon copolymers and use thereof as lube oil additive
US3109031A (en) 1962-04-05 1963-10-29 Olin Mathieson Organoboron polymers and process of making same
NL291450A (https=) * 1962-04-13
US3816380A (en) * 1971-06-18 1974-06-11 S Reed Telechelic copolymers of dienes and polymerizable ferrocene or carborane compounds
US4046745A (en) * 1975-10-24 1977-09-06 Phillips Petroleum Company Preparation of functional polymers
US4082585A (en) * 1976-05-27 1978-04-04 Western Electric Company, Inc. Insulating tinsel conductors
US4374235A (en) * 1981-02-17 1983-02-15 Ashland Oil, Inc. Anhydride containing polymers derived from alkenyl succinic anhydride
DE3108100A1 (de) * 1981-03-04 1982-09-16 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von copolymerisaten des maleinsaeureanhydrids
US5191052A (en) * 1985-06-21 1993-03-02 Exxon Chemical Patents Inc. Copolymers of ethylene and 1,3-butadiene
US4751276A (en) * 1986-12-24 1988-06-14 Exxon Research And Engineering Company Method for preparing functional alpha-olefin polymers and copolymers
US5198401A (en) * 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5173464A (en) * 1990-06-11 1992-12-22 Pettijohn Ted M Olefin polymerization
US5317058A (en) * 1992-04-17 1994-05-31 Hughes Aircraft Company Microwave-absorbing materials containing polar icosahedral molecular units and methods of making the same
US5688887A (en) * 1992-05-26 1997-11-18 Amoco Corporation Reactive, low molecular weight, viscous poly(1-olefins) and copoly(1-olefins) and their method of manufacture
US5739073A (en) * 1993-06-02 1998-04-14 Fina Technology, Inc. Addition of lithium compounds to ziegler-natta catalysts for increased molecular weight in polyolefins
US5504048A (en) * 1993-06-02 1996-04-02 Fina Technology, Inc. Addition of lithium compounds to Ziegler-Natta catalysts for increased molecular weight in polyolefins
US6008307A (en) * 1994-04-28 1999-12-28 Exxon Chemical Patents Inc Process for producing olefin polymers using cationic catalysts
US5731470A (en) * 1995-04-05 1998-03-24 Board Of Regents Of The University Of Colorado Weakly nucleophilic anions
US5807937A (en) * 1995-11-15 1998-09-15 Carnegie Mellon University Processes based on atom (or group) transfer radical polymerization and novel (co) polymers having useful structures and properties
US6121038A (en) * 1998-06-26 2000-09-19 Kirschner; Leon Method for pre-emptive potential in remediation of oil spills
US6265504B1 (en) * 1999-09-22 2001-07-24 Equistar Chemicals, Lp Preparation of ultra-high-molecular-weight polyethylene
FR2799468B1 (fr) * 1999-10-12 2006-04-28 Michelin Soc Tech Systeme catalytique utilisable pour la copolymerisation de l'ethylene et d'un diene conjugue, procede de preparation de ce systeme catalytique et d'un copolymere d'ethylene et d'un diene conjugue
US6828268B1 (en) * 1999-11-05 2004-12-07 Phillips Petroleum Company Polymerization catalyst systems and processes using alkyl lithium compounds as a cocatalyst
MXPA02011836A (es) 2000-05-31 2003-05-14 Du Pont Catalizadores para la polimerizacion de olefinas.
WO2002079210A2 (en) 2001-03-30 2002-10-10 The Board Of Regents Of The University And Community College System Of Nevada On Behalf Of The University Of Nevada, Reno Method for preparation of carborane anions
US6713582B2 (en) 2001-12-14 2004-03-30 Uniroyal Chemical Company, Inc. Process for the oligomerization of α-olefins having low unsaturation, the resulting polymers, and lubricants containing same
DE10162567A1 (de) * 2001-12-19 2003-07-03 Basf Ag Polyisobutene und Polyisobutenderivate für Schmierstoffzusammensetzungen
US6559251B1 (en) * 2002-08-02 2003-05-06 Equistar Chemicals, Lp Process for making low-density polyolefins
US6693155B1 (en) * 2003-03-05 2004-02-17 Equistar Chemicals, Lp Propylene polymerization process
US7202317B2 (en) * 2003-04-17 2007-04-10 The University Of Akron Polymerization of i-butene in hydrocarbon media using bis(borane) co-initiators
JP4567000B2 (ja) 2003-05-28 2010-10-20 オーバーン ユニバーシティ 可塑剤フリーのコポリマーを含むイオン検出センサー
KR20080064801A (ko) * 2005-08-04 2008-07-09 더 리젠츠 오브 더 유니버시티 오브 콜로라도, 어 바디 코포레이트 라디칼 중합 촉매
US20070294936A1 (en) * 2006-06-23 2007-12-27 Afton Chemical Corporation Method For Producing Polyolefinic Amines and compositions Containing Same

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09500921A (ja) * 1993-07-23 1997-01-28 ミネソタ マイニング アンド マニュファクチャリング カンパニー 重合用触媒および開始剤
JPH08114916A (ja) * 1994-10-13 1996-05-07 Konica Corp 平版印刷版作成用感光性材料及び平版印刷版の作成方法
JP2001518883A (ja) * 1997-04-03 2001-10-16 コロラド ステート ユニバーシティ リサーチ ファンデーション ポリハロゲン化モノヘテロボランアニオン組成物
JP2006523766A (ja) * 2003-04-17 2006-10-19 ザ ユニバーシティ オブ アクロン ビス(ボラン)共開始剤を使用する、炭化水素媒体中でのi−ブテンの重合

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2022530670A (ja) * 2019-04-30 2022-06-30 ダウ グローバル テクノロジーズ エルエルシー アルケン官能化活性化剤
JP7689081B2 (ja) 2019-04-30 2025-06-05 ダウ グローバル テクノロジーズ エルエルシー アルケン官能化活性化剤

Also Published As

Publication number Publication date
US20090069520A1 (en) 2009-03-12
WO2007016700A3 (en) 2009-04-30
US20090018298A1 (en) 2009-01-15
EP1915400A4 (en) 2009-12-16
US7737234B2 (en) 2010-06-15
CA2618051A1 (en) 2007-02-08
KR20080064801A (ko) 2008-07-09
EP1915400A2 (en) 2008-04-30
WO2007016700A2 (en) 2007-02-08

Similar Documents

Publication Publication Date Title
US20090018298A1 (en) Copolymers formed by radical polymerization
JP3119305B2 (ja) 触媒、これら触媒の製法、およびこれら触媒の使用法
Vaughan et al. Enhancing molecularly imprinted polymer binding properties via controlled/living radical polymerization and reaction analysis
CA3014685C (en) Process for preparing high-reactivity isobutene homo- or copolymers
Groux et al. Insertion of acrylonitrile into palladium methyl bonds in neutral and anionic Pd (II) complexes
CA2577728C (en) Method for preparation of polyolefins containing exo-olefin chain ends
ES2732887T3 (es) Sistema de iniciación de polimerización y método para producir polibutenos muy reactivos
EP0260838A1 (en) Titanium, zirconium and hafnium enolates as initiators in the polymerization of acrylic monomers to "living" polymers
JP2014173091A (ja) 重合開始系および高反応性オレフィン機能性高分子の製造方法
Wu et al. Cationic polymerization of isobutyl vinyl ether in an imidazole-based ionic liquid: characteristics and mechanism
Vyakaranam et al. Air-Initiated Radical Polymerization of Lithium Salts of ω-(Undecamethylcarba-c loso-dodecaboran-1 ‘-yl) alk-1-enes, CH2 CH (CH2) n-2C (BMe) 11-Li+
KR20080078654A (ko) 금속 함유 촉매 착물을 이용한 고 반응성 이소부틸렌단독중합체 또는 공중합체의 제조 방법
Ali et al. To overcome the unconventional polymerization behavior of single-site symmetrical metallocene catalyst in the presence of borate
Wang et al. Copolymerization of ethylene with norbornene catalyzed by cationic rare earth metal fluorenyl functionalized N-heterocyclic carbene complexes
EP0058104B1 (fr) Nouvelles associations des bases résultant de la combinaison d'un alkyl ou aryl lithien avec un amidure ou hydrure alcalin - procédé de polymérisation les utilisant et produit obtenu
Chen et al. Controlled or high-speed group transfer polymerization by silyl ketene acetals without catalyst
EP4251658B1 (fr) Co-catalyseur comprenant plusieurs liaisons carbone magnésium
CN1273498C (zh) 制备高分子量异丁烯聚合物的方法
Zhao et al. 1-Hexene homopolymerization and copolymerization with polar ω-halo-α-alkenes by (benz) imidazolin-2-iminato scandium and yttrium complexes
Rodrigues et al. (t-BuC5H4) 3Nd: A triscyclopentadienyl rare earth compound as non-classical isoprene polymerization pre-catalyst
Diebl et al. Synthesis and application of molybdenum (III) complexes bearing weakly coordinating anions as catalysts of isobutylene polymerization
JP2022522794A (ja) 有機ボレート系触媒、これを用いたイソブテンオリゴマーの製造方法およびこれにより製造されたイソブテンオリゴマー
KR20200123088A (ko) 올레핀의 양이온성 중합을 위한 개시제 시스템
KR20060056889A (ko) 탄화수소 매개물에서의 비스(보란) 공개시제를 이용한이소부텐의 중합
Hadjikyriacou et al. Coupling and linking reactions of living polyisobutylene by allylsilanes

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20090722

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20090722

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20100323

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20120727

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20120731

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20130108