JP2009197149A - ディップ成形用共重合体ラテックス、ディップ成形用組成物およびディップ成形品 - Google Patents
ディップ成形用共重合体ラテックス、ディップ成形用組成物およびディップ成形品 Download PDFInfo
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- JP2009197149A JP2009197149A JP2008041032A JP2008041032A JP2009197149A JP 2009197149 A JP2009197149 A JP 2009197149A JP 2008041032 A JP2008041032 A JP 2008041032A JP 2008041032 A JP2008041032 A JP 2008041032A JP 2009197149 A JP2009197149 A JP 2009197149A
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- Prior art keywords
- dip
- copolymer latex
- polymerization
- weight
- latex
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- 229920000126 latex Polymers 0.000 title claims abstract description 78
- 239000004816 latex Substances 0.000 title claims abstract description 77
- 229920001577 copolymer Polymers 0.000 title claims abstract description 58
- 239000000203 mixture Substances 0.000 title claims abstract description 30
- 239000000178 monomer Substances 0.000 claims abstract description 50
- 239000002253 acid Substances 0.000 claims abstract description 34
- 239000002245 particle Substances 0.000 claims abstract description 29
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims abstract description 14
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000007720 emulsion polymerization reaction Methods 0.000 claims abstract description 4
- 238000000465 moulding Methods 0.000 claims description 36
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 11
- 238000006116 polymerization reaction Methods 0.000 abstract description 68
- 150000003839 salts Chemical class 0.000 abstract description 10
- 230000000704 physical effect Effects 0.000 abstract description 9
- 150000001735 carboxylic acids Chemical class 0.000 abstract description 2
- 150000007513 acids Chemical group 0.000 abstract 2
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 54
- 239000000047 product Substances 0.000 description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 20
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 18
- 235000011118 potassium hydroxide Nutrition 0.000 description 18
- 239000000243 solution Substances 0.000 description 17
- -1 diene compounds Chemical class 0.000 description 16
- YAJYJWXEWKRTPO-UHFFFAOYSA-N 2,3,3,4,4,5-hexamethylhexane-2-thiol Chemical compound CC(C)C(C)(C)C(C)(C)C(C)(C)S YAJYJWXEWKRTPO-UHFFFAOYSA-N 0.000 description 15
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 15
- 238000000034 method Methods 0.000 description 15
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 15
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 13
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- 150000001875 compounds Chemical class 0.000 description 11
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- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 9
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- 230000000052 comparative effect Effects 0.000 description 9
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- 238000002360 preparation method Methods 0.000 description 9
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- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 8
- FVCOIAYSJZGECG-UHFFFAOYSA-N diethylhydroxylamine Chemical compound CCN(O)CC FVCOIAYSJZGECG-UHFFFAOYSA-N 0.000 description 8
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- 239000007864 aqueous solution Substances 0.000 description 5
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- 239000003505 polymerization initiator Substances 0.000 description 5
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 5
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 5
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- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 4
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000000701 coagulant Substances 0.000 description 4
- 229920006173 natural rubber latex Polymers 0.000 description 4
- XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 3
- 159000000007 calcium salts Chemical class 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 235000013305 food Nutrition 0.000 description 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
- 239000002736 nonionic surfactant Substances 0.000 description 3
- KZCOBXFFBQJQHH-UHFFFAOYSA-N octane-1-thiol Chemical compound CCCCCCCCS KZCOBXFFBQJQHH-UHFFFAOYSA-N 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 229920006174 synthetic rubber latex Polymers 0.000 description 3
- ZOKCNEIWFQCSCM-UHFFFAOYSA-N (2-methyl-4-phenylpent-4-en-2-yl)benzene Chemical compound C=1C=CC=CC=1C(C)(C)CC(=C)C1=CC=CC=C1 ZOKCNEIWFQCSCM-UHFFFAOYSA-N 0.000 description 2
- PMBXCGGQNSVESQ-UHFFFAOYSA-N 1-Hexanethiol Chemical compound CCCCCCS PMBXCGGQNSVESQ-UHFFFAOYSA-N 0.000 description 2
- CTMHWPIWNRWQEG-UHFFFAOYSA-N 1-methylcyclohexene Chemical compound CC1=CCCCC1 CTMHWPIWNRWQEG-UHFFFAOYSA-N 0.000 description 2
- SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 description 2
- BYLSIPUARIZAHZ-UHFFFAOYSA-N 2,4,6-tris(1-phenylethyl)phenol Chemical compound C=1C(C(C)C=2C=CC=CC=2)=C(O)C(C(C)C=2C=CC=CC=2)=CC=1C(C)C1=CC=CC=C1 BYLSIPUARIZAHZ-UHFFFAOYSA-N 0.000 description 2
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 2
- FSWCCQWDVGZMRD-UHFFFAOYSA-N 4-methylcyclohexene Chemical compound CC1CCC=CC1 FSWCCQWDVGZMRD-UHFFFAOYSA-N 0.000 description 2
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
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- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
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- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
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- 229910001870 ammonium persulfate Inorganic materials 0.000 description 2
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- 230000003712 anti-aging effect Effects 0.000 description 2
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- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 2
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- 239000012986 chain transfer agent Substances 0.000 description 2
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- 238000007334 copolymerization reaction Methods 0.000 description 2
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Landscapes
- Compositions Of Macromolecular Compounds (AREA)
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Cited By (7)
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| JP2011132355A (ja) * | 2009-12-24 | 2011-07-07 | Nippon Zeon Co Ltd | 接着剤用ニトリルゴムラテックスおよびその製造方法 |
| CN103483499A (zh) * | 2013-09-27 | 2014-01-01 | 安庆华兰科技有限公司 | 一种工业及医疗检查手套浸渍用羧基丁腈胶乳的制备方法 |
| JP2015191876A (ja) * | 2014-03-31 | 2015-11-02 | 日本エイアンドエル株式会社 | 電池電極用バインダーおよび電池電極用組成物 |
| JPWO2015147010A1 (ja) * | 2014-03-28 | 2017-04-13 | 日本ゼオン株式会社 | ディップ成形用組成物及びディップ成形品 |
| JP2018505916A (ja) * | 2014-12-12 | 2018-03-01 | シントマー スンディリアン ブルハド | 浸漬成形用途のためのポリマーラテックス組成物 |
| WO2024048587A1 (ja) * | 2022-08-30 | 2024-03-07 | 日本エイアンドエル株式会社 | 二酸化炭素分離膜用共重合体ラテックス、二酸化炭素分離膜用組成物、二酸化炭素分離膜、及び二酸化炭素分離膜の製造方法 |
| WO2024070750A1 (ja) * | 2022-09-26 | 2024-04-04 | 住友精化株式会社 | 浸漬成形体の製造方法および浸漬成形体 |
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| JP2011132355A (ja) * | 2009-12-24 | 2011-07-07 | Nippon Zeon Co Ltd | 接着剤用ニトリルゴムラテックスおよびその製造方法 |
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| JP2018505916A (ja) * | 2014-12-12 | 2018-03-01 | シントマー スンディリアン ブルハド | 浸漬成形用途のためのポリマーラテックス組成物 |
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| WO2024048587A1 (ja) * | 2022-08-30 | 2024-03-07 | 日本エイアンドエル株式会社 | 二酸化炭素分離膜用共重合体ラテックス、二酸化炭素分離膜用組成物、二酸化炭素分離膜、及び二酸化炭素分離膜の製造方法 |
| JP2024033559A (ja) * | 2022-08-30 | 2024-03-13 | 日本エイアンドエル株式会社 | 二酸化炭素分離膜用共重合体ラテックス、二酸化炭素分離膜用組成物、二酸化炭素分離膜、及び二酸化炭素分離膜の製造方法 |
| JP7713917B2 (ja) | 2022-08-30 | 2025-07-28 | 日本エイアンドエル株式会社 | 二酸化炭素分離膜用共重合体ラテックス、二酸化炭素分離膜用組成物、二酸化炭素分離膜、及び二酸化炭素分離膜の製造方法 |
| WO2024070750A1 (ja) * | 2022-09-26 | 2024-04-04 | 住友精化株式会社 | 浸漬成形体の製造方法および浸漬成形体 |
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