JP2008083508A - ネガ型着色感光性組成物 - Google Patents
ネガ型着色感光性組成物 Download PDFInfo
- Publication number
- JP2008083508A JP2008083508A JP2006264605A JP2006264605A JP2008083508A JP 2008083508 A JP2008083508 A JP 2008083508A JP 2006264605 A JP2006264605 A JP 2006264605A JP 2006264605 A JP2006264605 A JP 2006264605A JP 2008083508 A JP2008083508 A JP 2008083508A
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- JP
- Japan
- Prior art keywords
- photosensitive composition
- acrylate
- color filter
- methacrylate
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000000203 mixture Substances 0.000 title claims abstract description 45
- 239000000178 monomer Substances 0.000 claims abstract description 42
- 229920000642 polymer Polymers 0.000 claims abstract description 22
- 239000011230 binding agent Substances 0.000 claims abstract description 18
- 239000003960 organic solvent Substances 0.000 claims abstract description 13
- 239000003999 initiator Substances 0.000 claims abstract description 12
- 238000000034 method Methods 0.000 claims description 20
- 239000004973 liquid crystal related substance Substances 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 5
- 238000003384 imaging method Methods 0.000 claims description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- 238000001459 lithography Methods 0.000 claims description 2
- -1 acrylic ester Chemical class 0.000 abstract description 17
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract description 14
- 239000003513 alkali Substances 0.000 abstract description 14
- 230000035945 sensitivity Effects 0.000 abstract description 7
- 230000006866 deterioration Effects 0.000 abstract description 5
- 230000002950 deficient Effects 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 description 51
- 239000000049 pigment Substances 0.000 description 33
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 27
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 26
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 25
- 229940048053 acrylate Drugs 0.000 description 22
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 20
- 239000000975 dye Substances 0.000 description 17
- 238000004040 coloring Methods 0.000 description 15
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 14
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 14
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 description 14
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 13
- 239000004793 Polystyrene Substances 0.000 description 12
- AOJOEFVRHOZDFN-UHFFFAOYSA-N benzyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC1=CC=CC=C1 AOJOEFVRHOZDFN-UHFFFAOYSA-N 0.000 description 12
- 229920002223 polystyrene Polymers 0.000 description 12
- 239000004094 surface-active agent Substances 0.000 description 12
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 11
- 239000004926 polymethyl methacrylate Substances 0.000 description 11
- 239000011347 resin Substances 0.000 description 11
- 229920005989 resin Polymers 0.000 description 11
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 10
- 239000006185 dispersion Substances 0.000 description 10
- 239000000758 substrate Substances 0.000 description 9
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 8
- GCTPMLUUWLLESL-UHFFFAOYSA-N benzyl prop-2-enoate Chemical compound C=CC(=O)OCC1=CC=CC=C1 GCTPMLUUWLLESL-UHFFFAOYSA-N 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 239000002904 solvent Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 238000011161 development Methods 0.000 description 7
- BTJPUDCSZVCXFQ-UHFFFAOYSA-N 2,4-diethylthioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC(CC)=CC(CC)=C3SC2=C1 BTJPUDCSZVCXFQ-UHFFFAOYSA-N 0.000 description 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- VYHBFRJRBHMIQZ-UHFFFAOYSA-N bis[4-(diethylamino)phenyl]methanone Chemical compound C1=CC(N(CC)CC)=CC=C1C(=O)C1=CC=C(N(CC)CC)C=C1 VYHBFRJRBHMIQZ-UHFFFAOYSA-N 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000002270 dispersing agent Substances 0.000 description 5
- 235000011187 glycerol Nutrition 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- UHFFVFAKEGKNAQ-UHFFFAOYSA-N 2-benzyl-2-(dimethylamino)-1-(4-morpholin-4-ylphenyl)butan-1-one Chemical compound C=1C=C(N2CCOCC2)C=CC=1C(=O)C(CC)(N(C)C)CC1=CC=CC=C1 UHFFVFAKEGKNAQ-UHFFFAOYSA-N 0.000 description 4
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 4
- LWRBVKNFOYUCNP-UHFFFAOYSA-N 2-methyl-1-(4-methylsulfanylphenyl)-2-morpholin-4-ylpropan-1-one Chemical compound C1=CC(SC)=CC=C1C(=O)C(C)(C)N1CCOCC1 LWRBVKNFOYUCNP-UHFFFAOYSA-N 0.000 description 4
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 4
- 239000000981 basic dye Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- FGTYTUFKXYPTML-UHFFFAOYSA-N 2-benzoylbenzoic acid Chemical compound OC(=O)C1=CC=CC=C1C(=O)C1=CC=CC=C1 FGTYTUFKXYPTML-UHFFFAOYSA-N 0.000 description 3
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical class OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 3
- 238000004043 dyeing Methods 0.000 description 3
- 150000002170 ethers Chemical class 0.000 description 3
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 3
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 150000003254 radicals Chemical class 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 125000003866 trichloromethyl group Chemical group ClC(Cl)(Cl)* 0.000 description 3
- UAJRSHJHFRVGMG-UHFFFAOYSA-N 1-ethenyl-4-methoxybenzene Chemical compound COC1=CC=C(C=C)C=C1 UAJRSHJHFRVGMG-UHFFFAOYSA-N 0.000 description 2
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 2
- JESXATFQYMPTNL-UHFFFAOYSA-N 2-ethenylphenol Chemical compound OC1=CC=CC=C1C=C JESXATFQYMPTNL-UHFFFAOYSA-N 0.000 description 2
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 2
- QJPPPIFMLKUMEW-UHFFFAOYSA-N 2-ethyl-2-methyloctanoic acid Chemical compound CCCCCCC(C)(CC)C(O)=O QJPPPIFMLKUMEW-UHFFFAOYSA-N 0.000 description 2
- XMLYCEVDHLAQEL-UHFFFAOYSA-N 2-hydroxy-2-methyl-1-phenylpropan-1-one Chemical compound CC(C)(O)C(=O)C1=CC=CC=C1 XMLYCEVDHLAQEL-UHFFFAOYSA-N 0.000 description 2
- XLLIQLLCWZCATF-UHFFFAOYSA-N 2-methoxyethyl acetate Chemical compound COCCOC(C)=O XLLIQLLCWZCATF-UHFFFAOYSA-N 0.000 description 2
- JKTORXLUQLQJCM-UHFFFAOYSA-N 4-phosphonobutylphosphonic acid Chemical compound OP(O)(=O)CCCCP(O)(O)=O JKTORXLUQLQJCM-UHFFFAOYSA-N 0.000 description 2
- LPEKGGXMPWTOCB-UHFFFAOYSA-N 8beta-(2,3-epoxy-2-methylbutyryloxy)-14-acetoxytithifolin Natural products COC(=O)C(C)O LPEKGGXMPWTOCB-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 description 2
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- 239000000980 acid dye Substances 0.000 description 2
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- 230000001476 alcoholic effect Effects 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 150000008064 anhydrides Chemical class 0.000 description 2
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 2
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- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
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- 239000000982 direct dye Substances 0.000 description 2
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- ODQWQRRAPPTVAG-GZTJUZNOSA-N doxepin Chemical compound C1OC2=CC=CC=C2C(=C/CCN(C)C)/C2=CC=CC=C21 ODQWQRRAPPTVAG-GZTJUZNOSA-N 0.000 description 2
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- 229940057867 methyl lactate Drugs 0.000 description 2
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- HWDXVBHSFVZMLS-UHFFFAOYSA-N 1-(2-benzylphenyl)-2-hydroxy-2-phenylethanone Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1CC1=CC=CC=C1 HWDXVBHSFVZMLS-UHFFFAOYSA-N 0.000 description 1
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- YNSNJGRCQCDRDM-UHFFFAOYSA-N 1-chlorothioxanthen-9-one Chemical compound S1C2=CC=CC=C2C(=O)C2=C1C=CC=C2Cl YNSNJGRCQCDRDM-UHFFFAOYSA-N 0.000 description 1
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- LMAUULKNZLEMGN-UHFFFAOYSA-N 1-ethyl-3,5-dimethylbenzene Chemical compound CCC1=CC(C)=CC(C)=C1 LMAUULKNZLEMGN-UHFFFAOYSA-N 0.000 description 1
- DKTOWFDVEJQWPF-UHFFFAOYSA-N 1-ethylthioxanthen-9-one Chemical compound S1C2=CC=CC=C2C(=O)C2=C1C=CC=C2CC DKTOWFDVEJQWPF-UHFFFAOYSA-N 0.000 description 1
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Landscapes
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Abstract
【解決手段】バインダーポリマー、光重合性モノマーとして、(ポリ)エトキシ化された(ポリ)グリセリンの(メタ)アクリル酸エステル、色素、光重合開始剤、及び有機溶剤を含有するネガ型の着色感光性組成物を調製する。この着色感光性組成物を用いることにより、感度低下や現像性不良等によるスループットへの影響が小さく、残渣や密着性が良好で、それらにより高品質なカラーフイルターを得ることが出来る。
【選択図】なし
Description
本発明は、感度低下やアルカリ現像液への耐性劣化を引き起こすことなく、現像性や残渣を改善し、高品質なカラーフィルターを製造する方法の実現を目的とする。
(1)バインダーポリマー、光重合性モノマー、色素、光重合開始剤、有機溶剤を含有し、該光重合性モノマーが下記式(1)で表わされる化合物であることを特徴とするネガ型着色感光性組成物、
(2)(1)記載のネガ型着色感光性組成物を用い、リソグラフィー法によりパターニングされてなるカラーフィルター用着色硬化膜、
(3)(2)記載のカラーフィルター用着色硬化膜からなるカラーフイルター、
(4)(3)記載のカラーフィルターを装着してなる液晶表示装置、
(5)(3)記載のカラーフィルターを装着してなる固体撮像素子
に関する。
バインダーポリマーとしてメタクリル酸/ベンジルメタクリレート共重合体(20/80 重量比、重量平均分子量22,000)のプロピレングリコールモノメチルエーテルアセテート(以下 PGMEAと略記)20%溶液 20g、光重合性モノマーとしてGEA−3E 6g、光重合開始剤としてイルガキュアー369(2−ベンジル−2−ジメチルアミノ−1−(4−モルホリノフェニル)ーブタノン−1、チバ・スペシャルティ・ケミカルズ製) 1g、カヤキュアーDETX−S(2,4−ジエチルチオキサントン、日本化薬製)0.5g、EAB(4,4'−ビス(ジエチルアミノ)ベンゾフェノン、保土ヶ谷化学工業製)0.1g、顔料として赤色顔料分散液(C.I.ピグメントレッド177/C.I.ピグメントイエロー139/分散剤/PGMEA=14.2/3.6/5.3/76.9 重量比)50g、溶剤としてPGMEA 45gを混合し、赤色の本発明のネガ型着色感光性組成物を得た。
又、上記で得られたネガ型着色感光性組成物をシリコンウエーハー上に熱硬化性下地膜を形成した基板上に塗布し、80℃×100秒の条件でプレベークしたのち、露光による硬化後、界面活性剤を含有するアルカリ水溶液で現像し、水でリンス後、200℃にて加熱し赤色パターンを得た。得られた赤色パターンは、ラインアンドスペースにて3μmの解像性を持ち、残渣、画素の剥がれ等は確認されなかった。
バインダーポリマーとしてメタクリル酸/2−ヒドロキシエチルメタクリレート/ベンジルメタクリレート共重合体(31/9/60 重量比、重量平均分子量16500)のPGMEA20%溶液 20g、光重合性モノマーとしてGEA−3E 6g 、光重合開始剤としてイルガキュアー907(2−メチル−1−(4−メチルチオフェニル)−2−モルホリノプロパン−1−オン、チバ・スペシャルティ・ケミカルズ製) 2g、カヤキュアーDETX−S(日本化薬製)1g、EAB(4,4'−ビス(ジエチルアミノ)ベンゾフェノン、保土ヶ谷化学工業製)0.2g、顔料として青色顔料分散液(C.I.ピグメントブルー15:6/ピグメントバイオレット23/分散剤/PGMEA=9.6/2.4/8.2/79.8 重量比)72g、溶剤としてPGMEA 46gを混合し、青色の本発明のネガ型着色感光性組成物を得た。
又、上記で得られたネガ型着色感光性組成物を前記基板上に塗布し、80℃×100秒の条件でプレベークしたのち、露光による硬化後、界面活性剤を含有するアルカリ水溶液で現像し、水でリンス後、200℃にて加熱し緑色パターンを得た。得られた青色パターンは、ラインアンドスペースにて3μmの解像性を持ち、残渣、画素の剥がれ等は確認されなかった。
バインダーポリマーとしてメタクリル酸/ベンジルメタクリレート共重合体(20/80 重量比、重量平均分子量22,000)のPGMEA20%溶液 20g、光重合性モノマーとしてGEA−3E 6g 、光重合開始剤として、イルガキュアー369(チバ・スペシャルティ・ケミカルズ製) 1.2g、カヤキュアーDETX−S(日本化薬製)0.6g、EAB(4,4'−ビス(ジエチルアミノ)ベンゾフェノン、保土ヶ谷化学工業製)0.1g、顔料として緑色顔料分散液(C.I.ピグメントグリーン17/C.I.ピグメントイエロー83/分散剤/PGMEA=12.1/5.2/7.4/75.3重量比)48g、溶剤としてPGMEA 48gを混合し、緑色の本発明のネガ型着色感光性組成物を得た。
又、上記で得られたネガ型着色感光性組成物を前記基板上に塗布し、80℃×100秒の条件でプレベークしたのち、露光による硬化後、界面活性剤を含有するアルカリ水溶液で現像し、水でリンス後、200℃にて加熱し緑色パターンを得た。得られた緑色パターンは、ラインアンドスペースにて3μm角の解像性を持ち、残渣、画素の剥がれ等は確認されなかった。
バインダーポリマーとしてメタクリル酸/2−ヒドロキシエチルメタクリレート/ベンジルメタクリレート共重合体(15/13/72 重量比、重量平均分子量17,000)のPGMEA20%溶液 20g、光重合性モノマーとしてDGEA−4E 6g 、光重合開始剤として、イルガキュアー369(チバ・スペシャルティ・ケミカルズ製) 1.2g、カヤキュアーDETX−S(日本化薬製)0.6g、EAB(4,4'−ビス(ジエチルアミノ)ベンゾフェノン、保土ヶ谷化学工業製)0.1g、顔料として緑色顔料分散液(C.I.ピグメントグリーン17/C.I.ピグメントイエロー83/分散剤/PGMEA=12.1/5.2/7.4/75.3重量比)48g、溶剤としてPGMEA 48gを混合し、緑色の本発明のネガ型着色感光性組成物を得た。
又、上記で得られたネガ型着色感光性組成物を前記基板上に塗布し、80℃×100秒の条件でプレベークしたのち、露光による硬化後、界面活性剤を含有するアルカリ水溶液で現像し、水でリンス後、200℃にて加熱し緑色パターンを得た。得られた緑色パターンは、ラインアンドスペースにて3μm角の解像性を持ち、残渣、画素の剥がれ等は確認されなかった。
Claims (5)
- 請求項記載のネガ型着色感光性組成物を用い、リソグラフィー法によりパターニングされてなるカラーフィルター用着色硬化膜
- 請求項2記載のカラーフィルター用着色硬化膜からなるカラーフィルター
- 請求項3記載のカラーフィルターを装着してなる液晶表示装置
- 請求項3記載のカラーフィルターを装着してなる固体撮像素子
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JP2008164886A (ja) * | 2006-12-28 | 2008-07-17 | Sumitomo Chemical Co Ltd | 着色感光性樹脂組成物 |
JP2010085972A (ja) * | 2008-09-05 | 2010-04-15 | Jsr Corp | 着色感放射線性組成物、カラーフィルタおよびカラー液晶表示素子 |
WO2013161803A1 (ja) * | 2012-04-24 | 2013-10-31 | 富士フイルム株式会社 | ソルダーレジスト組成物、硬化膜、および硬化膜の製造方法 |
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WO2021140907A1 (ja) * | 2020-01-09 | 2021-07-15 | 住友化学株式会社 | 着色硬化性組成物 |
CN114867791A (zh) * | 2020-01-09 | 2022-08-05 | 住友化学株式会社 | 着色固化性组合物 |
CN114867791B (zh) * | 2020-01-09 | 2023-12-05 | 住友化学株式会社 | 着色固化性组合物 |
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