JP2008511739A - 水性ベースコート及び溶媒性ベースコートの両方と適合性のあるクリアコート組成物 - Google Patents
水性ベースコート及び溶媒性ベースコートの両方と適合性のあるクリアコート組成物 Download PDFInfo
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- JP2008511739A JP2008511739A JP2007530315A JP2007530315A JP2008511739A JP 2008511739 A JP2008511739 A JP 2008511739A JP 2007530315 A JP2007530315 A JP 2007530315A JP 2007530315 A JP2007530315 A JP 2007530315A JP 2008511739 A JP2008511739 A JP 2008511739A
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- Japan
- Prior art keywords
- composition
- weight
- component
- binder
- silane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
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- 239000000203 mixture Substances 0.000 title claims abstract description 94
- 239000002904 solvent Substances 0.000 title abstract description 29
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims abstract description 65
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 57
- 229910000077 silane Inorganic materials 0.000 claims abstract description 57
- 239000011230 binding agent Substances 0.000 claims abstract description 38
- 239000008199 coating composition Substances 0.000 claims abstract description 38
- 239000000463 material Substances 0.000 claims abstract description 34
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- 239000011248 coating agent Substances 0.000 claims abstract description 25
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- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 13
- 229920000642 polymer Polymers 0.000 claims description 61
- 239000000178 monomer Substances 0.000 claims description 60
- -1 hydroxyalkyl acrylate Chemical compound 0.000 claims description 29
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 27
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- 125000000217 alkyl group Chemical group 0.000 claims description 14
- 125000004432 carbon atom Chemical group C* 0.000 claims description 12
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical group C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 claims description 8
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- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical class O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 claims description 6
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- HDPNBNXLBDFELL-UHFFFAOYSA-N 1,1,1-trimethoxyethane Chemical compound COC(C)(OC)OC HDPNBNXLBDFELL-UHFFFAOYSA-N 0.000 claims description 4
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- GKASDNZWUGIAMG-UHFFFAOYSA-N triethyl orthoformate Chemical compound CCOC(OCC)OCC GKASDNZWUGIAMG-UHFFFAOYSA-N 0.000 claims description 2
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- 238000012360 testing method Methods 0.000 description 9
- RUMACXVDVNRZJZ-UHFFFAOYSA-N 2-methylpropyl 2-methylprop-2-enoate Chemical compound CC(C)COC(=O)C(C)=C RUMACXVDVNRZJZ-UHFFFAOYSA-N 0.000 description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 8
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- 238000009472 formulation Methods 0.000 description 8
- 239000005056 polyisocyanate Substances 0.000 description 8
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- 238000004132 cross linking Methods 0.000 description 7
- 239000003431 cross linking reagent Substances 0.000 description 7
- 239000010410 layer Substances 0.000 description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- 125000005250 alkyl acrylate group Chemical group 0.000 description 6
- 150000001412 amines Chemical class 0.000 description 6
- 239000006185 dispersion Substances 0.000 description 6
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 6
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 5
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- 239000011324 bead Substances 0.000 description 5
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- 150000004756 silanes Chemical class 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 4
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 4
- 239000004971 Cross linker Substances 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 4
- 125000001931 aliphatic group Chemical group 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000007795 chemical reaction product Substances 0.000 description 4
- 125000000753 cycloalkyl group Chemical group 0.000 description 4
- 125000001841 imino group Chemical group [H]N=* 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- 238000010998 test method Methods 0.000 description 4
- APAUNQLFVGBQQW-UHFFFAOYSA-N (1,2,2-trimethylcyclohexyl) 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1(C)CCCCC1(C)C APAUNQLFVGBQQW-UHFFFAOYSA-N 0.000 description 3
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- IEVADDDOVGMCSI-UHFFFAOYSA-N 2-hydroxybutyl 2-methylprop-2-enoate Chemical compound CCC(O)COC(=O)C(C)=C IEVADDDOVGMCSI-UHFFFAOYSA-N 0.000 description 3
- GNSFRPWPOGYVLO-UHFFFAOYSA-N 3-hydroxypropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCO GNSFRPWPOGYVLO-UHFFFAOYSA-N 0.000 description 3
- NDWUBGAGUCISDV-UHFFFAOYSA-N 4-hydroxybutyl prop-2-enoate Chemical compound OCCCCOC(=O)C=C NDWUBGAGUCISDV-UHFFFAOYSA-N 0.000 description 3
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- 235000003385 Diospyros ebenum Nutrition 0.000 description 3
- 241000792913 Ebenaceae Species 0.000 description 3
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- 229910000831 Steel Inorganic materials 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
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- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
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- 125000005913 (C3-C6) cycloalkyl group Chemical group 0.000 description 2
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- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 2
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
- C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/2805—Compounds having only one group containing active hydrogen
- C08G18/2815—Monohydroxy compounds
- C08G18/282—Alkanols, cycloalkanols or arylalkanols including terpenealcohols
- C08G18/2825—Alkanols, cycloalkanols or arylalkanols including terpenealcohols having at least 6 carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D201/00—Coating compositions based on unspecified macromolecular compounds
- C09D201/02—Coating compositions based on unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups
- C09D201/025—Coating compositions based on unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups containing nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D201/00—Coating compositions based on unspecified macromolecular compounds
- C09D201/02—Coating compositions based on unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups
- C09D201/10—Coating compositions based on unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups containing hydrolysable silane groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/929,239 US7838078B2 (en) | 2004-08-30 | 2004-08-30 | Clearcoat composition compatible with both waterborne and solventborne basecoats |
| PCT/US2005/030985 WO2006026669A2 (en) | 2004-08-30 | 2005-08-30 | Clearcoat composition compatible with both waterborne and solventborne basecoats |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2008511739A true JP2008511739A (ja) | 2008-04-17 |
| JP2008511739A5 JP2008511739A5 (enExample) | 2008-10-16 |
Family
ID=35788105
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2007530315A Abandoned JP2008511739A (ja) | 2004-08-30 | 2005-08-30 | 水性ベースコート及び溶媒性ベースコートの両方と適合性のあるクリアコート組成物 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US7838078B2 (enExample) |
| EP (1) | EP1784466B1 (enExample) |
| JP (1) | JP2008511739A (enExample) |
| CA (1) | CA2576815C (enExample) |
| DE (1) | DE602005011306D1 (enExample) |
| MX (1) | MX2007002181A (enExample) |
| WO (1) | WO2006026669A2 (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011508005A (ja) * | 2007-12-20 | 2011-03-10 | ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツング | 優れたｍｖｓｓ接着性を得るためのコーティング組成物 |
| JP2013519767A (ja) * | 2010-02-16 | 2013-05-30 | ビーエーエスエフ ソシエタス・ヨーロピア | シリル化アミノプラスト樹脂 |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8318849B2 (en) * | 2006-04-21 | 2012-11-27 | Basf Coatings Gmbh | High solids nonaqueous dispersion clearcoats |
| US7772304B2 (en) * | 2006-11-17 | 2010-08-10 | Basf Corporation | Plasticizing component and a curable coating composition including the same |
| WO2008066893A1 (en) * | 2006-11-29 | 2008-06-05 | Basf Corporation | Clearcoating composition with unblocked acid catalyst |
| CA2675576A1 (en) * | 2007-02-13 | 2008-08-21 | Basf Corporation | Coating system for achieving excellent mvss adhesion |
| US20090017199A1 (en) * | 2007-07-10 | 2009-01-15 | Alex Kotyakov | Clear-coat scratch repair composition and refinishing process |
| WO2011042377A1 (de) | 2009-10-09 | 2011-04-14 | Basf Se | Silylierte melamin-formaldehyd-harze |
| US8309649B2 (en) | 2010-02-16 | 2012-11-13 | Basf Se | Silylated amino resins |
| WO2011150164A1 (en) * | 2010-05-27 | 2011-12-01 | E. I. Du Pont De Nemours And Company | Clearcoat composition and method of end of line repair using the clearcoat composition |
| US8513321B2 (en) | 2010-11-05 | 2013-08-20 | Ppg Industries Ohio, Inc. | Dual cure coating compositions, methods of coating a substrate, and related coated substrates |
| US8901198B2 (en) | 2010-11-05 | 2014-12-02 | Ppg Industries Ohio, Inc. | UV-curable coating compositions, multi-component composite coatings, and related coated substrates |
| US20150056394A1 (en) * | 2013-08-21 | 2015-02-26 | Nd Industries, Inc. | Coating Composition and Anti-Spatter Coating Formed Therefrom |
| EP4561831A1 (en) * | 2022-07-29 | 2025-06-04 | Danimer IPCo, LLC | Aqueous mixtures of novel poly(hydroxyalkanoates) |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4147688A (en) * | 1975-03-19 | 1979-04-03 | Ppg Industries, Inc. | Method of preparing dispersions of gelled polymeric microparticles and products produced thereby |
| US4075141A (en) * | 1975-10-09 | 1978-02-21 | Ppg Industries, Inc. | Carboxylic acid amide interpolymer-based coating compositions |
| GB1588976A (en) * | 1977-04-25 | 1981-05-07 | Ici Ltd | Coating composition containing metallic pigmentation |
| US4415681A (en) * | 1980-10-23 | 1983-11-15 | Ford Motor Company | Stabilized crosslinked dispersion |
| FR2565233B1 (fr) * | 1984-05-30 | 1986-09-12 | Rhone Poulenc Rech | Copolymere greffe de silicone et de polylactone lie par une liaison urethanne |
| US4591533A (en) * | 1985-06-03 | 1986-05-27 | E. I. Du Pont De Nemours And Company | Coating composition of an acrylic polymer, a dispersed acrylic polymer and an alkylated melamine crosslinking agent |
| MX9101079A (es) * | 1990-09-17 | 1992-05-04 | Du Pont | Composicion de revestimiento y proceso para revestir un substrato con la misma |
| US5162426A (en) * | 1990-12-17 | 1992-11-10 | E. I. Du Pont De Nemours And Company | Coatings comprising dispersed polymers with silane crosslinking |
| US5283084A (en) * | 1992-05-08 | 1994-02-01 | Basf Corporation | Process for making wrinkle-free coating using solventborne clearcoat composition over waterborne basecoat composition |
| DE19602555A1 (de) * | 1996-01-25 | 1997-08-07 | Basf Lacke & Farben | Wäßrige Bindemittellösungen und -dispersionen |
| US5747590A (en) * | 1996-12-04 | 1998-05-05 | E. I. Du Pont De Nemours And Company | Acrylic-melamine-functionalized oligomer coating composition |
| DE19730890C2 (de) * | 1997-07-18 | 2001-07-05 | Basf Coatings Ag | Verfahren zur Herstellung mehrschichtiger Überzüge und mit diesen beschichtete Substrate |
| US5962574A (en) * | 1997-07-25 | 1999-10-05 | Bee Chemical Company | Wet-on-wet primer with low film build U.V. light protection |
| US6080816A (en) * | 1997-11-10 | 2000-06-27 | E. I. Du Pont De Nemours And Company | Coatings that contain reactive silicon oligomers |
| US6239212B1 (en) | 1998-10-23 | 2001-05-29 | Basf Corporation. | Clearcoat composition and method for intercoat adhesion |
| WO2000055229A1 (en) | 1999-03-17 | 2000-09-21 | E.I. Du Pont De Nemours And Company | High solids acid etch resistant clear coating composition |
| US6391968B1 (en) * | 1999-12-15 | 2002-05-21 | Basf Corporation | Curable coating compositions containing carbamate functional polymers and carbamate functional reactive additives |
| US6451930B1 (en) * | 2000-03-14 | 2002-09-17 | Ppg Industries Ohio, Inc. | Topcoat with improved adhesive qualities |
| US6376016B1 (en) * | 2000-06-14 | 2002-04-23 | Ford Global Tech., Inc. | Method for painting a vehicle with at least two colors |
| US6592999B1 (en) * | 2001-07-31 | 2003-07-15 | Ppg Industries Ohio, Inc. | Multi-layer composites formed from compositions having improved adhesion, coating compositions, and methods related thereto |
| US6767642B2 (en) * | 2002-03-11 | 2004-07-27 | E. I. Du Pont Nemours And Company | Preparation and use of crosslinkable acrylosilane polymers containing vinyl silane monomers |
| US20040157980A1 (en) * | 2003-02-06 | 2004-08-12 | Fox Michael D. | Coating composition with improved hardness, mar and etch resistance |
| US20050074617A1 (en) | 2003-10-02 | 2005-04-07 | Jun Lin | Clearcoat composition having both windshield sealant and recoat adhesion |
-
2004
- 2004-08-30 US US10/929,239 patent/US7838078B2/en active Active
-
2005
- 2005-08-30 DE DE602005011306T patent/DE602005011306D1/de not_active Expired - Lifetime
- 2005-08-30 WO PCT/US2005/030985 patent/WO2006026669A2/en not_active Ceased
- 2005-08-30 MX MX2007002181A patent/MX2007002181A/es active IP Right Grant
- 2005-08-30 EP EP05793844A patent/EP1784466B1/en not_active Expired - Lifetime
- 2005-08-30 CA CA2576815A patent/CA2576815C/en not_active Expired - Fee Related
- 2005-08-30 JP JP2007530315A patent/JP2008511739A/ja not_active Abandoned
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011508005A (ja) * | 2007-12-20 | 2011-03-10 | ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツング | 優れたｍｖｓｓ接着性を得るためのコーティング組成物 |
| JP2013519767A (ja) * | 2010-02-16 | 2013-05-30 | ビーエーエスエフ ソシエタス・ヨーロピア | シリル化アミノプラスト樹脂 |
Also Published As
| Publication number | Publication date |
|---|---|
| MX2007002181A (es) | 2007-04-02 |
| EP1784466B1 (en) | 2008-11-26 |
| DE602005011306D1 (de) | 2009-01-08 |
| WO2006026669A3 (en) | 2006-05-26 |
| CA2576815C (en) | 2012-10-30 |
| US7838078B2 (en) | 2010-11-23 |
| CA2576815A1 (en) | 2006-03-09 |
| EP1784466A2 (en) | 2007-05-16 |
| WO2006026669A2 (en) | 2006-03-09 |
| US20060047036A1 (en) | 2006-03-02 |
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